Structural strengthening of the nano porous silica films has been reported. The films were prepared with a base/acid two-step catalyzed TEOS-based sol-gel processing and dip-coating, and then baked in the mixed gas of...Structural strengthening of the nano porous silica films has been reported. The films were prepared with a base/acid two-step catalyzed TEOS-based sol-gel processing and dip-coating, and then baked in the mixed gas of ammonia and water vapor. The silica films were characterized with TEM, AFM, FTIR, spectrophotometer, ellipsometer, and abrasion test, respectively. The experimental results have shown that the films have a nanostructure with a low refractive index and can form an excellent scratch-resistant broadband anti-reflectance. The two-step catalysis noticeably strengthens the films, and the mixed gas treatment further improves mechanical strength of the silica network. Finally the strengthening mechanism has been discussed.展开更多
Surface segregation is studied via the evolution of reflection high-energy electron diffraction （RHEED） patterns under different values of As4 BEP for InGaAs films. When the As4 BEP is set to be zero, the RHEED patt...Surface segregation is studied via the evolution of reflection high-energy electron diffraction （RHEED） patterns under different values of As4 BEP for InGaAs films. When the As4 BEP is set to be zero, the RHEED pattern keeps a 4x3/（nx3） structure with increasing temperature, and surface segregation takes place until 470 ℃ The RHEED pattern develops into a metal-rich （4x2） structure as temperature increases to 495℃. The reason for this is that surface segregation makes the In inside the InGaAs film climb to its surface. With the temperature increasing up to 515℃, the RHEED pattern turns into a GaAs（2x4） structure due to In desorption. While the As4 BEP comes up to a specific value （1.33 x 10-4 Pa-1.33 x 10-3 Pa）, the surface temperature can delay the segregation and desorption. We find that As4 BEP has a big influence on surface desorption, while surface segregation is more strongly dependent on temperature than surface desorption.展开更多
This paper investigates the issues on acoustic energy reflection of flexible film bulk acoustic resonators(FBARs). The flexible FBAR was fabricated with an air cavity in the polymer substrate, which endowed the resona...This paper investigates the issues on acoustic energy reflection of flexible film bulk acoustic resonators(FBARs). The flexible FBAR was fabricated with an air cavity in the polymer substrate, which endowed the resonator with efficient acoustic reflection and high electrical performance. The acoustic wave propagation and reflection in FBAR were first analyzed by Mason model, and then flexible FBARs of 2.66 GHz series resonance in different configurations were fabricated. To validate efficient acoustic reflection of flexible resonators, FBARs were transferred onto different polymer substrates without air cavities. Experimental results indicate that efficient acoustic reflection can be efficiently predicted by Mason model. Flexible FBARs with air cavities exhibit a higher figure of merit(FOM). Our demonstration provides a feasible solution to flexible MEMS devices with highly efficient acoustic reflection(i.e. energy preserving) and free-moving cavities, achieving both high flexibility and high electrical performance.展开更多
Materials with a low thermal emittance surface have been used for many years to create reflective insulations that reduce the rate of heat flow across building envelopes. Reflective insulation technology is now being ...Materials with a low thermal emittance surface have been used for many years to create reflective insulations that reduce the rate of heat flow across building envelopes. Reflective insulation technology is now being combined with other energy conserving technologies to optimize overall thermal performance. The basis for the performance of reflective insulations and radiant barriers will be discussed along with the combination of these materials with cellular plastic or mineral fiber insulations to form hybrid insulation assemblies. Calculations of thermal resistance for enclosed reflective air spaces and current field data from Southeast Asia will be presented. These data show that reductions in heat transfer across the building enclosure can be effectively reduced by the use of enclosed reflective air spaces and attic radiant barriers. Reflective technology increases the overall thermal resistance of the building enclosure when used to insulate poured concrete structures.展开更多
Structure and properties of anti-reflection thin films of spherical silicon solar cells were investigated and discussed. Conversion efficiencies of spherical Si solar cells coated with F-doped SnO2 anti-reflection fil...Structure and properties of anti-reflection thin films of spherical silicon solar cells were investigated and discussed. Conversion efficiencies of spherical Si solar cells coated with F-doped SnO2 anti-reflection films were improved by annealing. Optical absorption and fluorescence of the solar cells increased after annealing. Lattice constants of F-doped SnO2 anti-reflection layers, which were investigated by X-ray diffraction, decreased after annealing. A mechanism of atomic diffusion of F in SnO2 was discussed. The present work indicated a guideline for spherical silicon solar cells with higher efficiencies.展开更多
