Hydrogen Peroxide vapour is becoming more popular to use as a method of decontamination, particularly for medical equipment and enclosures. It is highly effective in terms of microbiological kill rates and has a varie...Hydrogen Peroxide vapour is becoming more popular to use as a method of decontamination, particularly for medical equipment and enclosures. It is highly effective in terms of microbiological kill rates and has a variety of uses in healthcare. Although it is environmentally acceptable as it spontaneously decomposes into water and oxygen, concentration of hydrogen peroxide in the air needs to be monitored and controlled. A method of calibrating hydrogen peroxide vapor sensors is described which is based on the concentration of hydrogen peroxide in saturated vapour over a solution in water at a defined temperature. The saturated vapour is generated by bubbling dry air into a solution of hydrogen peroxide at a defined concentration and temperature. A vapour at a concentration of 0.7 ppm was produced and used to successfully calibrate a hydrogen peroxide sensor.展开更多
Thermodynamic study was carried out on the reaction EuCl_(3(s))+(v/2)Al_2Cl_(6(g))= EuAl_vCl_((3v)+3(g))byquenching experiments within 6 3 8 ~ 7 6 2 K and 0 . 0 3 ~ 0 . 1 4 MPa . The results suggested that theEuAl_3...Thermodynamic study was carried out on the reaction EuCl_(3(s))+(v/2)Al_2Cl_(6(g))= EuAl_vCl_((3v)+3(g))byquenching experiments within 6 3 8 ~ 7 6 2 K and 0 . 0 3 ~ 0 . 1 4 MPa . The results suggested that theEuAl_3Cl_(12(g)) complex was the predormnant species. The equilibrium constants of the reaction were measured. The reaction enthalpy and entropy derived from the measurements were and展开更多
We describe the microfabrication of ^85Rb vapour cells using a glass-silicon anodic bonding technique and in situ chemical reaction between rubidium chloride and barium azide to produce Rb. Under controlled conditions...We describe the microfabrication of ^85Rb vapour cells using a glass-silicon anodic bonding technique and in situ chemical reaction between rubidium chloride and barium azide to produce Rb. Under controlled conditions, the pure metallic Rb drops and buffer gases were obtained in the cells with a few mm^3 internal volumes during the cell sealing process. At an ambient temperature of 90 ℃ the optical absorption resonance of ^85Rb D1 transition with proper broadening and the corresponding coherent population trapping (CPT) resonance, with a signal contrast of 1.5% and linewidth of about 1.7 kHz, have been detected. The sealing quality and the stability of the cells have also been demonstrated experimentally by using the helium leaking detection and the after-9-month optoelectronics measurement which shows a similar CPT signal as its original status. In addition, the physics package of chip-scale atomic clock (CSAC) based on the cell was realized. The measured frequency stability of the physics package can reach to 2.1 × 10^-10 at one second when the cell was heated to 100 ℃ which proved that the cell has the quality to be used in portable and battery-operated devices.展开更多
The inlet and outlet pressure of the SF6 high voltage circuit-breaker nozzle are of importance in determining the thermal interruption capability of a breaker. Besides, electrode evaporation is inevitable during the a...The inlet and outlet pressure of the SF6 high voltage circuit-breaker nozzle are of importance in determining the thermal interruption capability of a breaker. Besides, electrode evaporation is inevitable during the arcing process, which may affect the SF6 arc behaviour significantly. In this study a numerical investigation on the arc characteristics of a supersonic nozzle is carried out, by considering the influence of the pressure ratio between the inlet and outlet, and the Cu vapour. It is demonstrated that a lower inlet pressure may result in a higher arc temperature, a lower arc voltage and a smaller mach number, and Cu vapour from electrode evaporation may cool the arc significantly.展开更多
The fabrication and performance of 160-nm gate-length metamorphic AlInAs/GaInAs high electron mobility transistors (mHEMTs) grown on GaAs substrate by metal organic chemical vapour deposition (MOCVD) are reported....The fabrication and performance of 160-nm gate-length metamorphic AlInAs/GaInAs high electron mobility transistors (mHEMTs) grown on GaAs substrate by metal organic chemical vapour deposition (MOCVD) are reported. By using a novel combined optical and e-beam photolithography technology, submicron mHEMTs devices have been achieved. The devices exhibit good DC and RF performance. The maximum current density was 817 mA/mm and the maximum transconductance was 828 mS/mm. The non-alloyed Ohmic contact resistance Rc was as low as 0.02 Ω- ram. The unity current gain cut-off frequency (fT) and the maximum oscillation frequency (fmax) were 146 GHz and 189 GHz, respectively. This device has the highest fT yet reported for a 160-nm gate-length HEMTs grown by MOCVD. The output conductance is 28.9 mS/mm, which results in a large voltage gain of 28.6, Also, an input capacitance to gate-drain feedback capacitance ratio, Cgs/Cgd, of 4.3 is obtained in the device.展开更多
