When separated water droplets condense on the surface of a composite insulator,the electrical field on the insulator surface is distorted.In turn,such distortions change the trajectories of pollution particles.In this...When separated water droplets condense on the surface of a composite insulator,the electrical field on the insulator surface is distorted.In turn,such distortions change the trajectories of pollution particles.In this study,the COMSOL software is used to simulate such a process for the FXBW4-10/100 composite insulator with or without water droplets condensation under a 10 kV DC voltage.The influence of the wind speed and particles concentration on the contamination characteristics of the considered 110 kV insulator is analyzed.The results show that:1)in the presence of water droplets on the insulator surface,the ratio of electrical field force and gravity acting on the particles is large;2)the contamination on the insulator surface increases with the wind speed;3)when the wind speed is small,the relationship between the contamination amount and the pollution concentration is essentially linear.展开更多
Working with a biased atomic force microscope(AFM)tip in the tapping mode under ambient atmosphere,attoliter(10^(-18) L)water droplet patterns have been generated on a patterned carbonaceous surface.This is essentiall...Working with a biased atomic force microscope(AFM)tip in the tapping mode under ambient atmosphere,attoliter(10^(-18) L)water droplet patterns have been generated on a patterned carbonaceous surface.This is essentially electrocondensation of water leading to charged droplets,as evidenced from electrostatic force microscopy measurements.The droplets are unusual in that they exhibit a highly corrugated surface and evaporate rather slowly,taking several tens of minutes.展开更多
Vortexing limestone injection into furnace combined with calcium lime hydration in the downstream is the most promising technology for controlling SO 2 emission. Particle imaging velocimetry (PIV) is used to measure ...Vortexing limestone injection into furnace combined with calcium lime hydration in the downstream is the most promising technology for controlling SO 2 emission. Particle imaging velocimetry (PIV) is used to measure the gas liquid solid three phase flow field in a reactor. By image processing based on newly developed software, the number concentrations of sorbent particles and water droplets are presented. The measuring results are very helpful for better understanding the desulfurization mechanism and optimizing configurational and operational parameters in the hydration reactor.展开更多
Water is one of the most significant causes of lubrication failure.There is little research on the direct observation of the impact of water on lubrication properties.In this study,the influence of water on oil replen...Water is one of the most significant causes of lubrication failure.There is little research on the direct observation of the impact of water on lubrication properties.In this study,the influence of water on oil replenishment under different elastohydrodynamic(EHD)lubricating conditions is evaluated using optical interferometry and infrared microscopy,and a dimensionless criterion when water influences the film thickness is proposed.Evidence shows that the scour displacing effect and emulsification of water/oil are the main reasons for the reduction in film thickness.Once a water droplet enters an oil reservoir around the critical contact zone,it hardly moves away.This aggravates starvation,reduces the center film thickness of the contact,and leads to lubrication failure of the mechanical components.展开更多
Surface roughness plays a significant role in floatability of coal.In the present paper,coking coal surface was polished by three different sandpapers and the surface properties were characterized by contact angle and...Surface roughness plays a significant role in floatability of coal.In the present paper,coking coal surface was polished by three different sandpapers and the surface properties were characterized by contact angle and roughness measurements.The effect of surface roughness on floatability was investigated by adhesion force measurement system for measuring interaction forces between droplets/bubbles and coking coal surfaces with different roughness.The results showed that the contact angle decreased with increasing roughness yet the adhesion force between the water droplet and coal surface increased owing to the increased contact line and the appearance of line pinning.Maximum adhesion forces between water and surfaces were 111.70,125.48,and 136.42μN when the roughness was 0.23,0.98,and 2.79 μm,respectively.In contrast,under a liquid environment,the adhesion forces between air bubble/oil droplet and coal surfaces were decreased with increasing roughness because of the restriction by water.Maximum adhesion forces of increasing roughness were 97.14,42.76,and 17.86 μN measured at interfaces between air bubble and coal surfaces and 169.48,145.84,and 121.02 lN between oil droplet and surfaces,respectively.Decreasing roughness could be beneficial to the spreading of oil droplets and the adhesion of bubbles which is conducive to flotation separation.展开更多
