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CAEFusion: A New Convolutional Autoencoder-Based Infrared and Visible Light Image Fusion Algorithm
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作者 Chun-Ming Wu Mei-Ling Ren +1 位作者 Jin Lei Zi-Mu Jiang 《Computers, Materials & Continua》 SCIE EI 2024年第8期2857-2872,共16页
To address the issues of incomplete information,blurred details,loss of details,and insufficient contrast in infrared and visible image fusion,an image fusion algorithm based on a convolutional autoencoder is proposed... To address the issues of incomplete information,blurred details,loss of details,and insufficient contrast in infrared and visible image fusion,an image fusion algorithm based on a convolutional autoencoder is proposed.The region attention module is meant to extract the background feature map based on the distinct properties of the background feature map and the detail feature map.A multi-scale convolution attention module is suggested to enhance the communication of feature information.At the same time,the feature transformation module is introduced to learn more robust feature representations,aiming to preserve the integrity of image information.This study uses three available datasets from TNO,FLIR,and NIR to perform thorough quantitative and qualitative trials with five additional algorithms.The methods are assessed based on four indicators:information entropy(EN),standard deviation(SD),spatial frequency(SF),and average gradient(AG).Object detection experiments were done on the M3FD dataset to further verify the algorithm’s performance in comparison with five other algorithms.The algorithm’s accuracy was evaluated using the mean average precision at a threshold of 0.5(mAP@0.5)index.Comprehensive experimental findings show that CAEFusion performs well in subjective visual and objective evaluation criteria and has promising potential in downstream object detection tasks. 展开更多
关键词 Image fusion deep learning auto-encoder(AE) INFRARED visible light
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HY-PC:Enabling Consistent Positioning and Communication Using Visible Light
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作者 Xiangyu Liu Yaoheng Chen +1 位作者 Lei Guo Song Song 《China Communications》 SCIE CSCD 2023年第4期180-194,共15页
Visible light(VL)plays an important role in achieving high-precision positioning and low bit error radio(BER)data communication.However,most VL-based systems can not achieve positioning and communication,simultaneousl... Visible light(VL)plays an important role in achieving high-precision positioning and low bit error radio(BER)data communication.However,most VL-based systems can not achieve positioning and communication,simultaneously.There are two problems:1)the hybrid systems are difficult to extract distinguishable positioning beacon features without affecting communication performance,2)in the hybrid systems,the lost data bits in the inter-frame gap(IFG)are hard to recover,which affects positioning and communication performance.Therefore,in this article,we propose a novel VL-based hybrid positioning and communication system,named HY-PC system,to solve the above problems.First,we propose the robust T-W mapping for recognizing specific Light Emitting Diodes(LEDs),which can provide stable LED recognition accuracy without adding extra beacon data and does not decrease the communication rate.Furthermore,we also propose the novel linear block coding and bit interleaving mechanism,which can recover the lost data bits in the IFG and improve data communication performance.Finally,we use commercial off-the-shelf devices to implement our HY-PC system,extensive experimental results show that our HY-PC system can achieve consistent high-precision positioning and low-BER data communication,simultaneously. 展开更多
关键词 visible light positioning visible light communication T-W Mapping linear block coding bit interleaving
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Channel Capacity and Power Allocation of MIMO Visible Light Communication System 被引量:1
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作者 Shuai Ma Ruixin Yang +5 位作者 Guanjie Zhang Hang Li Wen Cao Linqiong Jia Yanyu Zhang Shiyin Li 《China Communications》 SCIE CSCD 2023年第2期122-138,共17页
