Effects of Volume Ratios of Water Phase to Oily Phase on Morphology and Releasing Performance of Emulsion Electrospun Fibers

Emulsion electrospinning as a novel process in spinning core-sheath fibers shows a promising potential in drug release control. The volume ratio of water phase to oily phase is one of the critical parameters in forming core-sheath fibers. In this study, water phase was presented by hydrophilic tetracycline hydrochloride and oily phase by hydrophobic poly （E-caprolactone） （PCL）. The effects of volume ratios of water phase to oily phase on fiber morphology and in vitro drug release were investigated. Scanning electron microscopy （ SEM ）, transmission electron microscopy （ TEM）, and eonfoeal laser scanning microscopy（CLSM） were used to observe the morphology, core.sheath structure of the fibers and drug loading in the fibers, respectively. Samples of three different volume ratios of water phase to oily phase, 1： 25, 1：15, and 1：10, were prepared with the same concentration of drug solution. Experiment results showed that, with an increase in the volume ratios of water phase to oily phase, the fiber diameter increased and diameter distribution scattered. The drug entrapment efficiency of the fibers reduces with the increase in volume ratios, L e. , from 73.48 % in the ratio of 1 ： 25, 62.23 % in 1 ： 15, down to 45.63 % in 1：10. In vitro release tests showed that a higher volume ratio of water phase to oily phase would lead to a lower release rate resulted from thicker fiber sheath.

Simultaneous Determination of Bisphenols and Alkylphenols in Water by Solid Phase Extraction and Ultra Performance Liquid Chromatography-tandem Mass Spectrometry

To establish an analytical method for determination of four bisphenols （BPA, BPB, BPF, and BPS） and two alkylphenols （4-n-OP, 4-n-NP） in water by ultra performance liquid chromatography- tandem mass spectrometry （UPLC/MS/MS）. The water samples were extracted and condensed with solid-phase extraction （SPE） using C18 cartridges and eluted by acetonitrile. Separation was carried out with Acquity BEH C8 column and detection were performed by UPLC/MS/MS. Quantification was calculated by using the internal standard BPA-d16 and 4-n-NP-d8. The linear correlation coefficients of these compounds in the range of 1.0-100.0μg/L were all over 0.999. The minimum detectable concentrations were 0.75-1.0 ng/L, and the recoveries ranged from 87.0% to 106.9%.

Attractor comparison analysis for characterizing vertical upward oil gas water three-phase flow

We investigate the dynamic characteristics of oil-gas-water three-phase flow in terms of chaotic attractor comparison. In particular, we extract a statistic to characterize the dynamical difference in attractor probability distribution. We first take time series from Logistic chaotic system with different parameters as examples to demonstrate the effectiveness of the method. Then we use this method to investigate the experimental signals from oil-gas-water three-phase flow. The results indicate that the extracted statistic is very sensitive to the change of flow parameters and can gain a quantitatively insight into the dynamic characteristics of different flow patterns.

A 100% Water Mobile Phase HPLC-PDA Analysis of Meamine and Related Analogues

This paper describes a reserved-phase high performance liquid chromatographic method for detecting melamine (MEL) and related analogues, cyanuric acid (CYA), ammeline (AML), and ammelide (AMD), using a 100% water mobile phase. Chromatographic separation was performed an Inertsil? ODS-4 (250 × 4.6 mm, 5 μm) with a water mobile phase and a photodiode-array detector. The monitoring wavelength was adjusted to 210 nm which represents an average maximum for all the analytes. The total run time was < 8 min. The method shows high stability, significant linearity and satisfactory sensitivity. The detection limits were established in the range 23 - 46 ng.mL–1. An inexpensive and harmless method for the simultaneous detection of MEL, CYA, AML, and AMD was developed and may be further applied to the quantification in foods.

Determination of volatile organic compounds in river water by solid phase extraction and gas chromatography

A simple, rapid, and reproducible method is described employing solid phase extraction(SPE) using dichloromethane followed by gas chromatography(GC) with flame ionization detection(FID) for determination of volatile organic compound(VOC) from the Buriganga River water of Bangladesh. The method was applied to detect the benzene, toluene, ethylbenzene, xylene and cumene(BTEXC) in the sample collected from the surface or 15 cm depth of water. Two hundred ml of n hexane pretreated and filtered water samples were applied directly to a C 18 SPE column. BTEXC were extracted with dichloromethane and average concentrations were obtained as 0 104 to 0 372 μg/ml. The highest concentration of benzene was found as 0 372 μg/ml with a relative standard deviation(RSD) of 6 2%, and cumene was not detected. Factors influencing SPE e.g., adsorbent types, sample load volume, eluting solvent, headspace and temperatures, were investigated. A cartridge containing a C 18 adsorbent and using dichloromethane gave better performance for extraction of BTEXC from water. Average recoveries exceeding 90% could be achieved for cumene at 4℃ with a 2 7% RSD.

