Effects of acid-rock reaction on physical properties during CO_(2)-rich industrial waste gas(CO_(2)-rich IWG)injection in shale reservoirs

"Carbon peaking and carbon neutrality"is an essential national strategy,and the geological storage and utilization of CO_(2)is a hot issue today.However,due to the scarcity of pure CO_(2)gas sources in China and the high cost of CO_(2)capture,CO_(2)-rich industrial waste gas(CO_(2)-rich IWG)is gradually emerging into the public's gaze.CO_(2)has good adsorption properties on shale surfaces,but acidic gases can react with shale,so the mechanism of the CO_(2)-rich IWG-water-shale reaction and the change in reservoir properties will determine the stability of geological storage.Therefore,based on the mineral composition of the Longmaxi Formation shale,this study constructs a thermodynamic equilibrium model of water-rock reactions and simulates the regularity of reactions between CO_(2)-rich IWG and shale minerals.The results indicate that CO_(2)consumed 12%after reaction,and impurity gases in the CO_(2)-rich IWG can be dissolved entirely,thus demonstrating the feasibility of treating IWG through water-rock reactions.Since IWG inhibits the dissolution of CO_(2),the optimal composition of CO_(2)-rich IWG is 95%CO_(2)and 5%IWG when CO_(2)geological storage is the main goal.In contrast,when the main goal is the geological storage of total CO_(2)-rich IWG or impurity gas,the optimal CO_(2)-rich IWG composition is 50%CO_(2)and 50%IWG.In the CO_(2)-rich IWG-water-shale reaction,temperature has less influence on the water-rock reaction,while pressure is the most important parameter.SO2 has the greatest impact on water-rock reaction in gas.For minerals,clay minerals such as illite and montmorillonite had a significant effect on water-rock reaction.The overall reaction is dominated by precipitation and the volume of the rock skeleton has increased by 0.74 cm3,resulting in a decrease in shale porosity,which enhances the stability of CO_(2)geological storage to some extent.During the reaction between CO_(2)-rich IWG-water-shale at simulated temperatures and pressures,precipitation is the main reaction,and shale porosity decreases.However,as the reservoir water content increases,the reaction will first dissolve and then precipitate before dissolving again.When the water content is less than 0.0005 kg or greater than 0.4 kg,it will lead to an increase in reservoir porosity,which ultimately reduces the long-term geological storage stability of CO_(2)-rich IWG.

Bird’s-eye view of recycled solid wastes in road engineering

Recent trends in road engineering have explored the potential of incorporating recycled solid wastes into infrastructures that including pavements,bridges,tunnels,and accessory structures.The utilization of solid wastes is expected to offer sustainable solutions to waste recycling while enhancing the performance of roads.This review provides an extensive analysis of the recycling of three main types of solid wastes for road engineering purposes:industrial solid waste,infrastructure solid waste,and municipal life solid waste.Industrial solid wastes suitable for road engineering generally include coal gangue,fly ash,blast furnace slag,silica fume,and steel slag,etc.Infrastructure solid wastes recycled in road engineering primarily consist of construction&demolition waste,reclaimed asphalt pavements,and recycled cement concrete.Furthermore,recent exploration has extended to the utilization of municipal life solid wastes,such as incinerated bottom ash,glass waste,electronics waste,plastic waste,and rubber waste in road engineering applications.These recycled solid wastes are categorized into solid waste aggregates,solid waste cements,and solid waste fillers,each playing distinct roles in road infrastructure.Roles of solid waste acting aggregates,cements,and fillers in road infrastructures were fully investigated,including their pozzolanic properties,integration effects to virgin materials,modification or enhancement solutions,engineering performances.Utilization of these materials not only addresses the challenge of waste management but also offers environmental benefits aiming carbon neutral and contributes to sustainable infrastructure development.However,challenges such as variability in material properties,environmental impact mitigation,secondary pollution to environment by leaching,and concerns regarding long-term performance need to be further addressed.Despite these challenges,the recycled solid wastes hold immense potential in revolutionizing road construction practices and fostering environmental stewardship.This review delves into a bird’seye view of the utilization of recycled solid wastes in road engineering,highlighting advances,benefits,challenges,and future prospects.

