Formation of large-and medium-sized Cretaceous volcanic reservoirs in the offshore Bohai Bay Basin,East China

Based on the geological and geophysical data of Mesozoic oil-gas exploration in the sea area of Bohai Bay Basin and the discovered high-yield volcanic oil and gas wells since 2019,this paper methodically summarizes the formation conditions of large-and medium-sized Cretaceous volcanic oil and gas reservoirs in the Bohai Sea.Research shows that the Mesozoic large intermediate-felsic lava and intermediate-felsic composite volcanic edifices in the Bohai Sea are the material basis for the formation of large-scale volcanic reservoirs.The upper subfacies of effusive facies and cryptoexplosive breccia subfacies of volcanic conduit facies of volcanic vent-proximal facies belts are favorable for large-scale volcanic reservoir formation.Two types of efficient reservoirs,characterized by high porosity and medium to low permeability,as well as medium porosity and medium to low permeability,are the core of the formation of large-and medium-sized volcanic reservoirs.The reservoir with high porosity and medium to low permeability is formed by intermediate-felsic vesicular lava or the cryptoexplosive breccia superimposed by intensive dissolution.The reservoir with medium porosity and medium to low permeability is formed by intense tectonism superimposed by fluid dissolution.Weathering and tectonic transformation are main formation mechanisms for large and medium-sized volcanic reservoirs in the study area.The low-source“source-reservoir draping type”is the optimum source-reservoir configuration relationship for large-and medium-sized volcanic reservoirs.There exists favorable volcanic facies,efficient reservoirs and source-reservoir draping configuration relationship on the periphery of Bozhong Sag,and the large intermediate-felsic lava and intermediate-felsic composite volcanic edifices close to strike-slip faults and their branch faults are the main directions of future exploration.

Evaluation of volcanic reservoirs with the "QAPM mineral model" using a genetic algorithm

Gas-bearing volcanic reservoirs have been found in the deep Songliao Basin, China. Choosing proper interpretation parameters for log evaluation is difficult due to complicated mineral compositions and variable mineral contents. Based on the QAPF classification scheme given by IUGS, we propose a method to determine the mineral contents of volcanic rocks using log data and a genetic algorithm. According to the QAPF scheme, minerals in volcanic rocks are divided into five groups： Q（quartz）, A （Alkaline feldspar）, P （plagioclase）, M （mafic） and F （feldspathoid）. We propose a model called QAPM including porosity for the volumetric analysis of reservoirs. The log response equations for density, apparent neutron porosity, transit time, gamma ray and volume photoelectrical cross section index were first established with the mineral parameters obtained from the Schlumberger handbook of log mineral parameters. Then the volumes of the four minerals in the matrix were calculated using the genetic algorithm （GA）. The calculated porosity, based on the interpretation parameters, can be compared with core porosity, and the rock names given in the paper based on QAPF classification according to the four mineral contents are compatible with those from the chemical analysis of the core samples.

Reservoir characteristics,formation mechanisms and petroleum exploration potential of volcanic rocks in China

Characterized by complex lithology and strong heterogeneity, volcanic reservoirs in China developed three reservoir space types： primary pores, secondary pores and fractures. The formation of reservoir space went through the cooling and solidification stage （including blast fragmentation, crystallization differentiation and solidification） and the epidiagenesis stage （including metasomatism, filling, weathering and leaching, formation fluid dissolution and tectonism）. Primary pores were formed at the solidification stage, which laid the foundation for the development and transformation of effective reservoirs. Secondary pores were formed at the epidiagenesis stage, with key factors as weathering and leaching, formation fluid dissolution and tectonism. In China, Mesozoic-Cenozoic volcanic rocks developed in the Songliao Basin and Bohai Bay Basin in the east and Late Paleozoic volcanic rocks developed in the Junggar Basin, Santanghu Basin and Ta- rim Basin in the west. There are primary volcanic reser- voirs and secondary volcanic reservoirs in these volcanic rocks, which have good accumulation conditions and great exploration potential.

