Detrital Zircon Geochronology and Provenance of Metasedimentary Rocks from the Susong Complex Zone in the Dabie Orogen

The Susong complex zone is a relatively low-grade metamorphic unit located in the southern part of the Dabie orogen and preserves a variety of metasedimentary rocks,mostly with epidote-amphibolite facies.However,their depositional age,provenance and tectonic setting of sedimentary protolith remain controversial due to the lack of fossils,precise dating and integrated geochemical investigation.This study has conducted whole-rock elemental,and zircon U-Pb SHRIMP dating and Lu-Hf isotope analyses on three types of representative metasedimentary rocks including garnetbearing mica-quartz schist,graphite-muscovite-quartz schist and dolomitic marble from the Susong complex zone.The UPb SHRIMP dating data indicate that the sedimentary protolith of these rocks have the maximum depositional ages of less than 840-750 Ma and have various sedimentary provenances.In combination with zircon Lu-Hf isotope compositions,the provenance of the metasedimentary rocks in the region is for the first time documented to be mainly derived from four groups of magmatic rocks formed at~2.5 Ga,~2.0 Ga,~1.4 Ga and~0.8 Ga in response to four episodes of igneous activity in the northeastern margin of the Yangtze Block.The conventional geothermobarometry combined with rare metamorphic zircon ages indicate that the studied rocks underwent the Late Triassic continental subduction-related metamorphism with peak epidote-amphibolite facies conditions at P=0.34-0.91 GPa and T=427-532°C.In addition,results of the elemental contents(i.e.,La,Ce,Th andΣREE)and ratios(i.e.,Eu/Eu^(*)and La_(N)/Yb_(N))suggest that the protoliths of the metasedimentary rocks were mainly shales,wackes and limestones,most probably related to the Rodinia supercontinent rifting along the northern margin of the Yangtze Block during the Neoproterozoic.

Zircon U-Pb geochronology,Hf isotopes,and geochemistry constraints on the age and tectonic affinity of the basement granitoids from the Qiongdongnan Basin,northern South China Sea

Studies in the northern South China Sea(SCS)basement remain important for understanding the evolution of the Southeast Asian continental margin.Due to a thick cover of sediments and scarce borehole penetration,little is known about the age and tectonic affinity of this basement.In this study,an integrated study of zircon U-Pb geochronology,Hf isotopes,and whole-rock major and trace elements on seven basement granitoids from seven boreholes of Qiongdongnan Basin has been carried out.New zircon U-Pb results for these granitoids present middle-late Permian((270.0±1.2)Ma;(253±3.4)Ma),middle to late Triassic((246.2±3.4)Ma;(239.3±0.96)Ma;(237.9±0.99)Ma;(228.9±1.0)Ma)and Late Cretaceous ages((120.6±0.6)Ma).New data from this study,in combination with the previous dataset,indicates that granitoid ages in northern SCS basement vary from 270 Ma to 70.5 Ma,with three age groups of 270–196 Ma,162–142 Ma,and 137–71 Ma,respectively.Except for the late Paleozoic-Mesozoic rocks in the basement of the northern SCS,a few old zircon grains with the age of(2708.1±17)Ma to(2166.6±19)Ma provide clues to the existence of the pre-Proterozoic components.The geochemical signatures indicate that the middle Permian-early Cretaceous granitoids from the Qiongdongnan Basin are I-type granites formed in a volcanic arc environment,which were probably related to the subduction of the Paleo-Pacific Plate.

Detrital zircon geochronology and provenance of sediments within the Mesozoic basins:New insights into tectonic evolution of the Qinling Orogen

