Reducing a Pt loading with improved power output and durability is essential to promote the large-scale application of proton exchange membrane fuel cells(PEMFCs).To achieve this goal,constructing optimized structure ...Reducing a Pt loading with improved power output and durability is essential to promote the large-scale application of proton exchange membrane fuel cells(PEMFCs).To achieve this goal,constructing optimized structure of catalyst layers with efficient mass transportation channels plays a vital role.Herein,PEMFCs with order-structured cathodic electrodes were fabricated by depositing Pt nanoparticles by Ebeam onto vertically aligned carbon nanotubes(VACNTs)growth on Al foil via plasma-enhanced chemical vapor deposition.Results demonstrate that the proportion of hydrophilic Pt-deposited region along VACNTs and residual hydrophobic region of VANCTs without Pt strongly influences the cell performance,in particular at high current densities.When Pt nanoparticles deposit on the top depth of around 600 nm on VACNTs with a length of 4.6μm,the cell shows the highest performance,compared with others with various lengths of VACNTs.It delivers a maximum power output of 1.61 W cm^(-2)(H_(2)/O_(2),150 k Pa)and 0.79 W cm^(-2)(H_(2)/Air,150 k Pa)at Pt loading of 50μg cm^(-2),exceeding most of previously reported PEMFCs with Pt loading of<100μg cm^(-2).Even though the Pt loading is down to 30μg cm^(-2)(1.36 W cm^(-2)),the performance is also better than 100μg cm^(-2)(1.24 W cm^(-2))of commercial Pt/C,and presents better stability.This excellent performance is critical attributed to the ordered hydrophobic region providing sufficient mass passages to facilitate the fast water drainage at high current densities.This work gives a new understanding for oxygen reduction reaction occurred in VACNTs-based ordered electrodes,demonstrating the most possibility to achieve a substantial reduction in Pt loading<100μg cm^(-2) without sacrificing in performance.展开更多
In the present study,the effect of injecting air bubble size on the thermal performance of a vertical counter-current shell and coiled tube heat exchanger is experimentally investigated.The experiments were accomplish...In the present study,the effect of injecting air bubble size on the thermal performance of a vertical counter-current shell and coiled tube heat exchanger is experimentally investigated.The experiments were accomplished in a cylindrical shape heat exchanger with a 50 cm height and 15 cm outer diameter.Copper coil with 3.939 m equivalent length and 0.6 cm outer diameter was used to carry the hot fluid(water).Four different cold fluid(shell side)flow rates(Q_(s)=2;4;6 and 8 LPM)Þunder laminar flow conditions(316≤Re≤1223),constant hot(coil side)flow rate fluid rates(Q_(h)=1 LPM),four different injected air flow rates(Q_(a)=0:5;1;1:5 and 2 LPM),invariant temperature difference(ΔT=20°C),and constant bubble’s number(1400)were tested.To demonstrate the effect of bubble size,a sparger with orifice diameters of 0.1,0.8,and 1.5 mm was manufactured and used in the study.The overall heat transfer coefficient(U),NTU,effectiveness,and pressure loss were invested.The experimental results clearly showed that the heat exchanger’s thermal efficiency significantly improved with increasing the shell side flow rate and the injected air flow rate.The maximum improvement in U,NTU,and effectiveness was 153%,153%,and 68%,respectively.The thermal performance of the heat exchanger was shown to be improved with increasing the bubble size.Although the latter finding agrees with recent CFD published results,more studies need to be confirmed.展开更多
Vertical structures of momentum exchange coefficient and sediment concentration are the keys in the research on es- tuarine and coastal suspended sediment transport. Based on the parabolic mixing length distribution p...Vertical structures of momentum exchange coefficient and sediment concentration are the keys in the research on es- tuarine and coastal suspended sediment transport. Based on the parabolic mixing length distribution pattern, the distribu- tion pattern of vertical momentum exchange coefficient which is suitable for estuarine and coastal waters is constructed. A compari^n with steady flow and measured momentum exchange coefficient during one tidal cycle in the Menai Strait of England shows that the result of this pattern is closer to the measured values than those of commonly used Rouse' s and van Rijn's patterns, and the pattern is also suitable for estuarine and coastal waters. Successively, based on the precon- dition that momentum exchange coefficient is equivalent to sediment turbulent diffusion coefficient, and combining with the Diffusion Theory, we obtain the exponential vertical distribution pattern of sediment concentration, which is also suitable for estuafine and coastal waters, Thereby, using measured vertical stratified sediment concentration data of the South and the North Passages of the Yangtze Estuary and Zhoushan archipelago waters for fitting calculation, and comparing the results with those from Rouse's (1938) and Zhang et al. 's (1989) formulas, the results show that the exponential vertical distribution pattern of sediment concentration obtained in the present study not only overcomes the defect of Rouse's formula that the surface sediment concentration will be 0, but also has a holistic higher precision along the vertical lines than those of Rouse's and Zhang et al. 's formulas.展开更多
