A propagation experiment was conducted in the South China Sea in 2014 with a flat bottom and seamounts respectively by using explosive sources. The effects of seamounts on sound propagation are analyzed by using the b...A propagation experiment was conducted in the South China Sea in 2014 with a flat bottom and seamounts respectively by using explosive sources. The effects of seamounts on sound propagation are analyzed by using the broadband signals. It is observed that the transmission loss (TL) decreases up to 7 dB for the signals in the first shadow zone due to the seamount reflection. Moreover, the TL might increase more than 30 dB in the converge zone due to the shadowing by seamounts. Abnormal TLs and pulse arrival structures at different ranges are explained by using the ray and wave theory. The experimental TLs and arrival pulses are compared with the numerical results and found to be in good agreement.展开更多
Transport properties and the associated structural heterogeneity of room temperature aqueous ionic liquids and especially of super-concentrated electrolyte aqueous solutions have received increasing attention,due to t...Transport properties and the associated structural heterogeneity of room temperature aqueous ionic liquids and especially of super-concentrated electrolyte aqueous solutions have received increasing attention,due to their potential application in ionic battery.This paper briefly reviews the results reported mainly since 2010 about the liquid-liquid separation,aggregation of polar and apolar domains in neat RTILs,and solvent clusters and 3D networks chiefly constructed by anions in super-concentrated electrolyte solutions.At the same time,the dominating effect of desolvation process of metal ions at electrode/electrolyte interface upon the transport of metal ions is stressed.This paper also presents the current understanding of how water affects the anion-cation interaction,structural heterogeneities,the structure of primary coordination sheath of metal ions and consequently their transport properties in free water-poor electrolytes.展开更多
The effects of water and ice clouds on the cloud microphysical budget associated with rainfall are investigated through the analysis of grid-scale data from a series of two-dimensional cloud-resolving model equilibriu...The effects of water and ice clouds on the cloud microphysical budget associated with rainfall are investigated through the analysis of grid-scale data from a series of two-dimensional cloud-resolving model equilibrium sensitivity simulations. The model is imposed without large-scale vertical velocity. In the control experiment, the contribution from rainfall (cM) associated with net evaporation and hydrometeor loss/convergence is about 29% of that from the rainfall (Cm) associated with net condensation and hydrometeor gain/divergence and about 39% of that from the rainfall (CM) associated with net condensation and hydrometeor loss/convergence. The exclusion of ice clouds enhances rainfall contribution of CM, whereas it reduces rainfall contributions of Cm and cM. The removal of radiative effects of water clouds increases rainfall contribution of CM, barely changes rainfall contribution of Cm and reduces the rainfall contribution of cM in the presence of the radiative effects of ice clouds. Elimination of the radiative effects of water clouds reduces the rainfall contributions of CM and Cm, whereas it increases the rainfall contribution of cM in the absence of the radiative effects of ice clouds.展开更多
PHOBOTEX~? RSY durable water repellent delivers best-in-class performance to support the industry's shift to non-fluorinated formulations Continuing to lead the textile sector’s transition to more sustainable and...PHOBOTEX~? RSY durable water repellent delivers best-in-class performance to support the industry's shift to non-fluorinated formulations Continuing to lead the textile sector’s transition to more sustainable and eco-friendly business models,Huntsman Textile Effects has introduced the new PHOBOTEX~?RSY non-fluorinated durable water repellent(DWR)that raises the standard for repellency especially on high-performance synthetic textiles.This new product will allow brands and retailers to meet global demand for eco-friendly clothing that require extreme rain-and stain-protection.展开更多
The principles of fracture development during underwater blasting are examined based on explosion and impact dynamics,fluid dynamics,fracture dynamics,and field testing.The research reveals that the fracturing of the ...The principles of fracture development during underwater blasting are examined based on explosion and impact dynamics,fluid dynamics,fracture dynamics,and field testing.The research reveals that the fracturing of the surrounding rock during underwater blasting is due to the combined action of shock and stress waves for the initial rock breakage and subsequent water expansion.The fracture development model for the surrounding rock of a drilling hole during underwater blasting is established.The rock fracturing range under the combined action of shock and stress waves is developed,as well as the fracture propagation rules after the wedging of the water medium into the fractures.Finally,the results of deep-hole underwater blasting tests on large rocks confirm the efficient utilization of explosive in the hole to improve the safety conditions.Accordingly,safe and static rock breaking under the detonation of high-effect explosive can be achieved.In addition,super-dynamic loading from the explosions and static loading from the water medium in the hole can be adequately combined for rock breaking.展开更多
