Wax from Pyrolysis of Waste Plastics as a Potential Source of Phase Change Material for Thermal Energy Storage

Over the past half-century, plastic consumption has grown rapidly due to its versatility, low cost, and unrivaled functional properties. Among the diff erent implemented strategies for recycling waste plastics, pyrolysis is deemed the most economical option. Currently, the wax obtained from the pyrolysis of waste plastics is mainly used as a feedstock to manufacture chemicals and fuels or added to asphalt for pavement construction, with no other applications of wax being reported. Herein, the thermal pyrolysis of three common waste polyolefin plastics: high-density polyethylene(HDPE), low-density polyethylene(LDPE), and polypropylene(PP), was conducted at 450 ℃. The waste plastics-derived waxes were characterized and studied for a potential new application: phase change materials(PCMs) for thermal energy storage(TES). Gas chromatography–mass spectrometry analysis showed that paraffin makes up most of the composition of HDPE and LDPE waxes, whereas PP wax contains a mixture of naphthene, isoparaffin, olefin, and paraffin. Diff erential scanning calorimetry(DSC) analysis indicated that HDPE and LDPE waxes have a peak melting temperature of 33.8 ℃ and 40.3 ℃, with a relatively high latent heat of 103.2 J/g and 88.3 J/g, respectively, whereas the PP wax was found to have almost negligible latent heat. Fourier transform infrared spectroscopy and DSC results revealed good chemical and thermal stability of HDPE and LDPE waxes after 100 cycles of thermal cycling. Performance evaluation of the waxes was also conducted using a thermal storage pad to understand their thermoregulation characteristics for TES applications.

Co-pyrolysis characteristics of typical components of waste plastics in a falling film pyrolysis reactor

Waste plastics mainly come from MSW and usually exist in the form of mixed plastics. During the co-pyrolysis process of mixed plastics, various plastic components have different physicochemical properties and reaction mechanisms. Considering the high viscosity and low thermal conductivity of molten plastics, a falling film pyrolysis reactor was selected to explore the rapid co-pyrolysis process of typical plastic components(PP, PE and PS).The oil and gas yields and the compositions of pyrolysis products of the three components under different ratios at pyrolysis temperatures were analyzed to explore the co-pyrolysis characteristics of PP, PE, and PS. The study is of great significance to the recycling of waste plastics.

Disposal of Waste Plastics With Traditional Coking Process

A new technology for treating waste plastics （WP） by traditional coking process was introduced. With a thermo-balance and a 10 g atmospheric fixed bed reactor, the thermo-gravimetric behavior and product were studied during co-coking of WP with blended coal. And then, using a coke-oven with capacity of 200 kg, the characteristics of products were assessed. The results showed that there is an overlapping temperature range （200-550℃ ） of decomposition between WP and blended coal, and the pyrolysis synergism index η and synergism strength β proposed could evaluate the synergism between them. 1% of added WP results in the maximum synergism in all series experiments. The increase of added WP decreases the synergism. Tar yield in co-coking is increased with the decrease of water yield for synergism. Moreover, it was also found that the quality indexes of coke, such as M10, M40, CRI and CSR, are degraded with the increase of WP until 4%, though the quality of tar and gas is optimized for WP addition.

Conversion of Municipal Waste Plastic into Liquid Hydrocarbon Fuel Using a Stainless Steel Reactor

Plastic wastes from milk containers, soft drink bottles, plastic wraps, plastic flatware, etc. have been successfully converted into fuel. Two approaches for the conversion of waste post consumer plastic into fuel have been investigated： （1） muffle furnace to reactor liquefaction system; （2） direct liquefaction system. Majority of used plastics are derived from ethylene, propylene, butadiene and benzene. Waste plastics are plastics that are used by the people in their daily life. It is collected from outside and city municipalities. Some of them are coded and rests are non-coded. A developed process discussed in this paper works with most of the waste plastic, both coded and non-coded. The plastics are heated up at 120-380 ℃ temperature to melt. The gaseous vapor is then condensed into liquid fuel.

Co-processing Vacuum Residue with Waste Plastics in a Delayed Coking Process:Kinetics and Modeling

Thermal upgrading of vacuum residue mixed with waste plastics was studied in a laboratory scale delayed coking unit.The model of feed thermal decomposition was set up and the first order reaction kinetics was used to predict products distribution during the coking process.The distillate yield was higher(70%) for the vacuum residue/polystyrene(VR/PS) feed system and the vacuum residue/low density polyethylene(VR/LDPE) feed system.The resulted distillate yield was separated into fractions according to their boiling points,with gasoline and diesel being our fractions of concern.The activation energy was higher for gasoline production(around 60 kcal/mol) varying with the type of feed system,while it was 33 kcal/mol for diesel fraction.The regression coefficient R was 0.990.