Heat exchange performance of vertical U-tube heat exchanger was studied with two different borehole fill materials and CFD software. Borehole surface temperature and water temperature distribution were simulated on th...Heat exchange performance of vertical U-tube heat exchanger was studied with two different borehole fill materials and CFD software. Borehole surface temperature and water temperature distribution were simulated on the condition of continuous operation for 8 h in winter with inlet water temperature being 10℃. The results show that there is no obvious difference on heat exchanger performance between the two different borehole fill materials.展开更多
Fe doped Beta zeolite with different Fe contents were prepared by ion exchange by changing the volume or the concentration of a Fe salt solution. For a particular mass of Fe salt precursor, the concentration of the me...Fe doped Beta zeolite with different Fe contents were prepared by ion exchange by changing the volume or the concentration of a Fe salt solution. For a particular mass of Fe salt precursor, the concentration of the metal salt solution during ion exchange influenced the ion exchange capacity of Fe, and resulted in different activities of the Fe-Beta catalyst. Fe-Beta catalysts with the Fe contents of (2.6, 6.3 and 9) wt% were synthesized using different amounts of 0.02 mol/L Fe salt solution. These catalysts were studied by various characterization techniques and their NH3-SCR activities were evaluated. The Fe-Beta catalyst with the Fe content of 6.3 wt% exhibited the highest activity, with a temperature range of 202-616℃ where the NOx conversion was 〉 80%. The Fe content in Beta zeolite did not influence the structure of Beta zeolite and valence state of Fe. Compared with the Fe-Beta catalysts with low Fe content (2.6 wt%), Fe-Beta catalysts with 6.3 wt% Fe content possessed more isolated Fe3. active sites which led to its higher NH3-SCR activity. A high capacity for NH3 and NO adsorption, and a high activity for NO oxidation also contributed to the high NH3-SCR activity of the Fe-Beta catalyst with 6.3 wt%. However, when the Fe content was further increased to 9.0 wt%, the amount of FexOy nanoparticles increased while the amount of isolated Fe3+ active sites was unchanged, which promoted NH3 oxidation and decreased the NH3-SCR activity at high temperature.展开更多
Vertical greening is a new model to broaden urban green space in Nanchang City. Baded on the narration of the concept of vertical greening, all kinds of ways to carry out the vertical greening in Nanchang, as well as ...Vertical greening is a new model to broaden urban green space in Nanchang City. Baded on the narration of the concept of vertical greening, all kinds of ways to carry out the vertical greening in Nanchang, as well as the available patterns, were explored by combining with the natural climatic conditions in Nanchang City, and then the current commonly used vertical greening plant varieties as well as their application value were introduced, which provided a new way of thinking for urban greening of Nanchang City.展开更多
Sediment cores were collected at an upstream site(Jintang) and a downstream site(Neijiang) in summer and winter in the Tuohe River, which is one of the five largest tributaries of the Changjiang(Yangtze) River in Chin...Sediment cores were collected at an upstream site(Jintang) and a downstream site(Neijiang) in summer and winter in the Tuohe River, which is one of the five largest tributaries of the Changjiang(Yangtze) River in China. A sequential leaching procedure was applied to determine the concentrations of the different forms of solid phosphorus, including exchangeable phosphorus(Exc-P) as well as phosphorus associated with iron oxides(Fe-P), with aluminum oxides(Al-P), with apatite(Ca-P) and with the residual fraction(Res-P), as correlated with water content and total organic carbon. The seasonal variations and the vertical distributions of phosphorus species in sediments at both sampling sites demonstrated that: 1) total phosphorus(TP) in summer and winter were ranged between 1 313–2 330, 1 491–2 228 mg/kg in Jintang and 543–2 128, 603–1 175 mg/kg in Neijiang, respectively. It can predicated the pollution of TP in Jintang is serious than that in Neijiang both in summer and winter; 2) total inorganic phosphorus(TIP) was the dominant form of TP; 3) Ca-P was the main chemical forms of TIP in the sediments. Based on the profiles in sediments and bio-available phosphorus data, it revealed that bio-available phosphorus(BAP) represented only a minor portion(0.61%–3.59%) of TP, and the vertical distribution of soluble reactive phosphorus(SRP) in corresponding porewaters was more abundant in the upper layer of the sediment, which suggests that BAP may be converted to non-bioavailable phosphorus in deeper layer of the sediment of this dynamic system.展开更多