This paper reported that the nano-catkin carbon films were prepared on Si substrates by means of electron cyclotron resonance microwave plasma chemical vapour deposition in a hydrogen and methane mixture. The surface ...This paper reported that the nano-catkin carbon films were prepared on Si substrates by means of electron cyclotron resonance microwave plasma chemical vapour deposition in a hydrogen and methane mixture. The surface morphology and the structure of the fabricated films were characterized by using scanning electron microscopes and Raman spectroscopy, respectively. The stable field emission properties with a low threshold field of 5V/μm corresponding to a current density of about 1μA/cm^2 and a current density of 3.2mA/cm^2 at an electric field of 10V/μm were obtained from the carbon film deposited at CH4 concentration of 8%. The mechanism that the threshold field decreased with the increase of the CH4 concentration and the high emission current appeared at the high CH4 concentration was explained by using the Fowler-Nordheim theory.展开更多
This paper describes the evolution of vapour bubbles and its effect on nonlinear ultrasound propagation and temperature rise through tissues for therapeutic ultrasound. An acoustic-thermo coupling algorithm incorporat...This paper describes the evolution of vapour bubbles and its effect on nonlinear ultrasound propagation and temperature rise through tissues for therapeutic ultrasound. An acoustic-thermo coupling algorithm incorporating nonlinearity, diffraction, and temperature-dependent tissue properties, is employed to describe nonlinear ultrasound propagation and thermal effect. Results demonstrate that an obvious migration of peak pressure toward transducer surface is observed while the position of peak temperature changes little in liver tissue before the generation of vapour bubbles, and that the boiling region enlarges towards the surface of transducer in axial direction but increases slowly in radial direction after the generation of vapour bubbles.展开更多
Two strain-state samples of GaN, labelled the strain-relief sample and the quality-improved sample, were grown by hydride vapour phase epitaxy (HVPE), and then characterized by high-resolution X-ray diffraction, pho...Two strain-state samples of GaN, labelled the strain-relief sample and the quality-improved sample, were grown by hydride vapour phase epitaxy (HVPE), and then characterized by high-resolution X-ray diffraction, photoluminescence and optical microscopy. Two strain states of GaN in HVPE, like 3D and 2[) growth modes in metal-organic chemical vapour deposition (MOCVD), provide an effective way to solve the heteroepitaxial problems of both strain relief and quality improvement. The gradual variation metbod (GVM), developed based on the two strain states, is characterized by growth parameters' gradual variation alternating between the strain-relief growth conditions and the quality-improved growth conditions. In GVM, the introduction of the strain-relief amplitude, which is defined by the range from the quality-improved growth conditions to the strain-relief growth conditions, makes the strain-relief control concise and effective. The 300-μm thick bright and crack-free GaN film grown on a two-inch sapphire proves the effectiveness of GVM.展开更多
In this paper we report that the GaN thin film is grown by metal-organic chemical vapour deposition on a sapphire (0001) substrate with double A1N buffer layers. The buffer layer consists of a low-temperature (LT)...In this paper we report that the GaN thin film is grown by metal-organic chemical vapour deposition on a sapphire (0001) substrate with double A1N buffer layers. The buffer layer consists of a low-temperature (LT) A1N layer and a high-temperature (HT) A1N layer that are grown at 600 ℃ and 1000 ℃, respectively. It is observed that the thickness of the LT-A1N layer drastically influences the quality of GaN thin film, and that the optimized 4.25-min-LT-A1N layer minimizes the dislocation density of GaN thin film. The reason for the improved properties is discussed in this paper.展开更多
