We analysed the photooxidation reaction in the electro-(1O2) and nucleophilic (O2•−) reaction of 2-pyridone azo derivatives. First, we calculated the energy (enthalpies) of tautomers formation, which is a measure of d...We analysed the photooxidation reaction in the electro-(1O2) and nucleophilic (O2•−) reaction of 2-pyridone azo derivatives. First, we calculated the energy (enthalpies) of tautomers formation, which is a measure of durability and the probability of their formation. We performed the light fastness calculations of the monoazopyridone dyes. Using the semi-empirical methods of quantum chemistry AM1 and PM3, the reactivity indicators of superdelocalisability (SrE(N)) and the electron density distribution in ground state on the highest occupied HOMO orbital and the lowest unoccupied excited state LUMO in 2-pyridone phenylazo derivatives were calculated. Superdelocalisability coefficients enable the stability to oxidising agents of various chemical molecules depending on the tautomeric forms in which they may occur. The results of the electron density calculations at the HOMO and LUMO boundary orbitals allow to determine the tendency to electrophilic attack with singlet oxygen 1O2 or nucleophilic attack of the superoxide anion O2•−on a specific atom in the molecule. The structure of the dyes was optimised with MM+, MD and AM1 or PM3 until a constant energy value was achieved with a convergence criterion of 0.01 kcal/mol.展开更多
ln this study, 12 maize populations were improved with the improved S1 selection method, aiming to increase the improvement efficiency of maize popula-tions. The results showed that number of rows per spike, number of...ln this study, 12 maize populations were improved with the improved S1 selection method, aiming to increase the improvement efficiency of maize popula-tions. The results showed that number of rows per spike, number of grains per row and 100-grain weight were the three important component traits of maize yield. The highest genetic increment was found in Mengqun 2, fol owed by Mengqun 4, Mengqun 1 and other 7 maize populations. Negative genetic increment was shown in Mengqun 3 and 3 introduced foreign maize populations. Some changes were shown in spikes, plant traits and genetic diversity of maize populations. Based on our results, we concluded that Mengqun 2, Mengqun 4, Zhongzong 7, Mengqun C and Mengqun A could be directly used for the line breeding by selfing for their higher genetic increment of yield and better improvement effects of other agricultural traits. Compared with these 5 populations, the improvement potential of other maize populations was limited for their lower genetic increment.展开更多
Satellite remote sensing of inland water body requires a high spatial resolution and a multiband narrow spectral resolution, which makes the fusion between panchromatic(PAN) and multi-spectral(MS) images particularly ...Satellite remote sensing of inland water body requires a high spatial resolution and a multiband narrow spectral resolution, which makes the fusion between panchromatic(PAN) and multi-spectral(MS) images particularly important. Taking the Daquekou section of the Qiantang River as an observation target, four conventional fusion methods widely accepted in satellite image processing, including pan sharpening(PS), principal component analysis(PCA), Gram-Schmidt(GS), and wavelet fusion(WF), are utilized to fuse MS and PAN images of GF-1.The results of subjective and objective evaluation methods application indicate that GS performs the best,followed by the PCA, the WF and the PS in the order of descending. The existence of a large area of the water body is a dominant factor impacting the fusion performance. Meanwhile, the ability of retaining spatial and spectral informations is an important factor affecting the fusion performance of different fusion methods. The fundamental difference of reflectivity information acquisition between water and land is the reason for the failure of conventional fusion methods for land observation such as the PS to be used in the presence of the large water body. It is suggested that the adoption of the conventional fusion methods in the observing water body as the main target should be taken with caution. The performances of the fusion methods need re-assessment when the large-scale water body is present in the remote sensing image or when the research aims for the water body observation.展开更多
