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GLOBAL SOLUTIONS TO 1D COMPRESSIBLE NAVIER-STOKES/ALLEN-CAHN SYSTEM WITH DENSITY-DEPENDENT VISCOSITY AND FREE-BOUNDARY 被引量:1
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作者 丁时进 李颖花 王喻 《Acta Mathematica Scientia》 SCIE CSCD 2024年第1期195-214,共20页
This paper is concerned with the Navier-Stokes/Allen-Cahn system,which is used to model the dynamics of immiscible two-phase flows.We consider a 1D free boundary problem and assume that the viscosity coefficient depen... This paper is concerned with the Navier-Stokes/Allen-Cahn system,which is used to model the dynamics of immiscible two-phase flows.We consider a 1D free boundary problem and assume that the viscosity coefficient depends on the density in the form ofη(ρ)=ρ^(α).The existence of unique global H^(2m)-solutions(m∈N)to the free boundary problem is proven for when 0<α<1/4.Furthermore,we obtain the global C^(∞)-solutions if the initial data is smooth. 展开更多
关键词 Navier-Stokes/Allen-Cahn system density-dependent viscosity free boundary global solutions
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Influence of variable viscosity and double diffusion on the convective stability of a nanofluid flow in an inclined porous channel
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作者 N.HUMNEKAR D.SRINIVASACHARYA 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2024年第3期563-580,共18页
The influence of variable viscosity and double diffusion on the convective stability of a nanofluid flow in an inclined porous channel is investigated.The DarcyBrinkman model is used to characterize the fluid flow dyn... The influence of variable viscosity and double diffusion on the convective stability of a nanofluid flow in an inclined porous channel is investigated.The DarcyBrinkman model is used to characterize the fluid flow dynamics in porous materials.The analytical solutions are obtained for the unidirectional and completely developed flow.Based on a normal mode analysis,the generalized eigenvalue problem under a perturbed state is solved.The eigenvalue problem is then solved by the spectral method.Finally,the critical Rayleigh number with the corresponding wavenumber is evaluated at the assigned values of the other flow-governing parameters.The results show that increasing the Darcy number,the Lewis number,the Dufour parameter,or the Soret parameter increases the stability of the system,whereas increasing the inclination angle of the channel destabilizes the flow.Besides,the flow is the most unstable when the channel is vertically oriented. 展开更多
关键词 NANOFLUID inclined channel variable viscosity linear stability double dif-fusion porous medium
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Nuclear magnetic resonance experiments on the time-varying law of oil viscosity and wettability in high-multiple waterflooding sandstone cores
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作者 JIA Hu ZHANG Rui +2 位作者 LUO Xianbo ZHOU Zili YANG Lu 《Petroleum Exploration and Development》 SCIE 2024年第2期394-402,共9页
A simulated oil viscosity prediction model is established according to the relationship between simulated oil viscosity and geometric mean value of T2spectrum,and the time-varying law of simulated oil viscosity in por... A simulated oil viscosity prediction model is established according to the relationship between simulated oil viscosity and geometric mean value of T2spectrum,and the time-varying law of simulated oil viscosity in porous media is quantitatively characterized by nuclear magnetic resonance(NMR)experiments of high multiple waterflooding.A new NMR wettability index formula is derived based on NMR relaxation theory to quantitatively characterize the time-varying law of rock wettability during waterflooding combined with high-multiple waterflooding experiment in sandstone cores.The remaining oil viscosity in the core is positively correlated with the displacing water multiple.The remaining oil viscosity increases rapidly when the displacing water multiple is low,and increases slowly when the displacing water multiple is high.The variation of remaining oil viscosity is related to the reservoir heterogeneity.The stronger the reservoir homogeneity,the higher the content of heavy components in the remaining oil and the higher the viscosity.The reservoir wettability changes after water injection:the oil-wet reservoir changes into water-wet reservoir,while the water-wet reservoir becomes more hydrophilic;the degree of change enhances with the increase of displacing water multiple.There is a high correlation between the time-varying oil viscosity and the time-varying wettability,and the change of oil viscosity cannot be ignored.The NMR wettability index calculated by considering the change of oil viscosity is more consistent with the tested Amott(spontaneous imbibition)wettability index,which agrees more with the time-varying law of reservoir wettability. 展开更多
