Defect Engineering:Can it Mitigate Strong Coulomb Effect of Mg^(2+)in Cathode Materials for Rechargeable Magnesium Batteries?

Rechargeable magnesium batteries(RMBs)have been considered a promising“post lithium-ion battery”system to meet the rapidly increasing demand of the emerging electric vehicle and grid energy storage market.However,the sluggish diffusion kinetics of bivalent Mg^(2+)in the host material,related to the strong Coulomb effect between Mg^(2+)and host anion lattices,hinders their further development toward practical applications.Defect engineering,regarded as an effective strategy to break through the slow migration puzzle,has been validated in various cathode materials for RMBs.In this review,we first thoroughly understand the intrinsic mechanism of Mg^(2+)diffusion in cathode materials,from which the key factors affecting ion diffusion are further presented.Then,the positive effects of purposely introduced defects,including vacancy and doping,and the corresponding strategies for introducing various defects are discussed.The applications of defect engineering in cathode materials for RMBs with advanced electrochemical properties are also summarized.Finally,the existing challenges and future perspectives of defect engineering in cathode materials for the overall high-performance RMBs are described.

Feature extraction of welding defect based on machine vision

There are many flaws in welding images such as noise, low contrast, and blurred edges, which affect feature extraction from welding defect regions and impede classification and recognition of welding defects. To deal with the complexity of welding defect images, this paper proposes an effective method for extracting the features of welding defect regions. Firstly, image preprocessing, image segmentation and image background removal are carried out to a welding image in order to extract welding defect region; and then an 8-connected-component labeling method is used to mark defect regions. Finally, it extracts geometric characteristic parameters including perimeter, area, circularity and others. The experimental result shows that the method proposed in the paper can accurately extract the features of welding defect regions. It has good adaptability and practicability.

Noise Reduction of Welding Defect Image Based on NSCT and Anisotropic Diffusion

In order to reduce noise effectively in the welding defect image and preserve the minutiae information, a noise reduction method of welding defect image based on nonsubsampled contourlet transform(NSCT) and anisotropic diffusion is proposed. Firstly, an X-ray welding defect image is decomposed by NSCT. Then total variation(TV) model and Catte_PM model are used for the obtained low-pass component and band-pass components, respectively. Finally, the denoised image is synthesized by inverse NSCT. Experimental results show that, compared with the hybrid method of wavelet threshold shrinkage with TV diffusion, the method combining NSCT with P_Laplace diffusion, and the method combining contourlet with TV model and adaptive contrast diffusion, the proposed method has a great improvement in the aspects of subjective visual effect, peak signal-to-noise ratio(PSNR) and mean-square error(MSE). Noise is suppressed more effectively and the minutiae information is preserved better in the image.

Enlarged-end tool for friction stir lap welding towards hook defect controlling

Hook defect is one of the trickiest issues for friction stir lap welding,which remains to be resolved.In this study,a designed pin with an enlarged-end was proposed to control the interfacial hook defect by optimizing its morphology orientation.The insert aduncous structure at the advancing side is dissected by multilayer metallographic observation,which is the main character to terminate the inner-ward extension of the hook.The application of this tool was verified practical with a varied plunge depth of pin into the lower plate from 0.1 mm to 1.6 mm.The angle of the hook was small and terminated at the insert-structure or oriented toward the material convergence region.No joint fractured along the hook line and the highest joint efficiency reached 86%of the parent 6082-T4 aluminum alloy.

Analysis of defects in clean fabrication process of friction stir welding

Striving for cleaner production is a sought-after manufacturing philosophy.Friction stir welding(FSW)is a joiningtechnique with par excellence and far less invasive to the environment than even best conventional welding processes.It is energyefficient and free from consumables,affluent and radiations.It is,thus,accepted as a clean welding process that can produceacceptable quality joints.It suffers from some major challenges of defects of its own kind that subject the process open toimprovements so as to prove itself a reliable production process.This study presents a holistic characterization of defects commonlyfound in FSW joints.The finding of the present study reveals that most defects are caused by inadequate heat generation,impropermaterial movement around the pin and inadequate material consolidation behind the pin.The amount of heat generation andmaterial stirring depends on several FSW parameters which may lead to the defect formation,if not selected properly.The resultsreported in this work are derived from sound literature support and experimentation.Prescriptions are made in the form ofcharacteristics of defects such as likelihood of their location,main responsible parameters along with the recommendations forminimizing them.

