Flowback and early-time production modeling of unconventional gas wells using an improved semi-analytical method

Multiple fractured horizontal wells (MFHWs) currently are the only possible means of commercial production from the low and ultra-low permeability unconventional gas reservoirs. In early production time, flowback fluid, which constitutes of hydraulic water and gas flow within fractures, is collected and analyzed. Flowback analysis has been shown to be a useful tool to estimate key properties of the hydraulic fracture such as conductivity and pore volume. Until date, most tools of flowback analysis rely on empirical and approximate methods. This study presents an improved Green-function-based semi-analytical solution for performance analysis of horizontal gas wells during flowback and early production periods. The proposed solution is derived based on coupling the solutions of two domains: a rigorously derived Green’s function-based integral solution for single-phase gas flow in matrix, and a finite-difference, multiphase solution for gas–water two-phase flow in the fracture. The validity of proposed semi-analytical solution is verified by finely gridded numerical models built in a commercial simulator for a series of synthetic cases considering a variety of fluid and reservoir property combinations, as well as various different production constraints. Comparisons against available empirical and approximate methods are also provided for these cases.

Development of unconventional gas and technologies adopted in China

This study analyses the geological characteristics and development progress of unconventional gas in China,summarizes the development theories and technologies,discusses the prospects and challenges of unconventional gas development,and puts forward the future trends of development technologies.Various technologies of unconventional gas development are available in China.Shale gas development technologies include comprehensive geological evaluation,volume fracturing of cluster horizontal wells under complex stress conditions,and factory-like operation of horizontal wells in complex mountainous area et al.Tight gas development technologies include fluid identification and quantitative prediction,optimization of well patterns,multi-layer fracturing in vertical well,staged fracturing in horizontal well,and drainage gas recovery.Coalbed methane(CBM)development technologies include the prediction of medium-high-and medium-low-rank CBM enrichment areas,rate-variable hydraulic fracturing,and quantitative drainage recovery with five stages,three pressures,and four controls.For economic and effective development of unconventional gas,further efforts should be made.First,intensified studies should be conducted on high-precision prediction and fine characterization technologies of high-quality shale reservoirs in deep marine,continental,and transitional facies.Second,key theories and technologies such as fast drilling and completion of wells with long laterals as well as large-scale volume fracturing should be developed to improve well productivity.Third,new technologies such as multiple well-type development,fluid injection,and nano-flooding should be developed to enhance the recovery.Fourth,effort should be made to identify the accumulation mechanism and large-scale effective development technologies for CBM.Fifth,the application of large amounts of data and artificial intelligence in the entire process of unconventional gas development should be considered to reduce the development cost.

A basic model of unconventional gas microscale flow based on the lattice Boltzmann method

A new method for selecting dimensionless relaxation time in the lattice Boltzmann model was proposed based on similarity criterion and gas true physical parameters.At the same time,the dimensionless relaxation time was modified by considering the influence of the boundary Knudsen layer.On this basis,the second-order slip boundary condition of the wall was considered,and the key parameters in the corresponding combined bounce-back/specular-reflection boundary condition were deduced to build a new model of unconventional gas microscale flow simulation based on the lattice Boltzmann method suitable for high temperatures and high pressures.The simulation results of methane gas flow driven by body force in infinite micro-channels and flow driven by inlet-outlet pressure differential in long straight channels were compared with the numerical and analytical solutions in the literature to verify the accuracy of the model,and the dimensionless relaxation time modification was formally optimized.The results show that the new model can effectively characterize the slippage effect,compression effect,gas density and the effect of boundary Knudsen layer in the micro-scale flow of unconventional natural gas.The new model can achieve a more comprehensive characterization of the real gas flow conditions and can be used as a basic model for the simulation of unconventional gas flow on the micro-nano scale.