In this paper,the channel capacity of the multiple-input multiple-output(MIMO)visible light communication(VLC)system is investigated under the peak,average optical and electrical power constraints.Finding the channel ... In this paper,the channel capacity of the multiple-input multiple-output(MIMO)visible light communication(VLC)system is investigated under the peak,average optical and electrical power constraints.Finding the channel capacity of MIMO VLC is shown to be a mixed integer programming problem.To address this open problem,we propose an inexact gradient projection method to find the channel capacity-achieving discrete input distribution and the channel capacity of MIMO VLC.Also we derive both upper and lower bounds of the capacity of MIMO VLC with the closed-form expressions.Furthermore,by considering practical discrete constellation inputs,we develop the optimal power allocation scheme to maximize transmission rate of MIMO VLC system.Simulation results show that more discrete points are needed to achieve the channel capacity as SNR increases.Both the upper and lower bounds of channel capacity are tight at low SNR region.In addition,comparing the equal power allocation,the proposed power allocation scheme can significantly increase the rate for the low-order modulation inputs. 展开更多
关键词 visible light communication MIMO discrete constellation inputs power allocation
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Magnetically Separable Straw@Fe_(3)O_(4)/Cu_(2)O Composites for Photocatalytic Degradation of Methyl Orange under Visible Light Irradiation
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作者 Wang Jingjing Zhang Yawen 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2023年第5期1003-1009,共7页
Fe_(3)O_(4)and Cu_(2)O were successively immobilized on alkali-treated straw,and the magnetically separable straw@Fe_(3)O_(4)/Cu_(2)O composite was obtained.The straw@Fe_(3)O_(4)/Cu_(2)O was characterized by Fourier t... Fe_(3)O_(4)and Cu_(2)O were successively immobilized on alkali-treated straw,and the magnetically separable straw@Fe_(3)O_(4)/Cu_(2)O composite was obtained.The straw@Fe_(3)O_(4)/Cu_(2)O was characterized by Fourier transform infrared spectroscopy,X-ray diffraction,scanning electron microscopy,X-ray photoelectron spectroscopy and vibrating sample magnetometry,respectively.Photocatalytic performance of the straw@Fe_(3)O_(4)/Cu_(2)O was evaluated by measuring the degradation of methyl orange(MO)under irradiation of visible light.The introduction of Fe3O4 not only endowed the straw@Fe_(3)O_(4)/Cu_(2)O with magnetic separation feature but also significantly enhanced photocatalytic activity because Fe3O4 could prevent recombination of hole-electron pairs.The active species capture experiment showed that holes(h+),hydroxyl(∙OH)and superoxide(∙O2ˉ)radicals all took part in the MO degradation.In addition,the photocatalytic mechanism of straw@Fe_(3)O_(4)/Cu_(2)O was proposed based on the experimental results.After five cycles for the photodegradation of MO,the straw@Fe_(3)O_(4)/Cu_(2)O still displayed good photocatalytic activity,suggesting that the as-prepared composite had great potential for practical use in wastewater treatment. 展开更多
关键词 STRAW Cu_(2)O Fe_(3)O_(4) Photocatalysis visible light
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Dynamic Visible Light Positioning Based on Enhanced Visual Target Tracking
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作者 Xiangyu Liu Jingyu Hao +1 位作者 Lei Guo Song Song 《China Communications》 SCIE CSCD 2023年第10期276-291,共16页
In visible light positioning systems,some scholars have proposed target tracking algorithms to balance the relationship among positioning accuracy,real-time performance,and robustness.However,there are still two probl... In visible light positioning systems,some scholars have proposed target tracking algorithms to balance the relationship among positioning accuracy,real-time performance,and robustness.However,there are still two problems:(1)When the captured LED disappears and the uncertain LED reappears,existing tracking algorithms may recognize the landmark in error;(2)The receiver is not always able to achieve positioning under various moving statuses.In this paper,we propose an enhanced visual target tracking algorithm to solve the above problems.First,we design the lightweight recognition/demodulation mechanism,which combines Kalman filtering with simple image preprocessing to quickly track and accurately demodulate the landmark.Then,we use the Gaussian mixture model and the LED color feature to enable the system to achieve positioning,when the receiver is under various moving statuses.Experimental results show that our system can achieve high-precision dynamic positioning and improve the system’s comprehensive performance. 展开更多
关键词 visible light positioning visual target tracking gaussian mixture model kalman filtering system performance
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Modelling and Performance Analysis of Visible Light Communication System in Industrial Implementations