Formative mechanism of the undercut defect in horizontal variable polarity plasma arc welding

Abstract Horizontal welding is important for heavy or huge welding structures. Keyhole mode variable polarity plasma arc welding of aluminum alloy plates with medium thickness was carried out in horizontal position. The characteristic of welding defects was introduced. Preliminary experiments indicated that the undercut defect could not be eliminated easily. The relationship between welding parameters and the undercut defect showed that this deject could be lessened by using higher heat input. The fluid flow of weld pool was observed by a high speed camera. The fluid flow in weld pool was not symmetric and much of molten metal gathered in the lower part. The fluid flow velocity in the lower part was bigger than that in the upper part. To this end, the formative mechanism of the undercut defect was proposed. The flowability of the molten metal was an influential factor for the undercut defect. A preheating method was designed to verify the formative mechanism.

Repair welding process of friction stir welding groove defect

The groove defect formed in the friction stir welding dramatically deteriorates weld appearances and mechanical properties of the joints owing to its larger size and penetration. Therefore, the friction stir repair welding was utilized to remove such a groove defect, and the focus was placed on the mechanical properties and microstructural characteristics of the repair joints so as to obtain an optimum repair welding process. The experimental results indicate that the groove defect can be removed by friction stir repair welding, and the offset repair welding process is superior to the symmetrical repair welding process. In the symmetrical repair welding process, a large number of fine cavity defects and an obvious aggregation of hard-brittle phase Al2Cu occur, accordingly the mechanical properties of the repair joint are weakened, and the fracture feature of repair joint is partially brittle and partially plastic. A good-quality repair joint can be obtained by the offset repair welding process, and the repair joint is fractured near the interface between the weld nugget zone and thermal-mechanically affected zone.

Finite element analysis of the effect of micro-pore defect on linear friction welding of medium carbon steel

Micro-pore is a very common material defect. In the present paper, the temperature fields of medium carbon steel joints with and without micro-pore defect during linear friction welding （LFW） were investigated by using finite element method. The effect of micro-pore defect on the axial shortening of joints during LFW was examined. The x- and y-direction displacements of micro-pore during the LFW process were also studied. In addition, the shape of micro-pore after LFW was observed. The heat conducted from the weld inteace to the specimen interior. The fluctuation range of the temperature curves for the joint with micro-pore is larger than that without micro-pore. Position of micro-pore changes with the change of the friction time. The circular shape of micro-pore becomes oval after welding.

Analysis of vibration signal responses on pre induced tunnel defects in friction stir welding using wavelet transform and empirical mode decomposition

Among many condition-monitoring systems in welding operation,Defect identification is an important method to ensure the precision in finishing operation.Friction stir welding is a solid state welding process used to join two metals without the use of electrode at lower temperatures.The aim of this present work is to identify and localize the tunnel defect in aluminum alloy and measure the distance of the defect zone in the time domain of the vibration signal during Friction stir welding.The vibration signals are captured from the experiments and the burst in the vibration signal is focused in the analysis.A signal-processing scheme is proposed to filter the noise and to measure the dimensional parameters of the defect area.The proposed technique consists of discrete wavelet transform(DWT),which is used to decompose the signal.The enveloping technique is applied on the decomposed zero padded signal.The continuous wavelet transform(CWT) has been implemented on detailed signal followed by a time marginal integration(TMI) of the CWT scalogram.Empirical mode decomposition(EMD) is used to replace the detailing coefficients from DWT with Intrinsic Mode Function(IMF).Statistical parameters such as mean,kurtosis,S.D and crest factor have been extracted from the final filtered signal for validating the defect welds from the control defect free welds.Results produced were found to be that kurtosis is 7.4402 for tunnel defect induced weld and 3.3862 for defect free welds.As the increase in kurtosis value predicts the defect zone impact in the signal.The measurement of the defect zone of the cut 1(voids) and cut 2(tunnel grooves) in correlation with the processed signal is found to produce a much redundant results with an error rate of 0.02.