Geologic Characteristics of Volcanic Hydrocarbon Reservoirs and Exploration Directions in China

Volcanic rocks are distributed widely in China, which are important exploration targets. By analyzing many discovered volcanic hydrocarbon reservoirs all over the world, the authors summarized the geologic characteristics of the formation of volcanic hydrocarbon reservoirs in China, and gave further exploration directions and advices. （1） There are mainly Carboniferous-Permian, Jurassic-Cretaceous, Paleogene-Neogene volcanic rocks in oil- and gas-bearing basins in China, which are mainly distributed in the Junggar Basin, Songliao Basin, Bohai Bay Basin, etc. There are mainly intermediate rocks and acidic rocks in east China, and intermediate rocks and basic rocks in west China. They primarily develop in intracontinentai rift settings and island arc environments. （2） Porefissure reservoirs are distributed widely in basins, which are volcanic rocks mainly in explosive and effusive facies. （3） Volcanic hydrocarbon reservoirs are chiefly near-source lithostratigraphic hydrocarbon reservoirs, and the oil and gas accumulation is predominantly controlled by lithotypes, faults and structural positions. （4） Deep-seated oil and gas reservoirs in the Songliao Basin and Carboniferous volcanic hydrocarbon reservoirs in the Junggar Basin are potential giant volcanic gas provinces, the volcanic hydrocarbon reservoirs in the Bohai Bay Basin and Santanghu Basin are favorable for oil and gas reserves increase, and volcanic rocks in the Turpan Basin, Sichuan Basin, Tarim Basin have exploration potentiality. （5） The technology series of oil and gas exploration in volcanic rocks have been preliminarily formed.

The effects of temperature and acid number of crude oil on the wettability of acid volcanic reservoir rock from the Hailar Oilfi eld

Wettability of acid volcanic reservoir rock from the Hailar Oilfield, China, was studied with crude oils of different acid numbers generated from an original crude oil with an acid number of 3.05 mg KOH/g. The modifed oils and their resultant acid numbers were： A （2.09 mg KOH/g）, B （0.75 mg KOH/g）, C （0.47 mg KOH/g）, D （0.30 mg KOH/g）, and E （0.18 mg KOH/g）. Contact angles and improved Amott water indexes were measured to study the effects of temperature and acid number on the wettability of the acid volcanic reservoir rock. Experimental results indicated that the wettability was not sensitive to variation in temperature when using the same oil, but the acid number of the crude oil was a key factor in changing the wettability of the rock. The Amott water index, Iw was an exponential function of the acid number, and the Amott water index increased as the acid number decreased （i.e. Amott water index exponentially decreased with the acid number increase）. The Iw value of the core saturated with oil A, with an acid number of 2.09 mg KOH/g, ranged from 0.06 to 0.11, which indicated low water wetness. If the acid number of the oil decreased to 0.18 mg KOH/g, the Iw value increased to 0.95, which indicated strong water wetness. The contact angle decreased from 80~ to 35~ when the aid number decreased from 0.75 to 0.18 mg KOH/g, indicating a change towards more water wet conditions. The oil recovery by spontaneous imbibition of water also increased as the acid number of the oil decreased. As an example, at 80 ~C, the recovery of Oil A with an acid number of 2.09 mg KOH/g was only 7.6%, while Oil E with an acid number of 0.18 mg KOH/g produced 56.4%, i.e. an increase of 48.8%.

Discovery and Significance of High CH_4 Primary Fluid Inclusions in Reservoir Volcanic Rocks of the Songliao Basin,NE China

