Prediction of the Biaxial Failure Strength of Composite Laminates with Unit Cell Analytic Model

A new method to predict the ultimate strength of fiber reinforced composites under arbitrary load condition is introduced. The micromechanics strength theory is used to perform the final failure prediction of composite laminates. The theory is based on unit cell analytic model which can provide the ply composite material properties by only using the constituent fiber and matrix properties and the laminate geometric parameters without knowing any experimental information of the laminates. To show that this method is suitable for predicting the strength of composite laminates, the micromechanics strength theory is ranked by comparing it with all the micro-level and the best two macro-level theories chosen from the World Wide Failure Exercise. The results show that this method can be used for predicting strength of any composite laminates and provide a direct reference for composite optimum design.

Unit Cell Modelling of Auxetic Structure

Auxetic material structures exhibit a negative Poisson ratio. The structure expands in the axial and transverse directions under tensile loading and vice versa under compression loading. Many fabricated designs for auxetic materials exist such as re-entrant hexagonal, chiral, and arrowhead geometries. This paper studies the unit cell of the re-entrant hexagonal geometry to understand how changing the internal angle and fillet radius of the structure affects the Poisson’s ratio. The material chosen for this study is acrylonitrile butadiene styrene (ABS) due to its availability and frequent use in additive manufacturing. The study was based on finite element analysis. It is observed that the direction of load applied to the unit cell affects the unit cell strain, Poisson’s ratio, and maximum load capacity before failure responses. It is noticed that the re-entrant cell starts by showing a standard non-auxetic behavior until it reaches a specific axial strain value. A quadratic correlation is identified between axial and transverse strain. Designing an auxetic structure starts with understanding the behavior of a unit cell structure. The auxetic structure design is a complex process that requires a compromise between auxetic property to be achieved and load capacity via avoiding stress concentration zones.

Industrial Preparation and Acid Resistance of Ultra-stable Y Zeolite with Small Cell Size Produced by Gas-phase Method

Small-cell HSY-S zeolite prepared by the gas-phase ultra-stable method had been researched and developed,and industrial preparation tests of HSY-S have been successfully carried out for the first time.The acid resistance of industrially prepared HSY-S was investigated by acid solutions with different pH values.The structures and properties of HSY-S and its acid-treated samples were characterized by XRD,XRF,BET,and IR.Results show that the HSY-S samples have the characteristics of high crystallinity,good stability,large specific surface area,and good acid resistance.

Correlations between trace elements in pyrite and gold mineralization of gold deposits on the North China platform

By studying both the microscopic physical and chemical typomorphic characteristics of typical mineral pyrite samples associated with representative gold deposits on the north-central margin of the North China Platform,this paper seeks to identify macroscopic metallogenic mechanisms of gold deposits and to reveal the formation mechanism of lattice gold in pyrite.Typomorphic characteristics of pyrite reveal that pyrite grain size has a negative correlation with gold content.Cubic pyrite,as the dominant crystal form,contains more gold than pentagonal dodecahedral pyrite.Both pyrite crystal forms and chemical compositions indicate that the replacement style of gold deposit formed in a low saturability,low sulfur fugacity,and at temperatures either much higher or much lower than its best forming temperature;comparatively,that of the quartz vein style of gold deposit occurred under conditions with the best temperature,rich in sulfur,and with high sulfur fugacity.The Au/Ag ratios of the pyrites show that both the replacement and quartz vein styles of deposits are mesothermal and hypothermal,while the Co/Ni ratios of the pyrites indicate that the quartz vein style is of magmatic-hydrothermal origin.The X-ray diffraction intensity of pyrite rich in gold is lower than that of pyrite poor in gold at the quartz vein style.In general,with an increase in gold content in pyrite,the total sum intensityΣI decreases.The pyroelectricity coefficient has a negative correlation trend with the values of(Co+Ni+Se+Te)-As and(Co+Ni+Se+Te)/As.The pyrite pyroelectricity of the replacement style is N-type,indicating that it formed under low sulfur fugacity,while that of the quartz vein style is a mixture of P-N types,indicating that it formed under high sulfur fugacity.On the pyroelectricity-temperature diagram,pyrite of the replacement style is mainly distributed between 200 and 270°C,while that of the quartz vein style varies between 90–118 and274–386°C,demonstrating a multistage forming process.In contrast to previous researchers'conclusions,the authors confirm the existence of lattice gold in pyrites through the use of an electron paramagnetic resonance(EPR)test.Au in the form of Au~+,entering pyrite as an isomorph and producing electron–hole centers,makes the centers produce spin resonance absorption and results in EPR absorption peak II.The intensity of auriferous pyrite absorption peak II has certain direct positive correlations with pyrite gold content.The#I and#III absorption peaks of pyrites possibly result from the existence of Ni^(2+)and/or Cu^(2+).γ1,γ2,andγ3 are the strongest and most typical absorption peaks of the infrared spectra of the pyrites.Generally,with the increase in gold content in the pyrite samples,γ1,γ2,andγ3 tend to shift to higher wavenumbers,and the gold content in the pyrite samples has a positive correlation with their relative absorbance.