Vertical greening is a new pattern of expanding urban green spaces. Based on the concept of vertical greening, several approaches and available patterns were introduced for the vertical greening of urban spaces. Moreo...Vertical greening is a new pattern of expanding urban green spaces. Based on the concept of vertical greening, several approaches and available patterns were introduced for the vertical greening of urban spaces. Moreover, the mostly-applied vertical greening plants in China and their value were given to provide a new thought for urban greening.展开更多
One of the critical challenges that limit broad commercialization of proton exchange membrane fuel cells(PEMFC)is to reduce the usage of Pt while maintaining high power output and sufficient durability.Herein,a novel ...One of the critical challenges that limit broad commercialization of proton exchange membrane fuel cells(PEMFC)is to reduce the usage of Pt while maintaining high power output and sufficient durability.Herein,a novel bifunctional layer consisting of vertically aligned carbon nanotubes(VACNTs)and nanoparticles of Pt-Co catalysts(Pt-Co/VACNTs)is reported for highperformance PEMFCs.Readily prepared by a two-step process,the Pt-Co/VACNTs layer with a hydrophilic catalyst-loaded side and a hydrophobic gas diffusion side enables a PTFE-free electrode structure with fully exposed catalyst active sites and superior gas–water diffusion capability.When tested in a PEMFC,the bi-functional Pt-Co/VACNTs layer with ultralow Pt loading(~65μgcathodecm-2)demonstrates a power density of 19.5 kW gPt cathode-1 at 0.6 V,more than seven times that of a cell with commercial Pt/C catalyst(2.7 kW gPt cathode-1 at 0.6 V)at a loading of 400μgcathodecm-2 tested under similar conditions.This remarkable design of VACNTs-based catalyst with dual functionalities enables much lower Pt loading,faster mass transport,and higher electrochemical performance and stability.Further,the preparation procedure can be easily scaled up for low-cost fabrication and commercialization.展开更多
The parameters of gas exchange and chlorophyl fluorescence in leaves of six rare and endangered species Neolitsea sericea, Cinnamomum japonicum var. cheni , Sinojackia microcarpa, Discocleidion glabrum var. trichocarp...The parameters of gas exchange and chlorophyl fluorescence in leaves of six rare and endangered species Neolitsea sericea, Cinnamomum japonicum var. cheni , Sinojackia microcarpa, Discocleidion glabrum var. trichocarpum, Parrotia sub-aequalis, Cercidiphyl um japonicum were measured in fields. The results showed that there were significant differences in photosynthetic capacity, intrinsic water use effi-ciency (WUEi ), the efficiency of primary conversion of light energy of PSⅡ and its potential activity, the quantum yield of PSⅡ electron transport, and the potential ca-pacity of heat dissipation among the six species. However, there was no significant difference in WUE. The highest values of net photosynthetic rate (Pn), transpiration rate (Tr) and stomatal conductance (gs) occurred in D. glabrum var. trichocarpum and the lowest in S. microcarpa. On the contrary, D. glabrum var. trichocarpum had the lowest WUE, intrinsic water use efficiency (WUEi ) and S. microcarpa had the highest. The results indicated that D. glabrum var. trichocarpum had higher photo-synthetic capacity and poorer WUE, while S. microcarpa had lower photosynthetic capacity and greater WUE. Furthermore, the mean values of maximal fluorescence (Fm), potential efficiency of primary conversion of light energy of PSⅡ (Fv/Fm),ΦPSⅡ, actual efficiency of primary conversion of light energy of PSⅡ (F′v/F′m) and non-photochemical quenching coefficient (NPQ) were the highest in S. micro-carpa, indicating that its PSⅡ had higher capacity of heat dissipation and could prevent photosynthetic apparatus from damage by excessive light energy. Correlation analysis showed that there were significant correlations among photosynthetic physi-ological parameters. However, the initial fluorescence (Fo) was not significantly cor-related with any other parameters. This study also revealed the extremely significant positive correlations between Pn and Tr, gs, apparent quantum yield (AQY), be-tween Tr and gs, between light saturation point (LSP) and AQY, between Fv/Fm and Fm, between ΦPSⅡ and photochemical quenching coefficient (qp), between Tr, gs and LSP, AQY. However, WUEi was significantly negatively correlated with Tr, gs, Pn, LSP and AQY.展开更多
Based on the first linearized Boussincsq equation, the analytical solution of the transient groundwater model, which is used for describing phreatic flow in a semiinfinite aquifer bounded by a linear stream and subjec...Based on the first linearized Boussincsq equation, the analytical solution of the transient groundwater model, which is used for describing phreatic flow in a semiinfinite aquifer bounded by a linear stream and subjected to time-dependent vertical seepage, is derived out by Laplace transform and the convolution integral. According to the mathematical characteristics of the solution, different methods for estimating aquifer parameters are constructed to satisfy different hydrological conditions. Then, tile equation for estimating water exchange between stream and aquifer is proposed, and a recursion equation or estimating the intensity of phreatic evaporation is also proposed. A phreatic aquifer stream system located in Huaibei Plain, Anhui Province, China, is taken as an example to demonstrate tile estimation process of the methods stated herein.展开更多