Water vapour and CO2 fluxes were measured by the eddy-covariance technique above a mixed needle and broad-leaved forest with affiliated meteorological measurements in Changbai Mountain as part of China's FLUX proj...Water vapour and CO2 fluxes were measured by the eddy-covariance technique above a mixed needle and broad-leaved forest with affiliated meteorological measurements in Changbai Mountain as part of China's FLUX projects since late August in 2002. Net water vapour exchange and environmental control over the forest were examined from September 1 to October 31 in 2002. To quantify the seasonal dynamics, the transition period was separated into leafed, leaf falling and leafless stages according to the development of leaf area. The results showed that (a) seasonal variation of water vapour exchange was mainly controlled by net radiation (Rn) which could account for 78.5%, 63.4% and 56.6% for leafed, leaf falling and leafless stages, respectively, while other environmental factors' effects varied evidently; (b) magnitude of water vapour flux decreased remarkably during autumn and daily mean of water vapour exchange was 24.2 mg m-2 s-1 (100%), 14.8 mg m-2 s-1 (61.2%) and 10.3 mg m-2 s-1 (42.6%) for leafed, leaf falling and leafless stage, respectively; and (c) the budget of water vapour exchange during autumn was estimated to be 87.1 kg H2O m-2, with a mean of 1427.2 g H2O d-1' varying markedly from 3104.0 to 227.5 g H2O m-2d-1.展开更多
Soil-water characteristics of Gaomiaozi(GMZ)Ca-bentonite at high suctions(3–287MPa)are measured by vapour equilibrium technique.The soil-water retention curve(SWRC)of samples with the same initial compaction states i...Soil-water characteristics of Gaomiaozi(GMZ)Ca-bentonite at high suctions(3–287MPa)are measured by vapour equilibrium technique.The soil-water retention curve(SWRC)of samples with the same initial compaction states is obtained in drying and wetting process.At high suctions,the hysteresis behaviour is not obvious in relationship between water content and suction,while the opposite holds between degree of saturation and suction.The suction variation can change its water retention behaviour and void ratio.Moreover,changes of void ratio can bring about changes in degree of saturation.Therefore,the total change in degree of saturation includes changes caused by suction and that by void ratio.In the space of degree of saturation and suction,the SWRC at constant void ratio shifts to the direction of higher suctions with decreasing void ratio.However,the relationship between water content and suction is less affected by changes of void ratio.The degree of saturation decreases approximately linearly with increasing void ratio at a constant suction.Moreover,the slope of the line decreases with increasing suction and they show an approximately linear relationship in semi-logarithmical scale.From this linear relationship,the variation of degree of saturation caused by the change in void ratio can be obtained.Correspondingly,SWRC at a constant void ratio can be determined from SWRC at different void ratios.展开更多
The secondary reinforcement,crbon whiskers,may grow on the surface of parent rein- forcement,carbon fibres,by chemical vapour growth from acetylene using Fe salt as catalyzer.The optimal growing temperature is about 1...The secondary reinforcement,crbon whiskers,may grow on the surface of parent rein- forcement,carbon fibres,by chemical vapour growth from acetylene using Fe salt as catalyzer.The optimal growing temperature is about 1000℃,and while the concentra- tion of catalytic solution is appropriate,the carbon whiskers may deposite uniformly and link each other on the parent carbon fibre surface.If the temperature or concentration is too high,the coarse clusters of carbon may deposite on the fibre surface.The mechanism of carbon whisker growth is believed that the carbon atoms in vapour phase dissolve in the Fe salt drops over fibres,then the solid carbon grains precipitate on the fibre surface.展开更多
This paper reports that the intrinsic microcrystalline silicon (μc-Si:H) films are prepared with plasma enhanced chemical vapour deposition from silane/hydrogen mixtures at 200℃ with the aim to increase the depos...This paper reports that the intrinsic microcrystalline silicon (μc-Si:H) films are prepared with plasma enhanced chemical vapour deposition from silane/hydrogen mixtures at 200℃ with the aim to increase the deposition rate. An increase of the deposition rate to 0.88 nm/s is obtained by using a plasma excitation frequency of 75 MHz. This increase is obtained by the combination of a higher deposition pressure, an increased silane concentration, and higher discharge powers. In addition, the transient behaviour, which can decrease the film crystallinity, could be prevented by filling the background gas with H2 prior to plasma ignition, and selecting proper discharging time after silane flow injection. Material prepared under these conditions at a deposition rate of 0.78nm/s maintains higher crystallinity and fine electronic properties. By H-plasma treatment before i-layer deposition, single junction μc-Si:H solar cells with 5.5% efficiency are fabricated.展开更多