Comparing compositions of the fluid inclusions in volcanic rocks to the contents and isotopes of the gases in corresponding volcanic reservoirs using microthermometry, Raman microspectroscopy and mass spectrum analysis, we found that： （1） up to 82 mole% methane exists in the primary inclusions hosted in the reservoir volcanic rocks; （2） high CH4 inclusions recognized in the volcanic rocks correspond to CH4-bcaring CO2 reservoirs that are rich in helium and with a high ^3He/^4He ratio and which show reversed order of 813C in alkane; （3） in gas reservoirs of such abiotic methane （〉80%） and a mix of CH4 and CO2, the enclosed content of CH4 in the volcanic inclusions is usually below 42 mole%, and the reversed order of δ^13C in alkane is sometimes irregular in the corresponding gas pools; （4） a glassy inclusion with a homogeneous temperature over 900℃ also contains a small portion of CH4 although predominantly CO2. This affinity between gas pool and content of inclusion in the same volcanic reservoirs demonstrates that magma-originated gases, both CH4 and CO2, have contributed significantly to the corresponding gas pools and that the assumed hydrocarbon budget of the bulk earth might be much larger than conventionally supposed.

Controlling factors of high-quality volcanic reservoirs of Yingcheng Formation in the Songnan gas field

Predicting high-quality volcanic reservoirs is one of the key issues for oil and gas exploration in the Songnan gas field.Core,seismic,and measurement data were used to study the lithologies,facies,reservoir porosity,and reservoir types of the volcanic rocks in the Songnan gas field.The primary controlling factors and characteristics of the high-quality volcanic reservoirs of the Yingcheng Formation in the Songnan gas field were investigated,including the volcanic eruptive stage,edifice,edifice facies,cooling unit,lithology,facies,and diagenesis.Stages with more volatile content can form more high-quality reservoirs.The effusive rhyolite,explosive tuff,and tuff lava that formed in the crater,near-crater,and proximal facies and in the high-volatility cooling units of large acidic-lava volcanic edifices are the most favorable locations for the development of the high-quality reservoirs in the Songnan gas field.Diagenesis dissolution,which is controlled by tectonic action,can increase the size of secondary pores in reservoirs.Studying the controlling factors of the high-quality reservoirs can provide a theoretical basis for the prediction and analysis of high-quality volcanic reservoirs.

Distribution and characteristics of volcanic reservoirs in China

About forty productive oil/gas fields hosted in volcanic reservoirs have been found since 1957 in fourteen basins of China.They can be simply subdivided into two groups,the east and the west.Reservoir volcanic rocks of the east group are predominantly composed of Late Jurassic to Early Cretaceous rhyolite and Tertiary basalt,preferred being considered as rift type volcanics developed in the circum-Pacific tectonic regime.Those of the west are Permo-Carboniferous intermediate/basic volcanic rocks,being island-arc type ones developed in paleo-Asian Ocean tectonic regime.

Facies-controlled volcanic reservoirs of northern Songliao Basin, NE China

Volcanic rocks of the late Mesozoic are very important reservoirs for the commercial natural gases including hydrocarbon, carbon dioxide and rare gases in the northern Songliao Basin. The reservoir volcanic rocks include rhyolite, andesite, Wachyte, basalt and tuff. Facies of the volcanic rocks can be classified into 5 categories and 15 special types. Porosity and permeability of the volcanic reservoirs arc facies-controlled, Commercial reservoirs were commonly found among the following volcanic subfacics： volcanic neck （Ⅰ1）, underground-explosive breccia （Ⅰ3）, pyroclastic-bcaring lava flow （Ⅱ3）, upper effusivc （Ⅲ3） and inner extrusive ones （ Ⅳ1）. The best volcanic reservoirs arc generally evolved in the interbedded explosive and effusivc volcanics. Rhyolites show in general better reservoir features than other types of rocks do.

Methods of identifying gas-bearing reservoirs by logs and applications of volcanic formations

The authors generalized the methods how to identify and evaluate gas zones using logs,and put forward the methods of crossplots and overlays of porosity logs on the identification of volcanic gas-bearing reservoirs in the northern Songliao Basin with good results.This study provides technical clues in deep formations and offers references for other areas to identify oil and gas layers.

