The coordination reactions of Cu（Ⅱ） and Ni（Ⅱ） with acid alizarine blue B （AABB） in the presence of cetyltrimethylammonium bromide （CTAB） micelle were investigated using the microsurface adsorptionspectral co...The coordination reactions of Cu（Ⅱ） and Ni（Ⅱ） with acid alizarine blue B （AABB） in the presence of cetyltrimethylammonium bromide （CTAB） micelle were investigated using the microsurface adsorptionspectral correction technique （MSASC）. The aggregation of AABB on CTAB followed the Langmuir isothermal adsorption law. The enrichment of AABB on CTAB sensitized the complexation between Cu（Ⅱ） or Ni（Ⅱ）and AABB. The binding ratio of AABB to CTAB was 1：2.5, and monomeric aggregate, AABB2CTAB5, was formed with an adsorption constant of 5.95×10^5 at 20 ℃ or 2.48×10^5 at 40 ℃. In the ternary complexation, the ratio of AABB：Cu and AABB：Ni were 1：1 and 1：2.5, respectively. Two types of aggregates, Cu2.AABB2·CTAB80 and Ni5.AABB2.CTAB80, were formed.展开更多
The present work was done in order to develop and find out suitable conversion methods for coconut husk wastes into value-added products. It is well-known that coconuts husk waste is hydrophobic therefore ethanol with...The present work was done in order to develop and find out suitable conversion methods for coconut husk wastes into value-added products. It is well-known that coconuts husk waste is hydrophobic therefore ethanol with different doses was used as a surfactant to enhance the removal efficiency. Treated samples at different adsorbent amounts, sintering temperatures & sintering time, stirring time, pH, and solution temperatures for color removal of Methylene Blue (MB) & Rhodamine B (RhB) and ammonium concentration were evaluated by using UV-Visible Spectroscopy. At 300°C, results showed complete removal for MB and more than 75% for RhB, whereas removal of ammonium ion reached around 52% when sintering product from husk waste was used. Further investigation was carried out for ammonium ion to understand the desorption kinetic behaviors and isotherm models. Kinetics indicated that desorption of ammonium ion followed pseudo-first order equation. Adsorption thermodynamic parameters such as ΔG, ΔH, and ΔS followed Van’t Hoff plot for adsorption and found to be negative which indicated that the adsorption process for ammonium onto coconut husk was physical, spontaneous and exothermic.展开更多
The 1991 Booker Prize--winning novelist Ben Okri, while traveling in the Deep South after Barack Obama＇s victory in the November 2008 presidential election, wrote that Elvis Presley was a lingering deity in the city ...The 1991 Booker Prize--winning novelist Ben Okri, while traveling in the Deep South after Barack Obama＇s victory in the November 2008 presidential election, wrote that Elvis Presley was a lingering deity in the city of Memphis. The images of Elvis Presley, who earned the sobriquet ＂King of Rock＂ early in his career, and that of B. B. King, the exemplar extraordinaire of the Blues, are ubiquitous in the city of Memphis, which may be regarded as a metonym for the Blues and Rock ＇n Roll. The byline for the city of Memphis is, ＂Home of the Blues, Birthplace of Rock ＇n Roll＂, and this fact announces itself to the visitor as soon as he/she enters the arrivals concourse of the Memphis International Airport. As one proceeds towards the baggage claims area, the images which saturate the walkway create an aura that is redolent of the city＇s vibrant Rock ＇n Roll era. Drawing on Foucault＇s notion of heterotopias, as well as Jakobson＇s work on metonymy, this paper explores the hybrid musical spatiality of the city of Memphis and its environs, as well as its iconic status in the evolution of Rock ＇n Roll which was engendered by the Blues.展开更多
The color reaction of amoxicillin with victoria blue B was studied.A novel visible spectrophotometric method for the determination of amoxicillin has been established.Under pH 8.50～10.5 condition,victoria blue B reac...The color reaction of amoxicillin with victoria blue B was studied.A novel visible spectrophotometric method for the determination of amoxicillin has been established.Under pH 8.50～10.5 condition,victoria blue B reacteds with amoxicillin to form red ion association complex.The maximum absorption wavelength was at 630nm and the apparent molar absorptivity(ε) was 2.67×104 L·mol-1·cm-1 and the linear ranges was 0～5.5 mg·L-1.Amoxicillin obey Beer’s law in definite concentration range.The optimum reaction conditions and the methodological precision were studied simultaneity.The method was simple and rapid and sensitive for the determination of amoxicillin.This method has been applied to the determination of amoxicillin is in the city sell amoxicillin medicament is in point and average recovery at 98.2%～101.0%.展开更多