Formation of Polyethersulfone Film with Regular Microporous Structure by Water Vapor Induced Phase Separation

Polyethersulfone(PES)film with regular microporous structure was formed using dichloromethane as the solvent via water vapor induced phase separation(VIPS).The effects of solution concentration,atmospheric humidity and temperature,as well as molecular weight of PES on the surface morphology of the polymer film were investigated.The surface morphology characterized by SEM showed that the pore size reduced as the solution concentration increased.There was an optimum range of relative humidity for the formation of regular pore structure, which was from 60%to 90%at concentration of 20 g·L-1 and 20°C.With the atmospheric temperature varied from 20 to 30°C,the pore became larger and the space between pores increased.The pore size in the PES film with low molecular weight was smaller than that with high molecular weight.

Availability of MCNP & MATLAB for reconstructing the water-vapor two-phase flow pattern in neutron radiography

The China Advanced Research Reactor (CARR) is scheduled to be operated in the autumn of 2008.In this paper,we report preparations for installing the neutron radiography instrument (NRI) and for utilizing it efficiently. The 2-D relative neutron intensity profiles for the water-vapor two-phase flow inside the robe were obtained using the MCNP code without influence of y-ray and electronic-noise.The MCNP simulation of the 2-D neutron intensity profile for the water-vapor two-phase flow was demonstrated.The simulated 2-D neutron intensity profiles could be used as the benchmark data base by calibrating part of the data measured by the CARR-NRI.The 3-D objective images allow us to understand the flow pattern more clearly and it is reconstructed using the MATLAB through the threshold transformation techniques.And thus it is concluded that the MCNP code and the MATLAB are very useful for constructing the benchmark data base for the investigation of the water-vapor two-phase flow using the CARR-NRI.

Preparation and Phase Transformation Behavior of Boehmite via Heat Treatment in Water Vapor

Boehmite was prepared under heat treatment in water vapour, and the phase transformation of gibbsite heat-treated at various temperatures was investigated. The sample was characterized by scanning electron microscopy(SEM), X-ray diffraction (XRD), thermogravimetry and differential thermalanalysis (TG-DTA), fourier transform infrared (FTIR),and BET surface area.Effect of temperature on preparation was studied in the range of 155°–195°.With the increase in temperature, transformation of gibbsite into crystalline boehmites took place as indicated by the X-ray diffraction (XRD). The shape of the grains in the prepared sample was cube-like morphology.In water vapour gibbsite transform into boehmite by a dissolution - precipitation mechanism.

THE STUDY ON THREE-DIMENSIONAL MATHEMATICAL MODEL OF RIVER BED EROSION FOR WATER-SEDIMENT TWO-PHASE FLOW

Based on the tensor analysis of water-sediment two-phase how, the basic model equations for clear water flow and sediment-laden flow are deduced in the general curve coordinates for natural water variable-density turbulent how. Furthermore, corresponding boundary conditions are also presented in connection with the composition and movement of non-uniform bed material. The theoretical results are applied to the calculation of the float open caisson in the construction period and good results are obtained.

Phase Equilibria of Salt-water Systems Containing Magnesium and Borate Ions

1 Introduction A salt lake is a naturally occurring complex body of water and salt interaction.More than 700 salt lakes are widely distributed in the area of the Qinghai-Tibet Plateau.Most of the salt lakes are famous for their abundance of lithium,potassium,magnesium,and boron resources.It is

Preparation and Characterization of CA-MA Eutectic/Silicon Dioxide Nanoscale Composite Phase Change Material from Water Glass via Sol-Gel Method