An alternative approach to match field production data from unconventional gas-bearing systems

Nowadays,the unconventional gas-bearing system plays an increasingly important role in energy market.The performances of the current history-matching techniques are not satisfied when applied to such systems.To overcome this shortfall,an alternative approach was developed and applied to investigate production data from an unconventional gas-bearing system.In this approach,the fluid flow curve obtained from the field is the superposition of a series of Gaussian functions.An automatic computing program was developed in the MATLAB,and both gas and water field data collected from a vertical well in the Linxing Block,Ordos Basin,were used to present the data processing technique.In the reservoir study,the automatic computing program was applied to match the production data from a single coal seam,multiple coal seams and multiple vertically stacked reservoirs with favourable fitting results.Compared with previous approaches,the proposed approach yields better results for both gas and water production data and can calculate the contributions from different reservoirs.The start time of the extraction for each gas-containing unit can also be determined.The new approach can be applied to the field data prediction and designation for the well locations and patterns at the reservoir scale.

Distribution and Development of Unconventional Gas in China

China is abundant in unconventional gas, and stunning growth of gas reserves and production therefore can be expected in foreseeable future because of the exploration and development of the gas. For the next 5 to 10 years, conventional gas will still dominate energy market but in a long run, its influence will weaken gradually as unconventional gas kicks in and expands. Though the exploration and development of unconventional gas in China is still at a very early stage, three Chinese oil majors have already assessed the resources, including tight gas, coal-bed methane, shale gas and gas hydrate.

Dual-Porosity Apparent Permeability Models of Unconventional Gas Migration Based on Biot’s Porous Media

Stress-dependent permeability models are developed for the organic pores and inorganic cleats/fractures in unconventional gas reservoirs,which are modeled as Biot’s porous media of dual-porosity.Further considering multiple flow mechanisms such as dynamic effects of gas flow and surface diffusion,apparent permeability models are obtained to investigate the characteristics of unconventional gas migration.Compared to the gas transfer in single-porosity reservoirs,the gas migration ability of cleats in dual-porosity stratums rarely changes while that of organic pores is greatly improved because cleats sustain major geomechanical shrinkage deformation when the pore pressure drops.Further,the mass flux of reservoirs is dominated by the mass flux of cleats,which has a lower peak value,but a much longer production term than those in single-porosity reservoirs due to the interaction between organic pores and cleats.Parametric analysis is conducted to identify key factors significantly impacting mass flux in unconventional reservoirs.Reasons for the mass flux variation are also explored in terms of gas migration ability and pore pressure distribution.

Whole petroleum system and ordered distribution pattern of conventional and unconventional oil and gas reservoirs

The classical source-to-trap petroleum system concept only considers the migration and accumulation of conventional oil and gas in traps driven dominantly by buoyance in a basin,although revised and improved,even some new concepts as composite petroleum system,total petroleum system,total composite petroleum system,were proposed,but they do not account for the vast unconventional oil and gas reservoirs within the system,which is not formed and distributed in traps dominantly by buoyancedriven.Therefore,the petroleum system concept is no longer adequate in dealing with all the oil and gas accumulations in a basin where significant amount of the unconventional oil and gas resources are present in addition to the conventional oil and gas accumulations.This paper looked into and analyzed the distribution characteristics of conventional and unconventional oil/gas reservoirs and their differences and correlations in petroliferous basins in China and North America,and then proposed whole petroleum system(WPS)concept,the WPS is defined as a natural system that encompasses all the conventional and unconventional oil and gas,reservoirs and resources originated from organic matter in source rocks,the geological elements and processes involving the formation,evolution,and distribution of these oil and gas,reservoirs and resources.It is found in the WPS that there are three kinds of hydrocarbons dynamic fields,three kinds of original hydrocarbons,three kinds of reservoir rocks,and the coupling of these three essential elements lead to the basic ordered distribution model of shale oil/gas reservoirs contacting or interbeded with tight oil/gas reservoirs and separated conventional oil/gas reservoirs from source rocks upward,which is expressed as“S\T-C”.Abnormal conditions lead to other three special ordered distribution models:The first is that with shale oil/gas reservoirs separated from tight oil/gas reservoirs.The second is that with two direction ordered distributions from source upward and downward.The third is with lateral distribution from source outside.