文摘The coordination reactions of Cu（Ⅱ） and Ni（Ⅱ） with acid alizarine blue B （AABB） in the presence of cetyltrimethylammonium bromide （CTAB） micelle were investigated using the microsurface adsorptionspectral correction technique （MSASC）. The aggregation of AABB on CTAB followed the Langmuir isothermal adsorption law. The enrichment of AABB on CTAB sensitized the complexation between Cu（Ⅱ） or Ni（Ⅱ）and AABB. The binding ratio of AABB to CTAB was 1：2.5, and monomeric aggregate, AABB2CTAB5, was formed with an adsorption constant of 5.95×10^5 at 20 ℃ or 2.48×10^5 at 40 ℃. In the ternary complexation, the ratio of AABB：Cu and AABB：Ni were 1：1 and 1：2.5, respectively. Two types of aggregates, Cu2.AABB2·CTAB80 and Ni5.AABB2.CTAB80, were formed.
文摘The present work was done in order to develop and find out suitable conversion methods for coconut husk wastes into value-added products. It is well-known that coconuts husk waste is hydrophobic therefore ethanol with different doses was used as a surfactant to enhance the removal efficiency. Treated samples at different adsorbent amounts, sintering temperatures & sintering time, stirring time, pH, and solution temperatures for color removal of Methylene Blue (MB) & Rhodamine B (RhB) and ammonium concentration were evaluated by using UV-Visible Spectroscopy. At 300°C, results showed complete removal for MB and more than 75% for RhB, whereas removal of ammonium ion reached around 52% when sintering product from husk waste was used. Further investigation was carried out for ammonium ion to understand the desorption kinetic behaviors and isotherm models. Kinetics indicated that desorption of ammonium ion followed pseudo-first order equation. Adsorption thermodynamic parameters such as ΔG, ΔH, and ΔS followed Van’t Hoff plot for adsorption and found to be negative which indicated that the adsorption process for ammonium onto coconut husk was physical, spontaneous and exothermic.
文摘The 1991 Booker Prize--winning novelist Ben Okri, while traveling in the Deep South after Barack Obama＇s victory in the November 2008 presidential election, wrote that Elvis Presley was a lingering deity in the city of Memphis. The images of Elvis Presley, who earned the sobriquet ＂King of Rock＂ early in his career, and that of B. B. King, the exemplar extraordinaire of the Blues, are ubiquitous in the city of Memphis, which may be regarded as a metonym for the Blues and Rock ＇n Roll. The byline for the city of Memphis is, ＂Home of the Blues, Birthplace of Rock ＇n Roll＂, and this fact announces itself to the visitor as soon as he/she enters the arrivals concourse of the Memphis International Airport. As one proceeds towards the baggage claims area, the images which saturate the walkway create an aura that is redolent of the city＇s vibrant Rock ＇n Roll era. Drawing on Foucault＇s notion of heterotopias, as well as Jakobson＇s work on metonymy, this paper explores the hybrid musical spatiality of the city of Memphis and its environs, as well as its iconic status in the evolution of Rock ＇n Roll which was engendered by the Blues.
文摘The color reaction of amoxicillin with victoria blue B was studied.A novel visible spectrophotometric method for the determination of amoxicillin has been established.Under pH 8.50～10.5 condition,victoria blue B reacteds with amoxicillin to form red ion association complex.The maximum absorption wavelength was at 630nm and the apparent molar absorptivity(ε) was 2.67×104 L·mol-1·cm-1 and the linear ranges was 0～5.5 mg·L-1.Amoxicillin obey Beer’s law in definite concentration range.The optimum reaction conditions and the methodological precision were studied simultaneity.The method was simple and rapid and sensitive for the determination of amoxicillin.This method has been applied to the determination of amoxicillin is in the city sell amoxicillin medicament is in point and average recovery at 98.2%～101.0%.