Effects of Co^(2+)Doping on the Crystal Structure and Electrochemical Performance of LiFePO_4

Co2＋-doped LiFePO4/C composite material was prepared by solid-state synthesis method using Fe2O3,Li2CO3 and NH4H2PO4 as the starting materials.The structures and elec-trochemical performance of samples were studied by XRD,SEM and constant current charge-discharge method.The results showed that the Co2＋ doping did not change the crystal structure of LiFePO4.The unit cell volume changed with the increase of Co2＋,and reached the maximum at x = 0.04.The LiFe0.96Co0.04PO4/C sample proved the best electrochemical properties.Its initial discharge capacity was 138.5 mA·h /g at 1 C rate.After 30 cycles,the capacity remained 127.7 mA·h /g,and the capacity retention rate was 92.2%.

INCLINED LAMINAL COMBINATION MODEL OF 3D BRAIDED COMPOSITES

As an advanced composite material, the 3D braided composite has received more and more attention in foreign countries. However, it has received less attention in China. The geometric unit cell which can describe the basic structure and the relationship between the braiding angle and geometric parameters of the fabric and fiber volume ratio are given in this paper based on two 3D braiding processes, namely, the four-step and the twostep ones. Several existing mechanical models to predict groperties of the 3D braided comPOsites are discussed and their shortcomings are pointed out herein. Then a new model called the inclined laminal combination model is proposed, which is based on the classical laminated plate theory and can predict the basic mechanical behavior of the two 3D braided composites with four-step or two-step braid. In the model, each yarn in the unit cell is regarded as an inclined laminate and then a 3D analysis is performed. It is found that the predicted mechanical properties of the 3D braided composites by the proposed model are compared well with the experimental data.

Microstructure Analysis of 4-Step Three-Dimensional Braided Composite

The yarn architecture of 3-D braided composites products by the four-step 1×1 braiding technique has been studied by means of a control volume method in conjunction with experimental investigation and a numerical method, respectively. An ellipse assumption for the cross-section of yarn was proposed in this analysis method with considering the yarn size and yarn-packing factor. Two types of local unit cell structures were identified for 4-step braided composites by considering the nature of the braiding processes and by observing the sample cross-sections. The relationship between the braiding procedure and the properties for 3-D braided structural shapes was established. This method provides the basis for analyzing stiffness and strength of 3-D braided composites.

Collapse-type shrinkage characteristics in plantation-grown eucalypts： I . Correlations of basic density and some structural indices with shrinkage and collapse properties

Collapse-type shrinkage is one of highly refractory drying defects inlow-medium density plantation-grown eucalypt wood used as solid wood products. Basic density (BD),microfibril angle (MFA), double fibre cell wall thickness (DWT), proportion of ray parenchyma (RP),unit cell wall shrinkage, total shrinkage and residual collapse, which are associated withcollapse-type shrinkage characteristics, were investigated by using simple regression method forthree species of collapse-susceptible Eucalyptus urophyll,, E. grandis and E. urophyllaxE.grandis,planted at Dong-Men Forest Farm in Guangxi autonomous region, China. The results indicated that:unit cell wall shrinkage had a extremely strong positive correlation with BD, moderately strongpositive correlation with DWT, and a weakly or moderately negative correlation with RP and MFA;total shrinkage was positively correlated with BD, DWT and RP and negatively related to MFA, but notable to be predicted ideally by any examined factors alone owing to lower R^2 value (R^2≤0.5712);residual collapse was negatively correlated with BD and DWT, linearly positively correlated withMFA, and had strongly positive linear correlation with RP. It is concluded that BD can be used assingle factor (R^2≥ 0.9412) to predicate unit cell wall shrinkage and RP is the relatively soundindicator for predicting residual collapse