Aqueous phase layer around bubble and water droplet are two additional processes in solvent sublation. In the dynamic process of mass transfer, they are always neglected, but they are very important in the investigati...Aqueous phase layer around bubble and water droplet are two additional processes in solvent sublation. In the dynamic process of mass transfer, they are always neglected, but they are very important in the investigation of thermodynamic equilibrium. In this paper, the effect of water droplet in solvent sublation was discussed in detail, and the previous mathematical model of solvent subaltion was improved. Matlab 6.5 was used to simulate the process of water droplets, and the comparison between the previous hypothesis and the improvement in this paper showed the superiority, especially in the investigation of thermodynamic equilibrium. Moreover, the separation and concentration of the complex compound dithizone-Co(Ⅱ) from aqueous phase to n-octanol by solvent sublation also proved the improved mathematical model was reasonable.展开更多
The cooling of a(pebble bed)spent fuel in a high-temperature gas-cooled reactor(HTGR)is adversely affected by an increase in the temperature of the used gas(air).To investigate this problem,a configuration consisting ...The cooling of a(pebble bed)spent fuel in a high-temperature gas-cooled reactor(HTGR)is adversely affected by an increase in the temperature of the used gas(air).To investigate this problem,a configuration consisting of three copper spheres arranged in tandem subjected to a forced mistflow inside a cylindrical channel is considered.The heat transfer coefficients and related variations as a function of Reynolds number are investigated accord-ingly.The experimental results show that when compared to those with only airflow,the heat transfer coefficient of the spherical elements with mistflow(j=112 kg/m2 hr,Re=55000)increases by 180%,75%,and 20%,respec-tively for thefirst,second,and third spherical element(the corresponding heat transfer enhancement ratio being 2.3,1.4,and 1.1).Additional numerical simulations reveal that the presence of stagnant zones with intense vortex formation around each spherical element contributes significantly to determine the heat transfer behavior.展开更多
Numerical simulation using Ansys Fluent code is performed,to investigate droplet generation in cross-junction based VOF method.Droplets of water are generated by the shear stress applied by continuous phase(oil),two c...Numerical simulation using Ansys Fluent code is performed,to investigate droplet generation in cross-junction based VOF method.Droplets of water are generated by the shear stress applied by continuous phase(oil),two configurations of cross-junction are suggested;the first is a simple model no modification is performed at the outer channel,while the second model is characterized by a lateral obstacle.we study the effect of velocity ratio,viscous parameter,interfacial tension,flow condition on droplet size and frequency,the effect of lateral obstacles on droplets generation is also focused and analysed.The numerical simulations showed that the velocity ratio and interfacial tension play a significant role in determining the droplet breakup and non-breakup.On the other side,the increase of flow rate ratio can be effectively used to decrease the droplet size.In addition,droplets produced in cross-junction with lateral obstacles are generally found to be larger than that produced with the first model.Moreover,the frequency of droplet production was increasing by increasing of flow rate ratio.The numerical results show very good agreements with previous numerical and experimental works for the growth of droplet breakup,size and frequency.展开更多
Climate room is an important instrument to study the icing problems in power networks,and the accuracy of the data from the climate room is under debate.There are many climate rooms in the world,but no standards about...Climate room is an important instrument to study the icing problems in power networks,and the accuracy of the data from the climate room is under debate.There are many climate rooms in the world,but no standards about the parameters of the climate room such as the room's temperature,the velocity of the wind,and the particle diameters of the water droplets etc.These parameters will influence the icing processes on the lines and insulators.This paper gave a summary of the process and the feature of atmospheric icing of power networks.The speed of the icing on a cylinder rod as a new characteristic quantity was proposed to study the de-icing problems in this paper.For the purpose to analyze the equivalence between atmospheric icing and icing in climate room,a finite element model was made based on a small climate room located in the Graduate School at Shenzhen,Tsinghua University.Through the simulation analysis for the heat transfer and flow issues,the result showed that precooling droplets were cooled into supercooled ones soon after they came into the climate room.Based on the most serious icing-speed in Hengshan,Hunan and a series of experiments,the values of some parameters in studying icing problems were proposed to better simulate the atmospheric icing in climate room.展开更多