Shale samples of Silurian Longmaxi Formation in the Changning area of the Sichuan Basin, SW China, were selected to carry out scanning electron microscopy, CT imaging, high-pressure mercury injection, low-temperature ...Shale samples of Silurian Longmaxi Formation in the Changning area of the Sichuan Basin, SW China, were selected to carry out scanning electron microscopy, CT imaging, high-pressure mercury injection, low-temperature nitrogen adsorption and imbibition experiments to compare the hydration characteristics of montmorillonite and illite, analyze the main factors affecting the water block removal of shale, and reveal the mechanisms of pore structure evolution during shale hydration. The hydration characteristics of shale are closely related to the composition of clay minerals, the shale with high illite content is not susceptible to hydration and thus has limited room for pore structure improvement;the shale with high montmorillonite is susceptible to hydration expansion and thus has higher potential of pore structure improvement by stimulation;the shale with high illite content has stronger imbibition in the initial stage, but insufficient diffusion ability, and thus is likely to have water block;the shale with high montmorillonite content has weaker imbibition in the initial stage but better water diffusion, so water blocking in this kind of shale can be removed to some degree;the shale reservoir has an optimal hydration time, when it is best in physical properties, but hydration time too long would cause damage to the reservoir, and the shale with high illite content has a shorter optimal hydration time;inorganic cations can inhibit the hydration of clay minerals and have stronger inhibition to illite expansion, especially K^(+);for the reservoir with high content of montmorillonite, the cation content of fracturing fluid can be lowered to promote the shale hydration;fracturing fluid with high K^(+) content can be injected into reservoirs with high illite content to suppress hydration.展开更多
In this study,the Jinzhou 9-3 CEPD float-over installation project was investigated.During the undocking condition,the water depth of the motion path of the working barge gradually changed from 10.31 m to 9.41 m.The u...In this study,the Jinzhou 9-3 CEPD float-over installation project was investigated.During the undocking condition,the water depth of the motion path of the working barge gradually changed from 10.31 m to 9.41 m.The undocking clearance of the HYSY 228 is smaller than 1 m;therefore,the barge shows highly nonlinear hydrodynamic characteristics,and it is difficult to be accurately simulated by numerical analysis.Thus,it is necessary to obtain the hydrodynamic characteristics and laws of the float-over barge at different water depths by using tank model test,to provide some reference and guidance for float-over operations in shallow water.展开更多
Combined with irregular wave-maker, the growing process of Wave Energy Spectrum in shallow water can be studied in wind wave channel on different water depth conditions, and its transformation characteristics and rule...Combined with irregular wave-maker, the growing process of Wave Energy Spectrum in shallow water can be studied in wind wave channel on different water depth conditions, and its transformation characteristics and rules can be obtained.展开更多
Large-scale gas accumulation areas in large oil-gas basins in central and Western China have multiple special accumulation mechanisms and different accumulation effects.Based on the geological theory and method of nat...Large-scale gas accumulation areas in large oil-gas basins in central and Western China have multiple special accumulation mechanisms and different accumulation effects.Based on the geological theory and method of natural gas reservoir formation,this study examined the regional geological and structural background,formation burial evolution,basic characteristics of gas reservoirs,and fluid geology and geochemistry of typical petroliferous basins.The results show that the geological processes such as structural pumping,mudstone water absorption,water-soluble gas degasification and fluid sequestration caused by uplift and denudation since Himalayan stage all can form large-scale gas accumulation and different geological effects of gas accumulation.For example,the large-scale structural pumping effect and fluid sequestration effect are conducive to the occurrence of regional ultra-high pressure fluid and the formation of large-scale ultra-high pressure gas field;mudstone water absorption effect in the formation with low thickness ratio of sandstone to formation is conducive to the development of regional low-pressure and water free gas reservoir;the water-soluble gas degasification effect in large-scale thick sandstone can not only form large-scale natural gas accumulation;moreover,the degasification of water-soluble gas produced by the lateral migration of formation water will produce regional and regular isotopic fractionation effect of natural gas,that is,the farther the migration distance of water-soluble gas is,the heavier the carbon isotopic composition of methane formed by the accumulation.展开更多