The current popular methods for decision making and project optimisation in mine ventilation contain a number of deficiencies as they are solely based on either subjective knowledge or objective information.This paper...The current popular methods for decision making and project optimisation in mine ventilation contain a number of deficiencies as they are solely based on either subjective knowledge or objective information.This paper presents a new approach to rank the alternatives by G1-coefficient of variation method.The focus of this approach is the use of the combination weighing,which is able to compensate for the deficiencies in the method of evaluation index single weighing.In the case study,an appropriate evaluation index system was established to determine the evaluation value of each ventilation mode.Then the proposed approach was used to select the best development face ventilation mode.The result shows that the proposed approach is able to rank the alternative development face ventilation mode reasonably,the combination weighing method had the advantages of both subjective and objective weighing methods in that it took into consideration of both the experience and wisdom of experts,and the new changes in objective conditions.This approach provides a more reasonable and reliable procedure to analyse and evaluate different ventilation modes.展开更多
A simple and fast route for the synthesis of metal-organic framework（MOF） particles was presented.Cu 3（BTC） 2（HKUST-1,BTC=1,3,5-benzenetricarboxylate）,one of the most well-known MOFs,was synthesized at room temp...A simple and fast route for the synthesis of metal-organic framework（MOF） particles was presented.Cu 3（BTC） 2（HKUST-1,BTC=1,3,5-benzenetricarboxylate）,one of the most well-known MOFs,was synthesized at room temperature via coordination modulation method.By adding different modulators（monocarboxylic acids） into the reaction system,the morphologies of HKUST-1 crystals were tuned from nano spheres to micro octahedrons at room temperature without any complex equipment.X-Ray diffractions and gas sorption measurements revealed highly crystalline particles with large Brunauer-Emmett-Teller（BET） surface areas（1116―1273 m^ 2 /g） and total pore volumes（0.62―0.73 cm^ 3 /g）.The significantly small particle sizes and high capacity of gas sorption are considered advantageous for envisaged application in practical industrial process.展开更多
Two series of perovskite-type oxides with composition (La_(1-x))Sr_xFeO_3(x≤0.8)and La_(1-x)Sr_xFe_(1-y)Co_yO_3(x=0.2; y=0.2, 0.4)powder productions were synthesized by EDTA complexing sol-gel method. The products we...Two series of perovskite-type oxides with composition (La_(1-x))Sr_xFeO_3(x≤0.8)and La_(1-x)Sr_xFe_(1-y)Co_yO_3(x=0.2; y=0.2, 0.4)powder productions were synthesized by EDTA complexing sol-gel method. The products were characterized by XRD, TEM, SEM, BET method(N_2 adsorption)and laser granularity analysis for different synthesis conditions to obtain the optimum conditions for the preparation process. Single-phased, uniform perovskite-type oxides with small particle size were obtained by EDTA sol-gel process with high stability and repeatability, and the process temperature is much lower than that of solid state reaction method.展开更多
An H^1-Galerkin mixed finite element method is discussed for a class of second order SchrSdinger equation. Optimal error estimates of semidiscrete schemes are derived for problems in one space dimension. At the same t...An H^1-Galerkin mixed finite element method is discussed for a class of second order SchrSdinger equation. Optimal error estimates of semidiscrete schemes are derived for problems in one space dimension. At the same time, optimal error estimates are derived for fully discrete schemes. And it is showed that the H1-Galerkin mixed finite element approximations have the same rate of convergence as in the classical mixed finite element methods without requiring the LBB consistency condition.展开更多
The （G＇/G, 1/G）-expansion method for finding exact travelling wave solutions of nonlinear evolution equations, which can be thought of as an extension of the （G＇/G）-expansion method proposed recently, is present...The （G＇/G, 1/G）-expansion method for finding exact travelling wave solutions of nonlinear evolution equations, which can be thought of as an extension of the （G＇/G）-expansion method proposed recently, is presented. By using this method abundant travelling wave so- lutions with arbitrary parameters of the Zakharov equations are successfully obtained. When the parameters are replaced by special values, the well-known solitary wave solutions of the equations are rediscovered from the travelling waves.展开更多
A new trust region algorithm for solving convex LC 1 optimization problem is presented.It is proved that the algorithm is globally convergent and the rate of convergence is superlinear under some reasonable assum...A new trust region algorithm for solving convex LC 1 optimization problem is presented.It is proved that the algorithm is globally convergent and the rate of convergence is superlinear under some reasonable assumptions.展开更多