Study on intelligent image welding defects in recognition for the tube pressure vessels

Currently, the welding defects recognition of X-ray nondestructive inspection is principally carried out by manual work, which highly depends on the experience of the inspectors and costs plenty of workload. In this paper, an intelligent image processing and recognition method for the tube welding radiographic testing in large-scale pressure vessels is proposed. Firstly, the raw image is preprocessed by median filtering, pseudo point removing and non-lincar image enhancement. Secondly, the welded joints parts are separated from the whole image by edge detection and threshold segmentation algorithms. Then, the separated images are handled by FFT transformation. Finally, whether defects exist and the specific type of defects are judged by Support Vector Machine. Software developed basing on this method works stably on site, and experiments demonstrate that the recognition results are compliance with the JB/T 4730. 2 or ASME standards.

Classified recognition for metal magnetic memory signals of welding defects in API 5L X65 pipeline steel

Feature extraction and selection from signals is a key issue for metal magnetic memory testing technique. In order to realize the classification of metal magnetic memory signals of welding defects, four fractal analysis methods, such as box- counting, detrended fluctuation, minimal cover and rescaled-range analysis, were used to extract the feature signal after the original metal magnet memory signal was de-noising and differential processing, then the Karhunen-Lo^e transformation was adopted as classification tool to identify the defect signals. The result shows that this study can provide an efficient classification method for metal magnetic memory signal of welding defects.

Decade Milestone Advancement of Defect-Engineered g-C_(3)N_(4) for Solar Catalytic Applications

Over the past decade, graphitic carbon nitride(g-C_(3)N_(4)) has emerged as a universal photocatalyst toward various sustainable carbo-neutral technologies. Despite solar applications discrepancy, g-C_(3)N_(4) is still confronted with a general fatal issue of insufficient supply of thermodynamically active photocarriers due to its inferior solar harvesting ability and sluggish charge transfer dynamics. Fortunately, this could be significantly alleviated by the “all-in-one” defect engineering strategy, which enables a simultaneous amelioration of both textural uniqueness and intrinsic electronic band structures. To this end, we have summarized an unprecedently comprehensive discussion on defect controls including the vacancy/non-metallic dopant creation with optimized electronic band structure and electronic density, metallic doping with ultraactive coordinated environment(M–N_(x), M–C_(2)N_(2), M–O bonding), functional group grafting with optimized band structure, and promoted crystallinity with extended conjugation π system with weakened interlayered van der Waals interaction. Among them, the defect states induced by various defect types such as N vacancy, P/S/halogen dopants, and cyano group in boosting solar harvesting and accelerating photocarrier transfer have also been emphasized. More importantly, the shallow defect traps identified by femtosecond transient absorption spectra(fs-TAS) have also been highlighted. It is believed that this review would pave the way for future readers with a unique insight into a more precise defective g-C_(3)N_(4) “customization”, motivating more profound thinking and flourishing research outputs on g-C_(3)N_(4)-based photocatalysis.

Fatigue Behavior of a Dissimilar Aluminum Alloy Welding Joint With and Without Natural Defect

In order to investigate the influence of natural defect on the fatigue behavior of 5A06/7A05 dissimilar aluminum alloys welding joint,fatigue tests of two types of specimens with and without defects were carried out systematically under stress amplitude control conditions (stress ratio R=0.1) at normal temperature in laboratory air condition.Furthermore,a new parameter,i e,fatigue defect effect factor (FDEF) was introduced to assess the effect of defect on fatigue strength.The fatigue failure analysis was conducted as well to compare the fatigue and fracture behavior of the two types of specimens.The results show that:(1) natural defects have a strong effect on the fatigue lives of welding joint,and the differences between the specimens with and without defects can reach 80 times under a same theoretical net sectional stress;(2) the FDEF parameter introduced is effective to deal with the defect effect,and the FDEF decreases along with the increase of fatigue life.The mean relative error between the experimental data and predicted fatigue strength based on the FDEF is 10.2%;(3) the macro fracture of both types of specimens have three typical zones,i e,fatigue source zone,crack propagation zone and final fracture zone,while there are more than one fatigue sources for specimens with natural defects.The overall pattern of crack propagation zone and fracture zone are quite similar,but the morphologies are different in details.