Nano-sheet carbon films are prepared on Si wafers by means of quartz-tube microwave plasma chemical vapour deposition (MPCVD) in a gas mixture of hydrogen and methane. The structure of the fabricated films is invest...Nano-sheet carbon films are prepared on Si wafers by means of quartz-tube microwave plasma chemical vapour deposition (MPCVD) in a gas mixture of hydrogen and methane. The structure of the fabricated films is investigated by using field emission scanning electron microscope (FESEM) and Raman spectroscopy. These nano^carbon films are possessed of good field emission (FE) characteristics with a low threshold field of 2.6 V/μm and a high current density of 12.6 mA/cm^2 at an electric field of 9 V/μm. As the FE currents tend to be saturated in a high E region, no simple Fowler-Nordheim (F-N) model is applicable. A modified F N model considering statistic effects of FE tip structures and a space-charge-limited-current (SCLC) effect is applied successfully to explaining the FE data observed at low and high electric fields, respectively.展开更多
This paper reports that an atmospheric pressure dielectric barrier discharge plasma jet, which uses argon or argon + hydrogen peroxide vapour as the working gas, is designed to sterilize the bacillus subtilis. Compar...This paper reports that an atmospheric pressure dielectric barrier discharge plasma jet, which uses argon or argon + hydrogen peroxide vapour as the working gas, is designed to sterilize the bacillus subtilis. Compared with the pure argon plasma, the bacterial inactivation efficacy has a significant improvement when hydrogen peroxide vapour is added into the plasma jet. In order to determine which factors play the main role in inactivation, several methods are used, such as determination of optical emission spectra, high temperature dry air treatment, protein leakage quantification, and scanning electron microscope. These results indicate that the possible inactivation mechanisms are the synergistic actions of chemically active species and charged species.展开更多
The population ratio between the excited states of rubidium in the electrodeless discharge rubidium vapour lamp is calculated according to the near-infrared spectra in the region of 780-1550 nm. By using a 1529 nm las...The population ratio between the excited states of rubidium in the electrodeless discharge rubidium vapour lamp is calculated according to the near-infrared spectra in the region of 780-1550 nm. By using a 1529 nm laser, we measure the density of natural rubidium atoms at the 5P3/2 level. The populations of different excited states are then clarified.展开更多
A procedure for purification of single walled carbon nanotubes(SWNTs) grown by the chemical vapour deposition(CVD) of carbon monooxide has been developed. Based on the result from TGA/DTA of as prepared sample, the ...A procedure for purification of single walled carbon nanotubes(SWNTs) grown by the chemical vapour deposition(CVD) of carbon monooxide has been developed. Based on the result from TGA/DTA of as prepared sample, the oxidation temperature was determined. The process included sonication, oxidation and acid washing steps. The purity and yield after purification were determined and estimated by TEM. Moreover, for the first time, a loop structure for CVD SWNTs has been observed.展开更多
Nano-crystalline diamond films are successfully deposited on silicon substrates via the hot filament chemical vapour deposition process using a CH_(4)/H_(2)/Ar gas mixture.The as-grown films are analysed by using fiel...Nano-crystalline diamond films are successfully deposited on silicon substrates via the hot filament chemical vapour deposition process using a CH_(4)/H_(2)/Ar gas mixture.The as-grown films are analysed by using field emission scanning electron microscopy,micro-Raman spectroscopy and x-ray diffraction.These results show that the films consist of nano-diamond grains with sizes ranging from 10 to 100 nm,and argon is an important element in the formation of nano-crystalline diamonds.展开更多
We chose xylene C_(8)H_(10) as carbon source instead of conventional methane CH_(4) to fabricate a-Si_(1-x)C_(x):H films using plasma-enhanced chemial vapour deposition method.The optical band gap of this material cou...We chose xylene C_(8)H_(10) as carbon source instead of conventional methane CH_(4) to fabricate a-Si_(1-x)C_(x):H films using plasma-enhanced chemial vapour deposition method.The optical band gap of this material could be widened to 3.1eV.And the infrared absorption spectra of our films manifest the existence of aromatic ring in them.Strong blue light emission with a peak wavelength of 490nm has been observed at room temperature.展开更多