Numerical simulation and experimental validation on fabrication of nickel-based superalloy Kagome lattice sandwich structures

Nickel-based superalloy lattice sandwich structures present higher stiffness,higher strength and higher temperature resistance in comparison with other metals.In this study,the Kagome unit was adopted to design the lattice sandwich structure and ProCAST software was used to simulate the filling and solidification processes of the nickel-based superalloy.Grain morphology and sizes of the nickel-based superalloy lattice sandwich structures were simulated by using of cellular automaton coupled with finite element model(CAFE),and indirect additive manufacture combining with investment casting were carried out to fabricate the nickel-based superalloy lattice sandwich structures.The calculated grain morphology and sizes are in good agreement with the experimental results.The grains are mainly equiaxed with an average size of about 500µm.The simulated results also show that the superheat of melting and the mold preheated temperature have significant influence on the grain size of the Kagome lattice sandwich structures,lower superheat of melting and mold preheated temperatures are encouraged to obtain the fine grains while assuring the integrity of the Kagome lattice sandwich structures for industrial application.

NUMERICAL STUDY ON CREEP DAMAGE OF COMPOSITES AT HIGH TEMPERATURE

A unit cell model is applied to study the creep damage behavior after fiber fractures in the fiber-reinforced composites at high temperature. The user subroutine CREEP has been programmed for ABAQUS. The fiber breakage results in a new crack. The results show that the stress concentration factor resulted from the fiber breakage increases with the creep time. The creep damage takes place near the crack, and then grows in the matrix along a certain angle, up to the total failure. The influences of the ratio of modulus of the fiber to the matrix (Ef/Em) on the creep deformation, damage and stress distributions have been studied. With the increasing Ef/Em, the damage in the matrix increases. Analysis on the different ductility of matrix shows that the creep damage of low ductile matrix composites is higher than high ductile matrix composites.

3D FINITE ELEMENT ANALYSIS OF THE DAMAGE EFFECTS ON THE DENTAL COMPOSITE SUBJECT TO WATER SORPTION

The damage effects of water sorption on the mechanical properties of the hydroxyapatite particle reinforced Bis-GMA/TEGDMA copolymer （HA/Bis-GMA/TEGDMA） h-ave been predicted using 3D finite cell models. The plasticizer effect on the polymer matrix was considered as a variation of its Young＇s modulus. Three different cell models were used to determine the influence of varying particle contents, interphase strength and moisture concentration on the debonding damage. The stress distribution pattern has been examined and the stress transfer mode clarified. The Young＇s modulus and fracture strength of the Bis-GMA/TEGDMA composite were also predicted using the model with and without consideration of the damage. ine Iormer results with consideration of the debonding damage are in good agreement with existing literature experimental data. The shielding effect of our proposed model and an alternative approach were discussed. The FCC cell model has also been extended to predict the critical load for the damaged and the undamaged composite subject to the 3-point flexural test.

Chemical and physical characteristics of quartz from gold deposits in the North China platform: relationship to gold mineralization