Proppant transport in rough fractures of unconventional oil and gas reservoirs

A method to generate fractures with rough surfaces was proposed according to the fractal interpolation theory.Considering the particle-particle,particle-wall and particle-fluid interactions,a proppant-fracturing fluid two-phase flow model based on computational fluid dynamics(CFD)-discrete element method(DEM)coupling was established.The simulation results were verified with relevant experimental data.It was proved that the model can match transport and accumulation of proppants in rough fractures well.Several cases of numerical simulations were carried out.Compared with proppant transport in smooth flat fractures,bulge on the rough fracture wall affects transport and settlement of proppants significantly in proppant transportation in rough fractures.The higher the roughness of fracture,the faster the settlement of proppant particles near the fracture inlet,the shorter the horizontal transport distance,and the more likely to accumulate near the fracture inlet to form a sand plugging in a short time.Fracture wall roughness could control the migration path of fracturing fluid to a certain degree and change the path of proppant filling in the fracture.On the one hand,the rough wall bulge raises the proppant transport path and the proppants flow out of the fracture,reducing the proppant sweep area.On the other hand,the sand-carrying fluid is prone to change flow direction near the contact point of bulge,thus expanding the proppant sweep area.

Geological characteristics of unconventional tight oil reservoir (10^(9) t): A case study of Upper Cretaceous Qingshankou Formation, northern Songliao Basin, NE China

The Daqing exploration area in the northern Songliao Basin has great potential for unconventional oil and gas resources,among which the total resources of tight oil alone exceed 109 t and is regarded as an important resource base of Daqing oilfield.After years of exploration in the Qijia area,Songliao Basin,NE China,tight oil has been found in the Upper Cretaceous Qingshankou Formation.To work out tight oil’s geological characteristics,taking tight oil in Gaotaizi oil layers of the Upper Cretaceous Qingshankou Formation in northern Songliao Basin as an example,this paper systematically analyzed the geological characteristics of unconventional tight oil in Gao3 and Gao4 layers of the Qijia area,based on the data of the geological survey,well drilling journey,well logging,and test.It is that three sets of hydrocarbon source rocks(K2qn1,K2qn2+3,and K2n1)develop in the examined area,and exhibit excellent type I and II kerogens,high organic matter abundance,and moderate maturity.The reservoir is generally composed of thin-bedded mudstone,siltstone,and sandstone,and presents poor porosity(average 8.5 vol.%)and air permeability(average 4 mD).The main reservoir space primarily includes intergranular pores,secondary soluble pores,and intergranular soluble pores.Three types of orifice throats were identified,namely fine throat,extra-fine throat,and micro-fine throat.The siltstone is generally oil-bearing,the reservoirs with slime and calcium become worse oil-bearing,and the mudstone has no obvious oil-bearing characteristics.The brittleness indices of the sandstone in the tight oil reservoir range from 40%to 60%,and those of the mudstone range from 40%to 45%,indicating a better brittleness of the tight oil reservoir.Based on the study of typical core hole data,this paper gives a comprehensive evaluation of the properties of the tight oil and establishes a tight oil single well composite bar chart as well as the initial evaluation system with the core of properties in the tight oil reservoir.This study has theoretical guiding significance and practical application value for tight oil exploration and evaluation in the Qijia area.

Progress in China's Unconventional Oil & Gas Exploration and Development and Theoretical Technologies