Droplet shear stress is considered as an important indicator that reflects soil erosion in sprinkler irrigation more accurately than kinetic energy,and the effect of droplet impact angle on the shear stress cannot be ...Droplet shear stress is considered as an important indicator that reflects soil erosion in sprinkler irrigation more accurately than kinetic energy,and the effect of droplet impact angle on the shear stress cannot be ignored.In this study,radial distribution of droplet impact angles,velocities,and shear stresses were investigated using a two-dimensional video disdrometer with three types of low-pressure sprinkler(Nelson D3000,R3000,and Komet KPT)under two operating pressures(103 and 138 kPa)and three nozzle diameters(3.97,5.95,and 7.94 mm).Furthermore,the relationships among these characteristical parameters of droplet were analyzed,and their influencing factors were comprehensively evaluated.For various types of sprinkler,operating pressures,and nozzle diameters,the smaller impact angles and larger velocities of droplets were found to occur closer to the sprinkler,resulting in relatively low droplet shear stresses.The increase in distance from the sprinkler caused the droplet impact angle to decrease and velocity to increase,which contributed to a significant increase in the shear stress that reached the peak value at the end of the jet.Therefore,the end of the jet was the most prone to soil erosion in the radial direction,and the soil erosion in sprinkler irrigation could not only be attributed to the droplet kinetic energy,but also needed to be combined with the analysis of its shear stress.Through comparing the radial distributions of average droplet shear stresses among the three types of sprinklers,D3000 exhibited the largest value(26.94-3313.51 N/m^(2)),followed by R3000(33.34-2650.80 N/m^(2)),and KPT(16.15-2485.69 N/m^(2)).From the perspective of minimizing the risk of soil erosion,KPT sprinkler was more suitable for low-pressure sprinkler irrigation than D3000 and R3000 sprinklers.In addition to selecting the appropriate sprinkler type to reduce the droplet shear stress,a suitable sprinkler spacing could also provide acceptable results,because the distance from the sprinkler exhibited a highly significant(P<0.01)effect on the shear stress.This study results provide a new reference for the design of low-pressure sprinkler irrigation system.展开更多
The freezing and melting process of a small water droplet on a superhydrophobic cold surface was investigated using the Laser Induced Fluorescence(LIF)technique.The superhydrophobic surface was prepared using a sol-ge...The freezing and melting process of a small water droplet on a superhydrophobic cold surface was investigated using the Laser Induced Fluorescence(LIF)technique.The superhydrophobic surface was prepared using a sol-gel method on a red copper test plate.From the obtained fluorescence images,the phase transition characteristics during the freezing and melting process of a water droplet were clearly observed.It was found that,at the beginning of the droplet freezing process,liquid water turned into ice at a very fast rate.Such phase transition process decreased gradually with time and the volume of frozen ice approached a constant value at the end of the icing process.In addition,the freezing time was found to reduce with the decrease of the test plate temperature.Besides,when the test plate temperature is relatively high,the effect of droplet volume on the freezing time is very significant.Over all,we provide some tentative insights into the microphysical process related to the icing and melting process of water droplets.展开更多
