Organometal halide perovskite based solar cells have emerged as one of the most promising candidates for low-cost and high-efficiency solar cell technologies. Here a Vapor Transfer Method （VTM） is used to fabricate ...Organometal halide perovskite based solar cells have emerged as one of the most promising candidates for low-cost and high-efficiency solar cell technologies. Here a Vapor Transfer Method （VTM） is used to fabricate high quality perovskite thin films in a balanced vacuum capsule. By adjusting the reaction tem- perature, CH_3NHl_3 saturated vapor which then reacts with Pbl_2 films can be controlled and the formation process of CH_3NH_3Pbl_3 perovskite films can be further influenced. Prepared perovskite films which ex- hibit pure phase, smooth surface and high crystallinity are assembled into planar heterojunction inverted solar cells. The whole fabrication process of solar cell devices is organic solution free. Finally, the cham- pion cell achieved power conversion efficiency （PCE） of 13.08% with negligible current-voltage hysteresis under fully open-air conditions. The photovoltaic performance could be further enhanced by optimizing perovskite composition and the device structure.展开更多
The phase transitions and the effect on this process of two factors: relative motion and the external influence of the carrier flow (pressure perturbation) are investigated. A mathematical model describing all the sta...The phase transitions and the effect on this process of two factors: relative motion and the external influence of the carrier flow (pressure perturbation) are investigated. A mathematical model describing all the stages of the phenomenon is constructed. The model includes mass, momentum and energy balance equations (both for the vapor and for the liquid) or their first integrals.展开更多
A similarity analysis for Marangoni convection induced flow over a vapor-liquid interface due to an imposed temperature gradient was carried out. The analysis assumes that the surface tension varies linearly with temp...A similarity analysis for Marangoni convection induced flow over a vapor-liquid interface due to an imposed temperature gradient was carried out. The analysis assumes that the surface tension varies linearly with temperature but the temperature variation is a power law function of the location. The similarity solutions are presented numerically and the associated transfer characteristics are discussed.展开更多
Hot-filament chemical vapor deposition ( HFCVD) is a promising method for commercial production of diamond films. Filament performance in heat transfer and hydrogen decomposition in reactive environment was investigat...Hot-filament chemical vapor deposition ( HFCVD) is a promising method for commercial production of diamond films. Filament performance in heat transfer and hydrogen decomposition in reactive environment was investigated. Power consumption by the filament in vacuum, helium and 2% CH4/H2 was experimentally determined in temperature range 1300℃-2200℃. Filament heat transfer mechanism in C-H reactive environment was calculated and analyzed. The result shows that due to surface carburization and slight carbon deposition, radiation in stead of hydrogen dissociation, becomes the largest contributor to power consumption. Filament-surface dissociation of H2 was observed at temperatures below 1873K, demonstrating the feasibility of diamond growth at low filament temperatures. The effective activation energies of hydrogen dissociation on several clean refractory flaments were derived from power consumption data in literatures. They are all lower than that of thermal dissociation of hydrogen revealing the nature of catalytic dissociation of hydrogen on filament surface. Observation of substrate temperature suggested a weaker role of atomic hydrogen recombination in heating substrates in C-H environment than in pure hydrogen.展开更多
It is known from the New Energy and Industry Technology Development Organization (NEDO) roam map Japan, 2017 that the polymer electrolyte fuel cell (PEFC) power generation system is required to operate at 100°C f...It is known from the New Energy and Industry Technology Development Organization (NEDO) roam map Japan, 2017 that the polymer electrolyte fuel cell (PEFC) power generation system is required to operate at 100°C for application of mobility usage from 2020 to 2025. This study aims to clarify the effect of separator thickness on the distribution of the temperature of reaction surface (T<sub>react</sub>) at the initial temperature of cell (T<sub>ini</sub>) with flow rate, relative humidity (RH) of supply gases as well as RH of air surrounding cell of PEFC. The distribution of T<sub>react</sub> is estimated by means of the heat transfer model considering the H<sub>2</sub>O vapor transfer proposed by the authors. The relationship between the standard deviation of T<sub>react</sub>-T<sub>ini</sub> and total voltage obtained in the experiment is also investigated. We can know the effect of the flow rate of supply gas as well as RH of air surrounding cell of PEFC on the distribution of T<sub>react</sub>-T<sub>ini</sub> is not significant. It is observed the wider distribution of T<sub>react</sub>-T<sub>ini</sub> provides the reduction in power generation performance irrespective of separator thickness. In the case of separator thickness of 1.0 mm, the standard deviation of T<sub>react</sub>-T<sub>ini</sub> has smaller distribution range and the total voltage shows a larger variation compared to the other cases.展开更多
This paper puts forward a new method to achieve flux cored wire TIG welding and uses high-speed photography to analyze the droplet transfer behavior and forces acting on the droplet. The droplet transfer forms include...This paper puts forward a new method to achieve flux cored wire TIG welding and uses high-speed photography to analyze the droplet transfer behavior and forces acting on the droplet. The droplet transfer forms include bridging transfer, slag column guided transfer, and non-contact transfer; each of these forms may be observed as the melting position of the welding wire changes. The important role of surface tension in the process of droplet transfer is proposed using static force balance theory and pinch instability theory. The phenomenon of droplet backward swing during welding process could be attributed to the vapor recoil force produced by vapors from the droplet. The welding experiments show that the proposed welding process is stable and that the weld quality produced is good.展开更多
A novel vapor-liquid-solid circulating fluidized bed evaporator, meaning for enhancing heat transfer and preventing fouling, is applied to wheat straw black liquor, which is the primary pollutant in China’s papermaki...A novel vapor-liquid-solid circulating fluidized bed evaporator, meaning for enhancing heat transfer and preventing fouling, is applied to wheat straw black liquor, which is the primary pollutant in China’s papermaking industry. It is treated by alkali recovery, in which evaporation is a key process. The experimental results show that the vapor-liquid-solid three-phase boiling heat transfer coefficient is enhanced by 20%～40% than that of vapor-liquid two-phase boiling flow, also, the novel evaporator exhibits an excellent function of fouling prevention.展开更多
文摘Organometal halide perovskite based solar cells have emerged as one of the most promising candidates for low-cost and high-efficiency solar cell technologies. Here a Vapor Transfer Method （VTM） is used to fabricate high quality perovskite thin films in a balanced vacuum capsule. By adjusting the reaction tem- perature, CH_3NHl_3 saturated vapor which then reacts with Pbl_2 films can be controlled and the formation process of CH_3NH_3Pbl_3 perovskite films can be further influenced. Prepared perovskite films which ex- hibit pure phase, smooth surface and high crystallinity are assembled into planar heterojunction inverted solar cells. The whole fabrication process of solar cell devices is organic solution free. Finally, the cham- pion cell achieved power conversion efficiency （PCE） of 13.08% with negligible current-voltage hysteresis under fully open-air conditions. The photovoltaic performance could be further enhanced by optimizing perovskite composition and the device structure.