New Renewable Source of Energy from Municipal Solid Waste Plastics

The use of renewable energy is not new. More than 150 years ago, wood, which is one form of biomass, supplied up to 90 percent of our energy needs. Today, we are looking again at renewable resources to find new ways to use them to help meet our energy needs. Overall consumption from renewable sources in the United States totaled 6.8 quads BTU （quadrillion Btu） in 2007 or about 7 percent of all energy used nationally. Consumption from renewable sources was at its highest point in 1997, at about 7.2 quads. Over half of renewable energy goes to producing electricity. Renewable energy plays an important role in the supply of energy. Even with the current fluctuating prices for fuel, U.S. residents and businesses pay a significant price for their utilities. Emissions from the evaporation and combustion of these traditional fossil fuels contributing to a range of environmental and health problems, causing poor air quality, and emitting greenhouse gases caused global warming. The method of producing alternative energy from municipal solid waste plastic is considered an effective way to meet the demand of energy need and save the environment at the same time.

Alternative Fuels Derived from Solid Waste Plastics

The demand for fossil fuel is at an all time high worldwide. Annually-30 billion barrels of petroleum is being consumed worldwide. In this busy society, transportation is vital and, for transportation, petroleum is a requirement. All the major forms of business, agricultural, exports and imports depend on transportation. There are three forms of major transportation： by ground, air and sea. These transportations require petroleum to function. Vehicles in the road require gasoline/diesel, airway transportation requires aviation fuel and sea transportation requires fuel oil and other forms of fuels. For not only transportation but, petroleum is required to make all kind of daily use plastics. If the consumption of petroleum continues this way, it will be finished in the near future. Emissions released from evaporation and combustion of these fuel contribute to many environmental and health problems, including emitting greenhouse gases that contribute immensely to global warming. Annually-7 billion tons of carbon is released to the environment due to burning of petroleum. Moreover, when the plastics are discarded into the landfill, it becomes waste plastic and since plastic is non-biodegradable, it can remain in the landfill for a long time. Waste plastics presence in the landfill causes environmental problems for example, it can cause soil to decay, pollute underground water resource and cause land to be infertile. Alternative source of energy created from solar, wind, hydrogen fuel, biomass fuel, bio-diesel, green diesel, bio-ethanol, and geo-thermal has been proposed as a solution to these problems and in future with further research, these alternative sources will play an important role in the field of alternative energy.

Generation of Transportation Fuel from Solid Municipal Waste Plastics

Transportation fuels derived from imported fossil fuels are subjected to the price fluctuations of the global marketplace, and constitute a major expense in the operation of a vehicle. Emissions from the evaporation and combustion of these fuels contribute to a range of environmental and health problems, causing poor air quality and emitting greenhouse gases that contribute to global warming. Alternative fuel created from domestic sources has been proposed as a solution to these problems, and many fuels are being developed based on biomass and other renewable sources. Natural State Research, Inc. proposes a different alternative hydrocarbon fuel which is produced from abundant waste plastic materials. This fuel burns more efficiently and cleaner than commercial gasoline and diesel. The process exists to efficiently convert waste plastic into a reliable low cost source of fuel.

Waste Plastic Conversion into Hydrocarbon Fuel like Low Sulfur Diesel

Energy plays a vital role in our modern civilization. Energy has needs in every sector all over the world, such as transportation, industrial development, home heating, and electricity production and in our daily life. Till now most of the energy production depends on the crude oil sources but in our planet the crude oil sources are limited. There is a probability that once these energy sources may come to an end, it could cause disastrous collapse of the human civilization considering the future fade of this universe scientist and researchers all over the world had been doing research for new alternate energy sources like solar energy, wind energy, bio-fuel etc. Plastics are produced mainly from crude oil. Incomprehensible amount of plastic bags are consumed every year all over the world and after use the discarded plastics bags become a severe problems to the natural environment. Dumping of these waste plastics create hazardous land fill problems, to avoid this problem transport of plastic waste to landfill cost $2800/ton. A new simple and cost effective technology has been developed for the conversion of the waste plastics into low sulfur diesel fuel. This developed technology can convert most types of waste plastic into low sulfur diesel fuel.