The new century has witnessed a strategic breakthrough in unconventional oil ＆ gas.Hydrocarbon accumulated in micro-/nano-scale pore throat shale systems has become an important domain that could replace current oil ＆ gas resources.Unconventional oil ＆ gas plays an increasingly important role in our energy demand.Tight gas,CBM,heavy oil and asphaltic sand have served as a key domain of exploration ＆ development,with tight oil becoming a ＇bright spot＇ domain and shale gas becoming a ＇hotspot＇ domain.China has made great breakthroughs in unconventional oil ＆ gas resources,such as tight gas,shale gas,tight oil and CBM,and great progress in oil shale,gas hydrate,heavy oil and oil sand.China has an estimated（223-263）×10~8t of unconventional oil resources and（890-1260）×l0^（12）m^3 of gas resources.China has made a breakthrough for progress in unconventional oil ＆ gas study.New progress achieved in fine-grained sedimentary studies related to continental open lacustrine basin large-scale shallow-water delta sand bodies,lacustrine basin central sandy clastic flow sediments and marine-continental fine-grained sediments provide a theoretical basis for the formation and distribution of basin central reservoir bodies.Great breakthroughs have been made in unconventional reservoir geology in respect of research methodology ＆ technology,multi-scale data merging and physical simulation of formation conditions.Overall characterization of unconventional reservoirs via multi-method and multi-scale becomes increasingly popular and facilitates the rapid development of unconventional oil ＆ gas geological theory,method and technology.The formation of innovative,continuous hydrocarbon accumulation theory,the establishment of the framework of the unconventional oil ＆ gas geological theory system,and the determination of the implications,geological feature,formation mechanism,distribution rule and core technology of unconventional oil＆ gas geological study lays a theoretical foundation for extensive unconventional oil ＆ gas exploration and development.Theories and technologies of unconventional oil ＆ gas exploration and development developed rapidly,including some key evaluation techniques such as ＇sweet spot zone＇ integrated evaluation and a six-property evaluation technique that uses hydrocarbon source,lithology,physical property,brittleness,hydrocarbon potential and stress anisotropy,and some key development ＆engineering technologies including micro-seismic monitoring,horizontal drilling ＆ completion and ＂factory-like＂ operation pattern, ＂man-made reservoir＂ development,which have facilitated the innovative development of unconventional oil ＆ gas.These breakthroughs define a new understanding in four aspects：①theoretical innovation;② key technologies;③ complete market mechanism and national policy support;and ④ well-developed ground infrastructure,which are significant for prolonging the life cycle of petroleum industry,accelerating the upgrade and development of theories and technologies and altering the global traditional energy structure.

A"One Engine with Six Gears"System Engineering Methodology for the Economic Development of Unconventional Oil and Gas in China

Unconventional oil and gas resources have become the most important and realistic field for increasing China’s domestic oil and gas reserves and production.At present,the production scale does not match the massive amount of resources and the rapid growth of proven geological reserves.The challenges of technology,cost,management,and methodology restrict large-scale and economic development.Based on successful practices,a"one engine with six gears"system engineering methodology is put forward,which includes life-cycle management,overall synergy,interdisciplinary cross-service integration,marketoriented operation,socialized support,digitalized management,and low-carbon and green development.The methodology has been proved to be effective in multiple unconventional oil and gas national demonstration areas,including the Jimusar continental shale oil demonstration area.Disruptive views are introduced-namely,that unconventional oil and gas do not necessarily yield a low return,nor do they necessarily have a low recovery factor.A determination to achieve economic benefit must be a pervasive underlying goal for managers and experts.Return and recovery factors,as primary focuses,must be adhered to during China’s development of unconventional oil and gas.The required methodology transformation includes a revolution in management systems to significantly decrease cost and increase production,resulting in technological innovation.

“Extreme utilization”development theory of unconventional natural gas

In the process of unconventional natural gas development practice,the"extreme utilization"concept that focuses on"continuously breaking through the limit of development technology"is gradually formed,and supports the scale benefit exploration of unconventional gas in China.On this basis,the development theory of"extreme utilization"is proposed,its theoretical connotation together with development technologies of unconventional natural gas are clarified.The theoretical connotation is that,aiming at"extreme gas reservoirs","extreme techniques"are utilized to build subsurface connected bodies,expand the discharge area,and enlarge the production range,to obtain the maximum single-well production,extreme recovery,and eventually achieve the"extreme effect"of production.The series of development technologies include micro/nano-scale reservoir evaluation,"sweet spot"prediction,unconventional percolation theory and production capacity evaluation,optimization of grid well pattern,optimal-fast drilling and volume fracturing,and working regulation optimization and"integrated"organizing system.The"extreme utilization"development theory has been successfully applied in the development of unconventional gas reservoirs such as Sulige tight gas,South Sichuan shale gas,and Qinshui coalbed methane.Such practices demonstrate that,the"extreme utilization"development theory has effectively promoted the development of unconventional gas industry in China,and can provide theoretical guidance for effective development of other potential unconventional and difficult-to-recovery resources.