Global Positioning System (GPS) has been widely used to estimate the total zenith tropo- spheric delay (ZTD) and precipitable water vapour (PWV) for weather prediction and at- mospheric research as a continuous ...Global Positioning System (GPS) has been widely used to estimate the total zenith tropo- spheric delay (ZTD) and precipitable water vapour (PWV) for weather prediction and at- mospheric research as a continuous and all-weather technique. However, estimations of ZTD and PWV are subject to effects of geophysical models with large uncertainties, particularly imprecise ocean tide models of inland seas in Turkey. In this paper, GPS data from Jan. 1, 2010 to Dec. 31, 2011 are processed using GAMIT/GLOBK at four co-located GPS stations (ISTN, ERZR, SAMN, and IZMI) with Radiosonde from the Turkish Met-Office together with several nearby IGS stations. Four widely used ocean tide models are adopted to evaluate their effects on GPS-estimated PWV, such as IERS recommended FES2004, NAO99b, CSR4.0 and GOT00. Five different strategies are taken without ocean tide model and with four ocean tide models, respectively, which are used to evaluate ocean tide models effects on GPS-estimated PWV through comparing with co-located Radiosonde. Results showed that ocean tide models have greatly affected the estimation of the pre- cipitable water vapour at stations near coasts. The ocean tide model FES2004 gave the best results when compared to Radiosonde with +2.12 mm in PWV at stations near coastline. While other ocean tides models agree each other at millimeter level in PWV. However, at inland GPS stations, ocean tide models have less effect on GPS-estimated PWV.展开更多
文摘Hydrogen Peroxide vapour is becoming more popular to use as a method of decontamination, particularly for medical equipment and enclosures. It is highly effective in terms of microbiological kill rates and has a variety of uses in healthcare. Although it is environmentally acceptable as it spontaneously decomposes into water and oxygen, concentration of hydrogen peroxide in the air needs to be monitored and controlled. A method of calibrating hydrogen peroxide vapor sensors is described which is based on the concentration of hydrogen peroxide in saturated vapour over a solution in water at a defined temperature. The saturated vapour is generated by bubbling dry air into a solution of hydrogen peroxide at a defined concentration and temperature. A vapour at a concentration of 0.7 ppm was produced and used to successfully calibrate a hydrogen peroxide sensor.
文摘Thermodynamic study was carried out on the reaction EuCl_(3(s))+(v/2)Al_2Cl_(6(g))= EuAl_vCl_((3v)+3(g))byquenching experiments within 6 3 8 ~ 7 6 2 K and 0 . 0 3 ~ 0 . 1 4 MPa . The results suggested that theEuAl_3Cl_(12(g)) complex was the predormnant species. The equilibrium constants of the reaction were measured. The reaction enthalpy and entropy derived from the measurements were and
基金Project supported by National 863/973 Plans Projects (Grant Nos. 2006AA04Z361,2006CB932402)NSFC (Grant No. 60971002)
文摘We describe the microfabrication of ^85Rb vapour cells using a glass-silicon anodic bonding technique and in situ chemical reaction between rubidium chloride and barium azide to produce Rb. Under controlled conditions, the pure metallic Rb drops and buffer gases were obtained in the cells with a few mm^3 internal volumes during the cell sealing process. At an ambient temperature of 90 ℃ the optical absorption resonance of ^85Rb D1 transition with proper broadening and the corresponding coherent population trapping (CPT) resonance, with a signal contrast of 1.5% and linewidth of about 1.7 kHz, have been detected. The sealing quality and the stability of the cells have also been demonstrated experimentally by using the helium leaking detection and the after-9-month optoelectronics measurement which shows a similar CPT signal as its original status. In addition, the physics package of chip-scale atomic clock (CSAC) based on the cell was realized. The measured frequency stability of the physics package can reach to 2.1 × 10^-10 at one second when the cell was heated to 100 ℃ which proved that the cell has the quality to be used in portable and battery-operated devices.
基金supported by the Program for New Century Excellent Talents in University of China(NCET-06-0830)
文摘The inlet and outlet pressure of the SF6 high voltage circuit-breaker nozzle are of importance in determining the thermal interruption capability of a breaker. Besides, electrode evaporation is inevitable during the arcing process, which may affect the SF6 arc behaviour significantly. In this study a numerical investigation on the arc characteristics of a supersonic nozzle is carried out, by considering the influence of the pressure ratio between the inlet and outlet, and the Cu vapour. It is demonstrated that a lower inlet pressure may result in a higher arc temperature, a lower arc voltage and a smaller mach number, and Cu vapour from electrode evaporation may cool the arc significantly.