The preparation of conducting PPQ film was first reported in the previous paper. It is very interesting that this film is highly sensitive to moisture in air. The hydration and dehydration of the film are accompanied ...The preparation of conducting PPQ film was first reported in the previous paper. It is very interesting that this film is highly sensitive to moisture in air. The hydration and dehydration of the film are accompanied by change not only in color but also in conductivity and UV-visible spectrum. The conducting PPQ is reduced to PPQ and loses its conductivity after being soaked in water.展开更多
As the classical transient flow model cannot simulate the water hammer effect of gas well, a transient flow mathematical model of multiphase flow gas well is established based on the mechanism of water hammer effect a...As the classical transient flow model cannot simulate the water hammer effect of gas well, a transient flow mathematical model of multiphase flow gas well is established based on the mechanism of water hammer effect and the theory of multiphase flow. With this model, the transient flow of gas well can be simulated by segmenting the curved part of tubing and calculating numerical solution with the method of characteristic curve. The results show that the higher the opening coefficient of the valve when closed, the larger the peak value of the wellhead pressure, the more gentle the pressure fluctuation, and the less obvious the pressure mutation area will be. On the premise of not exceeding the maximum shut-in pressure of the tubing, adopting large opening coefficient can reduce the impact of the pressure wave. The higher the cross-section liquid holdup, the greater the pressure wave speed, and the shorter the propagation period will be. The larger the liquid holdup, the larger the variation range of pressure, and the greater the pressure will be. In actual production, the production parameters can be adjusted to get the appropriate liquid holdup, control the magnitude and range of fluctuation pressure, and reduce the impact of water hammer effect. When the valve closing time increases, the maximum fluctuating pressure value of the wellhead decreases, the time of pressure peak delays, and the pressure mutation area gradually disappears. The shorter the valve closing time, the faster the pressure wave propagates. Case simulation proves that the transient flow model of gas well can optimize the reasonable valve opening coefficient and valve closing time, reduce the harm of water hammer impact on the wellhead device and tubing, and ensure the integrity of the wellbore.展开更多
A new Monte Carlo simulation of the track structure of low-energy electrons (〈10keV) in liquid water is presented. The feature of the simulation is taken into consideration of the condensed-phase effect of liquid w...A new Monte Carlo simulation of the track structure of low-energy electrons (〈10keV) in liquid water is presented. The feature of the simulation is taken into consideration of the condensed-phase effect of liquid water on electron elastic scattering with the use of the Champion model, while the dielectric response formalism incorporating the optical-data model developed by Emfietzoglou et al. is applied for calculating the electron inelastic scattering. The spatial distributions of energy deposition and inelastic scattering events of low-energy electrons with different primary energies in liquid water are calculated and compared with other theoretical evaluations. The present work shows that the condensed-phase effect of liquid water on electron elastic scattering may be of the influence on the fraction of absorbed energy and distribution of inelastic scattering events at lower primary energies, which also indicate potential effects on the DNA damage induced by low-energy electrons.展开更多
The effects of sea surface temperature(SST),cloud radiative and microphysical processes,and diurnal variations on rainfall statistics are documented with grid data from the two-dimensional equilibrium cloud-resolvin...The effects of sea surface temperature(SST),cloud radiative and microphysical processes,and diurnal variations on rainfall statistics are documented with grid data from the two-dimensional equilibrium cloud-resolving model simulations.For a rain rate of higher than 3 mm.h 1,water vapor convergence prevails.The rainfall amount decreases with the decrease of SST from 29℃ to 27℃,the inclusion of diurnal variation of SST,or the exclusion of microphysical effects of ice clouds and radiative effects of water clouds,which are primarily associated with the decreases in water vapor convergence.However,the amount of rainfall increases with the increase of SST from 29℃ to 31℃,the exclusion of diurnal variation of solar zenith angle,and the exclusion of the radiative effects of ice clouds,which are primarily related to increases in water vapor convergence.For a rain rate of less than 3 mm.h 1,water vapor divergence prevails.Unlike rainfall statistics for rain rates of higher than 3 mm.h 1,the decrease of SST from 29℃ to 27℃ and the exclusion of radiative effects of water clouds in the presence of radiative effects of ice clouds increase the rainfall amount,which corresponds to the suppression in water vapor divergence.The exclusion of microphysical effects of ice clouds decreases the amount of rainfall,which corresponds to the enhancement in water vapor divergence.The amount of rainfall is less sensitive to the increase of SST from 29℃ to 31℃ and to the radiative effects of water clouds in the absence of the radiative effects of ice clouds.展开更多