Toxicological and Life-Cycle Perspectives on Waste-Derived Nanoparticles

Many nanoparticles have been created over the last few decades using a variety of techniques and used to develop environmental technology, including water treatment, the detection of persistent contaminants, and soil and water remediation. The studies of alternative inputs for nanoparticle production as well as the use of green synthesis techniques are driven by the field of materials science and engineering’s growing interest in increasing the sustainability of the processes involved in their production. In this paper, we begin by providing an overview of the fundamental principles of producing nanoparticles from different sources, such as plastic, electronic, metal, and industrial waste. We elaborate on key facts of waste identification as a workable input for the treatment and recovery of metal and carbon-based nanoparticles. We next go over several controlling factors that play a role in creating nanoparticles, pointing out probable conclusions as we go. Then, we show some instances of waste-derived nanoparticles used in a proof-of-concept experiment of technology for applications in water quality and safety. Before scaling up production and implementing waste-derived nanoparticles, there are several present problems from the toxicological and life-cycle perspectives that must be taken into account.

Alkaline leaching of metal melting industry wastes and separation of zinc and lead in the leach solution

In this work, a thorough examinations on the extractability of zinc and lead present in the steelmaking dusts using alkaline leaching process and the effectiveness of the zinc and lead separation in the resultant leaching solutions using sulfide precipitation method were made. It was found that only about 53% of zinc and over 70% of the lead could be leached out of the dusts, while the other 47% of zinc and 30% of lead were left in the leaching residues. The zinc and lead in the resultant leaching solution can be effectively and selectively separated. When the weight ratio of sodium sulfide (M.W. = 222-240) to Pb was kept at 1.8, the lead in the solution could be precipitated out quantitatively while all the zinc was remained in the solution. The zinc left in the solution can be further recovered by the addition of extra sodium sulfide with a weight ratio of sodium sulfide to the zinc over 2.6. The resultant filtrate can be recycled to the leaching of dust in the next leaching process.

New application notion of pipeline transport——integrated in industry solid waste innocuous and efficient disposition

In order to solve transport problems of industry solid,firstly,a new applicationnotion of pipeline transport was presented,that is to say,combining pretreatment andtransport with disposal techniques of industry solid waste.Secondly,the integrated dis-posal and transport system for industry solid waste was introduced,in particular,the oper-ating principles,equipment set-up,key technology and technical parameters.Next,thispaper illustrated the application of this integrated system.Such as it can transport coalsludge with sufficiently high solids content(about 72%～77%)and high apparent viscosity(about 1 000～3 000 Pa.s)directly by pipeline having no use for water and addition agent.Generally,the transport distance is about 1 000 m.This system has been successfullyused in innocuous disposition and efficient utilization of other industrial byproducts or solidwastes,such as city sludge and paper making waste.The integrated system causes nopollution to the environment for its complete seal and realizes protecting the environment,conserving the energy,promoting the development of cycling economic.Finally,the paperdiscussed the research works that were needed for studying such pipeline transport sys-tem and narrates the relevant condition and application status.

A Comparative Investigation of the Biodegradation Behaviour of Linseed Oil-Based Cross-Linked Composites Filled with Industrial Waste Materials in Two Different Soils

The biodegradation of polymeric biocomposites formed from epoxidized linseed oil and various types of fillers(pine needles,pine bark,grain mill waste,rapeseed cake)and a control sample without filler was studied during 180 days of exposure to two types of forest soil:deciduous and coniferous.The weight loss,morphological,and structural changes of polymer composites were noticed after 180 days of the soil burial test.The greatest weight loss of all tested samples was observed in coniferous forest soil(41.8%–63.2%),while in deciduous forest soil,it ranged between 37.7%and 42.3%.The most significant changes in the intensities of the signals evaluated by attenuated total reflectance infrared spectroscopy,as well as morphological changes determined by scanning electron microscopy,were assessed for polymer composite with rapeseed cake and specimen without filler in coniferous forest soil and are in a good agreement with weight loss results.Whereas significantly lower changes in weight loss,morphology,and structure of polymeric film with pine bark were noticed in both soils.It was suggested that fungi of Trichoderma,Penicillium,Talaromyces and Clonostachys genera are the possible soil microorganisms that degrade linseed oil-based cross-linked polymer composites.Moreover,the novel polymer composites have the potential to be an environmentally friendly alternative to petroleum-based mulching films.