Policies for Unconventional Oil and Gas Resources in China

Regarding the abundant reserves in China, unconventional oil and gas resources has great potential in exploration and development, and may be the significant complement to conventional oil and gas resources. Based on the summary of the reservoir potential and current situation of exploration and development of unconventional oil and gas resources, such as coalbed methane(CBM), shale gas and oil shale, we analyzed the incentive policies proposed to promote the development of unconventional oil and gas industry, including industrial planning, resource management and related tax policy. These policies played an important role in promoting the exploration, development and utilization of unconventional oil and gas resources.

Evidence of the Near-Source Accumulation of the Tight Sandstone Gas in Northern Ordos Basin,North-Central China

The tight sandstone gas in Upper Paleozoic Formation of the northern Ordos Basin is a typical giant unconventional tight gas province. Evidences from geochemistry, reservoir geology and paleotectonic setting all verify that the present-day tight sandstone gas accumulation in the Ordos Basin is the result of near-source accumulation. The evidences are listed as following： tight sandstone gas is mainly distributed in the area with high gas-generating strength; gas composition was not subjected tofractionation; gas saturation significantly decreases with the distance away from the source rocks; gas isotopes suggest their origin is the same and maturity is consistent with in-place source rocks; reservoirs have experienced three types of densification digenesis, including intense compaction, siliceous cementation and calcareous cementation, which took place before the formation of a large amount of tight sandstone gas, forming tight reservoirs with low porosity and permeability, fine pore throat and great capillary resistance; the paleo-structural gradient ratio is small from the main hydrocarbon generation period to present. It is indicated the present distribution of tight sandstone gas in the northern Ordos Basin is the result of near-source and short-distance migration and accumulation.

Novel Water-Based Drilling and Completion Fluid Technology to Improve Wellbore Quality During Drilling and Protect Unconventional Reservoirs

The efficient exploration and development of unconventional oil and gas are critical for increasing the self-sufficiency of oil and gas supplies in China.However,such operations continue to face serious problems(e.g.,borehole collapse,loss,and high friction),and associated formation damage can severely impact well completion rates,increase costs,and reduce efficiencies.Water-based drilling fluids possess certain advantages over oil-based drilling fluids(OBDFs)and may offer lasting solutions to resolve the aforementioned issues.However,a significant breakthrough with this material has not yet been made,and major technical problems continue to hinder the economic and large-scale development of unconventional oil and gas.Here,the international frontier external method,which only improves drilling fluid inhibition and lubricity,is expanded into an internal-external technique that improves the overall wellbore quality during drilling.Bionic technologies are introduced into the chemical material synthesis process to imitate the activity of life.A novel drilling and completion fluid technique was developed to improve wellbore quality during drilling and safeguard formation integrity.Macroscopic and microscopic analyses indicated that in terms of wellbore stability,lubricity,and formation protection,this approach could outperform methods that use typical OBDFs.The proposed method also achieves a classification upgrade from environmentally protective drilling fluid to an ecologically friendly drilling fluid.The developed technology was verified in more than 1000 unconventional oil and gas wells in China,and the results indicate significant alleviation of the formation damage attributed to borehole collapse,loss,and high friction.It has been recognized as an effective core technology for exploiting unconventional oil and gas resources.This study introduces a novel research direction for formation protection technology and demonstrates that observations and learning from the natural world can provide an inexhaustible source of ideas and inspire the creation of original materials,technologies,and theories for petroleum engineering.