1 Introduction Shallow water delta in the middle-newborn Stratum Widely developed with huge oil and gas in China(Hu Shengwu et al.,2013).The control factors on the deltadevelopment like Climate,sea level,tectonic subs...1 Introduction Shallow water delta in the middle-newborn Stratum Widely developed with huge oil and gas in China(Hu Shengwu et al.,2013).The control factors on the deltadevelopment like Climate,sea level,tectonic subsidence,sediment supply(flow,type),the geometric characteristics of the upstream river,the energy(wave,展开更多
Mechanistic understanding of the active intermediates of 2,6-diaminopyridine(DAP) dinitration in the concentrated nitric-sulfuric acid system is of crucial importance for the selectivity control of target product, i.e...Mechanistic understanding of the active intermediates of 2,6-diaminopyridine(DAP) dinitration in the concentrated nitric-sulfuric acid system is of crucial importance for the selectivity control of target product, i.e., 2,6-diamino-3,5-dinitropyridine(DADNP). The active intermediates determining the product selectivity are theoretically studied. The HSO_(4)^(-)-NO_(2)^(+) complex is proposed as the dominant active nitrating intermediate for the first time, which shows low energy barrier(i.e., 10.19 kcal·mol^(-1),1 kcal = 4.186 k J) for direct dinitration of DAP to DADNP. The formed water during the reaction results in not only the formation of less active SO_(4)^(2-)-NO_(2)^(+) complex, but also the occurance of DAP sulfonation(DAP-SO_(3)H intermediate)to facilitate the formation of mononitration byproduct. Meanwhile, the accompanied thermal effects cause the generation of undesirable pyridine-NHNO_(2) intermediate, which is difficult to be rearranged to yield DADNP, inhibiting the reaction and thus giving low DAP conversion. The insights reported here elucidates the importance of thermal effects elimination and water content control, confirmed experimentally in the batch-and micro-reaction systems.展开更多
The water promotion effects,where water can provide a solution-mediated reaction pathway in various heterogeneous chemical catalysis,have been presented and attracted wide attention recently,yet,the rational design of...The water promotion effects,where water can provide a solution-mediated reaction pathway in various heterogeneous chemical catalysis,have been presented and attracted wide attention recently,yet,the rational design of catalysts with a certain ability of enhancing water-induced reaction process is full of challenges and difficulties.Here,we show that by incorporating alkali(Na,K)cations as an electronic and/or structural promoter into Pd/rGO-ZnCr_(2)O_(4)(r GO,reduced graphene oxide),the obtained Pd(Na)/rGO-ZnCr_(2)O_(4)as a representative example demonstrates an outstanding benzyl alcohol oxidation activity in the Pickering emulsion system in comparison to the alkali-free counterpart.The response experiments of water injection confirm the enhanced activity,and the Na-modified catalyst can further enhance the promotion effects of water on the reaction.The effects of alkali cations for Pd nanoparticles are identified and deciphered by a series of experimental characterizations(XPS,in situ CO-DRIFTS,and CO-TPR coupled with MS),showing that there is abundant-OH on the surface of the catalyst,which is stabilized by the formation of Pd-OH_(x).The alkali-stabilized Pd-OH_(x)is helpful to enhance the waterinduced reaction process.According to the results of in situ Raman as well as UV-vis absorption spectra,the Na-modulated Pd(Na)/rGO-ZnCr_(2)O_(4)enables the beneficial characteristics for distorting the benzyl alcohol structure and enhancing the adsorption of benzyl alcohol.Further,the mechanism for enhanced water promotion effects is rationally proposed.The strategy of alkali cations-modified catalysts can provide a new direction to effectively enhance the chemical reaction involving small molecule water.展开更多
基金Supported by the National Nature Science Foundation of China under Grant Nos 11434012 and 11174312
文摘A propagation experiment was conducted in the South China Sea in 2014 with a flat bottom and seamounts respectively by using explosive sources. The effects of seamounts on sound propagation are analyzed by using the broadband signals. It is observed that the transmission loss (TL) decreases up to 7 dB for the signals in the first shadow zone due to the seamount reflection. Moreover, the TL might increase more than 30 dB in the converge zone due to the shadowing by seamounts. Abnormal TLs and pulse arrival structures at different ranges are explained by using the ray and wave theory. The experimental TLs and arrival pulses are compared with the numerical results and found to be in good agreement.