This paper seeks to identify macroscopic metallogenic mechanisms of various mineral deposits by studying microscopic typomorphic characteristics of typical minerals associated with the deposits and to reveal the mechanism of lattice gold in detail by studying both physical and chemical characteristics of quartz from representative gold deposits in the North China Platform.As part of their extensive research,the authors examine the relationship between trace elements with wall rock,the ore-forming media,and gold immigration of various types of gold deposits,including their salinity,type,temperature.These are key factors to revealing the mineralization mechanism,and indicators for mineral prospecting,exploration,mining,and metallurgical technology.In order to address the questions posed,the following methods were used:field investigations of geology and sampling of the representative gold deposits,physical study and chemical analysis of quartz including,but not limited to,fluid inclusions as well as their compositions and trace elements in quartz,the unit cell parameters,electron paramagnetic resonance spectrum(EPR),and infrared spectroscopic analysis(ISA).As a result of this study,the authors observe the following key findings:unit cell parameters of quartz vary with their contents of foreign elements including gold,paragenetic stage,wall rock type,and other factors;the higher the forming temperature and the lower the gold content in quartz,the smaller the unit cell parameters,and vice versa.Additionally,the EPR absorption lines resulted from the O–Al defect center.The density of these types of hole centers increases and the EPR signal strengthens when the temperature decreases.Based on the findings,the authors conclude that lattice gold exists in quartz.Gold,in the form of Au^(+)and/or Au^(3+),entering quartz and producing an electron–hole center,namely,the O-Au hole center,makes the center produce spin resonance absorption and results in the EPR absorption peak#I.Both unit cell parameters and EPR of quartz can potentially be used in mineral prospecting,relative ore-forming temperature determination,and grade control during mining.

Theoretical aspects of selecting repeated unit cell model in micromechanical analysis using displacement-based finite element method

Repeated Unit Cell（RUC）is a useful tool in micromechanical analysis of composites using Displacement-based Finite Element（DFE）method,and merely applying Periodic Displacement Boundary Conditions（PDBCs）to RUC is almost a standard practice to conduct such analysis.Two basic questions arising from this practice are whether Periodic Traction Boundary Conditions（PTBCs,also known as traction continuity conditions）are guaranteed and whether the solution is independent of selection of RUCs.This paper presents the theoretical aspects to tackle these questions,which unify the strong form,weak form and DFE method of the micromechanical problem together.Specifically,the solution’s independence of selection of RUCs is dealt with on the strong form side,PTBCs are derived from the weak form as natural boundary conditions,and the validity of merely applying PDBCs in micromechanical Finite Element（FE）analysis is proved by referring to its intrinsic connection to the strong form and weak form.Key points in the theoretical aspects are demonstrated by illustrative examples,and the merits of setting micromechanical FE analysis under the background of a clear theoretical framework are highlighted in the efficient selection of RUCs for Uni Directional（UD）fiber-reinforced composites.

Calculating the shading reduction coefficient of photovoltaic system efficiency using the anisotropic sky scattering model

The front-row shading reduction coefficient is a key parameter used to calculate the system efficiency of a photovoltaic(PV)power station.Based on the Hay anisotropic sky scattering model,the variation rule of solar radiation intensity on the surface of the PV array during the shaded period is simulated,combined with the voltage-current characteristics of the PV modules,and the shadow occlusion operating mode of the PV array is modeled.A method for calculating the loss coefficient of front shadow occlusion based on the division of the PV cell string unit and Hay anisotropic sky scattering model is proposed.This algorithm can accurately evaluate the degree of influence of the PV array layout,wiring mode,array spacing,PV module specifications,and solar radiation on PV power station system efficiency.It provides a basis for optimizing the PV array layout,reducing system loss,and improving PV system efficiency.

Isomorphous Substitution of Metallic Elements for Zeolite Y in the Aqueous Solution

The substitutions of Ti, Fe and Zr into zeolite Y in the aqueous solutions of (NH4)2TiF6, (NH4)3ZrF7 and (NH4)3FeF6 were systematically Investigated. It was found that Ai atoms in the framework can be replaced by some metallic elements and the extent of substitution depends on the M/A1 ratio of the solution. The maximum allowable M/A1 ratio of the aqueous solution Is related with the radius of the M atom and the stability constant of the MFnm- complex. The substituted zeolite samples with crystallinity greater than 80% were characterized by means of XRD, IR, DTA, TPR and NH3-TPD measurements. The incorporation of Ti, Fe and Zr into the zeolite leads to an increase in the unit cell parameter, a lowering of thermal stability and a red shift of the asymmetric stretching frequency. The extent of these changes is apparently related with the ionic radius of the metallic element and the degree of substitution. The results of various characterization methods show that the het-eroatoms are readily Introduced into the zeolite framework by this preparation method. It was also observed that the substitution of heteroatoms may strengthen or weaken the surface acidity of zeolite Y.