Oil Pool in Volcanic Reservoir Discovered in Dagang

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Methane-rich fluid inclusions and their hosting volcanic reservoir rocks of the Songliao Basin, NE China

Methane-rich fluids were recognized to be hosted in the reservoir volcanic rocks as primary inclusions. Samples were collected from core-drillings of volcanic gas reservoirs with reversed δ13C of alkane in the Xujiaweizi depression of the Songliao Basin. The volcanic rocks are rhyolite dominant being enriched in the more incompatible elements like Cs, Rb, Ba, Th, U and Th with relative high LREE, depleted HREE and negative anomalies of Ti and Nb, suggesting a melt involving both in mantle source and crustal assimilation. Primary fluids hosted in the volcanic rocks should have the same provenance with the magma. The authors concluded that the enclosed CH4 in the volcanics are mantle/magma-derived alkane and the reversed δ13C of alkane in the corresponding gas reservoirs is partly resulted from mixture between biogenic and abiogenic gases.

Characteristics,Distribution Patterns,and Classification of Volcanic Reservoirs in the Huanghua Depression,Bohai Bay Basin,China

Identifying volcanic reservoir types and their distribution patterns in volcanic edifices is important for accurate prediction and exploration of hydrocarbon reservoirs.Herein,we analyzed the distribution patterns of different reservoir levels in volcanic edifices,discussed controlling factors,and reclassified reservoir types.This was done using core observations,whole-rock geochemistry,and reservoir physical property analysis,combined with logging,drilling,seismic,and oil-gas test data.Reservoirs can be divided into three classes based on their physical properties.The Mesozoic intermediate and basic rocks formed ClassⅠreservoirs,most lithologies formed ClassⅡreservoirs,and diabase intrusions and tight volcanic rocks formed ClassⅢreservoirs.Reservoirs form in different lithologies in the Huanghua depression due to weathering.Tectonic faults deepen the influence of weathering leading to the formation of reservoirs in tight.Additionally,volcanic rhythms and fractures control the vertical distribution of Cenozoic basaltic reservoirs.Volcanic reservoirs are classified into five types based on the main controlling factors and distribution patterns in volcanic edifices:tectonic-alteration,vesiclefracture,weathered-effusive,weathered-eruptive,and weathered-tectonic types.Among these,the weathered-eruptive type can easily form ClassⅠreservoirs,making it the best target for exploration.Whereas the weathered-tectonic and vesicle-fracture types tend to develop ClassⅡreservoirs and can be potential targets.The new classification takes into account the relationship between reservoir levels and their distribution in volcanic edifices,it is more conducive to igneous reservoir prediction in the Huanghua depression.This study provides a novel idea for the classification and comparative study of igneous reservoirs in petroliferous basins.

Fault Systems and their Control of Deep Gas Accumulations in Xujiaweizi Area

A study of faults and their control of deep gas accumulations has been made on the basis of dividing fault systems in the Xujiaweizi area. The study indicates two sets of fault systems are developed vertically in the Xujiaweizi area, including a lower fault system and an upper fault system. Formed in the period of the Huoshiling Formation to Yingcheng Formation, the lower fault system consists of five fault systems including Xuxi strike-slip extensional fault system, NE-trending extensional fault system, near-EW-trending regulating fault system, Xuzhong strike-slip fault system and Xudong strike-slip fault system. Formed in the period of Qingshankou Formation to Yaojia Formation, the upper fault system was affected mainly by the boundary conditions of the lower fault system, and thus plenty of muiti-directionally distributed dense fault zones were formed in the T2 reflection horizon. The Xuxi fault controlled the formation and distribution of Shahezi coal-measure source rocks, and Xuzhong and Xndong faults controlled the formation and distribution of volcanic reservoirs of Y1 Member and Y3 Member, respectively. In the forming period of the upper fault system, the Xuzhong fault was of successive strong activities and directly connected gas source rock reservoirs and volcanic reservoirs, so it is a strongly-charged direct gas source fault. The volcanic reservoir development zones of good physical properties that may be found near the Xuzhong fault are the favorable target zones for the next exploration of deep gas accumulations in Xujiaweizi area.

