We have shown that certain non-commutative integral rings can be immersed in a field by a method which is not that of the construction of the field of fractions on the right ℝ ℝ ∗−1 , or left ℝ ∗−1 ℝ , of the ring ℝ u...We have shown that certain non-commutative integral rings can be immersed in a field by a method which is not that of the construction of the field of fractions on the right ℝ ℝ ∗−1 , or left ℝ ∗−1 ℝ , of the ring ℝ under consideration.展开更多
The reaction of a ruthenium carbide complex RuCl2（C：）（PCy3）2 with [H（Et2O）x]＋[BF4]- at a molar ratio of 1：2 produced a two-core ruthenium carbene complex, {[RuCl（=CHPCy3）（PCy3）]2（μ-Cl）3}＋·[BF4]-,...The reaction of a ruthenium carbide complex RuCl2（C：）（PCy3）2 with [H（Et2O）x]＋[BF4]- at a molar ratio of 1：2 produced a two-core ruthenium carbene complex, {[RuCl（=CHPCy3）（PCy3）]2（μ-Cl）3}＋·[BF4]-, in the form of a yellow-green crystalline solid in a yield of 94%. This two-core ruthenium complex is a selective catalyst for ring closing metathesis of unsubstituted terminal dienes. More importantly, no isomerized byproduct was observed for N-substrates when the two-core ruthenium complex was used as the catalyst at an elevated temperature（137 °C）, indicating that the complex is a chemo-selective catalyst for ring closing metathesis reactions.展开更多
The transmission properties of double-ring split ring resonator(SRR) arrays and closed ring resonator arrays are measured using terahertz(THz) time-domain spectroscopy. This technique allows for the simultaneous measu...The transmission properties of double-ring split ring resonator(SRR) arrays and closed ring resonator arrays are measured using terahertz(THz) time-domain spectroscopy. This technique allows for the simultaneous measurement of the amplitude and phase of the transmission coefficient as a function of frequency. The ability to directly measure the phase spectrum is expected to be important in characterizing potential negative index media. In the employed experimental geometry, THz pulses are normally incident on the arrays. Thus, the magnetic field lies in the plane of the arrays and cannot contribute to the magnetic resonance of the SRR. However, it is found that the electric field, when appropriately polarized, can couple to the magnetic resonance. Shifts in the resonance properties with changes in the SRR dimensions and the substrate medium are measured, the results of which are consistent with theory.展开更多
Ring-closing metathesis reactions involving diallyldiphenylsilane and diallyloxydiphenylsilane were successfully performed by using only 0 01 mol or even less of Grubbs' catalyst 1. The effects of reaction parame...Ring-closing metathesis reactions involving diallyldiphenylsilane and diallyloxydiphenylsilane were successfully performed by using only 0 01 mol or even less of Grubbs' catalyst 1. The effects of reaction parameters, such as solvents, temperature and concentration of the catalyst are discussed.展开更多
针对窄频差硅基环形波动陀螺动态性能差的问题,提出了一种基于比例积分微分-惯性环节(proportion integral differential-inertial element,PID-IE)的串联式相位校正检测闭环系统控制器。以硅微机械陀螺仪结构运动方程为基础建立了理想...针对窄频差硅基环形波动陀螺动态性能差的问题,提出了一种基于比例积分微分-惯性环节(proportion integral differential-inertial element,PID-IE)的串联式相位校正检测闭环系统控制器。以硅微机械陀螺仪结构运动方程为基础建立了理想的窄频差U形弹性梁硅基环形波动陀螺仪的系统模型。通过对环形陀螺开环工作状态下的系统模型及其外围电路的传递函数和波特图分析,设计了一种基于PID-IE的检测闭环系统控制器。通过对其系统模型及外围电路时域仿真,验证了该检测闭环控制系统的可行性,通过仿真发现,加入该控制器后的陀螺输出稳定时间减少了50%,陀螺检测位移输出减小了2个数量级,基本实现了该陀螺的检测位移抑制。在模拟电路中实现了该检测闭环控制系统后,通过实验测试了陀螺检测闭环控制前后的各项性能指标。通过实验测试发现,实现闭环控制后,陀螺输出稳定时间约为0.15 s,陀螺检测位移在闭环工作状态下比开环工作状态减小了97%,陀螺的标度因数比检测开环提高了10倍,零偏及零偏不稳定性与检测开环相比分别提升了3倍和8倍,且闭环控制系统的工作带宽比开环工作带宽提高了30倍。展开更多
文摘We have shown that certain non-commutative integral rings can be immersed in a field by a method which is not that of the construction of the field of fractions on the right ℝ ℝ ∗−1 , or left ℝ ∗−1 ℝ , of the ring ℝ under consideration.