Fluorine (F-) stands out for its phytotoxic potential, because it accumulates in plants, changes enzymes activity, reduces chlorophyll content and, consequently, affects growth and yield of crop plants. An experiment ...Fluorine (F-) stands out for its phytotoxic potential, because it accumulates in plants, changes enzymes activity, reduces chlorophyll content and, consequently, affects growth and yield of crop plants. An experiment was conducted to evaluate the effects of F- on leaf gas exchange in coffee and sweet orange plants, compared to sensitive (gladiolus) and tolerant (ryegrass) reference species. Plants grown in pots were exposed to F- in a semi-open mist chamber. The experimental design was completely randomized with treatments defined by the combination of plant species and two intensities of exposure to atmospheric F, with nebulization of HF solutions (low = 0.065 mmol·m-3 and high = 0.260 mmol·m-3) in a mist chamber, as well as with non-exposed control samples. CO2 assimilation (A), transpiration (E), stomatal conductance (gs) and chlorophyll fluorescence rates were measured after 27 days of treatment application. The leaf gas exchange variables in ryegrass and orange plants did not vary in response to the increase in atmospheric F, while an increase in gs and E values was observed in gladiolus and coffee plants. A decrease in A and potential quantum efficiency of photosystem II (Fv/Fm) was found for gladiolus plants. On the contrary, an increase of A for coffee plants was associated with the apparent effect previously reported about the loss of leaf stomatal regulation related to the short assessment period of plants in this experiment. Damages caused to the photosynthetic system were reflected in the susceptibility of the evaluated species to the contamination by the element.展开更多
Agroforests are man-made ecosystems in which crops are associated with a main perennial species like Robusta Coffee Agroforests (RCAs), which is counted among the main modes of perennial crops production in Cameroon. ...Agroforests are man-made ecosystems in which crops are associated with a main perennial species like Robusta Coffee Agroforests (RCAs), which is counted among the main modes of perennial crops production in Cameroon. Despite the rich ecosystem services provided, the diversity of Associated Species (AS) found in these RCAs and the structure of the landscapes they form remain little known in Cameroon. The current study aimed to inventory AS and characterize the structure of RCAs in four sites (Ayos, Malantouen, Melong and Nkongsamba) belonging to three robusta coffee production basins in Cameroon. A systematic inventory with dendrometric measurements of the wood AS and coffee trees was carried out on 120 one-hectare plot unit, i.e. 30 plots per site. The results showed that 102 AS belonging to 83 genera and 41 families were identified in these RCAs. The RCAs of Ayos in the dense rainforest zone with bimodal rainfall pattern were the most diverse with 71 species, followed by those of Melong and Nkongsamba with respectively 39 and 33 species respectively in the dense rainforest zone with monomodal rainfall pattern, and Malantouen with 33 species in the high savannahs of the west. Structurally, average coffee tree and AS densities founded ranged from 1208 - 1456 plants/ha and 71 - 214 stems/ha and those of basal area from 7.29 - 17.40 m<sup>2</sup>/ha for coffee trees and 7.97 - 16.14 m<sup>2</sup>/ha for AS in function of site. Basis on the vertical stratification, the proportion of the 3 - 6 m stratum, which is mainly represented by introduced AS, varied from 38% - 62% depending on the site. The results of this study showed that RCAs contribute to the conservation of plant biodiversity, given the specific richness identified in these ecosystems.展开更多
We examined the global biogeography of the Scytodes thoracica group of spitting spiders based on 23 years of sampling at the species level(61 species in the thoracica group and 84 species of Scytodes)using DNA data fr...We examined the global biogeography of the Scytodes thoracica group of spitting spiders based on 23 years of sampling at the species level(61 species in the thoracica group and 84 species of Scytodes)using DNA data from six loci.Our results indicated that the thoracica group initially dispersed from Southeast Asia to East Africa between 46.5 and 33.0 million years ago,and dispersal events intensified between Southeast/South Asia and East/South Africa from the early to late Miocene.The timing of these events indicates that Asian-African faunal exchange of the thoracica group was driven by the Indian monsoon,and the pattern of dispersal suggests that colonialization took root when the Indian monsoon shifted from a North-South direction to an East-West direction from the middle Eocene.展开更多
基金finically supported by the National Natural Science Foundation of China(22075055)the Guangxi Science and Technology Project(AB16380030)the Innovation Project of Guangxi Graduate Education(YCSW2020052)。