Electropulsing induced phase transformation and crystal orientation change and their effects on electrical conductivity, THz reflection and surface roughness of thin-films of Al<sub>2</sub>O<sub>3<...Electropulsing induced phase transformation and crystal orientation change and their effects on electrical conductivity, THz reflection and surface roughness of thin-films of Al<sub>2</sub>O<sub>3</sub> (2 wt%) doped ZnO were studied using XRD, SEM, AFM and Thz spectroscopy techniques. AZO-2 thin-films showed an effective response in THz spectroscopy under electropulsing. Electropulsing induced circular preferred crystal orientation changes and phase transformations were observed. The preferred crystal orientation changes accompanying decrease in stress and the secondary phase precipitation favored enhancing conductivity and THz reflection of the AZO-2 thin-films. After adequate electropulsing, both THz reflection and electrical conductivity of the thin-films were enhanced by 22.8% and 6.8%, respectively;meanwhile surface roughness reduced. The property responses of electropulsing are discussed from point view of microstructural change and dislocation dynamics.展开更多
In this Letter,we presented a flexible omnidirectional reflective film made of polymer substrates and multiple alternating layers of two chalcogenide glasses for full-angle CO_(2) laser protection.The structure parame...In this Letter,we presented a flexible omnidirectional reflective film made of polymer substrates and multiple alternating layers of two chalcogenide glasses for full-angle CO_(2) laser protection.The structure parameters of the device were simulated for theoretical prediction of best device structure.The reflector was fabricated by alternate thermal evaporation of two chalcogenide glasses with large refractive index contrast.The reflectivity was greater than 78%at 10.6μm.The flexible reflective film can provide an effective solution for full-angle CO_(2) laser protection of the moving targets,such as laser operators and mobile optical components,with potential applications for wearable laser protective clothing.展开更多
基金the National Natural Science Foundation of China(No:69978017,20133040)Shanghai Key Subject Programme,Chinese Foundation of High Technology(2002AA842052)Shanghai Natural Science Foundation(02ZE14101)as well as Shanghai Nanotechnology Promotion Center(0159um039).
文摘Structural strengthening of the nano porous silica films has been reported. The films were prepared with a base/acid two-step catalyzed TEOS-based sol-gel processing and dip-coating, and then baked in the mixed gas of ammonia and water vapor. The silica films were characterized with TEM, AFM, FTIR, spectrophotometer, ellipsometer, and abrasion test, respectively. The experimental results have shown that the films have a nanostructure with a low refractive index and can form an excellent scratch-resistant broadband anti-reflectance. The two-step catalysis noticeably strengthens the films, and the mixed gas treatment further improves mechanical strength of the silica network. Finally the strengthening mechanism has been discussed.
基金supported by the National Natural Science Foundation of China (Grant No. 60866001)the Special Assistant to High-Level Personnel Research Projects of Guizhou Provincial Party Committee Organization Department of China (Grant No. TZJF- 2008-31)+3 种基金the Support Plan of New Century Excellent Talents of Ministry of Education, China (Grant No. NCET-08-0651)the Doctorate Foundation of the State Education Ministry of China (Grant No. 20105201110003)the Special Governor Fund of Outstanding Professionals in Science and Technology and Education of Guizhou Province, China (Grant No. 2009114)the Doctoral Foundation Projects of Guizhou College of Finance and Economics in 2010
文摘Surface segregation is studied via the evolution of reflection high-energy electron diffraction （RHEED） patterns under different values of As4 BEP for InGaAs films. When the As4 BEP is set to be zero, the RHEED pattern keeps a 4x3/（nx3） structure with increasing temperature, and surface segregation takes place until 470 ℃ The RHEED pattern develops into a metal-rich （4x2） structure as temperature increases to 495℃. The reason for this is that surface segregation makes the In inside the InGaAs film climb to its surface. With the temperature increasing up to 515℃, the RHEED pattern turns into a GaAs（2x4） structure due to In desorption. While the As4 BEP comes up to a specific value （1.33 x 10-4 Pa-1.33 x 10-3 Pa）, the surface temperature can delay the segregation and desorption. We find that As4 BEP has a big influence on surface desorption, while surface segregation is more strongly dependent on temperature than surface desorption.