Atmospheric corrosion of metals is the most common type of corrosion which has a significant impact on the environment and operational safety in various situations of everyday life.Some of the common examples can be o...Atmospheric corrosion of metals is the most common type of corrosion which has a significant impact on the environment and operational safety in various situations of everyday life.Some of the common examples can be observed in land,water and air transportation systems,electronic circuit boards,urban and offshore infrastructures.The dew drops formed on metal surface due to condensation of atmospheric moisture facilitates corrosion as an electrolyte.The corrosion mechanisms under these droplets are different from classically known bulk electrolyte corrosion.Due to thin and non-uniform geometric thickness of the droplet electrolyte,the atmospheric oxygen requires a shorter diffusion path to reach the metal surface.The corrosion under a droplet is driven by the depletion of oxygen in the center of the droplet compared to the edge,known as differential aeration.In case of a larger droplet,differential aeration leads to preferential cathodic activity at the edge and is controlled by the droplet geometry.Whereas,for a smaller droplet,the oxygen concentration remains uniform and hence cathodic activity is not controlled by droplet geometry.The geometry of condensed droplets varies dynamically with changing environmental parameters,influencing corrosion mechanisms as the droplets evolve in size.In this review,various modelling approaches used to simulate the corrosion under droplet electrolytes are presented.In the efforts of developing a comprehensive model to estimate corrosion rates,it has been noted from this review that the influence of geometric evolution of the droplet due to condensation/evaporation processes on corrosion mechanisms are yet to be modelled.Dynamically varying external factors like environmental temperature,relative humidity,presence of hygroscopic salts and pollutants influence the evolution of droplet electrolyte,making it a complex phenomenon to investigate.Therefore,an overview of available dropwise condensation and evaporation models which describes the formation and the evolution of droplet geometry are also presented from an atmo s pheric corrosion viewpoint.展开更多
The collision of a supercooled water droplet with a surface result an object creates ice accretion on the surface. The icing problem in any cold environments leads to severe damages on aircrafts, and a lot of studies ...The collision of a supercooled water droplet with a surface result an object creates ice accretion on the surface. The icing problem in any cold environments leads to severe damages on aircrafts, and a lot of studies on prevention and prediction techniques for icing have been conducted so far. Therefore, it is very important to know the detail of freezing mechanism of supercooled water droplets to improve the anti-and de-icing devices and icing simulation codes. The icing mechanism of a single supercooled water droplet impacting on an object surface would give us great insights for the purpose. In the present study, we develop a dual-luminescent imaging technique to measure the time-resolved temperature of a supercooled water droplet impacting on the surface under different temperature conditions. We apply this technique to measure the exact temperature of a water droplet, and to discuss the detail of the freezing process.展开更多
基金Science and Technology Project of State Grid Corporation(GY7111053)[www.sgcc.com.cn]。
文摘When separated water droplets condense on the surface of a composite insulator,the electrical field on the insulator surface is distorted.In turn,such distortions change the trajectories of pollution particles.In this study,the COMSOL software is used to simulate such a process for the FXBW4-10/100 composite insulator with or without water droplets condensation under a 10 kV DC voltage.The influence of the wind speed and particles concentration on the contamination characteristics of the considered 110 kV insulator is analyzed.The results show that:1)in the presence of water droplets on the insulator surface,the ratio of electrical field force and gravity acting on the particles is large;2)the contamination on the insulator surface increases with the wind speed;3)when the wind speed is small,the relationship between the contamination amount and the pollution concentration is essentially linear.
基金The authors thank Professor C.N.R.Rao,Fellow of Royal Society(FRS)for his encouragement.Support from the Department of Science and Technology,Government of India is gratefully acknowledged.N.K.acknowledges Council of Scientific and Industrial Research(CSIR)for funding.N.K.acknowledges Ritu for reading the manuscript.The authors thank Veeco India Nano-technology Laboratory at Jawaharlal Nehru Centre for Advanced Scientific Research(JNCASR)for the AFM facility.A.S.acknowledges INDO-US Science&Technology Forum(IUSSTF)for funding.
文摘Working with a biased atomic force microscope(AFM)tip in the tapping mode under ambient atmosphere,attoliter(10^(-18) L)water droplet patterns have been generated on a patterned carbonaceous surface.This is essentially electrocondensation of water leading to charged droplets,as evidenced from electrostatic force microscopy measurements.The droplets are unusual in that they exhibit a highly corrugated surface and evaporate rather slowly,taking several tens of minutes.
