We report the fabrication and optical characterization of spherical whispering gallery mode(WGM) resonators made from ultraviolet(UV)-curable adhesive. The fabricated microspheres have good sphericity and surface smoo...We report the fabrication and optical characterization of spherical whispering gallery mode(WGM) resonators made from ultraviolet(UV)-curable adhesive. The fabricated microspheres have good sphericity and surface smoothness, and can directly adhere to the tip of half-tapered fibers for easy manipulation. WGMs are e?ciently excited in the microsphere using an evanescent field of the tapered silica optical fibers. Resonances with quality factors of 1.3×10 5 are observed. The dependence of wavelength shifts of WGM resonances on the input light powers shows that the resonant wavelength of the proposed microsphere resonators can be tuned thermo-optically.展开更多
In this paper, we combined high-end cationic UV-curable material with fluorinated chain obtaining a series of new fluorine-containing aromatic oxetane monomers via a mild nucleophilic substitution reaction. The struct...In this paper, we combined high-end cationic UV-curable material with fluorinated chain obtaining a series of new fluorine-containing aromatic oxetane monomers via a mild nucleophilic substitution reaction. The structures and properties of monomers were characterized using ~1 H-NMR, ^（19） F-NMR, dynamic viscosity tests and differential scanning calorimetry（DSC）. It was determined that all of the fluorinated monomers obtained had much lower viscosity and higher thermostability after the introduction of hexafluorobenzene. Then, UV-curable coatings were prepared using four fluorine-containing aromatic oxetane monomers（FOX1-4）; the UV-curing kinetics, with three kinds of initiators, and properties of the cured films were evaluated using real-time Fourier transform infrared（FTIR） spectroscopy, water and diiodomethane contact angle tests, surface energy calculations and scanning electron microscopy（SEM）. The FTIR spectroscopy results showed that the coatings possessed excellent conversion rate（〉 99% with liquid initiator PAG-201 in 150 s）, and as the fluorine content increased, the monomers exhibited decreased mobility with the increasing viscosity and worse solubility with fluorinated monomers, resulting in a lower conversion rate. Moreover, the coatings possessed favorable hydrophobic and oleophobic properties and low surface energies owing to the fluoride chains floating to the membrane-air interface, which was also confirmed by discrete concave structures in SEM images. These new kinds of monomers can replace traditional fluorinated cationic monomers applied to the fingerprint resistant, fouling resistant, scratch resistant and anti-aging coatings, adhesives or printing ink materials.展开更多
基金supported by the National Natural Science Foundation of China(No.61275050)the Specialized Research Fund for the Doctoral Program of Higher Education(No.20120121110034)the Fundamental Research Funds for the Central Universities of Xiamen University(Nos.2010121059 and 2011121048)
文摘We report the fabrication and optical characterization of spherical whispering gallery mode(WGM) resonators made from ultraviolet(UV)-curable adhesive. The fabricated microspheres have good sphericity and surface smoothness, and can directly adhere to the tip of half-tapered fibers for easy manipulation. WGMs are e?ciently excited in the microsphere using an evanescent field of the tapered silica optical fibers. Resonances with quality factors of 1.3×10 5 are observed. The dependence of wavelength shifts of WGM resonances on the input light powers shows that the resonant wavelength of the proposed microsphere resonators can be tuned thermo-optically.
基金financially supported by the National Natural Science Foundation of China (No. 21574014)
文摘In this paper, we combined high-end cationic UV-curable material with fluorinated chain obtaining a series of new fluorine-containing aromatic oxetane monomers via a mild nucleophilic substitution reaction. The structures and properties of monomers were characterized using ~1 H-NMR, ^（19） F-NMR, dynamic viscosity tests and differential scanning calorimetry（DSC）. It was determined that all of the fluorinated monomers obtained had much lower viscosity and higher thermostability after the introduction of hexafluorobenzene. Then, UV-curable coatings were prepared using four fluorine-containing aromatic oxetane monomers（FOX1-4）; the UV-curing kinetics, with three kinds of initiators, and properties of the cured films were evaluated using real-time Fourier transform infrared（FTIR） spectroscopy, water and diiodomethane contact angle tests, surface energy calculations and scanning electron microscopy（SEM）. The FTIR spectroscopy results showed that the coatings possessed excellent conversion rate（〉 99% with liquid initiator PAG-201 in 150 s）, and as the fluorine content increased, the monomers exhibited decreased mobility with the increasing viscosity and worse solubility with fluorinated monomers, resulting in a lower conversion rate. Moreover, the coatings possessed favorable hydrophobic and oleophobic properties and low surface energies owing to the fluoride chains floating to the membrane-air interface, which was also confirmed by discrete concave structures in SEM images. These new kinds of monomers can replace traditional fluorinated cationic monomers applied to the fingerprint resistant, fouling resistant, scratch resistant and anti-aging coatings, adhesives or printing ink materials.