Mesozoic sedimentary units within the Nanzhao and Mashiping basins record the paleogeographic and tectonic evolution of the Qinling Orogen(QO).This study uses new detrital zircon U-Pb ages and Hf isotopic data to constrain the timing of deposition and provenance of the Taishanmiao,Taizishan,Nanzhao,and Mashiping formations of the North Qinling Orogen(NQO).The detrital zircons can be split by age peaks into five major groups,including Early Cretaceous,Late Triassic,Early Paleozoic,Neoproterozoic and Paleoproterozoic age peaks.On the basis of the youngest zircon ages and age-diagnostic fossils,we conclude that the Taishanmiao(youngest age of 234 Ma)and Taizishan(216 Ma)formations were deposited during the Late Triassic,whereas the Nanzhao Formation(110 Ma)was deposited during the Early Cretaceous rather than the Late Jurassic as previously thought.The Mashiping Formation(110 Ma)was also deposited during the Early Cretaceous.Combined with zircon Hf isotopic compositions,zircons from Late Triassic units were generally derived from the NQO,South Qinling Orogen(SQO),and North China Craton(NCC),with minor amounts derived from the Xing-Meng Orogenic Belt.The sediments within the Nanzhao Formation were mainly derived from the QO,with a minor contribution from the NCC.The Early Cretaceous conglomerates of the Mashiping Formation were generally derived from recycled earlier detritus.This implies that Late Triassic deposition was related to the final closure of the Mianlue Ocean,whereas Early Cretaceous deposition was correlated to the continued intercontinental subduction of the Yangtze Craton beneath the QO.The change in provenance within these Mesozoic sediments suggests the QO underwent two periods of significant uplift,which was a process generated sediments that were deposited in a series of basins of this area.

海南岛雷鸣盆地鹿母湾组碎屑岩地球化学特征、锆石U-Pb年龄和Hf同位素组成:对物源及构造环境的启示

海南岛雷鸣盆地鹿母湾组的确切沉积时限和沉积物来源是研究的空白区域。本文选取雷鸣盆地鹿母湾组作为研究对象,通过全岩地球化学、碎屑锆石U-Pb年代学和Lu-Hf同位素分析,旨在限定其沉积时限及物质来源,并探讨其沉积构造环境。鹿母湾组碎屑沉积岩的最年轻碎屑锆石年龄峰(113.3 Ma)与侵入其中的花岗闪长岩岩体年龄(~107 Ma)限定鹿母湾组沉积时限为109.9~113.3 Ma。全岩地球化学研究表明,鹿母湾组碎屑沉积岩的分异指数(ICV)为0.78~1.52(平均值0.96)、化学风化指数(CIA)为51.11~73.45(平均值65.27),反映其源区岩石具有中等成熟度并经历了弱的化学风化作用。结合微量元素、稀土元素含量及相关比值(如La、Th、Sc、Zr、Hf、∑REE及δEu)、源区判别图和构造环境判别图解,本文认为鹿母湾组碎屑沉积岩可能沉积于活动大陆边缘相关的盆地,主要来源于同时代的长英质火山岩或火山物质,少量碎屑来自华南内陆和海南岛早古生代岩浆岩。

New Insights into the Late Triassic Nadigangri Formation of Northern Qiangtang, Tibet, China： Constraints from U-Pb Ages and Hf Isotopes of Detrital and Magmatic Zircons

We report here U-Pb age and in situ Hf isotopic results for detrital and magmatic zircons from one conglomerate and four tuffite samples from the Late Triassic Nadigangri Formation across the North Qiangtang depression, Tibet. Coupled with previously published data in the region, this paper proposes new insights into the geochronological framework for the Nadigangri Formation. The deposition ages of tuffite from top to bottom in the Woruo Mountain, Quem Co and Dongqu River, are 203 Ma, 226 Ma, 221.5 Ma and 221.1 Ma, respectively. The detrital zircons yield a younger cluster of ages of 201.5-225 Ma from the conglomerate of the Quem Co Formation. The Late Triassic Nadigangri Formation defines a temporal range approximately between 201 and 225 Ma （Norian-Rhaetian）, including three predominant groups of 220-225 Ma, 210-217 Ma and 201-205 Ma, which correspond with the three main rifting episodes of initial rifting, further rifting and final rifting. Positive ~Hf（t） value and low model ages in younger detrital zircons suggests a juvenile character. However, the Hf isotopes of magmatic zircons display the presence of reworked ancient crust with 1.1-1.8 Ga. These results provide strong constraints not only on the temporal range of the Late Triassic Nadigangri Formation, but also on the onset of the Qiangtang Mesozoic rift basin.