Techno-Economic Evaluation of Thermal and Catalytic Pyrolysis Plants for the Conversion of Heterogeneous Waste Plastics to Liquid Fuels in Nigeria

Techno-economic potentials of thermal and catalytic pyrolysis plants for the conversion of waste plastics to liquid fuels have been widely studied, but it is not obvious which of the two plants is more profitable, as the existing studies used different assumptions and cost bases in their analyses, thereby making it difficult to compare the economic potentials of the two plants. In this study, industrial-scale thermal and catalytic waste plastics pyrolysis plants were designed and economically analyzed using ASPEN PLUS. Amorphous silica-alumina was considered the optimum catalyst, with 3:1 feed to catalyst ratio. Based on 20,000 tons/year of feed and 20% interest rate, the catalytic plant, having a net present value (NPV) of &#83582208 million, was found to be economically less attractive than the thermal plant, having the NPV of &#83582426.4 million. On the contrary, sensitivity analyses of the two plants at a feed rate of 50,000 tons/year gave rise to a slightly higher NPV for the catalytic plant (&#83589861 million) than the thermal plant having NPV of &#83589838 million, thereby making the former more economically attractive for processing large amounts of waste plastics into liquid fuels. Consequently, as the catalytic plant showed a better scale economy and would produce higher quality liquid fuels than the thermal plant, it is recommended for commercialization in Nigeria.

Municipal Waste Plastics Conversion into Aviation Fuel

Aviation fuel is in great demand globally. The increased demand and high price for energy sources are driving efforts to convert natural non-renewable organic compounds into useful hydrocarbon fuel materials such as in form of aviation fuel. Alternate sources to these non-renewable hydrocarbon fuels are important and necessary. Much of these alternative sources are focused on biomass however, there are strong benefits of deriving fuels from waste plastic materials. Thermal processes can be used to convert waste plastics into hydrocarbon fuels like aviation fuel, which have unlimited applications in airline industries, as well as in transportation and power generation industries. These thermal processes are used to break down the long carbon chains found in plastics into the shorter chains in a temperature range from 300-450 ℃. This method has been carried out in succession in previous experiments. This simple and economically viable process has been developed to convert the hydrocarbon polymers of waste plastics into the short and medium chain hydrocarbons of liquid fuels. Based on the initial characterization, a fractionated portion of the developed fuel shows properties similar to some of the commercially available aviation fuels.

Power Generation from Municipal Solid Waste Plastics

Generation of electrical energy from imported fossil fuels is subject to the price fluctuations of the global marketplace and, thus, constitutes a major expense in its distribution to the end users. Even with the current low prices of fuel, residents and businesses in the United States pay a significant price for their utilities, if not higher than most other countries in the world. Emissions from the evaporation and combustion of these traditional fossil fuels contribute to a range of environmental and health problems, causing poor air quality, and emitting greenhouse gases that contribute to global warming. Alternative fuel created from domestic sources has been proposed as a solution to these problems and much alternative energy are being developed based on solar, wind, biomass, hydropower, fuel cell, geothermal, etc. A new alternative hydrocarbon fuel which is produced from waste plastics can be used with compatble power plants and generators appliances to produce electricity that can be supplied into homes, businesses, power grids and other sectors.

Utilization of Hydrocarbons Obtained by Waste Plastic Pyrolysis： Energetic Utilization （Part Ⅰ）

The pyrolysis of different waste polymers （polyethylene, polypropylene and polystyrene） was investigated in a tube reactor at 550 ℃ in the absence of oxygen. Additionally the energetic utilization of products have also been followed both in refining and petrochemical industry. Pyrolysis products were separated into fractions of gases, naphtha, middle distillates and heavy oil. Raw materials have been collected both from industrial and household sources： polyethylene from agriculture, polyethylene from packaging and polystyrene from packaging and electronic equipments. Yields and properties of volatile products have changed by the raw materials. Products have been analyzed by gas chromatography. Fourier transformed infrared spectroscopy, size exclusion chromatography and other standardized methods. Naphtha had high octane numbers （80 〈 RON）, while high cetane numbers （〉 75） in case of middle distillates. Moreover fractions contained approximately half of unsaturated hydrocarbons, mainly α-olefins, but the percentage was depending on the raw materials. These properties are advantageous for fuel-like applications.