文摘Vortexing limestone injection into furnace combined with calcium lime hydration in the downstream is the most promising technology for controlling SO 2 emission. Particle imaging velocimetry (PIV) is used to measure the gas liquid solid three phase flow field in a reactor. By image processing based on newly developed software, the number concentrations of sorbent particles and water droplets are presented. The measuring results are very helpful for better understanding the desulfurization mechanism and optimizing configurational and operational parameters in the hydration reactor.
基金This work was financially supported by the National Natural Science Foundation of China(Grant Nos.51805505,52075514,and 51605460).
文摘Water is one of the most significant causes of lubrication failure.There is little research on the direct observation of the impact of water on lubrication properties.In this study,the influence of water on oil replenishment under different elastohydrodynamic(EHD)lubricating conditions is evaluated using optical interferometry and infrared microscopy,and a dimensionless criterion when water influences the film thickness is proposed.Evidence shows that the scour displacing effect and emulsification of water/oil are the main reasons for the reduction in film thickness.Once a water droplet enters an oil reservoir around the critical contact zone,it hardly moves away.This aggravates starvation,reduces the center film thickness of the contact,and leads to lubrication failure of the mechanical components.
基金This work was supported by the Jiangsu Natural Science Fund-Youth Fund(BK20190639)National Nature Science Foundation of China(Nos.21978318,51904300,and 51922106)National Key R&D Program of China(2020YFC1908803).
文摘Surface roughness plays a significant role in floatability of coal.In the present paper,coking coal surface was polished by three different sandpapers and the surface properties were characterized by contact angle and roughness measurements.The effect of surface roughness on floatability was investigated by adhesion force measurement system for measuring interaction forces between droplets/bubbles and coking coal surfaces with different roughness.The results showed that the contact angle decreased with increasing roughness yet the adhesion force between the water droplet and coal surface increased owing to the increased contact line and the appearance of line pinning.Maximum adhesion forces between water and surfaces were 111.70,125.48,and 136.42μN when the roughness was 0.23,0.98,and 2.79 μm,respectively.In contrast,under a liquid environment,the adhesion forces between air bubble/oil droplet and coal surfaces were decreased with increasing roughness because of the restriction by water.Maximum adhesion forces of increasing roughness were 97.14,42.76,and 17.86 μN measured at interfaces between air bubble and coal surfaces and 169.48,145.84,and 121.02 lN between oil droplet and surfaces,respectively.Decreasing roughness could be beneficial to the spreading of oil droplets and the adhesion of bubbles which is conducive to flotation separation.
文摘Aqueous phase layer around bubble and water droplet are two additional processes in solvent sublation. In the dynamic process of mass transfer, they are always neglected, but they are very important in the investigation of thermodynamic equilibrium. In this paper, the effect of water droplet in solvent sublation was discussed in detail, and the previous mathematical model of solvent subaltion was improved. Matlab 6.5 was used to simulate the process of water droplets, and the comparison between the previous hypothesis and the improvement in this paper showed the superiority, especially in the investigation of thermodynamic equilibrium. Moreover, the separation and concentration of the complex compound dithizone-Co(Ⅱ) from aqueous phase to n-octanol by solvent sublation also proved the improved mathematical model was reasonable.
文摘The cooling of a(pebble bed)spent fuel in a high-temperature gas-cooled reactor(HTGR)is adversely affected by an increase in the temperature of the used gas(air).To investigate this problem,a configuration consisting of three copper spheres arranged in tandem subjected to a forced mistflow inside a cylindrical channel is considered.The heat transfer coefficients and related variations as a function of Reynolds number are investigated accord-ingly.The experimental results show that when compared to those with only airflow,the heat transfer coefficient of the spherical elements with mistflow(j=112 kg/m2 hr,Re=55000)increases by 180%,75%,and 20%,respec-tively for thefirst,second,and third spherical element(the corresponding heat transfer enhancement ratio being 2.3,1.4,and 1.1).Additional numerical simulations reveal that the presence of stagnant zones with intense vortex formation around each spherical element contributes significantly to determine the heat transfer behavior.