Precambrian Tectonic Affinity of the Southern Langshan Area, Northeastern Margin of the Alxa Block: Evidence from Zircon U-Pb Dating and Lu-Hf Isotopes

The Alxa Block is the westernmost part of the North China Craton(NCC), and is regarded as one of the basement components of the NCC. Its geological evolution is of great significance for the understanding of the NCC.However, the Precambrian basement of the Alxa Block is still poorly studied. In this study, we present new in situ LA-ICPMS zircon U-Pb and Lu-Hf isotope data from the Diebusige Metamorphic Complex(DMC) which located in the eastern Alxa Block. Field and petrological studies show that the DMC consists mainly of metamorphic supracrustal rocks and minor metamorphic plutonic rocks and has experienced amphibolite-granulite facies metamorphism. Zircon U-Pb dating results suggested that the amphibolite sample yields a crystallization age of 2636 ± 14 Ma and metamorphic ages of 2517–2454 Ma and 1988–1952 Ma, proving the existence of exposed Archean rocks in the Langshan area and indicating that late Neoarchean to Paleoproterozoic metamorphic events existed in the Alxa Block. Two paragneiss samples show that the magmatic detrital zircons from the DMC yield 207Pb/206Pb ages ranging from 2.48 Ga to 2.10 Ga with two youngest peaks at 2.13 Ga and 2.16 Ga, respectively, and they were also overprinted by metamorphic events at 1.97–1.90 Ga and 1.89–1.79Ga. Compilation of U-Pb ages of magmatic detrital and metamorphic zircons suggested that the main part of the DMC may have been formed at 2.1–2.0 Ga. Zircon Lu-Hf isotope data show that the source materials of the main part of the DMC were originated from the reworking of ancient Archean crust(3.45–2.78 Ga). The Hf isotope characteristics and the tectonothermal event records exhibit different evolution history with the Khondalite Belt and the Yinshan Block and the other basements of the Alxa Block, indicating that the Langshan was likely an independent terrain before the middle Paleoproterozoic and was subjected to the middle to late Paleoproterozoic tectonothermal events with the Khondalite Belt as a whole.

Late Paleozoic Mantle Source Nature of Tianshan Orogen, Northwest China: Evidence from the Geochemistry, Zircon U-Pb Dating, Hf and Whole Rock Sr-Nd-Pb Isotopes of the Mafic Dykes

The Tianshan Orogen(TO)is one of the largest typical accretionary orogenic belts in the world.Of which,the late Paleozoic was a critical era to understand the tectonic and geodynamic transition from accretion to collision.However,the late Paleozoic tectonic evolutionary history,especially for the time of the ocean-continent transition,is still debated although the origin and tectonic settings for the Paleozoic volcanic,felsic igneous magmatism in TO and reginal geology have been done in the last decades.In contrast,the researches on the mafic dykes in TO was not systematically carried out till now.Reginal-scale mafic dykes are commonly regarded as the products created in a extensional setting,and used to identify the major tectonic events such as rifting and continental break-up and further trace the mantle natures and geodynamic mechanism(Halls,1982;Bleeker and Ernst,2006;Li et al.,2008;Ernst et al.,2010;Srivastava,2011;Hou,2012;Peng,2015;Peng et al.,2019).There are widespread late Paleozoic mafic dykes beside the huge of intermediate-acid igneous rocks in the TO,being an idea object to reveal the extensional events,tectonic evolution and the mantle nature and geodynamic processes.We present the ICPMS in situ zircon U–Pb dating,Lu-Hf and whole-rock Sr-Nd isotopes as well as the geochemistry data for these mafic dykes to better constraint their petrogenesis and mantle nature.New zircon U-Pb dating for 12 samples from the representative basic dykes and basalts yield three distinct stages of^332 Ma,316–302 Ma and 288–282 Ma,respectively.In which,the first stage of mafic dykes is mainly occurred in both East Tianshan Orogen(ETO)and West Tianshan Orogen(WTO),and composed of dolerite with minor basalts.The second stage of mafic dyke also can be found in both ETO and WTO.However,in contrast to the first stage of mafic dykes,they have relatively variable rock types from the dolerite/or gabbros to gabbroic diorite.The third stage of mafic dykes are slightly intermediate in composition,and chiefly consist of andesitic-basaltic dolerite with some diorites.They are widely developed not only in both ETO and WTO,but also in the Beishan area to the east of the ETO,indicating a large-scale mafic magmatism in Tianshan and adjacent areas.