This work mainly involved the preparation of a nano-scale form-stable phase change material（PCM） consisting of capric and myristic acid（CA-MA） binary eutectic acting as thermal absorbing material and nano silicon dioxide（nano-SiO_2） serving as the supporting material. Industrial water glass for preparation of the nano silicon dioxide matrix and CA-MA eutectic mixture were compounded by single-step sol-gel method with the silane coupling agent. The morphology, chemical characterization and form stability property of the composite PCM were investigated by transmission electron microscopy（TEM）, scanning electron microscopy（SEM）, Fourier-transform infrared（FT-IR） spectroscopy and polarizing microscopy（POM）. It was indicated that the average diameter of the composite PCM particle ranged from 30-100 nm. The CA-MA eutectic was immobilized in the network pores constructed by the Si-O bonds so that the composite PCM was allowed no liquid leakage above the melting temperature of the CA-MA eutectic. Differential scanning calorimetry（DSC） and thermogravimetric analysis（TGA） measurement were conducted to investigate the thermal properties and stability of the composite PCM. From the measurement results, the mass fraction of the CA-MA eutectic in the composite PCM was about 40%. The phase change temperature and latent heat of the composite were determined to be 21.15 ℃ and 55.67 J/g, respectively. Meanwhile, thermal conductivity of the composite was measured to be 0.208 W·m^（-1）·K^（-1） by using the transient hot-wire method. The composite PCM was able to maintain the surrounding temperature close to its phase change temperature and behaved well in thermalregulated performance which was verified by the heat storage-release experiment. This kind of form-stable PCM was supposed to complete thermal insulation even temperature regulation by the dual effect of relatively low thermal conductivity and phase change thermal storage-release properties. So it can be formulated that the nanoscale CA-MA/SiO_2 composite PCM with the form-stable property, good thermal storage capacity and relatively low thermal conductivity can be applied for energy conservation as a kind of thermal functional material.

Experimental study on steam-water two-phase flow frictional pressure drops in helical coils

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Phase transition model of water flow irradiated by high-energy laser in a chamber

In the absorption chamber of a high-energy laser energy meter, water is directly used as an absorbing medium and the interaction of the high-power laser and the water flow can produce a variety of physical phenomena such as phase transitions. The unit difference method is adopted to deduce the phase transition model for water flow irradiated by a high-energy laser. In addition, the model is simulated and verified through experiments. Among them, the experimental verification uses the photographic method, shooting the distribution and the form of the air mass of water flow in different operating conditions, which are compared with the simulation results. The research shows that it is achievable to reduce the intensity of the phase transition by increasing the water flow, reducing the power intensity of the beam, shortening the distance the beam covers, reducing the initial water temperature or adopting a shorter wavelength laser. The study＇s results will provide the reference for the design of a water-direct-absorption-type high-energy laser energy meter as well as an analysis of the interaction processes of other similar high-power lasers and water flow.

Measurement and correlation of solid–liquid phase equilibria for binary and ternary systems consisting of N-vinylpyrrolidone, 2-pyrrolidone and water

The solid–liquid equilibria(SLE)for binary and ternary systems consisting of N-Vinylpyrrolidone(NVP),2-Pyrrolidone(2-P)and water are measured.The phase diagrams of NVP(1)+2-P(2),NVP(1)+water(2),NVP(1)+2-P(2)+1 wt%water(3)and NVP(1)+2-P(2)+2 wt%water(3)are identified as simple eutectic type with the eutectic points at 263.75 K(x_(1E)=0.5427),251.65 K(x_(1E)=0.3722),260.25 K(x_(1E)=0.5031)and256.55 K(x_(1E)=0.4684),respectively.The phase diagram of 2-P(1)+water(2)has two eutectic points(x_(1E)=0.1236,T_E=259.15 K and x_(1E)=0.7831,T_E=286.15 K)and one congruent melting point(x_(1C)=0.4997,T_C=303.55 K)because of the generation of a congruently melting addition compound:2-P·H_2O.The ideal solubility and the UNIFAC models were applied to predict the SLE,while the Wilson and NRTL models were employed in correlating the experimental data.The best correlation of the SLE data has been obtained by the Wilson model for the binary system of NVP+2-P.The UNIFAC model gives more satisfactory predictions than the ideal solubility model.

A Proton Nuclear Magnetic Resonance (¹H NMR) Investigation of NaCl-Induced Phase Separation of Acetonitrile-Water Mixtures

The microscopic properties of NaCl-induced phase separation of acetonitrile (ACN)-water mixtures have been studied by proton nuclear magnetic resonance (1H NMR). Acetonitrile-rich phase increases with increasing NaCl concentration (cNaCl) at xACN ≈ 0.25. 1H chemical shift of water for acetonitrile-rich phase rapidly decreases with decreasing NaCl mole concentration and that for water-rich phase quickly increases with increasing cNaCl. However, 1H chemical shift of acetonitrile has nothing to do with the molar concentration of NaCl, and it keeps relatively stable for all solutions (±0.002). These results reveal that Na+ and Cl- are rapidly hydrated by water, not by acetonitrile. The change of 1H chemical shift of water has shown that the number of hydrogen bond increases or hydrogen bond strengths with increasing NaCl molarity in mixtures. But hydrogen bond is broken or weaken with the temperature rising. 1H chemical shifts of pure water and the water in acetonitrile-rich phase have been investigated at 293 K, 298 K and 303 K. The hydration number of Na+ (6.05) in water-rich phase is determined by an empirical equation involving 1H chemical shift, temperature and NaCl molarity, which is in good agreement with the literatures.