STATISTIC MODELING OF THE CREEP BEHAVIOR OF METAL MATRIX COMPOSITES BASED ON FINITE ELEMENT ANALYSIS

The aim of the paper is to discover the general creep mechanisms for the short fiber reinforcement matrix composites (MMCs) under uniaxial stress states and to build a relationship between the macroscopic steady creep behavior and the material micro geometric parameters. The unit cell models were used to calculate the macroscopic creep behavior with different micro geometric parameters of fibers on different loading directions. The influence of the geometric parameters of the fibers and loading directions on the macroscopic creep behavior had been obtained, and described quantitatively. The matrix/fiber interface had been considered by a third layer, matrix/fiber interlayer, in the unit cells with different creep properties and thickness. Based on the numerical results of the unit cell models, a statistic model had been presented for the plane randomly-distributed-fiber MMCs. The fiber breakage had been taken into account in the statistic model for it starts experimentally early in the creep life. With the distribution of the geometric parameters of the fibers, the results of the statistic model agree well with the experiments. With the statistic model, the influence of the geometric parameters and the breakage of the fibers as well as the properties and thickness of, the interlayer on the macroscopic steady creep rate have been discussed.

Effective Yield Strength for Material Powder Consolidated at Stage II Compaction

This work is concerned with the estimation from the outside of effective yield strength for the stage II consolidated material package of axisymmetric solid particles. Once an appropriate simple representative axisymmetric unit cell is chosen, the kinematical approach of the yield design homogenization method is used in order to obtain external estimates which has been found depending on the loading history (isostatic and closed die compactions) as well as on the relative density of the material powder. For comparison purpose, finite element simulations that describe the behavior of spherical elastic plastic particles uniformly distributed inside the material powder are carried out.

United block sequence mapping-based visible light positioning for dense small cell deployment

Visible light positioning （VLP） is an emerging candidate for indoor positioning, which carl simultaneously meet the requirements for accuracy, cost, coverage area, and security. However, intercell interference causcd by light intensity superposition linfits the application of VLP. In this Letter, we propose a united block sequence mapping （UBSM）-based VLP that utilizes superposition to integrate the multidimensional information from dense small cells into 2D information. The experimental result shows that UBSM-based VLP can achieve an accuracy of 1.5 cm with a 0.4 m row spacing and 0.35 m column spacing of LED lights.

The impact of HLA haplotype and alleles mismatches of donor-recipient pairs on outcome of haplo-identical hematopoietic stem cell transplantation with a third part cord blood unit

Objective To analyze allele mismatches of HLA-A,-B,-C,-DRB1,-DQB1 and haplotype mismatch of donor-recipient pairs on the outcome of haploidentical transplantation combined with a third part cord blood unit.Methods 230 pairs of donor-recipient were performed HLA-A,B,C,DRB1,DQB1 typing using

Underwater cylindrical sandwich meta-structures composed of graded semi re-entrant zero Poisson’s ratio metamaterials with pre-strained wave propagation properties

Zero Poisson’s ratio(ZPR)mechanical metamaterials can yield no transverse displacements when unidi-rectionally compressed,and cylindrical sandwich meta-structures composed of semi re-entrant(SRE)ZPR metamaterials are thus explored for applications on cylindrical shells of underwater equipment or sub-mersible structures.A group of ZPR unit cells with specified pre-strained wave propagation characteristics and adequate load-bearing capabilities is optimally designed based on the periodic boundary condition(PBC)and Bloch’s Theorem.The sound transmission and pressure-resistant performance of cylindrical sandwich meta-structures comprising the homogeneous and graded SRE ZPR unit cells are then investi-gated.The results show that the designed meta-structures can perfectly yield better vibroacoustic atten-uation behavior within the specified frequency regions corresponding to the pre-strained band gaps and safely bear the hydrostatic pressure equivalent to 1000 m depth with low weight-bulk ratios.In addition,the functionally graded metamaterial core can boost vibroacoustic performance within broader frequency ranges.