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作者 Mohammed S.M.Gismalla Asrul I.Azmi +5 位作者 Mohd R.Salim Farabi Iqbal Mohammad F.L.Abdullah Mosab Hamdan Muzaffar Hamzah Abu Sahmah M.Supa’at 《Computers, Materials & Continua》 SCIE EI 2023年第11期2189-2204,共16页
Visible light communication(VLC)has a paramount role in industrial implementations,especially for better energy efficiency,high speed-data rates,and low susceptibility to interference.However,since studies on VLC for ... Visible light communication(VLC)has a paramount role in industrial implementations,especially for better energy efficiency,high speed-data rates,and low susceptibility to interference.However,since studies on VLC for industrial implementations are in scarcity,areas concerning illumination optimisation and communication performances demand further investigation.As such,this paper presents a new modelling of light fixture distribution for a warehouse model to provide acceptable illumination and communication performances.The proposed model was evaluated based on various semi-angles at half power(SAAHP)and different height levels for several parameters,including received power,signal to noise ratio(SNR),and bit error rate(BER).The results revealed improvement in terms of received power and SNR with 30 Mbps data rate.Various modulations were studied to improve the link quality,whereby better average BER values of 5.55×10^(−15) and 1.06×10^(−10) had been achieved with 4 PAM and 8 PPM,respectively.The simulation outcomes are indeed viable for the practical warehouse model. 展开更多
关键词 visible light communication(VLC) industrial applications warehouse model light fixtures bit error rate(BER)
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Optimizing Optical Attocells Positioning of Indoor Visible Light Communication System
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作者 Mohammed S.M.Gismalla Asrul I.Azmi +5 位作者 Mohd R.Salim Farabi Iqbal Mohammad F.L.Abdullah Mosab Hamdan Muzaffar Hamzah Abu Sahmah M.Supa’at 《Computers, Materials & Continua》 SCIE EI 2023年第2期3607-3625,共19页
Visible light communication(VLC),which is a prominent emerging solution that complements the radio frequency(RF)technology,exhibits the potential to meet the demands of fifth-generation(5G)and beyond technologies.The ... Visible light communication(VLC),which is a prominent emerging solution that complements the radio frequency(RF)technology,exhibits the potential to meet the demands of fifth-generation(5G)and beyond technologies.The random movement of mobile terminals in the indoor environment is a challenge in the VLC system.The model of optical attocells has a critical role in the uniform distribution and the quality of communication links in terms of received power and signal-to-noise ratio(SNR).As such,the optical attocells positions were optimized in this study with a developed try and error(TE)algorithm.The optimized optical attocells were examined and compared with previous models.This novel approach had successfully increased minimum received power from−1.29 to−0.225 dBm,along with enhanced SNR performance by 2.06 dB.The bit error rate(BER)was reduced to 4.42×10−8 and 6.63×10−14 by utilizing OOK-NRZ and BPSK modulation techniques,respectively.The optimized attocells positions displayed better uniform distribution,as both received power and SNR performances improved by 0.45 and 0.026,respectively.As the results of the proposed model are optimal,it is suitable for standard office and room model applications. 展开更多
关键词 visible light communication(VLC) optical attocell received power signal-to-noise ratio(SNR) bit error rate(BER) coefficient of variation(CV)
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Characteristic of Line-of-Sight in Infrastructure-to-Vehicle Visible Light Communication Using MIMO Technique
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作者 Adisorn Kaewpukdee Peerapong Uthansakul 《Computers, Materials & Continua》 SCIE EI 2023年第1期1025-1048,共24页