Seismic volcanostratigraphy of large, extrusive complexes in continental rift basins of Northeast China：Analysis of general bedding patterns in volcanostratigraphy and their seismic reflection configurations

The aim of this work is to establish volcanic seismic reflection configuration models in the rift basins of Northeast China from a new perspective,the volcanostratigraphic structure.Accordingly,the volcanostratigraphic structure of an outcrop near the Hailaier Rift Basin was analyzed to understand the characteristics and causal factors of physical boundaries.Further,3D seismic reflection data and analysis of deep boreholes in the Songliao Rift Basin were used to establish the relationship between volcanic seismic reflection configurations and volcanostratigraphic structures.These studies suggested that in volcanic successions,physical boundaries coincide with volcanic boundaries,and their distributions are controlled by the stacking patterns of volcanic units.Therefore,volcanic seismic reflection configurations can be interpreted in terms of the stacking patterns of volcanic units.These are also referred to as general bedding patterns in volcanostratigraphy.Furthermore,four typical seismic reflection configurations were identified,namely,the chaotic,the parallel continuous,the hummocky,the multi-mound superimposed and the composite.The corresponding interpretation models comprised single massive unit,vertical,intersectional,lateral multi-mound,and composite stacking patterns.The hummocky and composite reflection configurations with intersectional and composite stacking patterns are the most favorable for the exploration of volcanic reservoirs in rift basins.

Gas accumulation mechanism in Denglouku Formation of Changling fault depression, southern Songliao Basin, China

The Changling gas field is occurs in tight sandstone reservoirs of the Lower Cretaceous Denglouku Formation in the Changling fault depression,southern Songliao Basin,China,which constitutes a new gas-producing area in the depression. Using information on the source-reservoir-cap rock assemblage of the Denglouku Formation,fault activity,and single well burial history of well CS1,together with data on reservoir fluid inclusion and laser Raman spectroscopy,we described the formation of the Changling gas field and determine that this fault depression did not possess suitable conditions for hydrocarbon generation. Coal-derived methane generated from underlying hydrocarbon source rock accumulated in the Lower Cretaceous Yingcheng Formation. At the end of the Late Cretaceous Qingshankou Stage,underwater volcanic eruptions occurred in the northern part of the Changling gas field near Qian'an,resulting in the reactivation of deep faults. Mantle-sourced inorganic CO2 migrated along faults to hydrocarbon gas reservoirs in volcanic rocks of the Yingcheng Formation; Meanwhile,displaced methane( hydrocarbon gas) migrated upward to sand reservoirs of the Denglouku Formation.The methane accumulated and formed secondary gas reservoirs,Therefore fault activity was the main factor controlling the generation of gas reservoirs in the Denglouku Formation. The main accumulation period of the Yingcheng hydrocarbon gas reservoirs was 82 Ma. Whereas gas reservoir formation in the overlying Denglongku Formation was 79 Ma,slightly later than the time of formation of the Yingcheng gas reservoir in CS1 well area.At 79 Ma,the burial depth of the Denglouku Formation was 1 800--2 000 m,the diagenesis is relatively weak and the physical properties of the reservoir are relatively favorable for accumulation. This period is not only at gas generation peak time of three sets of source rock but also at the reactivation of deep faults during the formation of fault-bound depressions,thereby providing favorable conditions for the migration and accumulation of methane.

Mesozoic–Cenozoic Volcanic Cycle and Volcanic Reservoirs in East China

There are widespread Mesozoic–Cenozoic terrestrial volcanic activities in East China,and they produced favorable geologic factors for the volcanic reservoirs.To reveal the spatio-temporal evolution of regional volcanisms and their tectonic setting,we subdivide Mesozoic–Cenozoic volcanic activities into 6 volcanic cycles(Ⅰ–Ⅵ),and summarize the temporal-spatial distribution,rock association and tectonic setting of each cycle.The Cycle I forms a post-orogenic intraplate bimodal volcanic association.The cyclesⅡandⅢinclude arc volcanic associations formed in compressional and extensional subduction environments,respectively.The CycleⅣcontains a post-orogenic arc bimodal association.The CycleⅤis a basaltic association of tholeiite series under initial rift setting,and the CycleⅥis basaltic association of alkaline series under typical rift setting.The volcanic strata between each cycle are bounded by regional unconformity.The above 6 volcanic cycles correspond to 6 sequential stages of tectonic evolutions from the Early Jurassic post-orogeny,the Mid-Jurassic–Cretaceous subduction of the paleo-Pacific Plate to the Cenozoic marginal rifting.According to the geological characteristics of volcanic reservoirs in different volcanic cycles,it is put forward that the CycleⅤis the major formation period of volcanic reservoirs in East China and should be the focus of exploration,and that the volcanic reservoirs of the CycleⅣare also worthy of attention.