Conventional retrieval and neural network methods are used simultaneously to retrieve sea surface wind speed(SSWS)from HH-polarized Sentinel-1(S1)SAR images.The Polarization Ratio(PR)models combined with the CMOD5.N G...Conventional retrieval and neural network methods are used simultaneously to retrieve sea surface wind speed(SSWS)from HH-polarized Sentinel-1(S1)SAR images.The Polarization Ratio(PR)models combined with the CMOD5.N Geophysical Model Function(GMF)is used for SSWS retrieval from the HH-polarized SAR data.We compared different PR models developed based on previous C-band SAR data in HH-polarization for their applications to the S1 SAR data.The recently proposed CMODH,i.e.,retrieving SSWS directly from the HHpolarized S1 data is also validated.The results indicate that the CMODH model performs better than results achieved using the PR models.We proposed a neural network method based on the backward propagation(BP)neural network to retrieve SSWS from the S1 HH-polarized data.The SSWS retrieved using the BP neural network model agrees better with the buoy measurements and ASCAT dataset than the results achieved using the conventional methods.Compared to the buoy measurements,the bias,root mean square error(RMSE)and scatter index(SI)of wind speed retrieved by the BP neural network model are 0.10 m/s,1.38 m/s and 19.85%,respectively,while compared to the ASCAT dataset the three parameters of training set are–0.01 m/s,1.33 m/s and 15.10%,respectively.It is suggested that the BP neural network model has a potential application in retrieving SSWS from Sentinel-1 images acquired at HH-polarization.展开更多
The ?exp(-j(x))?method is employed to find the exact traveling wave solutions involving parameters for nonlinear evolution equations. When these parameters are taken to be special values, the solitary wave solutions a...The ?exp(-j(x))?method is employed to find the exact traveling wave solutions involving parameters for nonlinear evolution equations. When these parameters are taken to be special values, the solitary wave solutions are derived from the exact traveling wave solutions. It is shown that the ?exp(-j(x))??method provides an effective and a more powerful mathematical tool for solving nonlinear evolution equations in mathematical physics. Comparison between our results and the well-known results will be presented.展开更多
A generalized variable-coefficient algebraic method is appfied to construct several new families of exact solutions of physical interest for （3＋1）-dimensional Kadomtsev-Petviashvilli （KP） equation. Among them, th...A generalized variable-coefficient algebraic method is appfied to construct several new families of exact solutions of physical interest for （3＋1）-dimensional Kadomtsev-Petviashvilli （KP） equation. Among them, the Jacobi elliptic periodic solutions exactly degenerate to the soliton solutions at a certain limit condition. Compared with the existing tanh method, the extended tanh method, the Jacobi elliptic function method, and the algebraic method, the proposed method gives new and more general solutions.展开更多
C^1 natural element method （C^1 NEM） is applied to strain gradient linear elasticity, and size effects on mi crostructures are analyzed. The shape functions in C^1 NEM are built upon the natural neighbor interpolati...C^1 natural element method （C^1 NEM） is applied to strain gradient linear elasticity, and size effects on mi crostructures are analyzed. The shape functions in C^1 NEM are built upon the natural neighbor interpolation （NNI）, with interpolation realized to nodal function and nodal gradient values, so that the essential boundary conditions （EBCs） can be imposed directly in a Galerkin scheme for partial differential equations （PDEs）. In the present paper, C^1 NEM for strain gradient linear elasticity is constructed, and sev- eral typical examples which have analytical solutions are presented to illustrate the effectiveness of the constructed method. In its application to microstructures, the size effects of bending stiffness and stress concentration factor （SCF） are studied for microspeciem and microgripper, respectively. It is observed that the size effects become rather strong when the width of spring for microgripper, the radius of circular perforation and the long axis of elliptical perforation for microspeciem come close to the material characteristic length scales. For the U-shaped notch, the size effects decline obviously with increasing notch radius, and decline mildly with increasing length of notch.展开更多