Industrial wastes applications for alkalinity regulation in bauxite residue: A comprehensive review

Bauxite residue is a highly alkaline material generated from the production of alumina in which bauxite is dissolved in caustic soda.Approximately 4.4 billion tons of bauxite residues are either stockpiled or landfilled,creating environmental risks either from the generation of dust or migration of filtrates.High alkalinity is the critical factor restricting complete utilization of bauxite residues,whilst the application of alkaline regulation agents is costly and difficult to apply widely.For now,current industrial wastes,such as waste acid,ammonia nitrogen wastewater,waste gypsum and biomass,have become major problems restricting the development of the social economy.Regulation of bauxite residues alkalinity by industrial waste was proposed to achieve‘waste control by waste’with good economic and ecological benefits.This review will focus on the origin and transformation of alkalinity in bauxite residues using typical industrial waste.It will propose key research directions with an emphasis on alkaline regulation by industrial waste,whilst also providing a scientific reference point for their potential use as amendments to enhance soil formation and establish vegetation on bauxite residue disposal areas(BRDAs)following large-scale disposal.

Effect of quarry dust addition on the performance of controlled low-strength material made from industrial waste incineration bottom ash

The performance of industrial waste incineration bottom ash in controlled low-strength material （CLSM） was investigated in this paper, as the quarry dust was added. CLSM mixtures were made from the industrial waste incineration bottom ash, quarry dust, and cement. Tests for fresh density, bleeding, compressive strength, shear strength, hydraulic conductivity, and excavatability were carried out. The com- pressive strength ranges from 60 kPa to 6790 kPa, the friction angle varies from 5°to 19°, and the cohesion is from 4 to 604 kPa. Most of the mixtures are found to be non-excavatable. It is indicated that the quarry dust addition increases the compressive strength and shear parame- ters, decreases bleeding, and increases the removability modulus.

Reaction Process of Chromium Slag Reduced by Industrial Waste in Solid Phase

M, a particular industrial waste, was selected to detoxify chromium slag at a high temperature. The carbon remaining in M reduced Cr （ Ⅳ ） of Na2 CrO4 borne in the chromium slag to Cr （ Ⅲ ） in the solid phase reaction, and its thermodynamics and kinetics were studied. The reduction process of Na2CrO4 by carbon produced CO, whiCh＇was endothermic. Under the experimental condition, the apparent activation energy was 4. 41 kJ·mol^-1 , the＇apparent order of reaction for Na2 CrO4 was equal to one, and the partial pressure of CO was only 0.22 Pa at 1 330℃.

Review of the fabrication and application of porous materials from silicon-rich industrial solid waste

Porous materials have promise as sound insulation, heat barrier, vibration attenuation, and catalysts. Most industrial solid wastes, such as tailings, coal gangue, and fly ash are rich in silicon. Additionally, a high silicon content waste is a potential raw material for the syn- thesis of silicon-based, multi-porous materials such as zeolites, mesoporous silica, glass-ceramics, and geopolymer foams. Representative sil- icon-rich industrial solid wastes (SRISWs) are the focus of this mini review of the processing and application of porous silicon materials with respect to the physical and chemical properties of the SRISW. The transformation methods of preparing porous materials from SRISWs are summarized, and their research status in micro-, meso-, and macro-scale porous materials are described. Possible problems in the application of SRISWs and in the preparation of functional porous materials are analyzed, and their development prospects are discussed. This review should provide a typical reference for the recycling and use of industrial solid wastes to develop sustainable “green materials.”

Preparation of Super Composite Cement with a Lower Clinker Content and a Larger Amount of Industrial Wastes

The effects of the grinding mode,fineness,gypsum kinds and dosage,mix proportions on properties of the composite cements consisting of slag,fly ash,limestone and a lower content clinker were investigated,respectively.The results show that when the proportions among slag,fly ash and limestone are appropriate,the grinding technology and system are reasonable,the optimized gypsums and additives are effective,the 52.5R grade cement (52.5R grade cement means a higher strength than 52.5 at early age) can be prepared by clinker dosage of 50% in weight,the 42.5R or 42.5,32.5 grade composite cement containing 40% and 30% clinker also may be made, respectively.Moreover,the high performance concrete prepared from the above composite cements was studied experimentally.