文摘Numerical simulation using Ansys Fluent code is performed,to investigate droplet generation in cross-junction based VOF method.Droplets of water are generated by the shear stress applied by continuous phase(oil),two configurations of cross-junction are suggested;the first is a simple model no modification is performed at the outer channel,while the second model is characterized by a lateral obstacle.we study the effect of velocity ratio,viscous parameter,interfacial tension,flow condition on droplet size and frequency,the effect of lateral obstacles on droplets generation is also focused and analysed.The numerical simulations showed that the velocity ratio and interfacial tension play a significant role in determining the droplet breakup and non-breakup.On the other side,the increase of flow rate ratio can be effectively used to decrease the droplet size.In addition,droplets produced in cross-junction with lateral obstacles are generally found to be larger than that produced with the first model.Moreover,the frequency of droplet production was increasing by increasing of flow rate ratio.The numerical results show very good agreements with previous numerical and experimental works for the growth of droplet breakup,size and frequency.
基金Project Supported by National Natural Science Foundation of China(51077081)
文摘Climate room is an important instrument to study the icing problems in power networks,and the accuracy of the data from the climate room is under debate.There are many climate rooms in the world,but no standards about the parameters of the climate room such as the room's temperature,the velocity of the wind,and the particle diameters of the water droplets etc.These parameters will influence the icing processes on the lines and insulators.This paper gave a summary of the process and the feature of atmospheric icing of power networks.The speed of the icing on a cylinder rod as a new characteristic quantity was proposed to study the de-icing problems in this paper.For the purpose to analyze the equivalence between atmospheric icing and icing in climate room,a finite element model was made based on a small climate room located in the Graduate School at Shenzhen,Tsinghua University.Through the simulation analysis for the heat transfer and flow issues,the result showed that precooling droplets were cooled into supercooled ones soon after they came into the climate room.Based on the most serious icing-speed in Hengshan,Hunan and a series of experiments,the values of some parameters in studying icing problems were proposed to better simulate the atmospheric icing in climate room.
基金the National Natural Science Foundation of China(51939005)the Key Research and Development Program of Hebei Province,China(21327002D)+2 种基金the Hebei Forage Industry Innovation Team of Modern Agro-industry Technology Research System of China(HBCT2018160202)the Regional Collaborative Innovation Project of Xinjiang Uygur Autonomous Region of China(2021E02056)the China Agriculture Research System of Ministry of Finance and Ministry of Agriculture and Rural Affairs(CARS-34).
文摘Droplet shear stress is considered as an important indicator that reflects soil erosion in sprinkler irrigation more accurately than kinetic energy,and the effect of droplet impact angle on the shear stress cannot be ignored.In this study,radial distribution of droplet impact angles,velocities,and shear stresses were investigated using a two-dimensional video disdrometer with three types of low-pressure sprinkler(Nelson D3000,R3000,and Komet KPT)under two operating pressures(103 and 138 kPa)and three nozzle diameters(3.97,5.95,and 7.94 mm).Furthermore,the relationships among these characteristical parameters of droplet were analyzed,and their influencing factors were comprehensively evaluated.For various types of sprinkler,operating pressures,and nozzle diameters,the smaller impact angles and larger velocities of droplets were found to occur closer to the sprinkler,resulting in relatively low droplet shear stresses.The increase in distance from the sprinkler caused the droplet impact angle to decrease and velocity to increase,which contributed to a significant increase in the shear stress that reached the peak value at the end of the jet.Therefore,the end of the jet was the most prone to soil erosion in the radial direction,and the soil erosion in sprinkler irrigation could not only be attributed to the droplet kinetic energy,but also needed to be combined with the analysis of its shear stress.Through comparing the radial distributions of average droplet shear stresses among the three types of sprinklers,D3000 exhibited the largest value(26.94-3313.51 N/m^(2)),followed by R3000(33.34-2650.80 N/m^(2)),and KPT(16.15-2485.69 N/m^(2)).From the perspective of minimizing the risk of soil erosion,KPT sprinkler was more suitable for low-pressure sprinkler irrigation than D3000 and R3000 sprinklers.In addition to selecting the appropriate sprinkler type to reduce the droplet shear stress,a suitable sprinkler spacing could also provide acceptable results,because the distance from the sprinkler exhibited a highly significant(P<0.01)effect on the shear stress.This study results provide a new reference for the design of low-pressure sprinkler irrigation system.
