Graphene-based gas/vapor sensors have attracted much attention in recent years due to their variety of structures, unique sensing performances, room-temperature working conditions, and tremendous application prospects...Graphene-based gas/vapor sensors have attracted much attention in recent years due to their variety of structures, unique sensing performances, room-temperature working conditions, and tremendous application prospects, etc.Herein, we summarize recent advantages in graphene preparation, sensor construction, and sensing properties of various graphene-based gas/vapor sensors, such as NH_3, NO_2, H_2, CO, SO_2, H_2S, as well as vapor of volatile organic compounds.The detection mechanisms pertaining to various gases are also discussed. In conclusion part, some existing problems which may hinder the sensor applications are presented. Several possible methods to solve these problems are proposed, for example, conceived solutions, hybrid nanostructures, multiple sensor arrays, and new recognition algorithm.展开更多
Arrays of chemical vapor sensors based on graphene field effect transistors functionalized with single-stranded DNA have been demonstrated. Standard photolithographic processing was adapted for use on large-area graph...Arrays of chemical vapor sensors based on graphene field effect transistors functionalized with single-stranded DNA have been demonstrated. Standard photolithographic processing was adapted for use on large-area graphene by including a metal protection layer, which protected the graphene from contamination and enabled fabrication of high quality field-effect transistors （GFETs）. Processed graphene devices had hole mobilities of 1,640 ± 250 cm2.V-1.s-1 and Dirac voltages of 15 ± 10 V under ambient conditions. Atomic force microscopy was used to verify that the graphene surface remained uncontaminated and therefore suitable for controlled chemical functionalization. Single-stranded DNA was chosen as the functionalization layer due to its affinity to a wide range of target molecules and π-π stacking interaction with graphene, which led to minimal degradation of device characteristics. The resulting sensor arrays showed analyte- and DNA sequence-dependent responses down to parts-per-billion concentrations. DNA/GFET sensors were able to differentiate among chemically similar analytes, including a series of carboxylic acids, and structural isomers of carboxylic acids and pinene. Evidence for the important role of electrostatic chemical gating was provided by the observation of understandable differences in the sensor response to two compounds that differed only by the replacement of a （deprotonating） hydroxyl group by a neutral methyl group. Finally, target analytes were detected without loss of sensitivity in a large background of a chemically similar, volatile compound. These results motivate further development of the DNA/graphene sensor family for use in an electronic olfaction system.展开更多
Fluorescence sensors based on a trifluoroacetophone compound doped in ethyl cellulose (EC) thin films have been developed for the detection of methanol, ethanol, and 2-propanol (isopropanol, PriOH) vapors. Thin-film s...Fluorescence sensors based on a trifluoroacetophone compound doped in ethyl cellulose (EC) thin films have been developed for the detection of methanol, ethanol, and 2-propanol (isopropanol, PriOH) vapors. Thin-film sensors are prepared with 4-dibutylamino-4’-(trifluoroacetyl)stilbene (Chromoionophore IX or CIX) as the fluorescent dye and its solution in EC was spin-coated onto glass slides. The luminescence intensity of the dye (555 nm) is quenched when exposed to alcohol vapor. Tested in the range of ca. 0 - 1.5?× 104 ppm (wt) for MeOH and EtOH, and ca. 0 - 2.3 × 104 ppm for PriOH, the sensors gave detection limits of 9, 13, 21 ppm and quantification limits of 32, 43, and 70 ppm, respectively. To enhance the sensitivity of the sensors, TiO2 particles have been added to the films to induce Mie scattering, which increases the incident light interaction with the sensing films. The sensors in this work have been designed to work in a multianalyte platform for the simultaneous detection of multiple gas analytes.展开更多