Utilization of Hydrocarbons Obtained by Waste Plastic Pyrolysis： Application for Additive Production （Part Ⅱ）

New route of the utilization of products obtained by waste plastic pyrolysis has been investigated. ct-olefin-succinic-anhydride intermediate based on new experimental additives has been developed and used for achieving the better properties of carbon fibre reinforced polymer composites. Hydrocarbon fractions were produced by the pure thermal pyrolysis of waste polymers in a tube reactor using 550 ℃ in the absence of oxygen. Selected compounds （C30-C50） from pyrolysis products have been used as raw materials in the additive synthesis step. Polymer composite specimens have been investigated among others by universal tensile machine, SEM （scanning electron microscopy） and FTIR （fourier transformed infrared spectroscopy） methods. The tensile strength could be increased by 29.9%, the E-modulus by 24.2% and the Charpy impact strength by 13.3% in the presence of the experimental additive. Fibre-matrix interaction has been studied on SEM micrographs of the fractured face of composites. The results of mechanical testes have been supported by the SEM micrographs and possible shames of the coupling have been proposed.

Use of waste plastic oil as a fuel in reactivity-controlled compression ignition engines:a bibliometric investigation from 2017-23

Waste plastic oil,generated through the pyrolysis of plastic without oxygen,known as plastic-to-fuel conversion,stands as a promising alternative fuel.This research employs bibliometric analysis,a quantitative method,to comprehensively assess publications in the domain of waste plastic oil integration within reactivity-controlled compression ignition engines.Utilizing Scopus as the primary repository post-2017,the study categorizes information into pivotal aspects,including influential journals,countries,authors,affiliations,document types,thematic areas,sponsors and keywords.The analysis reveals significant contributions from diverse nations,prominently India,China,Turkey and Malaysia.Noteworthy is the prevalence of Energy,Engineering and Chemical Engineering as thematic focal points,with the journal Fuel leading the count followed by the journal Energy emerging as a prominent conduit.Institutional contributions are prolific,led by Gandhi Institute of Technology and Management University and Vellore Institute of Technology.Renowned authors‘Gugulothu S.K’and‘He Z’play a pivotal role in shaping the discourse.The National Natural Science Foundation of China stands out as a primary patron.This bibliometric analysis provides a structured understanding of waste plastic oil integration in reactivity-controlled compression ignition engines,laying the groundwork for future research avenues.The study identifies potential research platforms beyond Scopus,including Web of Science,CrossRef,Science Direct and Google Scholar,as valuable repositories for further exploration.Moreover,after careful observation of the research articles published by the top 10 authors as found in the study,it was found that the authors share a few common characteristics that helped them in advancing the understanding and application of waste plastic oil in reactivity-controlled compression ignition engines.These are also summarized in the present study with supporting data.

Three-stage pyrolysis–steam reforming–water gas shift processing of household,commercial and industrial waste plastics for hydrogen production

Five common single plastics and nine different household,commercial and industrial waste plastics were processed using a three-stage(i)pyrolysis,(ii)catalytic steam reforming and(iii)water gas shift reaction system to produce hydrogen.Pyrolysis of plastics produces a range of different hydrocarbon species which are subsequently catalytically steam reformed to produce H_(2)and CO and then undergo water gas shift reaction to produce further H_(2).The process mimics the commercial process for hydrogen production from natural gas.Processing of the single polyalkene plastics(high-density polyethylene(HDPE),low-density polyethylene(LDPE),and polypropylene(PP))produced similar H_(2)yields between 115 mmol and 120 mmol per gram plastic.Even though PS produced an aromatic product slate from the pyrolysis stage,further stages of reforming and water gas shift reaction produced a gas yield and composition similar to that of the polyalkene plastics(115 mmol H_(2)per gram plastic).PET gave significantly lower H_(2)yield(41 mmol per gram plastic)due to the formation of mainly CO,CO_(2)and organic acids from the pyrolysis stage which were not conducive to further reforming and water gas shift reaction.A mixture of the single plastics typical of that found in municipal solid waste produced a H_(2)yield of 102 mmol per gram plastic.Knowing the gas yields and composition from the single plastics enabled an estimation of the yields from a simulated waste plastic mixture and a‘real-world’waste plastic mixture to be determined.The different household,commercial and industrial waste plastic mixtures produced H_(2)yields between 70 mmol and 107 mmol per gram plastic.The H_(2)yield and gas composition from the single waste plastics gave an indication of the type of plastics in the mixed waste plastic samples.