Plant Test of Industrial Waste Disposal in a Cement Kiln

Destruction of industrial waste in cement rotary kilns (CRKs) is an alternative technology for the treatment of certain types of industrial waste (IW). In this paper, three typical types of industrial wastes were co-incinerated in the CRK at Beijing Cement Plant to determine the effects of waste disposal (especially solid waste disposal) on the quality of clinker and the concentration of pollutants in air emission. Experimental results show that (1) waste disposal does not affect the quality of clinker and fly ash, and fly ash after the IW disposal can still be used in the cement production, (2) heavy metals from IW are immobilized and stabilized in the clinker and cement, and (3) concentration of pollutants in air emission is far below than the permitted values in the China National Standard-Air Pollutants Emission Standard (GB 16297-1996).

Research Progress on Porous Ceramics Prepared from Industrial Solid Wastes

The situation of porous ceramics prepared from industrial waste slag(fly ash,red mud,metallurgical slag,tailings,etc.)was summarized.It was pointed out that the preparation of porous ceramics from industrial waste slag can bring long-term economic and social benefits.The development trend of secondary utilization of industrial waste slag was also prospected.

Research on Regional Industrial Solid Waste Comprehensive Utilization Ability Influencing Factors based on Panel Data

On the basis of panel data from 29 provinces and cities throughout the country in 2006-2010, a research is made on factors influencing regional industrial solid waste comprehensive utilization ability through a regression analysis method. Research result shows that a positive influence will generate on the comprehensive utilization ability of the industrial solid waste by three factors： regional industrial soldi waste treatment earning level, regional industrial soldi waste treatment investment level and regional industrial pollution treatment subsidy strength. And this thesis will propose suggestions from improving earning ability, enhartcing treatment investment and increasing government subsidy depending on result of empirical analysis.

Comparing End-Use Potential for Industrial Food-Waste Sources

Approximately one quarter of the global edible food supply is wasted. The drivers of food waste can occur at any level between production, harvest, distribution, processing, and the consumer. While the drivers vary globally, the industrialized regions of North America, Europe, and Asia share similar situations; in each of these regions the largest loss of food waste occurs with the consumer, at approximately 51% of total waste generated. As a consequence, handling waste falls on municipal solid waste operations. In the United States, food waste constitutes 15% of the solid waste stream by weight, contributes 3.4 -107 t of carbon dioxide （CO2） equivalent emissions, and costs 1.9 billion USD in disposal fees. The levels of carbon, nutrients, and moisture in food waste make bioprocessing into higher value products an attractive method for mitigation. Opportunities include extraction of nutraceuticals and bioactive compounds, or conversion to a variety of volatile acids-including lactic, acetic, and propionic acids-that can be recovered and sold at a profit. The conversion of waste into volatile acids can be paired with bioen- ergy production, including hydrogen or biogas. This present review compares the potential for upgrading industrial food waste to either specialty products or methane. Higher value uses of industrial food waste could alleviate approximately 1.9-108 t of CO2 equivalent emissions. As an example, potato peel could be upgraded to lactic acid via fermentation to recover 5600 million USD per year, or could be converted to methane via anaerobic digestion, resulting in a revenue of 900 million USD per year. The potential value to be recovered is significant, and food-waste valorization will help to close the loop for various food industries.

Zeolite Synthesis under Insertion of Silica Rich Filtration Residues from Industrial Wastewater Reconditioning

Zeolite synthesis was studied using two silica rich filtration residues (FR 1 and FR 2) as Si-source and sodium aluminate in a direct synthesis at 60°C at strong alkaline conditions (8 M - 16 M NaOH). In addition to these one-pot syntheses, a two-step process was investigated. Here, an alkaline digestion of FR at 60°C was followed by gel precipitation with sodium aluminate and gel crystallization under usual conditions of 80°C - 90°C. The results show that the substitution of chemical reagent sodium silicate by a waste material like FR as Si-source is possible but requires fine tuning of the reaction conditions as zeolite crystallization is a process under kinetic control. The solubility behaviour and impurities of the inserted filtration residues strongly influenced the course of reaction. Thus zeolites like hydrosodalite or intermediate zeolite between cancrinite and sodalite, or zeolite NaA or Z-21 in cocrystallization with hydrosodalite could be observed in the one pot syntheses already in a short time interval between 1 - 4 h depending on the alkalinity. The two step process yield to zeolites NaA and NaX in very good quality. The reaction process of FR in both reaction methods was characterized by chemical analyses, X-ray powder diffraction, Fourier transform infrared spectroscopy as well as scanning electron microscopy. Surface area and water content of selected products were further characterized by the BET-method and by thermogravimetry. Summing up the results, we can show that zeolite formation from filtration residues is possible by several reaction procedures as model cases for a re-use of industrial waste materials. Beside the importance for environmental protection, the reactions are of interest for zeolite chemistry as the re-use of FR is possible under economically conditions of low energy consumption at 60°C and short reaction periods.