HY-2 satellite is the first marine dynamic environment satellite of China.In this study,global evaporation and water vapor transport of the global sea surface are calculated on the basis of HY-2 multi-sensor data from...HY-2 satellite is the first marine dynamic environment satellite of China.In this study,global evaporation and water vapor transport of the global sea surface are calculated on the basis of HY-2 multi-sensor data from April 1 to 30,2014.The algorithm of evaporation and water vapor transport is discussed in detail,and results are compared with other reanalysis data.The sea surface temperature of HY-2 is in good agreement with the ARGO buoy data.Two clusters are shown in the scatter plot of HY-2 and OAFlux evaporation due to the uneven global distribution of evaporation.To improve the calculation accuracy,we compared the different parameterization schemes and adopted the method of calibrating HY-2 precipitation data by SSM/I and Global Precipitation Climatology Project(GPCP)data.In calculating the water vapor transport,the adjustment scheme is proposed to match the balance of the water cycle for data in the low latitudes.展开更多
Usefulness of sensor network applications in human life is increasing day by day and the concept of wireless connection promises new application areas. Sensor network can be very beneficial in saving human life from t...Usefulness of sensor network applications in human life is increasing day by day and the concept of wireless connection promises new application areas. Sensor network can be very beneficial in saving human life from terrorist attacks causing explosion in certain areas leading to casualties. But realization of the sensor network application in explosive detection requires high scalability of the sensor network and fast transmission of the information through real time monitoring and control. In this paper a novel mechanism for explosive trace detection in any populated area by the use of mobile telephony has been described. The aim is to create a system that will assure common men, local population and above all the nation a secured environment, without disturbing their freedom of movement. It would further help the police in detection of explosives more quickly, isolation of suicide bombers, remediation of explosives manufacturing sites, and forensic and criminal investigation. To achieve this, the paper has projected an idea that can combine the strength of the mobile phones, the polymer sensor and existing cellular network. The idea is to design and embed a tiny cog-nitive radio sensor node into the mobile phone that adapts to the changing environment by analyzing the RF surroundings and adjusting the spectrum use appropriately. The system would be capable of detecting explo-sives within a defined territory. It would communicate the location of the detected explosives to the respec-tive service provider, which in turn would inform the law and enforcement agency or Police.展开更多
基金financial supports provided by the National Basic Research Program of China(2013CB932500)the National Natural Science Foundation of China(21171117 and 61574091)+3 种基金the Program for New Century Excellent Talents in University(NCET-12-0356)the Program of Shanghai Academic/Technology Research Leader(15XD1525200)Shanghai Jiao Tong University Agri-X Funding(Agri-X2015007)the Program for Professor of Special Appointment(Eastern Scholar)at Shanghai Institutions of Higher Learning
文摘Graphene-based gas/vapor sensors have attracted much attention in recent years due to their variety of structures, unique sensing performances, room-temperature working conditions, and tremendous application prospects, etc.Herein, we summarize recent advantages in graphene preparation, sensor construction, and sensing properties of various graphene-based gas/vapor sensors, such as NH_3, NO_2, H_2, CO, SO_2, H_2S, as well as vapor of volatile organic compounds.The detection mechanisms pertaining to various gases are also discussed. In conclusion part, some existing problems which may hinder the sensor applications are presented. Several possible methods to solve these problems are proposed, for example, conceived solutions, hybrid nanostructures, multiple sensor arrays, and new recognition algorithm.
基金This research was supported by the Nano/Bio Interface Center through the National Science Foundation Nanoscale Science and Engineering Center （NSEC） DMR08-32802, and the work involved use of its facilities. Support from Lockheed Martin is also gratefully acknowledged. M.L. acknowledges the support of the Science, Mathematics, And Research for Transformation （SMART） Fellowship.