基金supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Education Ministry and Science and Techology Commission of Shanghai Municipality(Grant No.11DZ2260400)
文摘The freezing and melting process of a small water droplet on a superhydrophobic cold surface was investigated using the Laser Induced Fluorescence(LIF)technique.The superhydrophobic surface was prepared using a sol-gel method on a red copper test plate.From the obtained fluorescence images,the phase transition characteristics during the freezing and melting process of a water droplet were clearly observed.It was found that,at the beginning of the droplet freezing process,liquid water turned into ice at a very fast rate.Such phase transition process decreased gradually with time and the volume of frozen ice approached a constant value at the end of the icing process.In addition,the freezing time was found to reduce with the decrease of the test plate temperature.Besides,when the test plate temperature is relatively high,the effect of droplet volume on the freezing time is very significant.Over all,we provide some tentative insights into the microphysical process related to the icing and melting process of water droplets.
基金financially supported by the European Union’s Horizon 2020 Research and Innovation Programme under the Marie Sklodowska-Curie grant agreement(No.764977)。
文摘Atmospheric corrosion of metals is the most common type of corrosion which has a significant impact on the environment and operational safety in various situations of everyday life.Some of the common examples can be observed in land,water and air transportation systems,electronic circuit boards,urban and offshore infrastructures.The dew drops formed on metal surface due to condensation of atmospheric moisture facilitates corrosion as an electrolyte.The corrosion mechanisms under these droplets are different from classically known bulk electrolyte corrosion.Due to thin and non-uniform geometric thickness of the droplet electrolyte,the atmospheric oxygen requires a shorter diffusion path to reach the metal surface.The corrosion under a droplet is driven by the depletion of oxygen in the center of the droplet compared to the edge,known as differential aeration.In case of a larger droplet,differential aeration leads to preferential cathodic activity at the edge and is controlled by the droplet geometry.Whereas,for a smaller droplet,the oxygen concentration remains uniform and hence cathodic activity is not controlled by droplet geometry.The geometry of condensed droplets varies dynamically with changing environmental parameters,influencing corrosion mechanisms as the droplets evolve in size.In this review,various modelling approaches used to simulate the corrosion under droplet electrolytes are presented.In the efforts of developing a comprehensive model to estimate corrosion rates,it has been noted from this review that the influence of geometric evolution of the droplet due to condensation/evaporation processes on corrosion mechanisms are yet to be modelled.Dynamically varying external factors like environmental temperature,relative humidity,presence of hygroscopic salts and pollutants influence the evolution of droplet electrolyte,making it a complex phenomenon to investigate.Therefore,an overview of available dropwise condensation and evaporation models which describes the formation and the evolution of droplet geometry are also presented from an atmo s pheric corrosion viewpoint.
文摘The collision of a supercooled water droplet with a surface result an object creates ice accretion on the surface. The icing problem in any cold environments leads to severe damages on aircrafts, and a lot of studies on prevention and prediction techniques for icing have been conducted so far. Therefore, it is very important to know the detail of freezing mechanism of supercooled water droplets to improve the anti-and de-icing devices and icing simulation codes. The icing mechanism of a single supercooled water droplet impacting on an object surface would give us great insights for the purpose. In the present study, we develop a dual-luminescent imaging technique to measure the time-resolved temperature of a supercooled water droplet impacting on the surface under different temperature conditions. We apply this technique to measure the exact temperature of a water droplet, and to discuss the detail of the freezing process.