文摘Reducing a Pt loading with improved power output and durability is essential to promote the large-scale application of proton exchange membrane fuel cells(PEMFCs).To achieve this goal,constructing optimized structure of catalyst layers with efficient mass transportation channels plays a vital role.Herein,PEMFCs with order-structured cathodic electrodes were fabricated by depositing Pt nanoparticles by Ebeam onto vertically aligned carbon nanotubes(VACNTs)growth on Al foil via plasma-enhanced chemical vapor deposition.Results demonstrate that the proportion of hydrophilic Pt-deposited region along VACNTs and residual hydrophobic region of VANCTs without Pt strongly influences the cell performance,in particular at high current densities.When Pt nanoparticles deposit on the top depth of around 600 nm on VACNTs with a length of 4.6μm,the cell shows the highest performance,compared with others with various lengths of VACNTs.It delivers a maximum power output of 1.61 W cm^(-2)(H_(2)/O_(2),150 k Pa)and 0.79 W cm^(-2)(H_(2)/Air,150 k Pa)at Pt loading of 50μg cm^(-2),exceeding most of previously reported PEMFCs with Pt loading of<100μg cm^(-2).Even though the Pt loading is down to 30μg cm^(-2)(1.36 W cm^(-2)),the performance is also better than 100μg cm^(-2)(1.24 W cm^(-2))of commercial Pt/C,and presents better stability.This excellent performance is critical attributed to the ordered hydrophobic region providing sufficient mass passages to facilitate the fast water drainage at high current densities.This work gives a new understanding for oxygen reduction reaction occurred in VACNTs-based ordered electrodes,demonstrating the most possibility to achieve a substantial reduction in Pt loading<100μg cm^(-2) without sacrificing in performance.
文摘In the present study,the effect of injecting air bubble size on the thermal performance of a vertical counter-current shell and coiled tube heat exchanger is experimentally investigated.The experiments were accomplished in a cylindrical shape heat exchanger with a 50 cm height and 15 cm outer diameter.Copper coil with 3.939 m equivalent length and 0.6 cm outer diameter was used to carry the hot fluid(water).Four different cold fluid(shell side)flow rates(Q_(s)=2;4;6 and 8 LPM)Þunder laminar flow conditions(316≤Re≤1223),constant hot(coil side)flow rate fluid rates(Q_(h)=1 LPM),four different injected air flow rates(Q_(a)=0:5;1;1:5 and 2 LPM),invariant temperature difference(ΔT=20°C),and constant bubble’s number(1400)were tested.To demonstrate the effect of bubble size,a sparger with orifice diameters of 0.1,0.8,and 1.5 mm was manufactured and used in the study.The overall heat transfer coefficient(U),NTU,effectiveness,and pressure loss were invested.The experimental results clearly showed that the heat exchanger’s thermal efficiency significantly improved with increasing the shell side flow rate and the injected air flow rate.The maximum improvement in U,NTU,and effectiveness was 153%,153%,and 68%,respectively.The thermal performance of the heat exchanger was shown to be improved with increasing the bubble size.Although the latter finding agrees with recent CFD published results,more studies need to be confirmed.
基金supported by the National Key Basic Research Development Programof China (973 Program, Grant No.2010CB429002)the Foundation of the Key Laboratory of Port, Waterway and Sedimentation Engineering, Min-istry of Communications, PRC (Subject : The Vertical Characteristics of suspended sediment transport in Estuary)the Natural Science Foundation of Jiangsu Province (Grant No.BK2007179)
文摘Vertical structures of momentum exchange coefficient and sediment concentration are the keys in the research on es- tuarine and coastal suspended sediment transport. Based on the parabolic mixing length distribution pattern, the distribu- tion pattern of vertical momentum exchange coefficient which is suitable for estuarine and coastal waters is constructed. A compari^n with steady flow and measured momentum exchange coefficient during one tidal cycle in the Menai Strait of England shows that the result of this pattern is closer to the measured values than those of commonly used Rouse' s and van Rijn's patterns, and the pattern is also suitable for estuarine and coastal waters. Successively, based on the precon- dition that momentum exchange coefficient is equivalent to sediment turbulent diffusion coefficient, and combining with the Diffusion Theory, we obtain the exponential vertical distribution pattern of sediment concentration, which is also suitable for estuafine and coastal waters, Thereby, using measured vertical stratified sediment concentration data of the South and the North Passages of the Yangtze Estuary and Zhoushan archipelago waters for fitting calculation, and comparing the results with those from Rouse's (1938) and Zhang et al. 's (1989) formulas, the results show that the exponential vertical distribution pattern of sediment concentration obtained in the present study not only overcomes the defect of Rouse's formula that the surface sediment concentration will be 0, but also has a holistic higher precision along the vertical lines than those of Rouse's and Zhang et al. 's formulas.