Gas hydrate saturation model and equation for logging interpretation

Since gas hydrate exists in three different forms at the same time such as pore filling,particle support and separate stratification,the calculation method of hydrate saturation using traditional shaly sand formation interpretation models is equivalent to considering only the simple case that hydrate exists as pore filling,and does not consider other complex states.Based on the analysis of hydrate resistivity experimental data and the general form of the resistivity-oil(gas)saturation relationship,the best simplified formula of hydrate saturation calculation is derived,then the physical meaning of the three items are clarified:they respectively represent the resistivity index-saturation relationship when hydrate particles are completely distributed in the pores of formation rocks,supported in the form of particles,and exist in layers,corresponding quantitative evaluation method of hydrate saturation is built.The field application shows that the hydrate saturation calculated by this method is closer to that obtained by sampling analysis.At the same time,it also provides a logging analysis basis for the effective development after hydrate exploration.

Geological and Engineering‘Sweet Spots'in the Permian Lucaogou Formation,Jimusar Sag,Junggar Basin

Unconventional oil and gas resources require petrophysical logs to answer the question of how best to optimize geological and engineering‘sweet spots'.Therefore,the establishment of a key well with comprehensive descriptions of lithology,reservoir properties,hydrocarbon-bearing properties,electronic well log responses,source rock properties,brittleness,and in situ stress magnitude and direction is important for the effective exploration and production of unconventional hydrocarbon resources.Cores,thin sections,scanning electron microscopy(SEM)and comprehensive well log suites are used to build a key well for the Permian Lucaogou Formation,Jimusar Sag of the Junggar Basin.The results show that there are three main types of lithologies,including siltstone,mudstone and dolostone.Lithologies can be predicted using the combination of conventional well and image logs.The pore spaces consist of interparticle pores,intragranular dissolution pores and micropores.Nuclear Magnetic Resonance(NMR)T_(2)components longer than 1.7 ms are superposed as effective porosity.Permeability is calculated using the Coates model from NMR T_(2)spectra.The ratio of T_(2)components>7.0 ms to T_(2)components>0.3 ms is used to calculate oil saturation.TOC is calculated using theΔlog R method.Brittleness index is calculated using Poisson-Young's method,ranging from 13.42%-70.53%.In situ stress direction is determined,and in situ stress magnitudes(maximum horizontal stress SH_(max),minimum horizontal stress Sh_(min),vertical stress S_(v))are calculated using density and sonic logs.The strike-slip stress type(SH_(max)>S_(v)>Sh_(min))is encountered.The key well which comprehensively includes the above seven properties is established.Geological and engineering(geomechanical)‘sweet spots'are then optimized from the key well by fully analyzing lithology,reservoir property,oilbearing potential,in situ stress magnitude and brittleness.It is hoped that the results support engineers'and geologists'decisions for the future exploitation of unconventional hydrocarbon resources.

Petroleum geology of marl in Triassic Leikoupo Formation and discovery significance of Well Chongtan1 in central Sichuan Basin,SW China

In 2022,the risk exploration well Chongtan1(CT1)in the Sichuan Basin revealed commercial oil and gas flow during test in a new zone–the marl of the second submember of the third member of Leikoupo Formation(Lei-32)of Middle Triassic,recording a significant discovery.However,the hydrocarbon accumulation in marl remains unclear,which restricts the selection and deployment of exploration area.Focusing on Well CT1,the hydrocarbon accumulation characteristics of Lei-32 marl are analyzed to clarify the potential zones for exploration.The following findings are obtained.First,according to the geochemical analysis of petroleum and source rocks,oil and gas in the Lei-32 marl of Well CT1 are originated from the same marl.The marl acts as both source rock and reservoir rock.Second,the Lei-32 marl in central Sichuan Basin is of lagoonal facies,with a thickness of 40–130 m,an area of about 40000 km^(2),a hydrocarbon generation intensity of(4–12)×10^(8) m^(3)/km^(2),and an estimated quantity of generated hydrocarbons of 25×10^(12) m^(3).Third,the lagoonal marl reservoirs are widely distributed in central Sichuan Basin.Typically,in Xichong–Yilong,Ziyang–Jianyang and Moxi South,the reservoirs are 20–60 m thick and cover an area of 7500 km^(2).Fourth,hydrocarbons in the lagoonal marl are generated and stored in the Lei-32 marl,which means that marl serves as both source rock and reservoir rock.They represent a new type of unconventional resource,which is worthy of exploring.Fifth,based on the interpretation of 2D and 3D seismic data from central Sichuan Basin,Xichong and Suining are defined as favorable prospects with estimated resources of(2000–3000)×10^(8) m^(3).