陇山杂岩变沉积岩的沉积时代、物源及构造意义:来自地球化学、碎屑锆石U-Pb年代学和Lu-Hf同位素的证据

陇山杂岩位于秦-祁结合部位,长期以来该杂岩的形成时代及构造归属仍存在较大争议,对其进行详细的研究对于理解该地区的构造演化历史具有重要意义。本文对陇山杂岩中的5个变沉积岩样品进行了全岩主微量元素分析、碎屑锆石U-Pb定年及Lu-Hf同位素分析,在此基础上对其原岩类型、沉积时限、物源及其构造归属进行了探讨。初步判断陇山杂岩变沉积岩的原岩可能为杂砂岩。根据样品中最年轻的岩浆成因碎屑锆石的加权平均年龄值,结合陇山杂岩中侵入体的年龄,可以限定陇山杂岩变沉积岩的沉积时限在491~463Ma之间。变沉积岩中碎屑锆石的年龄分布存在593~486Ma、1294~634Ma两个主要区间,以及1876~1528Ma、2594~2027Ma两个次要区间;与之对应的两个主要年龄群的εHf(t)值分别为-21.69~11.48和-28.52~20.74,次要年龄群的εHf(t)分别为-11.88~8.81和-7.97~5.99;且5个样品中约70%以上的εHf(t)值均为负值,表明锆石的母岩浆主要来源于古老地壳的部分熔融和少量年轻地壳物质的加入;结合碎屑锆石年龄及Hf同位素特征,推断变沉积岩的物源主要来自于祁连造山带和秦岭造山带,并有少量华北克拉通南缘结晶基底的贡献。陇山杂岩变沉积岩碎屑锆石年龄特征与北秦岭造山带宽坪岩群及二郎坪岩群极其相似,同时得到390~338Ma、426Ma、465~442Ma三阶段变质锆石变质边的年龄,与北秦岭古生代变质作用年龄在误差范围内保持一致。综上,本文初步推断陇山杂岩是北秦岭造山带的西延部分,形成于商丹洋向北俯冲的大陆边缘弧环境。

Mesozoic Bimodal Volcanic Suite in Zhalantun of the Da Hinggan Range and Its Geological Significance: Zircon U-Pb Age and Hf Isotopic Constraints

Mesozoic bimodal volcanic rocks of basaltic andesite and rhyolite are widely distributed in the Da Hinggan Range, but their petrogenetic relationships and geodynamic implications are rarely constrained. Detailed studies on doleritic and porphyry dikes in the Zhalantun area indicate that they display features of magma mixing, suggesting their coeval formation. In situ zircon U-Pb dating shows that the porphyry was emplaced in the Early Cretaceous with a ^206Pb/^238U age of 130±1 Ma. Zircons from the dolerite also yield an Early Cretaceous emplacement age of 124±2 Ma although some inherited zircons have been identified. These age results indicate that the Early Cretaceous was an important period of magmatism in the Da Hinggan Range. Zircons from porphyry are characterized by positive value of εHf（t） as high as 10.3±0.5 with Hf depleted mantle model age of 349-568 Ma, whereas magmatic zircons from the dolerite have εHf（t） value of 11.0±1.4 with Hf depleted mantel model age of 342-657 Ma, consistent with those from the porphyry. Considering other data on the geological evolution of this area, it is concluded that the mafic magma originated from the partial melting of Paleozoic enriched lithospheric mantle, whereas the felsic magma came from recycling of juvenile crust formed during the Paleozoic. Both of the protoliths are closely related to the subduction of the Paleo-Asian Ocean during the Paleozoic, indicating that the Paleozoic is an important period of large-scale crustal growth in the area.

