The hydration process,hydration product and hydration heat of blended cement paste mixed with mineral admixture and expansive agent at low W/B ratio are studied by XRD,thermo analysis,and calorimetry instrument,and th...The hydration process,hydration product and hydration heat of blended cement paste mixed with mineral admixture and expansive agent at low W/B ratio are studied by XRD,thermo analysis,and calorimetry instrument,and they were compared with those of pure cement paste.The results show that pure cement and blended cement at low W/B ratio have the same types of hydration products,but their respective amounts of hydration products of various blended cements at same ages and the variation law of the amount of same hydration products with ages are different;The joint effect of tumefaction of gel-ettringite due to water absorption and the expansive pressure on the pore and rift caused by the crystalloid ettringite is the impetus of the volume expansion of cement paste,and the former effect is much greater than the latter one.展开更多
In order to study the durability of sprayed concrete （shotcrete）, effects of different hydration aging and water-binder ratio （w/b） on the microstructure of cement paste and basic mechanical properties of test spe...In order to study the durability of sprayed concrete （shotcrete）, effects of different hydration aging and water-binder ratio （w/b） on the microstructure of cement paste and basic mechanical properties of test specimens were investigated. The phase composition, mass percentage of ettringite and portland in hydration production and microstructure were characterized by X-ray diffraction （XRD）, thermo gravimetry-differential scanning calorimetry （TG-DSC） and scanning electron microscopy （SEM）, respectively. The experimental results showed that changes in phase composition was more significant than those of water-binder ratio. With hydration aging and water-binder ratio increased, the mass percentage of ettringite and portland was decreased from 4.42%, 1.49% to 3.31%, 1.35%, respectively and the microstructure of paste was significantly compacted. Likewise, the mechanical properties including cubic compressive strength and splitting tensile strength were rised obviously.展开更多
基于国内外珊瑚混凝土研究现状和高性能轻骨料混凝土的配合比设计原理,设计了4组净水胶比(W/B)为0.25~0.40的珊瑚礁砂海水混凝土,研究了标准养护龄期和W/B对珊瑚礁砂海水混凝土立方体抗压强度(f_(cu))的影响。结果表明:珊瑚礁砂海水混凝...基于国内外珊瑚混凝土研究现状和高性能轻骨料混凝土的配合比设计原理,设计了4组净水胶比(W/B)为0.25~0.40的珊瑚礁砂海水混凝土,研究了标准养护龄期和W/B对珊瑚礁砂海水混凝土立方体抗压强度(f_(cu))的影响。结果表明:珊瑚礁砂海水混凝土f_(cu)随着养护龄期的延长而增大,在养护初期,其f_(cu)增长速度较快,超过7 d时f_(cu)的增长速度逐渐减慢,并逐步趋于稳定;在养护初期时珊瑚礁砂海水混凝土f_(cu)增长速度相对普通混凝土f_(cu)要快,但是在养护后期,由于骨料的强度对混凝土强度的影响起重要作用,珊瑚礁砂海水混凝土28 d f_(cu)的增长速度反而比普通砂石混凝土28 d f_(cu)要小;珊瑚礁砂海水混凝土f_(cu)随着净胶水比(B/W)的增大而增大,两者之间较好地符合线性关系。展开更多
文摘The hydration process,hydration product and hydration heat of blended cement paste mixed with mineral admixture and expansive agent at low W/B ratio are studied by XRD,thermo analysis,and calorimetry instrument,and they were compared with those of pure cement paste.The results show that pure cement and blended cement at low W/B ratio have the same types of hydration products,but their respective amounts of hydration products of various blended cements at same ages and the variation law of the amount of same hydration products with ages are different;The joint effect of tumefaction of gel-ettringite due to water absorption and the expansive pressure on the pore and rift caused by the crystalloid ettringite is the impetus of the volume expansion of cement paste,and the former effect is much greater than the latter one.
基金Funded by the National Natural Science Foundation of China(Nos.51278403 and 51308445)the Program for Innovative Research Team in University(IRT 13089)
文摘In order to study the durability of sprayed concrete （shotcrete）, effects of different hydration aging and water-binder ratio （w/b） on the microstructure of cement paste and basic mechanical properties of test specimens were investigated. The phase composition, mass percentage of ettringite and portland in hydration production and microstructure were characterized by X-ray diffraction （XRD）, thermo gravimetry-differential scanning calorimetry （TG-DSC） and scanning electron microscopy （SEM）, respectively. The experimental results showed that changes in phase composition was more significant than those of water-binder ratio. With hydration aging and water-binder ratio increased, the mass percentage of ettringite and portland was decreased from 4.42%, 1.49% to 3.31%, 1.35%, respectively and the microstructure of paste was significantly compacted. Likewise, the mechanical properties including cubic compressive strength and splitting tensile strength were rised obviously.
文摘基于国内外珊瑚混凝土研究现状和高性能轻骨料混凝土的配合比设计原理,设计了4组净水胶比(W/B)为0.25~0.40的珊瑚礁砂海水混凝土,研究了标准养护龄期和W/B对珊瑚礁砂海水混凝土立方体抗压强度(f_(cu))的影响。结果表明:珊瑚礁砂海水混凝土f_(cu)随着养护龄期的延长而增大,在养护初期,其f_(cu)增长速度较快,超过7 d时f_(cu)的增长速度逐渐减慢,并逐步趋于稳定;在养护初期时珊瑚礁砂海水混凝土f_(cu)增长速度相对普通混凝土f_(cu)要快,但是在养护后期,由于骨料的强度对混凝土强度的影响起重要作用,珊瑚礁砂海水混凝土28 d f_(cu)的增长速度反而比普通砂石混凝土28 d f_(cu)要小;珊瑚礁砂海水混凝土f_(cu)随着净胶水比(B/W)的增大而增大,两者之间较好地符合线性关系。