基金supported by National Natural Science Foundation of China(Grant No.51375341)the National High Technology Research and Development Program of China(“863”Program,Grant No.2015AA042603)the 111 Project(Grant No.B07014)
文摘This paper investigates the issues on acoustic energy reflection of flexible film bulk acoustic resonators(FBARs). The flexible FBAR was fabricated with an air cavity in the polymer substrate, which endowed the resonator with efficient acoustic reflection and high electrical performance. The acoustic wave propagation and reflection in FBAR were first analyzed by Mason model, and then flexible FBARs of 2.66 GHz series resonance in different configurations were fabricated. To validate efficient acoustic reflection of flexible resonators, FBARs were transferred onto different polymer substrates without air cavities. Experimental results indicate that efficient acoustic reflection can be efficiently predicted by Mason model. Flexible FBARs with air cavities exhibit a higher figure of merit(FOM). Our demonstration provides a feasible solution to flexible MEMS devices with highly efficient acoustic reflection(i.e. energy preserving) and free-moving cavities, achieving both high flexibility and high electrical performance.
文摘Materials with a low thermal emittance surface have been used for many years to create reflective insulations that reduce the rate of heat flow across building envelopes. Reflective insulation technology is now being combined with other energy conserving technologies to optimize overall thermal performance. The basis for the performance of reflective insulations and radiant barriers will be discussed along with the combination of these materials with cellular plastic or mineral fiber insulations to form hybrid insulation assemblies. Calculations of thermal resistance for enclosed reflective air spaces and current field data from Southeast Asia will be presented. These data show that reductions in heat transfer across the building enclosure can be effectively reduced by the use of enclosed reflective air spaces and attic radiant barriers. Reflective technology increases the overall thermal resistance of the building enclosure when used to insulate poured concrete structures.
文摘Structure and properties of anti-reflection thin films of spherical silicon solar cells were investigated and discussed. Conversion efficiencies of spherical Si solar cells coated with F-doped SnO2 anti-reflection films were improved by annealing. Optical absorption and fluorescence of the solar cells increased after annealing. Lattice constants of F-doped SnO2 anti-reflection layers, which were investigated by X-ray diffraction, decreased after annealing. A mechanism of atomic diffusion of F in SnO2 was discussed. The present work indicated a guideline for spherical silicon solar cells with higher efficiencies.
文摘Electropulsing induced phase transformation and crystal orientation change and their effects on electrical conductivity, THz reflection and surface roughness of thin-films of Al<sub>2</sub>O<sub>3</sub> (2 wt%) doped ZnO were studied using XRD, SEM, AFM and Thz spectroscopy techniques. AZO-2 thin-films showed an effective response in THz spectroscopy under electropulsing. Electropulsing induced circular preferred crystal orientation changes and phase transformations were observed. The preferred crystal orientation changes accompanying decrease in stress and the secondary phase precipitation favored enhancing conductivity and THz reflection of the AZO-2 thin-films. After adequate electropulsing, both THz reflection and electrical conductivity of the thin-films were enhanced by 22.8% and 6.8%, respectively;meanwhile surface roughness reduced. The property responses of electropulsing are discussed from point view of microstructural change and dislocation dynamics.
基金supported by the National Natural Science Foundation of China(No.61875064)。
文摘In this Letter,we presented a flexible omnidirectional reflective film made of polymer substrates and multiple alternating layers of two chalcogenide glasses for full-angle CO_(2) laser protection.The structure parameters of the device were simulated for theoretical prediction of best device structure.The reflector was fabricated by alternate thermal evaporation of two chalcogenide glasses with large refractive index contrast.The reflectivity was greater than 78%at 10.6μm.The flexible reflective film can provide an effective solution for full-angle CO_(2) laser protection of the moving targets,such as laser operators and mobile optical components,with potential applications for wearable laser protective clothing.