Ages of the Laocheng Granitoids and Crustal Growth in the South Qinling Tectonic Domain,Central China:Zircon U-Pb and Lu-Hf Isotopic Constraints

The Laocheng granitoid pluton is located in the South Qinling tectonic domain of the Qinling orogenic belt,southern Shaanxi Province,and consists chiefly of quartz diorite,granodiorite and monzogranite.A LA-ICP-MS zircon U-Pb isotopic dating,in conjunction with cathodoluminescence images,reveals that the quartz diorite and granodiorite were emplaced from 220 Ma to 216 Ma,while the monzogranite was emplaced at～210 Ma.In-situ zircon Hf isotopic analyses show that theε_（Hf）（t） values of the quartz diorite and granodiorite range from-8.1 to ＋1.3,and single-stage Hf model ages from 809 Ma to 1171 Ma,while theε_（Hf）（t）values of the monzogranite are-14.5 to ＋16.7 and single-stage Hf model ages from 189 Ma to 1424 Ma.These Hf isotopic features reveal that the quartz diorite, granodiorite and monzogranite were formed from the mixing of the magmas derived from partial melting of the depleted mantle and the lower continent crustal materials,and there were two stages of continental crust growth during the Neoproterozoic（～800 Ma）and Indosinian（～210 Ma）eras, respectively,in the south Qinling tectonic domain of the Qinling orogrnic belt,Central China.

U-Pb Age and Hf Isotope Study of Detrital Zircons from the Wanzi Supracrustals:Constraints on the Tectonic Setting and Evolution of the Fuping Complex,Trans-North China Orogen

Located in the middle segment of the Trans-North China Orogen, the Fuping Complex is considered as a critical area in understanding the evolution history of the North China Craton （NCC）. The complex is composed of various high-grade and multiply deformed rocks, including gray gneiss, basic granulite, amphibolite, fine-grained gneiss and marble, metamorphosed to upper amphibolite or granulite facies. It can be divided into four rock units： the Fuping TTG gneisses, Longquanguan augen gneisses, Wanzi supracrustals, and Nanying granitic gneisses. U-Pb age and Hf isotope compositions of about 200 detrital zircons from the Wanzi supracrustals of the Fuping Complex have been analyzed. The data on metamorphic zircon rims give ages of 1.82-1.84 Ga, corresponding to the final amalgamation event of the NCC, whereas the data for igneous zircon cores yield two age populations at -2.10 and -2.51 Ga, with some inherited ages scattering between 2.5 and 2.9 Ga. These results suggest that the Wanzi supracrustals were derived from the Fuping TTG gneisses （-2.5 Ga） and the Nanying granitic gneisses （2.0-2.1 Ga） and deposited between 2.10 and 1.84 Ga. All zircons with -2.51 Ga age have positive initial εHf values from ＋1.4 to ＋10.9, suggesting an important crustal growth event at -2.5 Ga through the addition of juvenile materials from the mantle. The Hf isotope data for the detrital zircons further imply that the 2.8 Ga rocks are important components in the lower crust, which is consistent with a suggestion from Nd isotope data for the Eastern Block. The zircons of 2.10 Ga population have initial εHf values of-4.9 to ＋6.1, interpreted as mixing of crustal re-melt with minor juvenile material contribution at 2.1 Ga. These results are distinct from that for the Western Block, supporting that the Fuping Complex was emplaced in a tectonic active environment at the western margin of the Eastern Block.

Late Mesozoic Ore-forming Events in the Ningwu Ore District, Middle-Lower Yangtze River Polymetallic Ore Belt, East China: Evidence from Zircon U-Pb Geochronology and Hf Isotopic Compositions of the Granodioritic Stocks

Late Mesozoic volcanic-subvolcanic rocks and related iron deposits, known as porphyry iron deposits in China, are widespread in the Ningwu ore district （Cretaceous basin） of the middle-lower Yangtze River polymetallic ore belt, East China. Two types of Late Mesozoic magmatic rocks are exposed： one is dioritic rocks closely related to iron mineralization as the hosted rock, and the other one is granodioritic （-granitic） rocks that cut the ore bodies. To understand the age of the iron mineralization and the ore-forming event, detailed zircon U-Pb dating and Hf isotope measurement were performed on granodioritic stocks in the Washan, Gaocun-Nanshan, Dongshan and Heshangqiao iron deposits in the basin. Four emplacement and crystallization （typically for zircons） ages of granodioritic rocks were measured as 126.1±0.5 Ma, 126.8±0.5 Ma, 127.3±0.5 Ma and 126.3±0.4 Ma, respectively in these four deposits, with the LA-MC-ICP-MS zircon U-Pb method. Based on the above results combined with previous dating, it is inferred that the iron deposits in the Ningwu Cretaceous basin occurred in a very short period of 131-127 Ma. In situ zircon Hf compositions of εHf（t） of the granodiorite are mainly from -3 to -8 and their corresponding 176Hf/177Hf ratio are from 0.28245 to 0.28265, indicating similar characteristics of dioritic rocks in the basin. We infer that granodioritic rocks occurring in the Ningwu ore district have an original relationship with dioritic rocks. These new results provide significant evidence for further study of this ore district so as to understand the ore-forming event in the study area.