Visible Light Communication(VLC)technology is aggressive research for the next generation of communication.Currently,Radio Frequency(RF)communication has crowed spectrum.An Intelligent Transportation System(ITS)has be... Visible Light Communication(VLC)technology is aggressive research for the next generation of communication.Currently,Radio Frequency(RF)communication has crowed spectrum.An Intelligent Transportation System(ITS)has been improved in the communication network for Vehicle-to-Vehicle(V2 V),Vehicle-to-Infrastructure(V2I),and Infrastructure-to-Vehicle(I2V)by using the visible light spectrum instead of the RF spectrum.This article studies the characterization of Line-of-Sight(LOS)optical performance in an Outdoor Wireless Visible Light Communication(OWVLC)system employing a Multiple-Input Multiple-Output(MIMO)technique for I2V communications in ITS regulations.We design the new configuration of the OWVLC-I2V system,which is an alternative approach to communication for I2V system at nighttime.The results show the Channel Impulse Response(CIR)of the LOS links in visible light communication for I2V system in ITS by investigating the receiver on the vehicle moving along the coverage communication area.Furthermore,the OWVLC-I2V system using the MIMO technique depicts the performance of throughput and Bit Error Rate(BER)vs.vehicle speed while the vehicle passes a street light. 展开更多
关键词 Infrastructure to vehicle communication intelligent transportation system visible light communication channel impulse response
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Visible Light Communication for Vehicular Applications: A Novel Architecture with Proof-of-Concept Prototype
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作者 Yang Yang Fan Zhang +2 位作者 Zhiming Zeng Julian Cheng Caili Guo 《China Communications》 SCIE CSCD 2023年第6期249-259,共11页
When there is an increasing interest in visible light communication(VLC), outdoor vehicle VLC has emerged as a promising candidate technology for future intelligent transportation systems. However, in VLC based vehicu... When there is an increasing interest in visible light communication(VLC), outdoor vehicle VLC has emerged as a promising candidate technology for future intelligent transportation systems. However, in VLC based vehicular applications, several challenges impede successful commercial application of VLC based products. This article first provides a thorough overview of the existing challenges. To overcome these challenges, we propose a novel architecture with tracking and environment sensing ability for practical vehicular applications. Moreover, a proof-ofconcept prototype is implemented to validate the feasibility of the proposed system. Experimental and simulation results show that the proposed VLC system can provide reliable communications with a bit-error rate less than 10-4for vehicles under strong interference lights. Finally, based on the evaluations, we propose some key design issues for future studies in this research area. 展开更多
关键词 environment sensing vehicular communications visible light communications
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Stable yellow light emission from lead-free copper halides single crystals for visible light communication
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作者 Baiqian Wang Yuru Tang +6 位作者 Xin Yang Wensi Cai Ru Li Wen Ma Shuangyi Zhao Chen Chen Zhigang Zang 《Nano Materials Science》 EI CAS CSCD 2023年第1期78-85,共8页
Yellow light-emitting diodes(LEDs) as soft light have attracted abundant attention in lithography room, museum and art gallery. However, the development of efficient yellow LEDs lags behind green and blue LEDs, and th... Yellow light-emitting diodes(LEDs) as soft light have attracted abundant attention in lithography room, museum and art gallery. However, the development of efficient yellow LEDs lags behind green and blue LEDs, and the available perovskites yellow LEDs suffer from the instability. Herein, a pressure-assisted cooling method is proposed to grow lead-free CsCu2I3single crystals, which possess uniform surface morphology and enhanced photoluminescence quantum yield(PLQY) stability, with only 10% PLQY losses after being stored in air after 5000 h.Then, the single crystals used for yellow LEDs without encapsulation exhibit a decent Correlated Color Temperature(CCT) of 4290 K, a Commission Internationale de l’Eclairage(CIE) coordinate of(0.38, 0.41), and an excellent 570-h operating stability under heating temperature of 100°C. Finally, the yellow LEDs facilitate the application in wireless visible light communication(VLC), which show a-3 dB bandwidth of 21.5 MHz and a high achievable data rate of 219.2 Mbps by using orthogonal frequency division multiplexing(OFDM) modulation with adaptive bit loading. The present work not only promotes the development of lead-free single crystals, but also inspires the potential of CsCu2I3in the field of yellow illumination and wireless VLC. 展开更多
关键词 Lead-free copper halides Single crystals Yellow light-emitting diodes visible light communication(VLC)
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Intelligent MRI Room Design Using Visible Light Communication with Range Augmentation