By introducing a more general auxiliary ordinary differential equation （ODE）, a modified variable separated ordinary differential equation method is presented for solving the （2 ＋ 1）-dimensional sine-Poisson equa...By introducing a more general auxiliary ordinary differential equation （ODE）, a modified variable separated ordinary differential equation method is presented for solving the （2 ＋ 1）-dimensional sine-Poisson equation. As a result, many explicit and exact solutions of the （2 ＋ 1）-dimensional sine-Poisson equation are derived in a simple manner by this technique.展开更多
文摘We analysed the photooxidation reaction in the electro-(1O2) and nucleophilic (O2•−) reaction of 2-pyridone azo derivatives. First, we calculated the energy (enthalpies) of tautomers formation, which is a measure of durability and the probability of their formation. We performed the light fastness calculations of the monoazopyridone dyes. Using the semi-empirical methods of quantum chemistry AM1 and PM3, the reactivity indicators of superdelocalisability (SrE(N)) and the electron density distribution in ground state on the highest occupied HOMO orbital and the lowest unoccupied excited state LUMO in 2-pyridone phenylazo derivatives were calculated. Superdelocalisability coefficients enable the stability to oxidising agents of various chemical molecules depending on the tautomeric forms in which they may occur. The results of the electron density calculations at the HOMO and LUMO boundary orbitals allow to determine the tendency to electrophilic attack with singlet oxygen 1O2 or nucleophilic attack of the superoxide anion O2•−on a specific atom in the molecule. The structure of the dyes was optimised with MM+, MD and AM1 or PM3 until a constant energy value was achieved with a convergence criterion of 0.01 kcal/mol.
基金Supported by Science and Technology Innovation Guiding and Incentive Fund of Inner Mongolia Autonomous Region(20111705)~~
文摘ln this study, 12 maize populations were improved with the improved S1 selection method, aiming to increase the improvement efficiency of maize popula-tions. The results showed that number of rows per spike, number of grains per row and 100-grain weight were the three important component traits of maize yield. The highest genetic increment was found in Mengqun 2, fol owed by Mengqun 4, Mengqun 1 and other 7 maize populations. Negative genetic increment was shown in Mengqun 3 and 3 introduced foreign maize populations. Some changes were shown in spikes, plant traits and genetic diversity of maize populations. Based on our results, we concluded that Mengqun 2, Mengqun 4, Zhongzong 7, Mengqun C and Mengqun A could be directly used for the line breeding by selfing for their higher genetic increment of yield and better improvement effects of other agricultural traits. Compared with these 5 populations, the improvement potential of other maize populations was limited for their lower genetic increment.
基金The National Key Research and Development Program of China under contract Nos 2016YFC1400901 and 2018YFC1406600the National Natural Science Foundation of China under contract No.40706057+1 种基金the Environmental Protection and Science and Technology Plan Project of Zhejiang Province of China under contract No.2013A021the Research Center for Air Pollution and Health of Zhejiang University
文摘Satellite remote sensing of inland water body requires a high spatial resolution and a multiband narrow spectral resolution, which makes the fusion between panchromatic(PAN) and multi-spectral(MS) images particularly important. Taking the Daquekou section of the Qiantang River as an observation target, four conventional fusion methods widely accepted in satellite image processing, including pan sharpening(PS), principal component analysis(PCA), Gram-Schmidt(GS), and wavelet fusion(WF), are utilized to fuse MS and PAN images of GF-1.The results of subjective and objective evaluation methods application indicate that GS performs the best,followed by the PCA, the WF and the PS in the order of descending. The existence of a large area of the water body is a dominant factor impacting the fusion performance. Meanwhile, the ability of retaining spatial and spectral informations is an important factor affecting the fusion performance of different fusion methods. The fundamental difference of reflectivity information acquisition between water and land is the reason for the failure of conventional fusion methods for land observation such as the PS to be used in the presence of the large water body. It is suggested that the adoption of the conventional fusion methods in the observing water body as the main target should be taken with caution. The performances of the fusion methods need re-assessment when the large-scale water body is present in the remote sensing image or when the research aims for the water body observation.
