Cavitation erosion （CE） is the predominant cause for the failure of overflow components in fluid machinery. Advanced coatings have provided an effective solution to cavitation erosion due to the rapid development of...Cavitation erosion （CE） is the predominant cause for the failure of overflow components in fluid machinery. Advanced coatings have provided an effective solution to cavitation erosion due to the rapid development of surface engineering techniques. However, the influence of coating structures on CE resistance has not been sys- tematically studied. To better understand their relationship, micro-nano and conventional WC-10Co4Cr cermet coat- ings are deposited by high velocity oxygen fuel spray- ing（HVOF）, and their microstructures are analyzed by OM, SEM and XRD. Meanwhile, characterizations of mechan- ical and electrochemical properties of the coatings are carried out, as well as the coatings＇ resistance to CE in 3.5 wt % NaC1 solution, and the cavitation mechanisms are explored. Results show that micro-nano WC-10Co4Cr coating possesses dense microstructure, excellent mechanical and electrochemical properties, with very low porosity of 0.26 4-0.07% and extraordinary fracture toughness of 5.58 4-0.51 MPa.m1/2. Moreover, the CE resistance of micro-nano coating is enhanced above 50% than conventional coating at the steady CE period in 3.5 wt % NaC1 solution. The superior CE resistance of micro- nano WC-10Co4Cr coating may originate from the unique micro-nano structure and properties, which can effectively obstruct the formation and propagation of CE crack. Thus,a new method is proposed to enhance the CE resistance of WC-10Co4Cr coating by manipulating the microstructure.展开更多
Coatings obtained with magnetron sputtering exhibit a columnay structure. There are nodular defects distributed in the coatings, which are fomed by radial growth of columnay grains in groups. The fomation of them does...Coatings obtained with magnetron sputtering exhibit a columnay structure. There are nodular defects distributed in the coatings, which are fomed by radial growth of columnay grains in groups. The fomation of them does not necessarily depend on surface asperities of substrate. The columnar grain boundaries are enriched in oxygen, which causes microporosity in the intercolumnar regions.展开更多
Rotational fretting which exist in many engineering applications has incurred enormous economic loss. Thus, accessible methods are urgently needed to alleviate or eliminate damage by rotational fretting. Surface engin...Rotational fretting which exist in many engineering applications has incurred enormous economic loss. Thus, accessible methods are urgently needed to alleviate or eliminate damage by rotational fretting. Surface engineering is an effective approach that is successfully adopted to enhance the ability of components to resist the fretting damage. In this paper, using a high-velocity oxygen fuel sprayed（HVOF） technique WC-17 Co coating is deposited on an LZ50 steel surface to study its properties through Vickers hardness testing, scanning electric microscope（SEM）, energy dispersive X-ray spectroscopy（EDX）, and X-ray diffractrometry（XRD）. Rotational fretting wear tests are conducted under normal load varied from 10 N to 50 N, and angular displacement amplitudes vary from 0.125° to 1°. Wear scars are examined using SEM, EDX, optical microscopy（OM）, and surface topography. The experimental results reveal that the WC-17 Co coating adjusted the boundary between the partial slip regime（PSR） and the slip regime（SR） to the direction of smaller amplitude displacement. As a result, the coefficients of friction are consistently lower than the substrate＇s coefficients of friction both in the PSR and SR. The damage to the coating in the PSR is very slight. In the SR, the coating exhibits higher debris removal efficiency and load-carrying capacity. The bulge is not found for the coating due to the coating＇s higher hardness to restrain plastic flow. This research could provide experimental bases for promoting industrial application of WC-17 Co coating in prevention of rotational fretting wear.展开更多
基金Supported by National Natural Science Foundation of China (Grand No. 51422507)
文摘Cavitation erosion （CE） is the predominant cause for the failure of overflow components in fluid machinery. Advanced coatings have provided an effective solution to cavitation erosion due to the rapid development of surface engineering techniques. However, the influence of coating structures on CE resistance has not been sys- tematically studied. To better understand their relationship, micro-nano and conventional WC-10Co4Cr cermet coat- ings are deposited by high velocity oxygen fuel spray- ing（HVOF）, and their microstructures are analyzed by OM, SEM and XRD. Meanwhile, characterizations of mechan- ical and electrochemical properties of the coatings are carried out, as well as the coatings＇ resistance to CE in 3.5 wt % NaC1 solution, and the cavitation mechanisms are explored. Results show that micro-nano WC-10Co4Cr coating possesses dense microstructure, excellent mechanical and electrochemical properties, with very low porosity of 0.26 4-0.07% and extraordinary fracture toughness of 5.58 4-0.51 MPa.m1/2. Moreover, the CE resistance of micro-nano coating is enhanced above 50% than conventional coating at the steady CE period in 3.5 wt % NaC1 solution. The superior CE resistance of micro- nano WC-10Co4Cr coating may originate from the unique micro-nano structure and properties, which can effectively obstruct the formation and propagation of CE crack. Thus,a new method is proposed to enhance the CE resistance of WC-10Co4Cr coating by manipulating the microstructure.
文摘Coatings obtained with magnetron sputtering exhibit a columnay structure. There are nodular defects distributed in the coatings, which are fomed by radial growth of columnay grains in groups. The fomation of them does not necessarily depend on surface asperities of substrate. The columnar grain boundaries are enriched in oxygen, which causes microporosity in the intercolumnar regions.
基金Supported by Yangtze River Scholars and Innovation Team Development Plan of China(Grant No.IRT1178)Guizhou Provincial Joint Foundation of China(Grant No.LKG[2013]09)Guizhou Provincial Universities Engineering Research Center Project of China(Grant No.[2012]023)
文摘Rotational fretting which exist in many engineering applications has incurred enormous economic loss. Thus, accessible methods are urgently needed to alleviate or eliminate damage by rotational fretting. Surface engineering is an effective approach that is successfully adopted to enhance the ability of components to resist the fretting damage. In this paper, using a high-velocity oxygen fuel sprayed（HVOF） technique WC-17 Co coating is deposited on an LZ50 steel surface to study its properties through Vickers hardness testing, scanning electric microscope（SEM）, energy dispersive X-ray spectroscopy（EDX）, and X-ray diffractrometry（XRD）. Rotational fretting wear tests are conducted under normal load varied from 10 N to 50 N, and angular displacement amplitudes vary from 0.125° to 1°. Wear scars are examined using SEM, EDX, optical microscopy（OM）, and surface topography. The experimental results reveal that the WC-17 Co coating adjusted the boundary between the partial slip regime（PSR） and the slip regime（SR） to the direction of smaller amplitude displacement. As a result, the coefficients of friction are consistently lower than the substrate＇s coefficients of friction both in the PSR and SR. The damage to the coating in the PSR is very slight. In the SR, the coating exhibits higher debris removal efficiency and load-carrying capacity. The bulge is not found for the coating due to the coating＇s higher hardness to restrain plastic flow. This research could provide experimental bases for promoting industrial application of WC-17 Co coating in prevention of rotational fretting wear.