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作者 R.Priyadharsini A.Kunthavai 《Intelligent Automation & Soft Computing》 SCIE 2023年第1期261-279,共19页
Radio waves and strong magneticfields are used by Magnetic Reso-nance Imaging(MRI)scanners to detect tumours,wounds and visualize detailed images of the human body.Wi-Fi and other medical devices placed in the MRI pro... Radio waves and strong magneticfields are used by Magnetic Reso-nance Imaging(MRI)scanners to detect tumours,wounds and visualize detailed images of the human body.Wi-Fi and other medical devices placed in the MRI procedure room produces RF noise in MRI Images.The RF noise is the result of electromagnetic emissions produced by Wi-Fi and other medical devices that interfere with the operation of the MRI scanner.Existing techniques for RF noise mitigation involve RF shielding techniques which induce eddy currents that affect the MRI image quality.RF shielding techniques are complex and lead to RF leak-age.VLC(Visible light Communication)is an emerging and efficient technology to avoid RF interference near MRI scanners.Range augmentation with power conservation of the LED is a big challenge in existing VLC systems.The major objective of the proposed work is to develop an intelligent-MRI room design without RF interference using visible light communication and enhance the distance between VLC transmitter and VLC receiver.In this paper,it is proposed to implement VLC using On-Off keying modulation and enhance distance using large active area photodiodes with Automatic Gain Control Circuit(AGC)using software and hardware.The performance of the proposed intelligent MRI-VLC system is analyzed by calculating Bit Error Rate at an inclined distance of 50 cm away from line of sight of the LED.The Experimental results showed that the maximum distance achieved was 400 cm at Bit Error Rate(BER)of 1.5×10^(-5). 展开更多
关键词 visible light communication intelligent magnetic resonance imaging in VLC BER
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Visible Light and Its Influence on the Embryonic Viability of the Cricket Acheta domesticus
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作者 Matthew J. Ferenz 《Advances in Entomology》 2023年第4期309-324,共16页
During in vitro fertilization, human embryos are incubated without light, and these conditions do not ensure embryo survival. This study explored whether environmental conditions can influence the embryo viability rat... During in vitro fertilization, human embryos are incubated without light, and these conditions do not ensure embryo survival. This study explored whether environmental conditions can influence the embryo viability rates of the house cricket, Acheta domesticus. In particular, the experiment tested what colors of visible light provide the best incubation conditions to ensure cricket embryo viability. The concept was to use house cricket embryos to represent human embryos. Cricket embryos were chosen as their eggs have soft outer membrane casings and resemble human embryos during the first few days after fertilization. During the experiment, the adult crickets laid their eggs into one of six soil-filled boxes called substrates. Each substrate was placed into one of six storage containers filled with adult crickets and lit with a different colored visible light (red, yellow, green, blue, white, or no light). After two days of breeding, the egg-filled substrates were removed from the adult crickets and placed in another storage container of the same color light. After incubation under heat-emitting lamps and under one of six light colors, nymphs were counted after hatching to determine embryo viability. After three trials, the red light provided the significantly highest viability rate, with yellow and no light being comparable seconds. The green, blue, and white lights showed significantly lower viability rates than no visible light. My results raise the speculation that exposing fertilized mammal eggs to visible light colors might have the same effects during the in vitro fertilization process. 展开更多
关键词 EMBRYOLOGY EMBRYO Embryo Viability Embryonic Viability VIABILITY Viability Rate INCUBATION In Vitro fertilization In Vitro Fertilization visible light CRICKET Acheta domesticus
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Photoprotective Ability of Colored Iron Oxides in Tinted Sunscreens against Ultraviolet, Visible Light and Near-Infrared Radiation
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作者 Yohei Tanaka Richard Parker Amaryllis Aganahi 《Optics and Photonics Journal》 2023年第8期199-208,共10页