基金Projects(51504286,51374242)supported by the National Natural Science Foundation of ChinaProject(2015M572270)supported by China Postdoctoral Science FoundationProject(2015RS4004)supported by the Science and Technology Plan of Hunan Province,China
文摘The current popular methods for decision making and project optimisation in mine ventilation contain a number of deficiencies as they are solely based on either subjective knowledge or objective information.This paper presents a new approach to rank the alternatives by G1-coefficient of variation method.The focus of this approach is the use of the combination weighing,which is able to compensate for the deficiencies in the method of evaluation index single weighing.In the case study,an appropriate evaluation index system was established to determine the evaluation value of each ventilation mode.Then the proposed approach was used to select the best development face ventilation mode.The result shows that the proposed approach is able to rank the alternative development face ventilation mode reasonably,the combination weighing method had the advantages of both subjective and objective weighing methods in that it took into consideration of both the experience and wisdom of experts,and the new changes in objective conditions.This approach provides a more reasonable and reliable procedure to analyse and evaluate different ventilation modes.
基金Supported by the National Natural Science Foundation of China(Nos.21173034,20907006)
文摘A simple and fast route for the synthesis of metal-organic framework（MOF） particles was presented.Cu 3（BTC） 2（HKUST-1,BTC=1,3,5-benzenetricarboxylate）,one of the most well-known MOFs,was synthesized at room temperature via coordination modulation method.By adding different modulators（monocarboxylic acids） into the reaction system,the morphologies of HKUST-1 crystals were tuned from nano spheres to micro octahedrons at room temperature without any complex equipment.X-Ray diffractions and gas sorption measurements revealed highly crystalline particles with large Brunauer-Emmett-Teller（BET） surface areas（1116―1273 m^ 2 /g） and total pore volumes（0.62―0.73 cm^ 3 /g）.The significantly small particle sizes and high capacity of gas sorption are considered advantageous for envisaged application in practical industrial process.
文摘Two series of perovskite-type oxides with composition (La_(1-x))Sr_xFeO_3(x≤0.8)and La_(1-x)Sr_xFe_(1-y)Co_yO_3(x=0.2; y=0.2, 0.4)powder productions were synthesized by EDTA complexing sol-gel method. The products were characterized by XRD, TEM, SEM, BET method(N_2 adsorption)and laser granularity analysis for different synthesis conditions to obtain the optimum conditions for the preparation process. Single-phased, uniform perovskite-type oxides with small particle size were obtained by EDTA sol-gel process with high stability and repeatability, and the process temperature is much lower than that of solid state reaction method.
基金Supported by the National Natural Science Foundation of China (10601022)Natural Science Foundation of Inner Mongolia Autonomous Region (200607010106)Youth Science Foundation of Inner Mongolia University(ND0702)
文摘An H^1-Galerkin mixed finite element method is discussed for a class of second order SchrSdinger equation. Optimal error estimates of semidiscrete schemes are derived for problems in one space dimension. At the same time, optimal error estimates are derived for fully discrete schemes. And it is showed that the H1-Galerkin mixed finite element approximations have the same rate of convergence as in the classical mixed finite element methods without requiring the LBB consistency condition.
基金Supported by the International Cooperation and Exchanges Foundation of Henan Province (084300510060)the Youth Science Foundation of Henan University of Science and Technology of China (2008QN026)
文摘The （G＇/G, 1/G）-expansion method for finding exact travelling wave solutions of nonlinear evolution equations, which can be thought of as an extension of the （G＇/G）-expansion method proposed recently, is presented. By using this method abundant travelling wave so- lutions with arbitrary parameters of the Zakharov equations are successfully obtained. When the parameters are replaced by special values, the well-known solitary wave solutions of the equations are rediscovered from the travelling waves.