基金the National Natural Science Foundation of China(Grant Nos.11974385 and 91956101)the Fund from the Chinese Academy of Sciences(Grant No.1731300500030)the Strategic Priority Research Program of Chinese Academy of Sciences(Grant No.XDB07030100).
文摘Transport properties and the associated structural heterogeneity of room temperature aqueous ionic liquids and especially of super-concentrated electrolyte aqueous solutions have received increasing attention,due to their potential application in ionic battery.This paper briefly reviews the results reported mainly since 2010 about the liquid-liquid separation,aggregation of polar and apolar domains in neat RTILs,and solvent clusters and 3D networks chiefly constructed by anions in super-concentrated electrolyte solutions.At the same time,the dominating effect of desolvation process of metal ions at electrode/electrolyte interface upon the transport of metal ions is stressed.This paper also presents the current understanding of how water affects the anion-cation interaction,structural heterogeneities,the structure of primary coordination sheath of metal ions and consequently their transport properties in free water-poor electrolytes.
基金Project supported by the National Key Basic Research and Development Project of China (Grant No.2012CB417201)the National Natural Sciences Foundation of China (Grant Nos.40930950 41075043,41275065,and 41075044)the 985 Program of Zhejiang University (Grant No.188020+193432602/215)
文摘The effects of water and ice clouds on the cloud microphysical budget associated with rainfall are investigated through the analysis of grid-scale data from a series of two-dimensional cloud-resolving model equilibrium sensitivity simulations. The model is imposed without large-scale vertical velocity. In the control experiment, the contribution from rainfall (cM) associated with net evaporation and hydrometeor loss/convergence is about 29% of that from the rainfall (Cm) associated with net condensation and hydrometeor gain/divergence and about 39% of that from the rainfall (CM) associated with net condensation and hydrometeor loss/convergence. The exclusion of ice clouds enhances rainfall contribution of CM, whereas it reduces rainfall contributions of Cm and cM. The removal of radiative effects of water clouds increases rainfall contribution of CM, barely changes rainfall contribution of Cm and reduces the rainfall contribution of cM in the presence of the radiative effects of ice clouds. Elimination of the radiative effects of water clouds reduces the rainfall contributions of CM and Cm, whereas it increases the rainfall contribution of cM in the absence of the radiative effects of ice clouds.
文摘PHOBOTEX~? RSY durable water repellent delivers best-in-class performance to support the industry's shift to non-fluorinated formulations Continuing to lead the textile sector’s transition to more sustainable and eco-friendly business models,Huntsman Textile Effects has introduced the new PHOBOTEX~?RSY non-fluorinated durable water repellent(DWR)that raises the standard for repellency especially on high-performance synthetic textiles.This new product will allow brands and retailers to meet global demand for eco-friendly clothing that require extreme rain-and stain-protection.
基金National Natural Science Foundation of China(51604262)Foundation Research Project of Jiangsu Province(BK20160256)China Postdoctoral Science Foundation Project(2018M632424).