基金Project supported by CERG Grant (615506) from the Research Grants Council of Hong Kong Special Administrative Region of China and Intel CorporationScience and Technology Plan of the Education Bureau of Guangxi Zhuang Autonomous Region of China (Grant No. 200911MS93)
文摘The fabrication and performance of 160-nm gate-length metamorphic AlInAs/GaInAs high electron mobility transistors (mHEMTs) grown on GaAs substrate by metal organic chemical vapour deposition (MOCVD) are reported. By using a novel combined optical and e-beam photolithography technology, submicron mHEMTs devices have been achieved. The devices exhibit good DC and RF performance. The maximum current density was 817 mA/mm and the maximum transconductance was 828 mS/mm. The non-alloyed Ohmic contact resistance Rc was as low as 0.02 Ω- ram. The unity current gain cut-off frequency (fT) and the maximum oscillation frequency (fmax) were 146 GHz and 189 GHz, respectively. This device has the highest fT yet reported for a 160-nm gate-length HEMTs grown by MOCVD. The output conductance is 28.9 mS/mm, which results in a large voltage gain of 28.6, Also, an input capacitance to gate-drain feedback capacitance ratio, Cgs/Cgd, of 4.3 is obtained in the device.
文摘This paper reported that the nano-catkin carbon films were prepared on Si substrates by means of electron cyclotron resonance microwave plasma chemical vapour deposition in a hydrogen and methane mixture. The surface morphology and the structure of the fabricated films were characterized by using scanning electron microscopes and Raman spectroscopy, respectively. The stable field emission properties with a low threshold field of 5V/μm corresponding to a current density of about 1μA/cm^2 and a current density of 3.2mA/cm^2 at an electric field of 10V/μm were obtained from the carbon film deposited at CH4 concentration of 8%. The mechanism that the threshold field decreased with the increase of the CH4 concentration and the high emission current appeared at the high CH4 concentration was explained by using the Fowler-Nordheim theory.
基金supported by Program for New Century Excellent Talents in University of China (06-0450)National Natural Science Foundation of China (Grant No 10474044)
文摘This paper describes the evolution of vapour bubbles and its effect on nonlinear ultrasound propagation and temperature rise through tissues for therapeutic ultrasound. An acoustic-thermo coupling algorithm incorporating nonlinearity, diffraction, and temperature-dependent tissue properties, is employed to describe nonlinear ultrasound propagation and thermal effect. Results demonstrate that an obvious migration of peak pressure toward transducer surface is observed while the position of peak temperature changes little in liver tissue before the generation of vapour bubbles, and that the boiling region enlarges towards the surface of transducer in axial direction but increases slowly in radial direction after the generation of vapour bubbles.
基金Project supported by the National Basic Research Program of China (Grant No.2007CB307004)the National High Technology Research and Development Program of China (Grant No.2009AA03A198)+1 种基金the National Natural Science Foundation of China (Grant Nos.60776041 61076012,60876063,and 60676032)the Science and Technology Fund of Beijing,China (Grant No.Z101103050410003)
文摘Two strain-state samples of GaN, labelled the strain-relief sample and the quality-improved sample, were grown by hydride vapour phase epitaxy (HVPE), and then characterized by high-resolution X-ray diffraction, photoluminescence and optical microscopy. Two strain states of GaN in HVPE, like 3D and 2[) growth modes in metal-organic chemical vapour deposition (MOCVD), provide an effective way to solve the heteroepitaxial problems of both strain relief and quality improvement. The gradual variation metbod (GVM), developed based on the two strain states, is characterized by growth parameters' gradual variation alternating between the strain-relief growth conditions and the quality-improved growth conditions. In GVM, the introduction of the strain-relief amplitude, which is defined by the range from the quality-improved growth conditions to the strain-relief growth conditions, makes the strain-relief control concise and effective. The 300-μm thick bright and crack-free GaN film grown on a two-inch sapphire proves the effectiveness of GVM.
基金Project supported by the National Key Science & Technology Special Project,China(Grant No.2008ZX01002-002)the Fundamental Research Funds for the Central Universities,China(Grant No.JY10000904009)the Major Program and State Key Program of the National Natural Science Foundation of China(Grant Nos.60890191 and 60736033)
文摘In this paper we report that the GaN thin film is grown by metal-organic chemical vapour deposition on a sapphire (0001) substrate with double A1N buffer layers. The buffer layer consists of a low-temperature (LT) A1N layer and a high-temperature (HT) A1N layer that are grown at 600 ℃ and 1000 ℃, respectively. It is observed that the thickness of the LT-A1N layer drastically influences the quality of GaN thin film, and that the optimized 4.25-min-LT-A1N layer minimizes the dislocation density of GaN thin film. The reason for the improved properties is discussed in this paper.