Solar-induced skin damage continues to pose a problem to human health worldwide, despite the widespread recommendation and use of sunscreens. We have previously reported that solar visible light and near-infrared also... Solar-induced skin damage continues to pose a problem to human health worldwide, despite the widespread recommendation and use of sunscreens. We have previously reported that solar visible light and near-infrared also contribute to skin damage and photoageing. Most commonly recommended sunscreens are only effective throughout the UV spectrum, offering no protection from visible light and near-infrared. To evaluate the enhanced solar-spectrum blocking ability of iron oxides, a double-beam spectrophotometer was used to optically measure the transmission spectra. The spectrophotometer deploys a unique, single monochromatic design to detect wavelength penetration in the range of 240 to 2600 nm. The sample without iron oxide (control) blocked over 80% of ultraviolet-C and ultraviolet-B but did not block ultraviolet-A, visible light, or near-infrared wavelengths. The samples with yellow, and red iron oxide blocked over 90% ultraviolet, but did not block visible light and near-infrared effectively. The sample with black iron oxide blocked visible light, and near-infrared effectively compared with other samples with yellow, blue, and red iron oxide. The sample with red and black iron oxides, and the sample with yellow, blue, red, and black iron oxides blocked ultraviolet through to near-infrared. It can be concluded that dark colored iron oxide combinations are effective at blocking from ultraviolet through to visible light and near-infrared radiation. The results of this study may also suggest that biological colour of human skin and subcutaneous tissues are conserved for comprehensive photoprotection. 展开更多
关键词 Anti-Photoageing Photoimmunosuppression PHOTOPROTECTION SUNSCREEN ULTRAVIOLET visible light NEAR-INFRARED
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Novel Low Viscosity Zinc Oxide, Iron Oxides and Erioglaucine Sunscreen Potential to Protect from Ultraviolet, Visible Light and Near-Infrared Radiation
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作者 Yohei Tanaka Richard Parker +1 位作者 Amaryllis Aganahi Ailen Pedroso 《Optics and Photonics Journal》 2023年第9期217-226,共10页
Despite the widespread recommendation and use of sunscreens and ultraviolet blocking materials, solar-induced skin damage and photoageing continues to pose a problem to human health worldwide. We have previously repor... Despite the widespread recommendation and use of sunscreens and ultraviolet blocking materials, solar-induced skin damage and photoageing continues to pose a problem to human health worldwide. We have previously reported that solar visible light and near-infrared also contribute to skin damage and photo ageing. Most commonly recommended sunscreens are only effective throughout the UV spectrum, offering no protection from visible light and near-infrared. A possible solution could be to augment sunscreens with metal oxides which block visible light and near-infrared radiation. To evaluate the enhanced solar-spectrum blocking ability of novel low viscosity sunscreen containing zinc and iron oxides, a double-beam spectrophotometer was used to optically measure the transmission spectra. The spectrophotometer deploys a unique, single monochromatic design to detect wavelength penetration in the range of 240 to 2600 nm. The Sunscreen base without zinc oxide and iron oxides (control) blocked over 80% of ultraviolet-C and ultraviolet-B but did not block ultraviolet-A, visible light, or near-infrared. The novel low viscosity zinc oxide sample blocked almost over 90% ultraviolet, but did not block visible light and near-infrared sufficiently. However, the samples with the novel low viscosity zinc oxide, iron oxides and erioglaucine blocked almost over 90% of ultraviolet, visible light and near-infrared. It can be concluded that this novel combination of low viscosity zinc oxide, iron oxides and erioglaucine is effective at blocking ultraviolet, visible light and near-infrared radiation. The results of this study imply that sunscreens that provide comprehensive photoprotection from ultraviolet through to near-infrared should be adopted to prevent skin photodamage. 展开更多
关键词 Anti-Photoageing Photoimmunosuppression PHOTOPROTECTION SUNSCREEN ULTRAVIOLET visible light NEAR-INFRARED
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Photoprotective Ability of Sunscreens against Ultraviolet, Visible Light and Near-Infrared Radiation
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作者 Yohei Tanaka 《Optics and Photonics Journal》 2023年第6期140-146,共7页