A novel method for quantitatively identifying driving forces and evaluating their contributions to oil and gas accumulation

Different driving forces govern the formation of distinct types of oil and gas accumulation and yield diverse oil and gas distributions.Complex oil and gas reservoirs in basins are commonly formed by the combination of multiple forces.It is very difficult but essential to identify driving forces and evaluate their contributions in predicting the type and distribution of oil and gas reservoirs.In this study,a novel method is proposed to identify driving forces and evaluate their contribution based on the critical conditions of porosity and permeability corresponding to buoyancy-driven hydrocarbon accumulation depth(BHAD).The application of this method to the Nanpu Sag of the Bohai Bay Basin shows that all oil and gas accumulations in the reservoirs are jointly formed by four driving forces:buoyance(Ⅰ),non-buoyance(Ⅱ),tectonic stress(Ⅲ1)and geofluid activity(Ⅲ2).Their contributions to all proven reserves are approxi-mately 63.8%,16.2%,2.9%,and 17.0%,respectively.The contribution of the driving forces is related to the depth,distance to faults and unconformity surfaces.Buoyancy dominates the formation of conven-tional reservoirs above BHAD,non-buoyant dominate the formation of unconventional reservoirs below BHAD,tectonic stress dominates the formation of fractured reservoirs within 300 m of a fault,and geoflu-ids activity dominates the formation of vuggy reservoirs within 100 m of an unconformity surface.

Gas-in-place and its influence factors of the upper Paleozoic coal-bearing shale in the Qinshui Basin, China

Coal-bearing shale shows great potential for unconventional gas resources in China, while its exploration and development have been challenging for a long time. Gas-in-place (GIP) is critical to shale gas evaluation, but the major factors controlling the GIP content of coal-bearing shale remain unclear. To address this issue, the coal-bearing shales of the upper Carboniferous-lower Permian Taiyuan and Shanxi formations in the Zuoquan Block, Qinshui Basin, China, were collected for GIP measurements and an integrated investigation, including organic geochemistry, inorganic mineral compositions, and pore characterizations, was carried out. Our results show that the GIP content of the studied shales displays relatively low values and wide variations, which range from 0.30 to 2.28 m^(3)/t. The GIP is dominated by desorbed gas and residual gas. Total organic carbon (TOC) contents of the studied shales vary from 0.92% to 16.91%, and inorganic minerals are dominated by clays that mainly consist of illite/smectite mixed layer (I/S) and kaolinite. Inorganic pores have been widely observed in the studied shales, while the organic matter-hosted pores are rarely found using SEM observations. Total porosity of the studied shales is primarily contributed by clay minerals, followed by organic matter and quartz. Weak positive relationships between the GIP content and pore structure parameters imply that the adsorption of methane to nanopores is relatively weak, which may be attributed to the hydrophilicity of clay-hosted pores. Moreover, hydrophobic organic pores are not well developed. Positive correlations between the GIP contents and contents of TOC, clays, and the I/S indicate that major factors influencing the GIP contents of the coal-bearing shales are clays (especially I/S) and TOC content. In summary, these findings would be very helpful to reveal the enrichment mechanism of coal-bearing shale gas and provide a scientific basis for the exploration and development of coal-bearing shale gas.