文摘The principles of fracture development during underwater blasting are examined based on explosion and impact dynamics,fluid dynamics,fracture dynamics,and field testing.The research reveals that the fracturing of the surrounding rock during underwater blasting is due to the combined action of shock and stress waves for the initial rock breakage and subsequent water expansion.The fracture development model for the surrounding rock of a drilling hole during underwater blasting is established.The rock fracturing range under the combined action of shock and stress waves is developed,as well as the fracture propagation rules after the wedging of the water medium into the fractures.Finally,the results of deep-hole underwater blasting tests on large rocks confirm the efficient utilization of explosive in the hole to improve the safety conditions.Accordingly,safe and static rock breaking under the detonation of high-effect explosive can be achieved.In addition,super-dynamic loading from the explosions and static loading from the water medium in the hole can be adequately combined for rock breaking.
基金Supported by the Science and Technology Planning Project of Sichuan Province,China(2020YJ0135)National Natural Science Foundation of China(51874250)。
文摘Shale samples of Silurian Longmaxi Formation in the Changning area of the Sichuan Basin, SW China, were selected to carry out scanning electron microscopy, CT imaging, high-pressure mercury injection, low-temperature nitrogen adsorption and imbibition experiments to compare the hydration characteristics of montmorillonite and illite, analyze the main factors affecting the water block removal of shale, and reveal the mechanisms of pore structure evolution during shale hydration. The hydration characteristics of shale are closely related to the composition of clay minerals, the shale with high illite content is not susceptible to hydration and thus has limited room for pore structure improvement;the shale with high montmorillonite is susceptible to hydration expansion and thus has higher potential of pore structure improvement by stimulation;the shale with high illite content has stronger imbibition in the initial stage, but insufficient diffusion ability, and thus is likely to have water block;the shale with high montmorillonite content has weaker imbibition in the initial stage but better water diffusion, so water blocking in this kind of shale can be removed to some degree;the shale reservoir has an optimal hydration time, when it is best in physical properties, but hydration time too long would cause damage to the reservoir, and the shale with high illite content has a shorter optimal hydration time;inorganic cations can inhibit the hydration of clay minerals and have stronger inhibition to illite expansion, especially K^(+);for the reservoir with high content of montmorillonite, the cation content of fracturing fluid can be lowered to promote the shale hydration;fracturing fluid with high K^(+) content can be injected into reservoirs with high illite content to suppress hydration.
文摘In this study,the Jinzhou 9-3 CEPD float-over installation project was investigated.During the undocking condition,the water depth of the motion path of the working barge gradually changed from 10.31 m to 9.41 m.The undocking clearance of the HYSY 228 is smaller than 1 m;therefore,the barge shows highly nonlinear hydrodynamic characteristics,and it is difficult to be accurately simulated by numerical analysis.Thus,it is necessary to obtain the hydrodynamic characteristics and laws of the float-over barge at different water depths by using tank model test,to provide some reference and guidance for float-over operations in shallow water.
文摘Combined with irregular wave-maker, the growing process of Wave Energy Spectrum in shallow water can be studied in wind wave channel on different water depth conditions, and its transformation characteristics and rules can be obtained.
基金Supported by the National Science and Technology Major Project(2016ZX05003-002)Scientific Research Project of Petro China Company Limited(2016E-0601)
文摘Large-scale gas accumulation areas in large oil-gas basins in central and Western China have multiple special accumulation mechanisms and different accumulation effects.Based on the geological theory and method of natural gas reservoir formation,this study examined the regional geological and structural background,formation burial evolution,basic characteristics of gas reservoirs,and fluid geology and geochemistry of typical petroliferous basins.The results show that the geological processes such as structural pumping,mudstone water absorption,water-soluble gas degasification and fluid sequestration caused by uplift and denudation since Himalayan stage all can form large-scale gas accumulation and different geological effects of gas accumulation.For example,the large-scale structural pumping effect and fluid sequestration effect are conducive to the occurrence of regional ultra-high pressure fluid and the formation of large-scale ultra-high pressure gas field;mudstone water absorption effect in the formation with low thickness ratio of sandstone to formation is conducive to the development of regional low-pressure and water free gas reservoir;the water-soluble gas degasification effect in large-scale thick sandstone can not only form large-scale natural gas accumulation;moreover,the degasification of water-soluble gas produced by the lateral migration of formation water will produce regional and regular isotopic fractionation effect of natural gas,that is,the farther the migration distance of water-soluble gas is,the heavier the carbon isotopic composition of methane formed by the accumulation.