Despite the widespread prevalence of daily sunscreen usage, solar-induced skin damage continues to occur. We have previously reported that solar visible light and near-infrared, in addition to ultraviolet radiation, p... Despite the widespread prevalence of daily sunscreen usage, solar-induced skin damage continues to occur. We have previously reported that solar visible light and near-infrared, in addition to ultraviolet radiation, perform as aging factors and induce deleterious effects such as photoaging, vasodilation, muscle thinning, skin ptosis, photoimmunosupression and photocarcinogenesis. Despite this, most commonly used sunscreens only block ultraviolet radiation. To evaluate the complete solar-spectrum blocking ability of sunscreens produced by internationally well-known companies, a double-beam spectrophotometer was used to optically measure the transmission spectra. The spectrophotometer utilizes a unique, single monochromatic design covering a wavelength range of 240 to 2600 nm. Sunscreens (thickness, 0.1 mm, SPF50+, PA+++ or ++++) from internationally well-known companies blocked 78.8% - 99.9% of ultraviolet, 33.4% - 99.6% of visible light, and 27.0% - 76.4% of near-infrared. It can be concluded that while most commercially available sunscreens filter ultraviolet radiation, they are not effective at blocking visible light and near-infrared radiation. The results of this study imply that sunscreens that provide comprehensive photoprotection from ultraviolet through to near-infrared should be considered to prevent skin photodamage. 展开更多
关键词 Anti-Photoageing PHOTOPROTECTION SUNSCREEN ULTRAVIOLET visible light NEAR-INFRARED
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Visible light induced photodegradation of organic pollutants on nitrogen and fluorine co-doped TiO_2 photocatalyst 被引量:19
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作者 WANGZheng-peng XUJun CAIWei-min ZHOUBao-xue HEZheng-guang CAIChun-guang HONGXiao-ting 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2005年第1期76-80,共5页
The nitrogen and fluorine co doped TiO 2 polycrystalline powder was synthesized by calcinations of the hydrolysis product of tetra butyl titanate with ammonium fluoride. Nitrogen and fluorine co doping causes the abso... The nitrogen and fluorine co doped TiO 2 polycrystalline powder was synthesized by calcinations of the hydrolysis product of tetra butyl titanate with ammonium fluoride. Nitrogen and fluorine co doping causes the absorption edge of TiO 2 to shift to a lower energy region. The photocatalytic activity of co doped TiO 2 with anatase phases was found to be 2 4 times higher than that of the commercial TiO 2 photocatalyst Degussa P25 for phenol decomposition under visible light irradiation. The co doped TiO 2 powders only contain anatase phases even at 1000℃. Apparently, ammonium fluoride added retarded phase transformation of the TiO 2 powders from anatase to rutile. The substitutional fluorine and interstitial nitrogen atoms in co doped TiO 2 polycrystalline powder were responsible for the vis light response and caused the absorption edge of TiO 2 to shift to a lower energy region. 展开更多
关键词 PHOTOCATALYST visible light nitrogen and fluorine co-doped PHENOL band gap
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Photocatalytic Reduction of Cr^Ⅵ by Natural Sphalerite Suspensions under Visible Light Irradiation 被引量:15
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作者 LI Yan LU Anhuai WANG Changqiu 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2006年第2期267-272,共6页
The photocatalytic reductive capability of a natural semiconducting mineral, sphalerite has been studied for the first time. The sphalerite from the Huangshaping deposit of Hunan Province performed great photoreductiv... The photocatalytic reductive capability of a natural semiconducting mineral, sphalerite has been studied for the first time. The sphalerite from the Huangshaping deposit of Hunan Province performed great photoreductive capability that 91.95% of the Cr^6+ was reduced under 9 h visible light irradiation, higher than the 70.58% under 9.5 h UV light irradiation. The highly reductive ability results from its super negative potential of electrons in the conduction band. Furthermore, Fe substitution for Zn introduces donor states, and the oxidation process of Fe^2+ to Fe^3+ makes it an effective hole-scavenger. Cd and Cu substitute for Zn also reduce the bandgap and help broaden the absorbing edge towards the visible light. These substituting metal ions in natural sphalerite make it a hyper-active photocatalyst and very attractive for solar energy utilization. 展开更多
关键词 natural sphalerite PHOTOREDUCTION Cr^6+ visible light substituting ions bandgap