Rapid determination of atrazine in environmental water samples by a novel liquid phase microextraction

A novel method was described for the rapid determination of atrazine using dispersive liquid phase microextraction in combination with high performance liquid chromatography （HPLC）. Possible impact parameters such as sample pH, extraction and disperser solvents, salting-out effect, and extraction time were investigated. The experimental results indicated that proposed method possessed an excellent analytical performance, The linear range, detection limit, and precision （R.S.D.） were 0.1- 50 ng mL- 1 （R2 = 0.9955）, 0.601 ng mL- 1 and 6,4%, respectively. The proposed method was validated with the real water samples, and the spiked recoveries were in the range of 69.9-89.8%, respectively. These results indicated that the established method with high enrichment factor, short extraction time was an excellent alternative for the routine analysis of atrazine in environmental samples. 2007 Qing Xiang Zhou. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

Experimental and numerical simulation of air-water two-phase flow in the rod bundle with grid spacer

Experimental and numerical simulation were carried out on vertically upward air-water two-phase flow in the rod bundle with grid spacer. The related numerical simulation has been performed by using the Computational Fluid Dynamics code-CFX4.2, in which lateral interfacial effects based on a two-fluid model are accounted for. This model has been used to evaluate the velocity fields of gas and liquid phases, as well as phase distribution between elements in rod bundle by simulating 1/4 zone of experimental model, and mixing vanes of spacer in this area. Fur- thermore, this model has been used to predict the effects of spacer on flow and pressure drop along the rod bundle. The calculation results show that the mixing vane has significant influence on axial and lateral velocity. In order to obtain some experimental data to verify the numerical solutions, a series of tests, using a specially designed 3×3 rod bundle test section with AFA-2G structure spacer have been performed. An optical probe was used to measure local void fractions. At the same time, the pressure loss has been measured. A comparison between the calculated void pro- file and pressure loss and the measured results shows that the predicted void profiles are consistent at low gas appar- ent velocity. This research shows that the code CFX4.2 can be used to describe the 3-D air-water two-phase flow in the rod bundle channel with grid spacer.

Observation of cavitation and water-refilling processes in plants with X-ray phase contrast microscopy

With the spatial coherence of X-rays and high flux and brightness of the 3rd generation synchrotron radiation facility,X-ray phase contrast microscopy(XPCM)at Shanghai Synchrotron Radiation Facility(SSRF)can provide high resolution dynamic imaging of low electron density materials in principle.In this paper,we investigated the cavitation and water-refilling processes in rice and bamboo leaves utilizing XPCM at SSRF.The occurrence of xylem cavitation was recorded in vivo.The study also revealed that under different dehydration conditions,cavitation occurs in different degrees,and therefore,the refilling process is different.The results demonstrate that SSRF can provide high enough fluxes to study dynamic processes in plants in real-time,and XPCM is expected to be a promising method to reveal the mechanisms of cavitation and its repair in plants nondestructively.

TWO-PHASE FLOW FOR A HORIZONTAL WELL PENETRATING A NATURALLY FRACTURED RESERVOIR WITH EDGE WATER INJECTION

This paper examines the two-phase flow for a horizontal well penetrating a naturally fractured reservoir with edge water injection by means of a fixed streamlinemodel,The mathematical model of the verical two-dimensional flow or oil-water for a horizontal well in a medium with double-porosity is established ,and whose accuratesolutions are obtained by using the characteristic method .The saturation distributionsin the fractured system and the matrix system as well as the formula of the time of water free production are presented .All these results provide a theoretical basis and a computing method for oil displacement by edge water from naturally fracturedreservirs.

Numerical Study of Thermal Performance of Phase Change Material Energy Storage Floor in Solar Water Heating System

The conventional solar heating floor system contains a big water tank to store energy in the day time for heating at night,which takes much building space and is very heavy.In order to reduce the water tank volume even to cancel the tank,a novel structure of integrated water pipe floor heating system using shape-stabilized phase change materials(SSPCM)for thermal energy storage was developed.A numerical model was developed to analyze the performance of SSPCM floor heating system under the intermittent heating condition,which was verified by our experimental data.The thermal performance of the heating system and the effects of various factors on it were analyzed numerically.The factors including phase transition temperature,heat of fusion,thermal conductivity of SSPCM and thermal conductivity of the decoration material were analyzed.The results show that tm and kd are the most import influencing factors on the thermal performance of SSPCM floor heating system,since they determine the heat source temperature and thermal resistance between SSPCM plates and indoor air,respectively.Hm should be large to store enough thermal energy in the day time for nighttimes heating.The effects of kp can be ignored in this system.The SSPCM floor heating system has potential of making use of the daytime solar energy for heating at night efficiently in various climates when its structure is properly designed.