文摘Arrays of chemical vapor sensors based on graphene field effect transistors functionalized with single-stranded DNA have been demonstrated. Standard photolithographic processing was adapted for use on large-area graphene by including a metal protection layer, which protected the graphene from contamination and enabled fabrication of high quality field-effect transistors （GFETs）. Processed graphene devices had hole mobilities of 1,640 ± 250 cm2.V-1.s-1 and Dirac voltages of 15 ± 10 V under ambient conditions. Atomic force microscopy was used to verify that the graphene surface remained uncontaminated and therefore suitable for controlled chemical functionalization. Single-stranded DNA was chosen as the functionalization layer due to its affinity to a wide range of target molecules and π-π stacking interaction with graphene, which led to minimal degradation of device characteristics. The resulting sensor arrays showed analyte- and DNA sequence-dependent responses down to parts-per-billion concentrations. DNA/GFET sensors were able to differentiate among chemically similar analytes, including a series of carboxylic acids, and structural isomers of carboxylic acids and pinene. Evidence for the important role of electrostatic chemical gating was provided by the observation of understandable differences in the sensor response to two compounds that differed only by the replacement of a （deprotonating） hydroxyl group by a neutral methyl group. Finally, target analytes were detected without loss of sensitivity in a large background of a chemically similar, volatile compound. These results motivate further development of the DNA/graphene sensor family for use in an electronic olfaction system.
文摘Fluorescence sensors based on a trifluoroacetophone compound doped in ethyl cellulose (EC) thin films have been developed for the detection of methanol, ethanol, and 2-propanol (isopropanol, PriOH) vapors. Thin-film sensors are prepared with 4-dibutylamino-4’-(trifluoroacetyl)stilbene (Chromoionophore IX or CIX) as the fluorescent dye and its solution in EC was spin-coated onto glass slides. The luminescence intensity of the dye (555 nm) is quenched when exposed to alcohol vapor. Tested in the range of ca. 0 - 1.5?× 104 ppm (wt) for MeOH and EtOH, and ca. 0 - 2.3 × 104 ppm for PriOH, the sensors gave detection limits of 9, 13, 21 ppm and quantification limits of 32, 43, and 70 ppm, respectively. To enhance the sensitivity of the sensors, TiO2 particles have been added to the films to induce Mie scattering, which increases the incident light interaction with the sensing films. The sensors in this work have been designed to work in a multianalyte platform for the simultaneous detection of multiple gas analytes.
基金the financial support from the National Natural Science Foundation of China (No. 4197 6017)the Ministry of Science and Technology of China (No. 2016YFC1401405)the National Natural Science Foundation of China (No. U1406401)
文摘HY-2 satellite is the first marine dynamic environment satellite of China.In this study,global evaporation and water vapor transport of the global sea surface are calculated on the basis of HY-2 multi-sensor data from April 1 to 30,2014.The algorithm of evaporation and water vapor transport is discussed in detail,and results are compared with other reanalysis data.The sea surface temperature of HY-2 is in good agreement with the ARGO buoy data.Two clusters are shown in the scatter plot of HY-2 and OAFlux evaporation due to the uneven global distribution of evaporation.To improve the calculation accuracy,we compared the different parameterization schemes and adopted the method of calibrating HY-2 precipitation data by SSM/I and Global Precipitation Climatology Project(GPCP)data.In calculating the water vapor transport,the adjustment scheme is proposed to match the balance of the water cycle for data in the low latitudes.
文摘Usefulness of sensor network applications in human life is increasing day by day and the concept of wireless connection promises new application areas. Sensor network can be very beneficial in saving human life from terrorist attacks causing explosion in certain areas leading to casualties. But realization of the sensor network application in explosive detection requires high scalability of the sensor network and fast transmission of the information through real time monitoring and control. In this paper a novel mechanism for explosive trace detection in any populated area by the use of mobile telephony has been described. The aim is to create a system that will assure common men, local population and above all the nation a secured environment, without disturbing their freedom of movement. It would further help the police in detection of explosives more quickly, isolation of suicide bombers, remediation of explosives manufacturing sites, and forensic and criminal investigation. To achieve this, the paper has projected an idea that can combine the strength of the mobile phones, the polymer sensor and existing cellular network. The idea is to design and embed a tiny cog-nitive radio sensor node into the mobile phone that adapts to the changing environment by analyzing the RF surroundings and adjusting the spectrum use appropriately. The system would be capable of detecting explo-sives within a defined territory. It would communicate the location of the detected explosives to the respec-tive service provider, which in turn would inform the law and enforcement agency or Police.