Formation mechanism of in-situ volcanic reservoirs in eastern China:A case study from Xushen gasfield in Songliao Basin

A large number of in-situ volcanic reservoirs have been discovered from the Meso-Cenozoic rift basin group in eastern China.Based on drilling results in combination with geological and geophysical analysis,a case study from the Early Cretaceous Xujiaweizi fault-depression shows that the formation mechanism of in-situ volcanic reservoirs is characterized by"fault-controlled body,body-controlled facies,facies-controlled reservoir,and reservoir-controlled accumulation".In other words,deep faults control the volcanic eruption type,volcanic body,and gas reservoir distribution;the volcanic body determines the spatial distribution of volcanic facies and volcanic gas reservoir size;the volcanic facies control reservoir physical properties and effective thickness of gas formation;the volcanic reservoir properties control gas reservoir type and gas productivity.The result is useful to guiding the discovery of in-situ volcanic gas reservoirs in faulted basins in both theory and practice.

Volcanic Facies and Their Reservoirs Characteristics in Eastern China Basins

In these years, with more and more volcanic oil and gas fields being discovered and de- veloped, the volcanic rocks reveal a great petroleum potential in the eastern basins of China. There are five volcanic facies identified in the study area, which include volcanic conduit facies, explosive facies, effusive facies, extrusive facies, and volcanogenic sedimentary facies. The subaerial eruption usually happened in Mesozoic and Paleocene, and subaquatic eruption in Eocene. The upper subfacies and top autoclastic brecciation of effusive facies of subaquatic volcanic rocks and pyroclastic flow subfacies of explosive facies of subaerial volcanic rocks are the most favorable volcanic reservoirs. The intermittent belt formed between two times of volcanic eruptions is most effective for reservoirs both in subaquatic and subaerial volcanic rocks. Their main porosity types are interclast porosity, interflow laminar po- rosity, vesicular and gas pipes porosity, intercrystalline sieve of moldic porosity, secondary dissolution porosity, and tectonic fracture. Developed between pre-emplacement stage and final cooling, the pri- mary porosity may lead to high porosity and permeability, and the secondary porosity usually devel- oped upon them. The porosity of volcanic rocks was less influenced by the compaction and the burial depth.

Characteristics of Diagenesis and Pore Evolution of Volcanic Reservoir: A Case Study of Junggar Basin, Northwest China

Unconventional volcanic reservoir is different from conventional reservoir in reservoir space,diagenesis,pore formation and evolution.The Carboniferous volcanic reservoir was selected in Junggar Basin,Northwest China because based on sediment/rock cores and outcrop data,diagenesis and pore evolution were studied by elemental measurements,thin section observations,and diagenetic analyses.These analyses shows that the reservoir lithology is predominantly intermediate-basic volcanic,and the reservoir storage space is composed mainly of secondary dissolved pores and fractures.The reservoir displays great heterogeneity,and has experienced a great variety of diagenetic alteration during various diagenetic stages including:(1)eruption fragmentation,crystallization differentiation and condensing consolidation at consolidated diagenetic stage;(2)metasomatic alteration,filling,weathering and leaching,dissolution by formation fluids and tectonism at the epigenetic modifications stage.The formation and evolutionary process of the pores is extremely complicated.The primary pores were formed during the consolidated diagenetic stage,and laid a foundation for the late development and alteration of effective reservoir.During the epigenetic modifications stage secondary reservoir storage space was developed via the formation of secondary pores and the development of fractures through weathering and leaching,dissolution by formation fluids and tectonism.