基金Supported by the National Natural Science Foundation of China(No.20872108)
文摘The reaction of a ruthenium carbide complex RuCl2（C：）（PCy3）2 with [H（Et2O）x]＋[BF4]- at a molar ratio of 1：2 produced a two-core ruthenium carbene complex, {[RuCl（=CHPCy3）（PCy3）]2（μ-Cl）3}＋·[BF4]-, in the form of a yellow-green crystalline solid in a yield of 94%. This two-core ruthenium complex is a selective catalyst for ring closing metathesis of unsubstituted terminal dienes. More importantly, no isomerized byproduct was observed for N-substrates when the two-core ruthenium complex was used as the catalyst at an elevated temperature（137 °C）, indicating that the complex is a chemo-selective catalyst for ring closing metathesis reactions.
文摘The transmission properties of double-ring split ring resonator(SRR) arrays and closed ring resonator arrays are measured using terahertz(THz) time-domain spectroscopy. This technique allows for the simultaneous measurement of the amplitude and phase of the transmission coefficient as a function of frequency. The ability to directly measure the phase spectrum is expected to be important in characterizing potential negative index media. In the employed experimental geometry, THz pulses are normally incident on the arrays. Thus, the magnetic field lies in the plane of the arrays and cannot contribute to the magnetic resonance of the SRR. However, it is found that the electric field, when appropriately polarized, can couple to the magnetic resonance. Shifts in the resonance properties with changes in the SRR dimensions and the substrate medium are measured, the results of which are consistent with theory.
文摘Ring-closing metathesis reactions involving diallyldiphenylsilane and diallyloxydiphenylsilane were successfully performed by using only 0 01 mol or even less of Grubbs' catalyst 1. The effects of reaction parameters, such as solvents, temperature and concentration of the catalyst are discussed.
文摘针对窄频差硅基环形波动陀螺动态性能差的问题,提出了一种基于比例积分微分-惯性环节(proportion integral differential-inertial element,PID-IE)的串联式相位校正检测闭环系统控制器。以硅微机械陀螺仪结构运动方程为基础建立了理想的窄频差U形弹性梁硅基环形波动陀螺仪的系统模型。通过对环形陀螺开环工作状态下的系统模型及其外围电路的传递函数和波特图分析,设计了一种基于PID-IE的检测闭环系统控制器。通过对其系统模型及外围电路时域仿真,验证了该检测闭环控制系统的可行性,通过仿真发现,加入该控制器后的陀螺输出稳定时间减少了50%,陀螺检测位移输出减小了2个数量级,基本实现了该陀螺的检测位移抑制。在模拟电路中实现了该检测闭环控制系统后,通过实验测试了陀螺检测闭环控制前后的各项性能指标。通过实验测试发现,实现闭环控制后,陀螺输出稳定时间约为0.15 s,陀螺检测位移在闭环工作状态下比开环工作状态减小了97%,陀螺的标度因数比检测开环提高了10倍,零偏及零偏不稳定性与检测开环相比分别提升了3倍和8倍,且闭环控制系统的工作带宽比开环工作带宽提高了30倍。