基金Knowledge Innovation Project of CAS,No.KZCX1-SW-01-01A
文摘Water vapour and CO2 fluxes were measured by the eddy-covariance technique above a mixed needle and broad-leaved forest with affiliated meteorological measurements in Changbai Mountain as part of China's FLUX projects since late August in 2002. Net water vapour exchange and environmental control over the forest were examined from September 1 to October 31 in 2002. To quantify the seasonal dynamics, the transition period was separated into leafed, leaf falling and leafless stages according to the development of leaf area. The results showed that (a) seasonal variation of water vapour exchange was mainly controlled by net radiation (Rn) which could account for 78.5%, 63.4% and 56.6% for leafed, leaf falling and leafless stages, respectively, while other environmental factors' effects varied evidently; (b) magnitude of water vapour flux decreased remarkably during autumn and daily mean of water vapour exchange was 24.2 mg m-2 s-1 (100%), 14.8 mg m-2 s-1 (61.2%) and 10.3 mg m-2 s-1 (42.6%) for leafed, leaf falling and leafless stage, respectively; and (c) the budget of water vapour exchange during autumn was estimated to be 87.1 kg H2O m-2, with a mean of 1427.2 g H2O d-1' varying markedly from 3104.0 to 227.5 g H2O m-2d-1.
基金the National Natural Sciences Foundation of China (No. 41102163)
文摘Soil-water characteristics of Gaomiaozi(GMZ)Ca-bentonite at high suctions(3–287MPa)are measured by vapour equilibrium technique.The soil-water retention curve(SWRC)of samples with the same initial compaction states is obtained in drying and wetting process.At high suctions,the hysteresis behaviour is not obvious in relationship between water content and suction,while the opposite holds between degree of saturation and suction.The suction variation can change its water retention behaviour and void ratio.Moreover,changes of void ratio can bring about changes in degree of saturation.Therefore,the total change in degree of saturation includes changes caused by suction and that by void ratio.In the space of degree of saturation and suction,the SWRC at constant void ratio shifts to the direction of higher suctions with decreasing void ratio.However,the relationship between water content and suction is less affected by changes of void ratio.The degree of saturation decreases approximately linearly with increasing void ratio at a constant suction.Moreover,the slope of the line decreases with increasing suction and they show an approximately linear relationship in semi-logarithmical scale.From this linear relationship,the variation of degree of saturation caused by the change in void ratio can be obtained.Correspondingly,SWRC at a constant void ratio can be determined from SWRC at different void ratios.
文摘The secondary reinforcement,crbon whiskers,may grow on the surface of parent rein- forcement,carbon fibres,by chemical vapour growth from acetylene using Fe salt as catalyzer.The optimal growing temperature is about 1000℃,and while the concentra- tion of catalytic solution is appropriate,the carbon whiskers may deposite uniformly and link each other on the parent carbon fibre surface.If the temperature or concentration is too high,the coarse clusters of carbon may deposite on the fibre surface.The mechanism of carbon whisker growth is believed that the carbon atoms in vapour phase dissolve in the Fe salt drops over fibres,then the solid carbon grains precipitate on the fibre surface.
基金supported by the State Key Development Program for Basic Research of China (Grant No 2006CB202601)Basic Research Project of Henan Province in China (Grant No 072300410140)
文摘This paper reports that the intrinsic microcrystalline silicon (μc-Si:H) films are prepared with plasma enhanced chemical vapour deposition from silane/hydrogen mixtures at 200℃ with the aim to increase the deposition rate. An increase of the deposition rate to 0.88 nm/s is obtained by using a plasma excitation frequency of 75 MHz. This increase is obtained by the combination of a higher deposition pressure, an increased silane concentration, and higher discharge powers. In addition, the transient behaviour, which can decrease the film crystallinity, could be prevented by filling the background gas with H2 prior to plasma ignition, and selecting proper discharging time after silane flow injection. Material prepared under these conditions at a deposition rate of 0.78nm/s maintains higher crystallinity and fine electronic properties. By H-plasma treatment before i-layer deposition, single junction μc-Si:H solar cells with 5.5% efficiency are fabricated.