Mixed plastics waste valorization to high-added value products via thermally induced phase separation and spin-casting

Plastic waste is an underutilized resource that has the potential to be transformed into value-added materials.However,its chemical diversity leads to cost-intensive sorting techniques,limiting recycling and upcycling opportunities.Herein,we report an open-loop recycling method to produce graded feedstock from mixed polyolefins waste,which makes up 60%of total plastic waste.The method uses heat flow scanning to quantify the composition of plastic waste and resolves its compatibility through controlled dissolution.The resulting feedstock is then used to synthesize blended pellets,porous sorbents,and superhydrophobic coatings via thermally induced phase separation and spin-casting.The hybrid approach broadens the opportunities for reusing plastic waste,which is a step towards creating a more circular economy and better waste management practices.

How to enhance agricultural plastic waste management in China?Insights from public participation

Agricultural plastics play a pivotal role in agricultural production.However,due to expensive costs,agricultural plastic waste management(APWM)encounters a vast funding gap.As one of the crucial stakeholders,the public deserves to make appropriate efforts for APWM.Accordingly,identifying whether the public is willing to pay for APWM and clarifying the decisions’driving pathways to explore initiatives for promoting their payment intentions are essential to address the dilemma confronting APWM.To this end,by applying the extended theory of planned behavior(TPB),the study conducted an empirical analysis based on 1,288 residents from four provinces(autonomous regions)of northern China.Results illustrate that:1)respondents hold generally positive and relatively strong payment willingness towards APWM;2)respondents’attitude(AT),subjective norm(SN),and perceived behavioral control(PBC)are positively correlated with their payment intentions(INT);3)environmental cognition(EC)and environmental emotion(EE)positively moderate the relationships between AT and INT,and between SN and INT,posing significant indirect impacts on INT.The study’s implications extend to informing government policies,suggesting that multi-entity cooperation,specifically public payment for APWM,can enhance agricultural non-point waste management.

Photocatalytic Degradation of Plastic Waste: Recent Progress and Future Perspectives

Microplastics are persistent anthropogenic pollutants that have become a global concern due to their widespread distribution and unfamiliar threat to the environment and living organisms. Conventional technologies are unable to fully decompose and mineralize plastic waste. Therefore, there is a need to develop an environmentally friendly, innovative and sustainable photocatalytic process that can destroy these wastes with much less energy and chemical consumption. In photocatalysis, various nanomaterials based on wide energy band gap semiconductors such as TiO2 and ZnO are used for the conversion of plastic contaminants into environmentally friendly compounds. In this work, the removal of plastic fragments by photocatalytic reactions using newly developed photocatalytic composites and the mechanism of photocatalytic degradation of microplastics are systematically investigated. In these degradation processes, sunlight or an artificial light source is used to activate the photocatalyst in the presence of oxygen.

Impact of Plastic Waste on the Human Health in Low-Income Countries: A Systematic Review

Background: Plastic pollution is the accumulation of waste composed of plastic and its derivatives all over the environment. Whether in the form of visible garbage or microparticles, as it slowly degrades, plastic pollution poses significant threats to terrestrial and aquatic habitats and the wildlife that call them home, whether through ingestion, entanglement or exposure to the chemicals contained in the material. Unfortunately, there is a lack of documentation on the impact of plastic waste on human health in low- and middle-income countries (LMICs). Methods: We searched five electronic databases (PubMed, Embase, Global Health, CINAHL and Web of Science) and gray literature, following the preferred reporting elements for systematic reviews and meta-analyses (PRISMA), for the impact of plastic waste on human health in developing countries. We included quantitative and qualitative studies written in English and French. We assessed the quality of the included articles using the Mixed Methods Appraisal tool (MMAT). Results: A total of 3779 articles were initially identified by searching electronic databases. After eliminating duplicates, 3167 articles were reviewed based on title and abstract, and 26 were selected for full-text review. Only three articles were retained. The three articles dealt with practices likely to lead to oral exposure to plastic chemicals in human health, as well as the level of awareness of participants concerning the possible impact of plastic on human health, namely, the use of plastic baby bottles, the use of microwaves to cook food and reheat precooked food, the use of plastic bottles to store water in the refrigerator, water purifier containers with plastic bodies and plastic lunch boxes, the reuse of plastic bags and the inadequacy of treatment facilities. Conclusion: Plastic waste poses different risks to human health at every stage of its life cycle. Hence, strategies must be adopted to raise public awareness of the dangers of plastic waste to their health. Trial registration: The review protocol is registered in the PROSPERO international prospective register of systematic reviews (ID = CRD42023409087).