基金Project supported by the National Natural Science Foundation of China
文摘The preparation of conducting PPQ film was first reported in the previous paper. It is very interesting that this film is highly sensitive to moisture in air. The hydration and dehydration of the film are accompanied by change not only in color but also in conductivity and UV-visible spectrum. The conducting PPQ is reduced to PPQ and loses its conductivity after being soaked in water.
基金Supported by National Science and Technology Major Project of the Ministry of Science and Technology of China(2016ZX05026-002,2016ZX05028-001,2016ZX05024-005)
文摘As the classical transient flow model cannot simulate the water hammer effect of gas well, a transient flow mathematical model of multiphase flow gas well is established based on the mechanism of water hammer effect and the theory of multiphase flow. With this model, the transient flow of gas well can be simulated by segmenting the curved part of tubing and calculating numerical solution with the method of characteristic curve. The results show that the higher the opening coefficient of the valve when closed, the larger the peak value of the wellhead pressure, the more gentle the pressure fluctuation, and the less obvious the pressure mutation area will be. On the premise of not exceeding the maximum shut-in pressure of the tubing, adopting large opening coefficient can reduce the impact of the pressure wave. The higher the cross-section liquid holdup, the greater the pressure wave speed, and the shorter the propagation period will be. The larger the liquid holdup, the larger the variation range of pressure, and the greater the pressure will be. In actual production, the production parameters can be adjusted to get the appropriate liquid holdup, control the magnitude and range of fluctuation pressure, and reduce the impact of water hammer effect. When the valve closing time increases, the maximum fluctuating pressure value of the wellhead decreases, the time of pressure peak delays, and the pressure mutation area gradually disappears. The shorter the valve closing time, the faster the pressure wave propagates. Case simulation proves that the transient flow model of gas well can optimize the reasonable valve opening coefficient and valve closing time, reduce the harm of water hammer impact on the wellhead device and tubing, and ensure the integrity of the wellbore.
文摘A new Monte Carlo simulation of the track structure of low-energy electrons (〈10keV) in liquid water is presented. The feature of the simulation is taken into consideration of the condensed-phase effect of liquid water on electron elastic scattering with the use of the Champion model, while the dielectric response formalism incorporating the optical-data model developed by Emfietzoglou et al. is applied for calculating the electron inelastic scattering. The spatial distributions of energy deposition and inelastic scattering events of low-energy electrons with different primary energies in liquid water are calculated and compared with other theoretical evaluations. The present work shows that the condensed-phase effect of liquid water on electron elastic scattering may be of the influence on the fraction of absorbed energy and distribution of inelastic scattering events at lower primary energies, which also indicate potential effects on the DNA damage induced by low-energy electrons.
基金Project supported by the National Basic Research Program of China (Grant No. 2012CB417201)the National Natural Science Foundation of China (Grant Nos. 41075034,40930950,40975034,and 41075044)
文摘The effects of sea surface temperature(SST),cloud radiative and microphysical processes,and diurnal variations on rainfall statistics are documented with grid data from the two-dimensional equilibrium cloud-resolving model simulations.For a rain rate of higher than 3 mm.h 1,water vapor convergence prevails.The rainfall amount decreases with the decrease of SST from 29℃ to 27℃,the inclusion of diurnal variation of SST,or the exclusion of microphysical effects of ice clouds and radiative effects of water clouds,which are primarily associated with the decreases in water vapor convergence.However,the amount of rainfall increases with the increase of SST from 29℃ to 31℃,the exclusion of diurnal variation of solar zenith angle,and the exclusion of the radiative effects of ice clouds,which are primarily related to increases in water vapor convergence.For a rain rate of less than 3 mm.h 1,water vapor divergence prevails.Unlike rainfall statistics for rain rates of higher than 3 mm.h 1,the decrease of SST from 29℃ to 27℃ and the exclusion of radiative effects of water clouds in the presence of radiative effects of ice clouds increase the rainfall amount,which corresponds to the suppression in water vapor divergence.The exclusion of microphysical effects of ice clouds decreases the amount of rainfall,which corresponds to the enhancement in water vapor divergence.The amount of rainfall is less sensitive to the increase of SST from 29℃ to 31℃ and to the radiative effects of water clouds in the absence of the radiative effects of ice clouds.
