The title compound, [Ni（tssb）（2,2-bipy）2].5（H2O） 1 （tssbH2 =2-[（E）-（2-oxido- phenyl）methyleneamino]ethanesulfonato, 2,2-bipy = 2,2＇-bipyridinyl）, belongs to orthorhombic, space group Pbcn with a = 20.3983...The title compound, [Ni（tssb）（2,2-bipy）2].5（H2O） 1 （tssbH2 =2-[（E）-（2-oxido- phenyl）methyleneamino]ethanesulfonato, 2,2-bipy = 2,2＇-bipyridinyl）, belongs to orthorhombic, space group Pbcn with a = 20.3983（18）, b = 17.6929（15）, c = 17.0897（15） nm, V= 6167.8（9） nm^3, Mr= 688.38, Z = 8, De = 1.481 g.cm^-3, F（000） = 2880,μ = 0.758 mm-1 and S =1.099. Each NiIr atom is six-coordinated by one N and one O atoms from one tssb^2- anion and four N atoms from two 2,2-bipy ligands to give a distorted octahedral geometry. Noticeably, there exists a rare octa-mem- bered water ring which presents a 1D chain by sulfonic group.展开更多
A new complex, [Ni（L）2]·2（H2O） I （HL = 2-iminomethyl-6-methoxyphenol）, has been synthesized and structurally determined. The crystal belongs to the trigonal system, space group R3- with a = 1.9341 （3）, b ...A new complex, [Ni（L）2]·2（H2O） I （HL = 2-iminomethyl-6-methoxyphenol）, has been synthesized and structurally determined. The crystal belongs to the trigonal system, space group R3- with a = 1.9341 （3）, b = 1.9341 （3）, C = 1.2048（2） nm, V = 3.9029（11） nm^3, Mr = 395.05, Z = 9, Dc = 1.513 g·cm^-3, F（000） = 1854,μ= 1.153 mm^-1 and S = 1.014. Each Ni^Ⅱ atom is four-coordinated by two N and two O atoms from two different L anions to give a slightly distorted square-plane geometry. The complex forms a 3-D network structure through N-H...O and O-H...O hydrogen bonds containing an interesting six-membered water ring.展开更多
Pipes inevitably encounter high ambient pressure and bending moment during the deepwater pipe-laying process,which can lead to elliptical buckling and even deterioration failure.For the safety of pipe-laying operation...Pipes inevitably encounter high ambient pressure and bending moment during the deepwater pipe-laying process,which can lead to elliptical buckling and even deterioration failure.For the safety of pipe-laying operation,available formulas for the pipe stability are established on the basis of the assumption of uniform deformation along the tube length and symmetrical buckling.This method can predict the nonlinear response of elliptical collapse of steel circular tubes for different ratios of diameter to thickness（D/t）under pure bending or combined bending and external pressure.In these formulas,the strain-displacement relationship is deduced from the nonlinear ring theory,and the Ramberg-Osgood constitutive model is applied to simulate the inelastic material behavior.Meanwhile,the principle of virtual work is adopted to derive the equilibrium equations.A set of equations is solved by the Newton-Raphson method,and the iterative scheme contains nested iteration for the constitutive relation.In order to check the effectiveness of this theoretical method,illustrative examples are presented in this paper.Besides,the numerical simulation is carried out by use of ANSYS.A comparison of the results shows that the theoretical method can provide reasonable prediction for engineering practice.展开更多
基金Supported by the Key Laboratory of Non-ferrous Metal Materials and New Processing TechnologyMinistry of Education and the State Key Laboratory of Coordination Chemistry
文摘The title compound, [Ni（tssb）（2,2-bipy）2].5（H2O） 1 （tssbH2 =2-[（E）-（2-oxido- phenyl）methyleneamino]ethanesulfonato, 2,2-bipy = 2,2＇-bipyridinyl）, belongs to orthorhombic, space group Pbcn with a = 20.3983（18）, b = 17.6929（15）, c = 17.0897（15） nm, V= 6167.8（9） nm^3, Mr= 688.38, Z = 8, De = 1.481 g.cm^-3, F（000） = 2880,μ = 0.758 mm-1 and S =1.099. Each NiIr atom is six-coordinated by one N and one O atoms from one tssb^2- anion and four N atoms from two 2,2-bipy ligands to give a distorted octahedral geometry. Noticeably, there exists a rare octa-mem- bered water ring which presents a 1D chain by sulfonic group.
基金the Key Laboratory of Non-ferrous Metal Materials and New Processing Technology, Ministry of Education and the State Key Laboratory of Coordination Chemistry
文摘A new complex, [Ni（L）2]·2（H2O） I （HL = 2-iminomethyl-6-methoxyphenol）, has been synthesized and structurally determined. The crystal belongs to the trigonal system, space group R3- with a = 1.9341 （3）, b = 1.9341 （3）, C = 1.2048（2） nm, V = 3.9029（11） nm^3, Mr = 395.05, Z = 9, Dc = 1.513 g·cm^-3, F（000） = 1854,μ= 1.153 mm^-1 and S = 1.014. Each Ni^Ⅱ atom is four-coordinated by two N and two O atoms from two different L anions to give a slightly distorted square-plane geometry. The complex forms a 3-D network structure through N-H...O and O-H...O hydrogen bonds containing an interesting six-membered water ring.
基金supported by the National High Technology Research and Development Programof China(863 Program,Grant No.2006AA09A105)
文摘Pipes inevitably encounter high ambient pressure and bending moment during the deepwater pipe-laying process,which can lead to elliptical buckling and even deterioration failure.For the safety of pipe-laying operation,available formulas for the pipe stability are established on the basis of the assumption of uniform deformation along the tube length and symmetrical buckling.This method can predict the nonlinear response of elliptical collapse of steel circular tubes for different ratios of diameter to thickness（D/t）under pure bending or combined bending and external pressure.In these formulas,the strain-displacement relationship is deduced from the nonlinear ring theory,and the Ramberg-Osgood constitutive model is applied to simulate the inelastic material behavior.Meanwhile,the principle of virtual work is adopted to derive the equilibrium equations.A set of equations is solved by the Newton-Raphson method,and the iterative scheme contains nested iteration for the constitutive relation.In order to check the effectiveness of this theoretical method,illustrative examples are presented in this paper.Besides,the numerical simulation is carried out by use of ANSYS.A comparison of the results shows that the theoretical method can provide reasonable prediction for engineering practice.