Attribution of the Langshan Tectonic Belt: Evidence from zircon U-Pb ages and Hf isotope compositions

This study describes a previously unidentified Neoproterozoic mafic dyke emplaced in the northern flank of the Langshan Tectonic Belt. This dyke intruded into the micaquartz schist of the Zhaertaishan Group, and yielded an age of 908 ± 8 Ma. The youngest U-Pb ages of micaquartz schist from the Zhaertaishan Group in the Langshan area were 1118 ± 33 Ma,1187 ± 3 Ma and 1189 ± 39 Ma,suggesting that the depositional age of the protolith of the schist was between 908 ± 8 Ma and 1118 ± 33 Ma. In addition, 436 U-Pb age data and 155 Lu-Hf isotopic data from six samples in the Langshan Tectonic Belt and one Permian greywacke from the Wuhai area show distinct differences between the northern and southern flanks of the Main Langshan area. The U-Pb ages of the northern flank are primarily Meso-Neoproterozoic; similar ages have not been identified in the southern flank to date.Moreover, two-stage Hf model ages of the northern flank feature three age peaks at ～900 Ma,～1700 Ma and ～2600 Ma; this differs from Hf model ages of the southern flank, which feature one strong age peak at ～2700 Ma. These results suggest that the northern and southern flanks of the Main Langshan area have different geochronologic characteristics and should be divided further. Based on the U-Pb ages and Hf model ages, the northern and southern flanks of the Main Langshan area are named the North and South Langshan Tectonic Belts. Comparison of the U-Pb age and two-stage Hf model age distributions from the North Langshan Tectonic Belt, South Langshan Tectonic Belt, Alxa Block and the North China Craton(NCC) reveal that the North Langshan Tectonic Belt is similar to the Alxa Block and that the South Langshan Tectonic Belt is similar to the NCC. In addition, the zircon U-Pb age of 860 ±7 Ma commonly observed in the Alxa Block was detected in the Permian greywacke from the Wuhai area of the NCC, which suggests that the amalgamation of the North and South Langshan Tectonic belts(i.e.,the amalgamation of the Alxa Block and the NCC), occurred between Devonian and late Permian.

Ages and Hf isotopes of detrital zircons from the Permian strata in the engbatu area(Inner Mongolia) and tectonic implications

The Central Asian Orogenic Belt(CAOB) was built up through protracted accretion and collision of a variety of terranes/micro-continents during Neoproterozoice Mesozoic time. To understand potential links among Paleozoic subduction and accretionary processes that were operative during the development of the southeastern CAOB, we conducted a combined U-Pb and Hf-isotope analysis of detrital zircons from previously defined Devonian, Carboniferous and Early Permian strata in the Bengbatu area,Inner Mongolia. Detrital zircons from(meta-) sandstones in these strata commonly yield major Paleozoic age populations at ca. 300-261 Ma, 351-300 Ma and 517-419 Ma, and also give several Precambrian ages that range from 2687 Ma to 544 Ma. The youngest ages redefine the deposition of all these strata to be in the Middle Permian(Wordiane Capitanian) or later, much younger than previously considered.These ages, coupled with regional magmatic records, support an interpretation of most surrounding areas as possible detritus sources, including the Mongolian arcs to the north, the Northern Accretionary Orogen to the south, and the intervening Erenhote Hegenshan Ophiolite Belt. Zircons with magmatic ages of ca. 500-350 Ma and ca. 300-261 Ma display a large range of εHf(t) values(-13.97 to +15.31),whereas ca. 350-300 Ma zircons are dominated by positive εHf(t) values(+0.14 to +16.00). These results support the occurrence of two significant shifts of the zircon εHf(t) values, which has tectonic implications for the understanding of the Carboniferouse Permian evolution of the southeastern CAOB. A marked shift from mixed to positive zircon εHf(t) values at 350 -330 Ma likely manifests the incipient opening of the Hegenshan Ocean, due to the slab rollback of the subducting Paleo-Asian Oceanic lithosphere. Another shift from positive to mixed zircon εHf(t) values at ca. 300 Ma likely corresponds to a tectonic switch from syn-orogenic subduction-related to post-orogenic extensional setting, genetically related to the tectonic collapse of a formerly overthickened crust.