文摘Nano-sheet carbon films are prepared on Si wafers by means of quartz-tube microwave plasma chemical vapour deposition (MPCVD) in a gas mixture of hydrogen and methane. The structure of the fabricated films is investigated by using field emission scanning electron microscope (FESEM) and Raman spectroscopy. These nano^carbon films are possessed of good field emission (FE) characteristics with a low threshold field of 2.6 V/μm and a high current density of 12.6 mA/cm^2 at an electric field of 9 V/μm. As the FE currents tend to be saturated in a high E region, no simple Fowler-Nordheim (F-N) model is applicable. A modified F N model considering statistic effects of FE tip structures and a space-charge-limited-current (SCLC) effect is applied successfully to explaining the FE data observed at low and high electric fields, respectively.
基金Project supported by the Science Foundation of Hefei Institutes of Physical Science, Chinese Academy of Sciences (Grant No. 085FZ10134)
文摘This paper reports that an atmospheric pressure dielectric barrier discharge plasma jet, which uses argon or argon + hydrogen peroxide vapour as the working gas, is designed to sterilize the bacillus subtilis. Compared with the pure argon plasma, the bacterial inactivation efficacy has a significant improvement when hydrogen peroxide vapour is added into the plasma jet. In order to determine which factors play the main role in inactivation, several methods are used, such as determination of optical emission spectra, high temperature dry air treatment, protein leakage quantification, and scanning electron microscope. These results indicate that the possible inactivation mechanisms are the synergistic actions of chemically active species and charged species.
基金Project supported by the National Natural Science Foundation of China (Grant Nos.10874009 and 11074011)
文摘The population ratio between the excited states of rubidium in the electrodeless discharge rubidium vapour lamp is calculated according to the near-infrared spectra in the region of 780-1550 nm. By using a 1529 nm laser, we measure the density of natural rubidium atoms at the 5P3/2 level. The populations of different excited states are then clarified.
文摘A procedure for purification of single walled carbon nanotubes(SWNTs) grown by the chemical vapour deposition(CVD) of carbon monooxide has been developed. Based on the result from TGA/DTA of as prepared sample, the oxidation temperature was determined. The process included sonication, oxidation and acid washing steps. The purity and yield after purification were determined and estimated by TEM. Moreover, for the first time, a loop structure for CVD SWNTs has been observed.
基金Supported by the National Natural Science Foundation of Beijing under Grant No.2002009.
文摘Nano-crystalline diamond films are successfully deposited on silicon substrates via the hot filament chemical vapour deposition process using a CH_(4)/H_(2)/Ar gas mixture.The as-grown films are analysed by using field emission scanning electron microscopy,micro-Raman spectroscopy and x-ray diffraction.These results show that the films consist of nano-diamond grains with sizes ranging from 10 to 100 nm,and argon is an important element in the formation of nano-crystalline diamonds.
文摘We chose xylene C_(8)H_(10) as carbon source instead of conventional methane CH_(4) to fabricate a-Si_(1-x)C_(x):H films using plasma-enhanced chemial vapour deposition method.The optical band gap of this material could be widened to 3.1eV.And the infrared absorption spectra of our films manifest the existence of aromatic ring in them.Strong blue light emission with a peak wavelength of 490nm has been observed at room temperature.
文摘Global Positioning System (GPS) has been widely used to estimate the total zenith tropo- spheric delay (ZTD) and precipitable water vapour (PWV) for weather prediction and at- mospheric research as a continuous and all-weather technique. However, estimations of ZTD and PWV are subject to effects of geophysical models with large uncertainties, particularly imprecise ocean tide models of inland seas in Turkey. In this paper, GPS data from Jan. 1, 2010 to Dec. 31, 2011 are processed using GAMIT/GLOBK at four co-located GPS stations (ISTN, ERZR, SAMN, and IZMI) with Radiosonde from the Turkish Met-Office together with several nearby IGS stations. Four widely used ocean tide models are adopted to evaluate their effects on GPS-estimated PWV, such as IERS recommended FES2004, NAO99b, CSR4.0 and GOT00. Five different strategies are taken without ocean tide model and with four ocean tide models, respectively, which are used to evaluate ocean tide models effects on GPS-estimated PWV through comparing with co-located Radiosonde. Results showed that ocean tide models have greatly affected the estimation of the pre- cipitable water vapour at stations near coasts. The ocean tide model FES2004 gave the best results when compared to Radiosonde with +2.12 mm in PWV at stations near coastline. While other ocean tides models agree each other at millimeter level in PWV. However, at inland GPS stations, ocean tide models have less effect on GPS-estimated PWV.