基金Supported by the National Natural Science Foundation of P.R.China(1 9971 0 0 2 ) and the Subject ofBeijing Educational Committ
文摘A new trust region algorithm for solving convex LC 1 optimization problem is presented.It is proved that the algorithm is globally convergent and the rate of convergence is superlinear under some reasonable assumptions.
基金The National Key Research and Development Program under contract Nos 2016YFC1402703 and 2018YFC1407100
文摘Conventional retrieval and neural network methods are used simultaneously to retrieve sea surface wind speed(SSWS)from HH-polarized Sentinel-1(S1)SAR images.The Polarization Ratio(PR)models combined with the CMOD5.N Geophysical Model Function(GMF)is used for SSWS retrieval from the HH-polarized SAR data.We compared different PR models developed based on previous C-band SAR data in HH-polarization for their applications to the S1 SAR data.The recently proposed CMODH,i.e.,retrieving SSWS directly from the HHpolarized S1 data is also validated.The results indicate that the CMODH model performs better than results achieved using the PR models.We proposed a neural network method based on the backward propagation(BP)neural network to retrieve SSWS from the S1 HH-polarized data.The SSWS retrieved using the BP neural network model agrees better with the buoy measurements and ASCAT dataset than the results achieved using the conventional methods.Compared to the buoy measurements,the bias,root mean square error(RMSE)and scatter index(SI)of wind speed retrieved by the BP neural network model are 0.10 m/s,1.38 m/s and 19.85%,respectively,while compared to the ASCAT dataset the three parameters of training set are–0.01 m/s,1.33 m/s and 15.10%,respectively.It is suggested that the BP neural network model has a potential application in retrieving SSWS from Sentinel-1 images acquired at HH-polarization.
文摘The ?exp(-j(x))?method is employed to find the exact traveling wave solutions involving parameters for nonlinear evolution equations. When these parameters are taken to be special values, the solitary wave solutions are derived from the exact traveling wave solutions. It is shown that the ?exp(-j(x))??method provides an effective and a more powerful mathematical tool for solving nonlinear evolution equations in mathematical physics. Comparison between our results and the well-known results will be presented.
文摘A generalized variable-coefficient algebraic method is appfied to construct several new families of exact solutions of physical interest for （3＋1）-dimensional Kadomtsev-Petviashvilli （KP） equation. Among them, the Jacobi elliptic periodic solutions exactly degenerate to the soliton solutions at a certain limit condition. Compared with the existing tanh method, the extended tanh method, the Jacobi elliptic function method, and the algebraic method, the proposed method gives new and more general solutions.
基金supported by the SDUST Spring Bud (2009AZZ021)Taian Science and Technology Development (20112001)
文摘C^1 natural element method （C^1 NEM） is applied to strain gradient linear elasticity, and size effects on mi crostructures are analyzed. The shape functions in C^1 NEM are built upon the natural neighbor interpolation （NNI）, with interpolation realized to nodal function and nodal gradient values, so that the essential boundary conditions （EBCs） can be imposed directly in a Galerkin scheme for partial differential equations （PDEs）. In the present paper, C^1 NEM for strain gradient linear elasticity is constructed, and sev- eral typical examples which have analytical solutions are presented to illustrate the effectiveness of the constructed method. In its application to microstructures, the size effects of bending stiffness and stress concentration factor （SCF） are studied for microspeciem and microgripper, respectively. It is observed that the size effects become rather strong when the width of spring for microgripper, the radius of circular perforation and the long axis of elliptical perforation for microspeciem come close to the material characteristic length scales. For the U-shaped notch, the size effects decline obviously with increasing notch radius, and decline mildly with increasing length of notch.
基金Project supported by the National Natural Science Foundation of China (Grant No. 10672053)
文摘By introducing a more general auxiliary ordinary differential equation （ODE）, a modified variable separated ordinary differential equation method is presented for solving the （2 ＋ 1）-dimensional sine-Poisson equation. As a result, many explicit and exact solutions of the （2 ＋ 1）-dimensional sine-Poisson equation are derived in a simple manner by this technique.