文摘1 Introduction Shallow water delta in the middle-newborn Stratum Widely developed with huge oil and gas in China(Hu Shengwu et al.,2013).The control factors on the deltadevelopment like Climate,sea level,tectonic subsidence,sediment supply(flow,type),the geometric characteristics of the upstream river,the energy(wave,
基金financially supported by the National Natural Science Foundation of China, China (21922803, 22122807, and 22008072)the Innovation Program of Shanghai Municipal Education Commission, China+1 种基金the Program of Shanghai Academic/Technology Research Leader, China (21XD1421000)the China Postdoctoral Science Foundation, China (2020M671025 and 2019TQ0093)。
文摘Mechanistic understanding of the active intermediates of 2,6-diaminopyridine(DAP) dinitration in the concentrated nitric-sulfuric acid system is of crucial importance for the selectivity control of target product, i.e., 2,6-diamino-3,5-dinitropyridine(DADNP). The active intermediates determining the product selectivity are theoretically studied. The HSO_(4)^(-)-NO_(2)^(+) complex is proposed as the dominant active nitrating intermediate for the first time, which shows low energy barrier(i.e., 10.19 kcal·mol^(-1),1 kcal = 4.186 k J) for direct dinitration of DAP to DADNP. The formed water during the reaction results in not only the formation of less active SO_(4)^(2-)-NO_(2)^(+) complex, but also the occurance of DAP sulfonation(DAP-SO_(3)H intermediate)to facilitate the formation of mononitration byproduct. Meanwhile, the accompanied thermal effects cause the generation of undesirable pyridine-NHNO_(2) intermediate, which is difficult to be rearranged to yield DADNP, inhibiting the reaction and thus giving low DAP conversion. The insights reported here elucidates the importance of thermal effects elimination and water content control, confirmed experimentally in the batch-and micro-reaction systems.
基金supported by the National Natural Science Foundation of China(NSFC,Nos.51872035 and 22078052)the Innovation Program of Dalian City of Liaoning Province(No.2019RJ03)。
文摘The water promotion effects,where water can provide a solution-mediated reaction pathway in various heterogeneous chemical catalysis,have been presented and attracted wide attention recently,yet,the rational design of catalysts with a certain ability of enhancing water-induced reaction process is full of challenges and difficulties.Here,we show that by incorporating alkali(Na,K)cations as an electronic and/or structural promoter into Pd/rGO-ZnCr_(2)O_(4)(r GO,reduced graphene oxide),the obtained Pd(Na)/rGO-ZnCr_(2)O_(4)as a representative example demonstrates an outstanding benzyl alcohol oxidation activity in the Pickering emulsion system in comparison to the alkali-free counterpart.The response experiments of water injection confirm the enhanced activity,and the Na-modified catalyst can further enhance the promotion effects of water on the reaction.The effects of alkali cations for Pd nanoparticles are identified and deciphered by a series of experimental characterizations(XPS,in situ CO-DRIFTS,and CO-TPR coupled with MS),showing that there is abundant-OH on the surface of the catalyst,which is stabilized by the formation of Pd-OH_(x).The alkali-stabilized Pd-OH_(x)is helpful to enhance the waterinduced reaction process.According to the results of in situ Raman as well as UV-vis absorption spectra,the Na-modulated Pd(Na)/rGO-ZnCr_(2)O_(4)enables the beneficial characteristics for distorting the benzyl alcohol structure and enhancing the adsorption of benzyl alcohol.Further,the mechanism for enhanced water promotion effects is rationally proposed.The strategy of alkali cations-modified catalysts can provide a new direction to effectively enhance the chemical reaction involving small molecule water.