An overview on industrial waste management in China

The article is a summary of the industrial waste management in China during the recent years.An overall description of industrial waste was given from generation; treatment, disposal and emission and comprehensive utilization. In spite of the serious situation of industrial waste,China has realized it and made great progress in establishing corresponding legislation system, taking a series of administrative measures and developing effective treatment and disposal technologies.However, there still exist many problems , and it is of great urgency to take countermeasures in industrial waste management.

Application of Fe-Based Amorphous Alloy in Industrial Wastewater Treatment:A Review

Amorphous alloy(MGs)is a solid alloy with disordered atomic accumulation obtained by ultra-rapid solidification of alloy melt.The atom deviates from the equilibrium position and is in metastable state.Up to now,a large number of MGs have been applied to the treatment of dye and heavy metal contaminated wastewater and ideal experimental results have been obtained.However,there is no literature to systematically summarize the chemical reaction and degradation mechanism in the process of degradation.On the basis of reviewing the classification,application,and synthesis of MGs,this paper introduces in detail the chemical reactions such as decolorization,mineralization,and ion leaching of Fe-based amorphous alloy(Fe-MGs)in the degradation of organic and inorganic salt wastewater through direct reduction or advanced oxidation mechanism.Compared with crystalline materials,the higher reaction rate of Fe-MGs can be attributed to lower activation energy,negative redox potential,loose product layer,and band structure with downward shift of valence band top.Finally,some suggestions and prospects are put forward for the limitations and research prospects of MGs in the environmental field,which provides a new idea for the synthesis of new environmental functional materials.

Long-Term Effect of Industrial Waste Water Irrigation on Soil Chemical Properties

A laboratory experiment was conducted in Soil Science Division of BRRI during 2011 aimed to determine the vertical distribution of soil chemical properties under long-term industrial waste water irrigated rice field. Waste water irrigated rice field seemed to create some differences in soil pH profile. The pHW and pHKCl in all soil depth was higher with waste water irrigated rice field. The surface charge of both the soils was considerably negative. Waste water irrigated rice field developed more negative charges in soils. Irrigation with waste water increased Electrical Conductivity （EC） in rice soils profile. The organic carbon content （%） started to decrease sharply with the increase in soil depth. Organic carbon content was higher with waste water irrigated rice soils Total nitrogen （%） was high with underground water irrigated rice soils in surface but at deeper, total N was similar in both soils. Olsen P （mg/kg） was higher with underground water irrigated soil at 0-5 cm depth but at 5-100 cm soils profile, it was higher with waste water irrigated rice soils. Micronutrients （Zn, Fe, Cu and Mn） and heavy metals （Pb, Cd, Ni and Cr） in soils were increased significantly through irrigation with waste water in rice-rice cropping pattern.

Polluter Pays Principle： Who Pays for Industrial Waste in Ho Chi Minh City, Vietnam

Rapid industrialization in Vietnam has resulted in the difficult task of finding means to properly manage the generation of industrial waste. In an attempt to deal with this problem, the Vietnamese government revised the Law on Environmental Protection of 2005, with which it imposed strict regulations on industrial waste generators and the waste they discharge. However, questions remain about the current industrial solid waste management system because of the discrepancy between the ideals embodied in the Law and the actual practices occurring in industry. We report here on the effectiveness of governmental policies, focusing on environmental performance in industrial zones in Ho Chi Minh City （HCMC）, Vietnam. We examined government records, and reports from waste generators, as well as waste treatment methods at sites. In addition, on-site surveys were carried out at 44 companies in HCMC in 2009 and 2010 to obtain a better understanding of the companies＇ handling of and attitude toward the industrial waste they produced. Our results show that the incoherence of the revised Law and regulations in industrial waste management has caused a serious pressure on domestic landfills. We conclude that there is a strong need for change in the current regulatory and management system in order to increase the effectiveness of environmental management for future sustainable development.