基金Project(CSTC 2004AA7008 2 2) supported by Key Technologies for Development of Small Cities of ChongqingMunicipality
文摘Heat exchange performance of vertical U-tube heat exchanger was studied with two different borehole fill materials and CFD software. Borehole surface temperature and water temperature distribution were simulated on the condition of continuous operation for 8 h in winter with inlet water temperature being 10℃. The results show that there is no obvious difference on heat exchanger performance between the two different borehole fill materials.
基金supported by the National Key Basic Research Program of China (973 Program, 2013CB933201)the National Natural Science Foun-dation of China (21577034, 21333003, 91545103)+1 种基金Science and Technology Commission of Shanghai Municipality (16ZR1407900)Fundamental Research Funds for the Central Universities (WJ1514020)~~
文摘Fe doped Beta zeolite with different Fe contents were prepared by ion exchange by changing the volume or the concentration of a Fe salt solution. For a particular mass of Fe salt precursor, the concentration of the metal salt solution during ion exchange influenced the ion exchange capacity of Fe, and resulted in different activities of the Fe-Beta catalyst. Fe-Beta catalysts with the Fe contents of (2.6, 6.3 and 9) wt% were synthesized using different amounts of 0.02 mol/L Fe salt solution. These catalysts were studied by various characterization techniques and their NH3-SCR activities were evaluated. The Fe-Beta catalyst with the Fe content of 6.3 wt% exhibited the highest activity, with a temperature range of 202-616℃ where the NOx conversion was 〉 80%. The Fe content in Beta zeolite did not influence the structure of Beta zeolite and valence state of Fe. Compared with the Fe-Beta catalysts with low Fe content (2.6 wt%), Fe-Beta catalysts with 6.3 wt% Fe content possessed more isolated Fe3. active sites which led to its higher NH3-SCR activity. A high capacity for NH3 and NO adsorption, and a high activity for NO oxidation also contributed to the high NH3-SCR activity of the Fe-Beta catalyst with 6.3 wt%. However, when the Fe content was further increased to 9.0 wt%, the amount of FexOy nanoparticles increased while the amount of isolated Fe3+ active sites was unchanged, which promoted NH3 oxidation and decreased the NH3-SCR activity at high temperature.
基金Supported by the Planning Program for Arts and Social Sciences of Jiangxi Province(YG2015036&YG2015033)~~
文摘Vertical greening is a new model to broaden urban green space in Nanchang City. Baded on the narration of the concept of vertical greening, all kinds of ways to carry out the vertical greening in Nanchang, as well as the available patterns, were explored by combining with the natural climatic conditions in Nanchang City, and then the current commonly used vertical greening plant varieties as well as their application value were introduced, which provided a new way of thinking for urban greening of Nanchang City.
基金Supported by the National Natural Science Foundation of China(Nos.21773170,U1407113,U1607123)the Yangtze Scholars and Innovative Research Team in University of Ministry of Education of China(No.IRT_17R81)the Sichuan Province Outstanding Youth Leader Fund(No.05ZQ26-4)
文摘Sediment cores were collected at an upstream site(Jintang) and a downstream site(Neijiang) in summer and winter in the Tuohe River, which is one of the five largest tributaries of the Changjiang(Yangtze) River in China. A sequential leaching procedure was applied to determine the concentrations of the different forms of solid phosphorus, including exchangeable phosphorus(Exc-P) as well as phosphorus associated with iron oxides(Fe-P), with aluminum oxides(Al-P), with apatite(Ca-P) and with the residual fraction(Res-P), as correlated with water content and total organic carbon. The seasonal variations and the vertical distributions of phosphorus species in sediments at both sampling sites demonstrated that: 1) total phosphorus(TP) in summer and winter were ranged between 1 313–2 330, 1 491–2 228 mg/kg in Jintang and 543–2 128, 603–1 175 mg/kg in Neijiang, respectively. It can predicated the pollution of TP in Jintang is serious than that in Neijiang both in summer and winter; 2) total inorganic phosphorus(TIP) was the dominant form of TP; 3) Ca-P was the main chemical forms of TIP in the sediments. Based on the profiles in sediments and bio-available phosphorus data, it revealed that bio-available phosphorus(BAP) represented only a minor portion(0.61%–3.59%) of TP, and the vertical distribution of soluble reactive phosphorus(SRP) in corresponding porewaters was more abundant in the upper layer of the sediment, which suggests that BAP may be converted to non-bioavailable phosphorus in deeper layer of the sediment of this dynamic system.