A review of linear friction welding of Ni -based superalloys

Ni-based superalloys are one of the most important materials employed in high-temperature applications within the aerospace and nuclear energy industries and in gas turbines due to their excellent corrosion,radiation,fatigue resistance,and high-temperature strength.Linear friction welding(LFW)is a new joining technology with near-net-forming characteristics that can be used for the manu-facture and repair of a wide range of aerospace components.This paper reviews published works on LFW of Ni-based superalloys with the aim of understanding the characteristics of frictional heat generation and extrusion deformation,microstructures,mechanical proper-ties,flash morphology,residual stresses,creep,and fatigue of Ni-based superalloy weldments produced with LFW to enable future optim-um utilization of the LFW process.

Heterointerface Engineering-Induced Oxygen Defects for the Manganese Dissolution Inhibition in Aqueous Zinc Ion Batteries

Manganese-based material is a prospective cathode material for aqueous zinc ion batteries(ZIBs)by virtue of its high theoretical capacity,high operating voltage,and low price.However,the manganese dissolution during the electrochemical reaction causes its electrochemical cycling stability to be undesirable.In this work,heterointerface engineering-induced oxygen defects are introduced into heterostructure MnO_(2)(δa-MnO_(2))by in situ electrochemical activation to inhibit manganese dissolution for aqueous zinc ion batteries.Meanwhile,the heterointerface between the disordered amorphous and the crystalline MnO_(2)ofδa-MnO_(2)is decisive for the formation of oxygen defects.And the experimental results indicate that the manganese dissolution ofδa-MnO_(2)is considerably inhibited during the charge/discharge cycle.Theoretical analysis indicates that the oxygen defect regulates the electronic and band structure and the Mn-O bonding state of the electrode material,thereby promoting electron transport kinetics as well as inhibiting Mn dissolution.Consequently,the capacity ofδa-MnO_(2)does not degrade after 100 cycles at a current density of 0.5 Ag^(-1)and also 91%capacity retention after 500cycles at 1 Ag^(-1).This study provides a promising insight into the development of high-performance manganese-based cathode materials through a facile and low-cost strategy.

Impact Analysis of Microscopic Defect Types on the Macroscopic Crack Propagation in Sintered Silver Nanoparticles

Sintered silver nanoparticles(AgNPs)arewidely used in high-power electronics due to their exceptional properties.However,the material reliability is significantly affected by various microscopic defects.In this work,the three primary micro-defect types at potential stress concentrations in sintered AgNPs are identified,categorized,and quantified.Molecular dynamics(MD)simulations are employed to observe the failure evolution of different microscopic defects.The dominant mechanisms responsible for this evolution are dislocation nucleation and dislocation motion.At the same time,this paper clarifies the quantitative relationship between the tensile strain amount and the failure mechanism transitions of the three defect types by defining key strain points.The impact of defect types on the failure process is also discussed.Furthermore,traction-separation curves extracted from microscopic defect evolutions serve as a bridge to connect the macro-scale model.The validity of the crack propagation model is confirmed through tensile tests.Finally,we thoroughly analyze how micro-defect types influence macro-crack propagation and attempt to find supporting evidence from the MD model.Our findings provide a multi-perspective reference for the reliability analysis of sintered AgNPs.