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Degradation of dyestuff wastewater using visible light in the presence of a novel nano TiO_2 catalyst doped with upconversion luminescence agent 被引量:10
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作者 WANG Jun WEN Fu-yu +7 位作者 ZHANG Zhao-hong ZHANG Xiang-dong PAN Zhi-jun ZHANG Lei WANG Lei XU Liang KANG Ping-li ZHANG Peng 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2005年第5期727-730,共4页
A new upconversion luminescence agent, 40CdF2·60BaF2·0.8ErO3, was synthesized and its fluorescent spectra were determined. This upconversion luminescence agent can emit five upconversion fluorescent peaks sh... A new upconversion luminescence agent, 40CdF2·60BaF2·0.8ErO3, was synthesized and its fluorescent spectra were determined. This upconversion luminescence agent can emit five upconversion fluorescent peaks shown in the fluorescent spectra whose wavelengths are all below 387 nm under the excitation of 488 nm visible light. This upconversion luminescence agent was mixed into nano rutile TiO2 powder by ultrasonic and boiling dispersion and the novel doped nano TiO2 photocatalyst utilizing visible light was firstly prepared. The doped TiO2 powder was charactered by XRD and TEM and its photocatalytic activity was tested through the photocatalytic degradation of methyl orange as a model compound under the visible light irradiation emitted by six three basic color lamps. In order to compare the photocatalytic activities, the same experiment was carried out for undoped TiO2 powder. The degradation ratio of methyl orange in the presence of doped nano TiO2 powder reached 32.5% under visible light irradiation at 20 h which was obviously higher than the corresponding 1.64% in the presence of undoped nano TiO2 powder, which indicate the upconversion luminescence agent prepared as dopant can effectively turn visible lights to ultraviolet lights that are absorbed by nano TiO2 particles to produce the electron-cavity pairs. All the results show that the nano rutile TiO2 powder doped with upconversion luminescence agent is a promising photocatalyst using sunlight for treating the industry dye wastewater in great force. 展开更多
关键词 upconversion luminescence agent nano TiO2 photocatalytic degradation visible light methyl orange
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Synthesis of BiVO_4 nanosheets-graphene composites toward improved visible light photoactivity 被引量:7
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作者 Qianqian Yu Zi-Rong Tang Yi-Jun Xu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2014年第5期564-574,共11页
Two-dimensional (2-D) BiVO4 nanosheets-graphene (GR) composites with different weight addition ratios of GR have been prepared via a facile wet chemistry process. X-ray diffraction (XRD), Raman spectra, X-ray ph... Two-dimensional (2-D) BiVO4 nanosheets-graphene (GR) composites with different weight addition ratios of GR have been prepared via a facile wet chemistry process. X-ray diffraction (XRD), Raman spectra, X-ray photoelectron spectra (XPS), UV-vis diffuse reflectance spectra (DRS), field-emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), nitrogen adsorption-desorption, transient photocurrent response and photoluminescence (PL) spectra were employed to determine the properties of the samples. It is found that BiVO4 nanosheets could pave well on the surface of graphene sheets. BiVO4 nanosheets-GR composites with a proper addition amount of GR exhibited higher photocatalytic activity than bare BiVO4 nanosheets toward liquid-phase degradation of rhodamine B (RhB) and methyl orange (MO) under visible light irradiation. The enhancement of photocatalytic activities of BiVO4 nanosheets-GR composites can be attributed to the effective separation of photoexcited electron-hole pairs. This work not only provides a simple strategy for fabricating specific 2-D semiconductor-2-D GR composites, but also opens a new window of such 2-D semiconductor-2-D GR composites as visible light photocatalysts toward an improved visible light photoactivity in purifying polluted water resources. 展开更多
关键词 GRAPHENE BIVO4 liquid-phase degradation rhodamine B methyl orange visible light
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Photocatalytic degradation of Rhodamine B under visible light with Nd-doped titanium dioxide films 被引量:6
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作者 WU Xiaohong SU Peibo LIU Huiling QI Lili 《Journal of Rare Earths》 SCIE EI CAS CSCD 2009年第5期739-743,共5页
关键词 titanium dioxide visible light doping ion PHOTOCATALYSIS Rhodamine B rare earths
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