基金Supported by Planning Program of Jiangxi Provincial Artistic and Social Sciences(YG2012121)
文摘Vertical greening is a new pattern of expanding urban green spaces. Based on the concept of vertical greening, several approaches and available patterns were introduced for the vertical greening of urban spaces. Moreover, the mostly-applied vertical greening plants in China and their value were given to provide a new thought for urban greening.
基金supported by the National Natural Science Foundation of China under(No.21878158,2182880,51678291)Jiangsu Natural Science Foundation for Distinguished Young Scholars(No.BK20170043)+3 种基金the National Key R&D Program of China(2018YFB1502903)Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)China Postdoctoral Science Foundation(2019M660112)the Jiangsu Postdoctoral Science Funding Project
文摘One of the critical challenges that limit broad commercialization of proton exchange membrane fuel cells(PEMFC)is to reduce the usage of Pt while maintaining high power output and sufficient durability.Herein,a novel bifunctional layer consisting of vertically aligned carbon nanotubes(VACNTs)and nanoparticles of Pt-Co catalysts(Pt-Co/VACNTs)is reported for highperformance PEMFCs.Readily prepared by a two-step process,the Pt-Co/VACNTs layer with a hydrophilic catalyst-loaded side and a hydrophobic gas diffusion side enables a PTFE-free electrode structure with fully exposed catalyst active sites and superior gas–water diffusion capability.When tested in a PEMFC,the bi-functional Pt-Co/VACNTs layer with ultralow Pt loading(~65μgcathodecm-2)demonstrates a power density of 19.5 kW gPt cathode-1 at 0.6 V,more than seven times that of a cell with commercial Pt/C catalyst(2.7 kW gPt cathode-1 at 0.6 V)at a loading of 400μgcathodecm-2 tested under similar conditions.This remarkable design of VACNTs-based catalyst with dual functionalities enables much lower Pt loading,faster mass transport,and higher electrochemical performance and stability.Further,the preparation procedure can be easily scaled up for low-cost fabrication and commercialization.
基金Supported by Natural Science Foundation of Zhejiang Province(LY13C160007)Special Fund for Graduate Innovative Projects in Jiangxi Province(YC2014-B035)Lin’an Scientific and Technological Program of Zhejiang Province(201411)
文摘The parameters of gas exchange and chlorophyl fluorescence in leaves of six rare and endangered species Neolitsea sericea, Cinnamomum japonicum var. cheni , Sinojackia microcarpa, Discocleidion glabrum var. trichocarpum, Parrotia sub-aequalis, Cercidiphyl um japonicum were measured in fields. The results showed that there were significant differences in photosynthetic capacity, intrinsic water use effi-ciency (WUEi ), the efficiency of primary conversion of light energy of PSⅡ and its potential activity, the quantum yield of PSⅡ electron transport, and the potential ca-pacity of heat dissipation among the six species. However, there was no significant difference in WUE. The highest values of net photosynthetic rate (Pn), transpiration rate (Tr) and stomatal conductance (gs) occurred in D. glabrum var. trichocarpum and the lowest in S. microcarpa. On the contrary, D. glabrum var. trichocarpum had the lowest WUE, intrinsic water use efficiency (WUEi ) and S. microcarpa had the highest. The results indicated that D. glabrum var. trichocarpum had higher photo-synthetic capacity and poorer WUE, while S. microcarpa had lower photosynthetic capacity and greater WUE. Furthermore, the mean values of maximal fluorescence (Fm), potential efficiency of primary conversion of light energy of PSⅡ (Fv/Fm),ΦPSⅡ, actual efficiency of primary conversion of light energy of PSⅡ (F′v/F′m) and non-photochemical quenching coefficient (NPQ) were the highest in S. micro-carpa, indicating that its PSⅡ had higher capacity of heat dissipation and could prevent photosynthetic apparatus from damage by excessive light energy. Correlation analysis showed that there were significant correlations among photosynthetic physi-ological parameters. However, the initial fluorescence (Fo) was not significantly cor-related with any other parameters. This study also revealed the extremely significant positive correlations between Pn and Tr, gs, apparent quantum yield (AQY), be-tween Tr and gs, between light saturation point (LSP) and AQY, between Fv/Fm and Fm, between ΦPSⅡ and photochemical quenching coefficient (qp), between Tr, gs and LSP, AQY. However, WUEi was significantly negatively correlated with Tr, gs, Pn, LSP and AQY.