文摘The phase transitions and the effect on this process of two factors: relative motion and the external influence of the carrier flow (pressure perturbation) are investigated. A mathematical model describing all the stages of the phenomenon is constructed. The model includes mass, momentum and energy balance equations (both for the vapor and for the liquid) or their first integrals.
基金The work was financially supported by the National Natural Science Foundations of China (No.50476083).
文摘A similarity analysis for Marangoni convection induced flow over a vapor-liquid interface due to an imposed temperature gradient was carried out. The analysis assumes that the surface tension varies linearly with temperature but the temperature variation is a power law function of the location. The similarity solutions are presented numerically and the associated transfer characteristics are discussed.
基金Supported by the National Natural Science Foundation of China under contract No.59976038.
文摘Hot-filament chemical vapor deposition ( HFCVD) is a promising method for commercial production of diamond films. Filament performance in heat transfer and hydrogen decomposition in reactive environment was investigated. Power consumption by the filament in vacuum, helium and 2% CH4/H2 was experimentally determined in temperature range 1300℃-2200℃. Filament heat transfer mechanism in C-H reactive environment was calculated and analyzed. The result shows that due to surface carburization and slight carbon deposition, radiation in stead of hydrogen dissociation, becomes the largest contributor to power consumption. Filament-surface dissociation of H2 was observed at temperatures below 1873K, demonstrating the feasibility of diamond growth at low filament temperatures. The effective activation energies of hydrogen dissociation on several clean refractory flaments were derived from power consumption data in literatures. They are all lower than that of thermal dissociation of hydrogen revealing the nature of catalytic dissociation of hydrogen on filament surface. Observation of substrate temperature suggested a weaker role of atomic hydrogen recombination in heating substrates in C-H environment than in pure hydrogen.
文摘It is known from the New Energy and Industry Technology Development Organization (NEDO) roam map Japan, 2017 that the polymer electrolyte fuel cell (PEFC) power generation system is required to operate at 100°C for application of mobility usage from 2020 to 2025. This study aims to clarify the effect of separator thickness on the distribution of the temperature of reaction surface (T<sub>react</sub>) at the initial temperature of cell (T<sub>ini</sub>) with flow rate, relative humidity (RH) of supply gases as well as RH of air surrounding cell of PEFC. The distribution of T<sub>react</sub> is estimated by means of the heat transfer model considering the H<sub>2</sub>O vapor transfer proposed by the authors. The relationship between the standard deviation of T<sub>react</sub>-T<sub>ini</sub> and total voltage obtained in the experiment is also investigated. We can know the effect of the flow rate of supply gas as well as RH of air surrounding cell of PEFC on the distribution of T<sub>react</sub>-T<sub>ini</sub> is not significant. It is observed the wider distribution of T<sub>react</sub>-T<sub>ini</sub> provides the reduction in power generation performance irrespective of separator thickness. In the case of separator thickness of 1.0 mm, the standard deviation of T<sub>react</sub>-T<sub>ini</sub> has smaller distribution range and the total voltage shows a larger variation compared to the other cases.
基金supported by the National Natural Science Foundation of China(No.51175374)the Natural Science Foundation of Tianjin(No.16JCZDJC38700)
文摘This paper puts forward a new method to achieve flux cored wire TIG welding and uses high-speed photography to analyze the droplet transfer behavior and forces acting on the droplet. The droplet transfer forms include bridging transfer, slag column guided transfer, and non-contact transfer; each of these forms may be observed as the melting position of the welding wire changes. The important role of surface tension in the process of droplet transfer is proposed using static force balance theory and pinch instability theory. The phenomenon of droplet backward swing during welding process could be attributed to the vapor recoil force produced by vapors from the droplet. The welding experiments show that the proposed welding process is stable and that the weld quality produced is good.
文摘A novel vapor-liquid-solid circulating fluidized bed evaporator, meaning for enhancing heat transfer and preventing fouling, is applied to wheat straw black liquor, which is the primary pollutant in China’s papermaking industry. It is treated by alkali recovery, in which evaporation is a key process. The experimental results show that the vapor-liquid-solid three-phase boiling heat transfer coefficient is enhanced by 20%～40% than that of vapor-liquid two-phase boiling flow, also, the novel evaporator exhibits an excellent function of fouling prevention.