Trace Cobalt Doping and Defect Engineering of High Surface Area α-Ni(OH)_(2) for Electrocatalytic Urea Oxidation

Owing to the intrinsically sluggish kinetics of urea oxidation reaction(UOR)involving a six-electron transfer process,developing efficient UOR electrocatalyst is a great challenge remained to be overwhelmed.Herein,by taking advantage of 2-Methylimidazole,of which is a kind of alkali in water and owns strong coordination ability to Co^(2+)in methanol,trace Co(1.0 mol%)addition was found to induce defect engineering onα-Ni(OH)_(2)in a dual-solvent system of water and methanol.Physical characterization results revealed that the synthesized electrocatalyst(WM-Ni_(0.99)Co_(0.01)(OH)_(2))was a kind of defective nanosheet with thickness around 5-6 nm,attributing to the synergistic effect of Co doping and defect engineering,its electron structure was finely altered,and its specific surface a rea was tremendously enlarged from 68 to 172.3 m^(2)g^(-1).With all these merits,its overpotential to drive 10 mA cm^(-2)was reduced by 110 mV.Besides,the interfacial behavior of UOR was also well deciphered by operando electrochemical impedance spectroscopy.

YOLO-DD:Improved YOLOv5 for Defect Detection

As computer technology continues to advance,factories have increasingly higher demands for detecting defects.However,detecting defects in a plant environment remains a challenging task due to the presence of complex backgrounds and defects of varying shapes and sizes.To address this issue,this paper proposes YOLO-DD,a defect detectionmodel based on YOLOv5 that is effective and robust.To improve the feature extraction process and better capture global information,the vanilla YOLOv5 is augmented with a new module called Relative-Distance-Aware Transformer(RDAT).Additionally,an Information Gap Filling Strategy(IGFS)is proposed to improve the fusion of features at different scales.The classic lightweight attention mechanism Squeeze-and-Excitation(SE)module is also incorporated into the neck section to enhance feature expression and improve the model’s performance.Experimental results on the NEU-DET dataset demonstrate that YOLO-DDachieves competitive results compared to state-of-the-art methods,with a 2.0% increase in accuracy compared to the original YOLOv5,achieving 82.41% accuracy and38.25FPS(framesper second).Themodel is also testedon a self-constructed fabric defect dataset,and the results show that YOLO-DD is more stable and has higher accuracy than the original YOLOv5,demonstrating its stability and generalization ability.The high efficiency of YOLO-DD enables it to meet the requirements of industrial high accuracy and real-time detection.

Defect engineering in transition-metal(Fe,Co,andNi)-based electrocatalysts for water splitting

Electrocatalytic water splitting seems to be an efficient strategy to deal with increasingly serious environmental problems and energy crises but still suffers from the lack of stable and efficient electrocatalysts.Designing practical electrocatalysts by introducing defect engineering,such as hybrid structure,surface vacancies,functional modification,and structural distortions,is proven to be a dependable solution for fabricating electrocatalysts with high catalytic activities,robust stability,and good practicability.This review is an overview of some relevant reports about the effects of defect engineering on the electrocatalytic water splitting performance of electrocatalysts.In detail,the types of defects,the preparation and characterization methods,and catalytic performances of electrocatalysts are presented,emphasizing the effects of the introduced defects on the electronic structures of electrocatalysts and the optimization of the intermediates'adsorption energy throughout the review.Finally,the existing challenges and personal perspectives of possible strategies for enhancing the catalytic performances of electrocatalysts are proposed.An in-depth understanding of the effects of defect engineering on the catalytic performance of electrocatalysts will light the way to design high-efficiency electrocatalysts for water splitting and other possible applications.

Recent research progress in the mechanism and suppression of fusion welding-induced liquation cracking of nickel based superalloys

Nickel-based superalloys are extensively used in the crucial hot-section components of industrial gas turbines,aeronautics,and astronautics because of their excellent mechanical properties and corrosion resistance at high temperatures.Fusion welding serves as an effective means for joining and repairing these alloys;however,fusion welding-induced liquation cracking has been a challenging issue.This paper comprehensively reviewed recent liquation cracking,discussing the formation mechanisms,cracking criteria,and remedies.In recent investigations,regulating material composition,changing the preweld heat treatment of the base metal,optimizing the welding process parameters,and applying auxiliary control methods are effective strategies for mitigating cracks.To promote the application of nickel-based superalloys,further research on the combination impact of multiple elements on cracking prevention and specific quantitative criteria for liquation cracking is necessary.