Petrogenesis and Tectonic Significance of the Xiuwacu Two-Period Magmatism in Geza Arc of Yunnan Province： Constraints from Lithogeochemistry, Zircon U-Pb Geochronology and Hf isotopic Compositions

Objective The Late Cretaceous Xiuwacu ore-bearing porphyry is located in the Geza area of southern Yidun arc, SW China. In this area, the rock mass is mainly composed of three lithofacies： biotite granite porphyry, monzonitic granite and light alkali feldspar granite. As a part of the Yidun arc, the Geza arc has common structure and temporal- spatial evolution with the ~idun arc, which has experienced three stages of oceanic crust subduction, collision orogeny and intracontinent convergence stages. The molybdenite ores in the area are mainly hosted in monzonitic granite-porphyry and structural fracture zone, and the ore bodies are strictly controlled by faults. In recent years, great geological prospecting results have been achieved in Xiuwacu, and the deposit has reached a medium scale. However, there are few researches on the metallogenic porphyry. Based on the previous research, we determined the rock-forming and ore-forming age of the porphyry, and found that there were two stages of magmatism intrusion in Xiuwacu： Indosinian and Yanshanian. We also discussed the geochemical characteristics and source area of the rocks in the area.

Zircon U-Pb age,trace element and Hf isotope composition of Sepon Au-Cu deposit, Laos:tectonic and metallogenic implications

The Truong Son Fold Belt,located at the northeastern margin of the Indochina Block,is considered to be tectonically linked to the subduction of the Paleotethys Ocean and subsequent collision.Sepon is one of the most important super large deposits of the Truong Son Fold Belt.Our LA-ICP-MS zircon U-Pb dating results show that granodiorite porphyry samples from the Sepon deposit have ages of 302.1-4-2.9 Ma, which is a crucial phase for magmatic-tectonical activities from the Late Carboniferous to Early Permian and has avital influence on the mineralization of copper and gold.Zircon from granodiorite porphyry yields εHf (t)values of 4.32 to 9.64,and TDM2 has an average age of 914 Ma,suggesting that the source of the granodiorite porphyry in the region were mainly mantle components but underwent mixing and contamination of crust materials.The Ce^4+/Ce^3+ value of zircon in the granodiorite porphyry varys greatly from 2.4 to 1438.29,which shows magma mixing might occur.Considering the characteristics of trace elements in the zircon and the whole rock geochemical characteristics of intrusion rocks as well as the characteristics of regional volcanic-sedimentary association,it is indicated that the tectonic setting may be the continental arc environment.The Sepon Au-Cu deposit is derived from emplacement of calc-alkaline intermediate-acid magma with coming from deep sources in the subduction process of the Paleotethys Ocean,forming porphyry Mo-Cu,skam Cu-Au mineralization and a hydrothermal sedimentary-hosted Au mineralization in the wall rocks.

Petrogenesis of Kejie Granite in the Northern Changning-Menglian Zone, Western Yunnan: Constraints from Zircon U-Pb Geochronology, Geochemistry and Hf Isotope