基金National Natural Science Foundation of China(No.40474065)the National TCM Project in the 11th Five-Year Plan Period of China(No.2006BAB01B01)
文摘Based on the first linearized Boussincsq equation, the analytical solution of the transient groundwater model, which is used for describing phreatic flow in a semiinfinite aquifer bounded by a linear stream and subjected to time-dependent vertical seepage, is derived out by Laplace transform and the convolution integral. According to the mathematical characteristics of the solution, different methods for estimating aquifer parameters are constructed to satisfy different hydrological conditions. Then, tile equation for estimating water exchange between stream and aquifer is proposed, and a recursion equation or estimating the intensity of phreatic evaporation is also proposed. A phreatic aquifer stream system located in Huaibei Plain, Anhui Province, China, is taken as an example to demonstrate tile estimation process of the methods stated herein.
文摘Fluorine (F-) stands out for its phytotoxic potential, because it accumulates in plants, changes enzymes activity, reduces chlorophyll content and, consequently, affects growth and yield of crop plants. An experiment was conducted to evaluate the effects of F- on leaf gas exchange in coffee and sweet orange plants, compared to sensitive (gladiolus) and tolerant (ryegrass) reference species. Plants grown in pots were exposed to F- in a semi-open mist chamber. The experimental design was completely randomized with treatments defined by the combination of plant species and two intensities of exposure to atmospheric F, with nebulization of HF solutions (low = 0.065 mmol·m-3 and high = 0.260 mmol·m-3) in a mist chamber, as well as with non-exposed control samples. CO2 assimilation (A), transpiration (E), stomatal conductance (gs) and chlorophyll fluorescence rates were measured after 27 days of treatment application. The leaf gas exchange variables in ryegrass and orange plants did not vary in response to the increase in atmospheric F, while an increase in gs and E values was observed in gladiolus and coffee plants. A decrease in A and potential quantum efficiency of photosystem II (Fv/Fm) was found for gladiolus plants. On the contrary, an increase of A for coffee plants was associated with the apparent effect previously reported about the loss of leaf stomatal regulation related to the short assessment period of plants in this experiment. Damages caused to the photosynthetic system were reflected in the susceptibility of the evaluated species to the contamination by the element.
文摘Agroforests are man-made ecosystems in which crops are associated with a main perennial species like Robusta Coffee Agroforests (RCAs), which is counted among the main modes of perennial crops production in Cameroon. Despite the rich ecosystem services provided, the diversity of Associated Species (AS) found in these RCAs and the structure of the landscapes they form remain little known in Cameroon. The current study aimed to inventory AS and characterize the structure of RCAs in four sites (Ayos, Malantouen, Melong and Nkongsamba) belonging to three robusta coffee production basins in Cameroon. A systematic inventory with dendrometric measurements of the wood AS and coffee trees was carried out on 120 one-hectare plot unit, i.e. 30 plots per site. The results showed that 102 AS belonging to 83 genera and 41 families were identified in these RCAs. The RCAs of Ayos in the dense rainforest zone with bimodal rainfall pattern were the most diverse with 71 species, followed by those of Melong and Nkongsamba with respectively 39 and 33 species respectively in the dense rainforest zone with monomodal rainfall pattern, and Malantouen with 33 species in the high savannahs of the west. Structurally, average coffee tree and AS densities founded ranged from 1208 - 1456 plants/ha and 71 - 214 stems/ha and those of basal area from 7.29 - 17.40 m<sup>2</sup>/ha for coffee trees and 7.97 - 16.14 m<sup>2</sup>/ha for AS in function of site. Basis on the vertical stratification, the proportion of the 3 - 6 m stratum, which is mainly represented by introduced AS, varied from 38% - 62% depending on the site. The results of this study showed that RCAs contribute to the conservation of plant biodiversity, given the specific richness identified in these ecosystems.
基金supported by the Strategic Priority Research Program of the Chinese Academy of Sciences to S.Q.L.(XDB31000000)National Natural Sciences Foundation of China to Y.F.L.(NSFC-31860602,32170463,31660611)。
文摘We examined the global biogeography of the Scytodes thoracica group of spitting spiders based on 23 years of sampling at the species level(61 species in the thoracica group and 84 species of Scytodes)using DNA data from six loci.Our results indicated that the thoracica group initially dispersed from Southeast Asia to East Africa between 46.5 and 33.0 million years ago,and dispersal events intensified between Southeast/South Asia and East/South Africa from the early to late Miocene.The timing of these events indicates that Asian-African faunal exchange of the thoracica group was driven by the Indian monsoon,and the pattern of dispersal suggests that colonialization took root when the Indian monsoon shifted from a North-South direction to an East-West direction from the middle Eocene.