The Kejie pluton is located in the north of the Changning-Menglian suture zone. The rock types are mainly biotite-granite. Zircon LA-ICP-MS U-Pb dating indicates that the Kejie pluton emplaced at about 80-77 Ma, Late Cretaceous. The Kejie pluton samples are characterized by high SiO2 （71.68%-72.47%）, K2O （4.73%-5.54%）, total alkali （K2O ＋ Na2O = 8.21%-8.53%）, K2O/Na2O ratios （1.36-1.94） and low P2O5 （0.13%-0.17%）, with A/CNK of 1.025-1.055; enriched in U, Th, and K, depleted in Ba, Nb, St, Ti, P and Eu. They are highly fractionated, slightly peraluminous 1-type granite. The two samples of the Kejie pluton give a large variation of εHf（t） values （-5.04 to 1.96） and Hf isotope crustal model ages of 1.16-1.5 Ga. Zircon Hf isotopes and zircon saturation temperatures of whole-rock （801℃-823℃） show that the mantle-derived materials maybe have played a vital role in the generation of the Kejie pluton. The Kejie pluton was most likely generated in a setting associated with the eastward subduction of the neo-Tethys ocean, where intrusion of mantle wedge basaltic magmas in the crust caused the anatexis of the latter, forming hybrid melts, which subsequently experienced high-degree fractional crystallization.

Zircon U-Pb ages and Hf isotopic characteristics of the Dehe biotite monzonitic gneiss pluton in the North Qinling orogen and their geological significance

The Dehe granitic pluton intruded the Xiahe Group which is in the core complex of the North Qinling Orogenic Belt(NQOB).It shows gneissic bedding and possesses typical S-type granite minerals such as muscovite and garnet.LA-ICP-MS U-Pb isotopic dating of the Dehe granite yielded a weighted average age of 925±23 Ma which represents the emplacement age of the pluton.Most of the εHf(t) values are negative,and the two-stage model ages are consistent with the age of the Qinling Group.The isotope data show that the Dehe granite was formed in the following geological setting:in the syn-collision setting of the NQOB in the Neoproterozoic,crustal thickening induced partial melting of materials derived from the Qinling complex,and then the maga upwelled and intruded into the Xiahe Group.The formation of the Dehe S-type granite implied the occurrence of a convergent event in the QOB during the Neoproterozoic.

Zircon U-Pb Geochronology and Hf Isotopic Constraints on Petrogenesis of Plagiogranite from the Cuomuqu Ophiolite,Bangong Lake Area,North Tibet

Field observation, geochemical signatures and zircon Hf isotope data indicate that Cuomuqu ophiolite in the Bangonghu area was formed in a back-arc basin （BAB） above a supra- subduction zone （SSZ）. Zircon U-Pb dating of the diabase from the Cuomuqu massif yielded an age of 164.3±1.9 Ma, thus indicating that the ophiolite complex was formed in the Middle Jurassic during back-arc extension of the mature Bangonghu-Nujiang Ocean. The zircon εHf（t） and TDMC values of the plagiogranite are similar to the εHf（t） and TDM of the diabase, respectively. The mode of occurrence of plagiogranites and their bulk-rock and Hf isotope characteristics indicate that they were derived from the mantle, associated with the surrounding gabbro and diabase, and were formed by partial melting of altered and hydrated mafic rocks under shear conditions during lateral drifting of the oceanic crust. The zircon U-Pb age of the plagiogranite is 156.4±1.4 Ma, and it is 7.9 Ma younger than the hosting diabase. In this study, zircon chronological and Hf isotopic data were tentatively analyzed to determine the genesis of plagiogranites in the Cuomuqu ophiolite complex.

A ca. 2.2Ga Acidic Magmatic Event at the Northern Margin of the Yangtze Craton: Evidence from U-Pb Dating and Hf Isotope Analysis of Zircons from the Kongling Complex

Objective The Yangtze craton collisional orogeny at ca. extensional events at ca. 1 experienced Paleoproterozoic 1.95-2.0 Ga and post-orogenic 85 Ga related to amalgamation of the Columbia （Nuna） supercontinent （Zhao and Cawood, 2012）. A ca. 2.15 Ga suprasubduction zone ophiolitic melange was recongized in the Archean- Paleoproterozoic Kongling Complex of the northern Yangtze craton （Han et al., 2017）. However, the tectonic evolution in early Paleoproterozoic from 2.4 Ga to 2.2 Ga remains unclear. We report here the presence of a suite of Paleoproterozoic （2.2 Ga） granites in the Huangling dome, northern Yangtze craton, which may provide important insights into crustal growth processes in the craton prior to the assembly of Columbia.