关键词 SANDSTONE high-multiple waterflooding nuclear magnetic resonance oil viscosity rock wettability time-varying law
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Numerical Simulation of Slurry Diffusion in Fractured Rocks Considering a Time-Varying Viscosity
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作者 Lei Zhu Bin Liu +3 位作者 Xuewei Liu Wei Deng Wenjie Yao Ying Fan 《Fluid Dynamics & Materials Processing》 EI 2024年第2期401-427,共27页
To analyze the effects of a time-varying viscosity on the penetration length of grouting,in this study cement slur-ries with varying water-cement ratios have been investigated using the Bingham’sfluidflow equation and ... To analyze the effects of a time-varying viscosity on the penetration length of grouting,in this study cement slur-ries with varying water-cement ratios have been investigated using the Bingham’sfluidflow equation and a dis-crete element method.Afluid-solid coupling numerical model has been introduced accordingly,and its accuracy has been validated through comparison of theoretical and numerical solutions.For different fracture forms(a single fracture,a branch fracture,and a fracture network),the influence of the time-varying viscosity on the slurry length range has been investigated,considering the change in the fracture aperture.The results show that under different fracture forms and the same grouting process conditions,the influence of the time-varying viscosity on the seepage length is 0.350 m. 展开更多
关键词 Time-varying viscosity binghamfluids UDEC numerical simulation grout penetration length aperture
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Influences of clean fracturing fluid viscosity and horizontal in-situ stress difference on hydraulic fracture propagation and morphology in coal seam
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作者 Gang Wang Shuxin Wang +5 位作者 Yixin Liu Qiming Huang Shengpeng Li Shuliang Xie Jinye Zheng Jiuyuan Fan 《International Journal of Coal Science & Technology》 EI CAS CSCD 2024年第3期159-175,共17页
The viscosity of fracturing fluid and in-situ stress difference are the two important factors that affect the hydraulic fracturing pressure and propagation morphology. In this study, raw coal was used to prepare coal ... The viscosity of fracturing fluid and in-situ stress difference are the two important factors that affect the hydraulic fracturing pressure and propagation morphology. In this study, raw coal was used to prepare coal samples for experiments, and clean fracturing fluid samples were prepared using CTAB surfactant. A series of hydraulic fracturing tests were conducted with an in-house developed triaxial hydraulic fracturing simulator and the fracturing process was monitored with an acoustic emission instrument to analyze the influences of fracturing fluid viscosity and horizontal in-situ stress difference on coal fracture propagation. The results show that the number of branched fractures decreased, the fracture pattern became simpler, the fractures width increased obviously, and the distribution of AE event points was concentrated with the increase of the fracturing fluid viscosity or the horizontal in-situ stress difference. The acoustic emission energy decreases with the increase of fracturing fluid viscosity and increases with the increase of horizontal in situ stress difference. The low viscosity clean fracturing fluid has strong elasticity and is easy to be compressed into the tip of fractures, resulting in complex fractures. The high viscosity clean fracturing fluids are the opposite. Our experimental results provide a reference and scientific basis for the design and optimization of field hydraulic fracturing parameters. 展开更多
关键词 Clean fracturing fluid Hydraulic fracturing viscosity Horizontal in-situ stress difference Hydraulic fracture morphology Acoustic emission
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Study of the Viscosity and Specific Gravity of the Ternary Used Frying Oil (UFO)-Bioethanol-Diesel System
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作者 Konan Edmond Kouassi Abollé Abolle +3 位作者 N’guessan Luc Brou David Boa N’guessan Raymond Kre Kouassi Benjamin Yao 《Journal of Materials Science and Chemical Engineering》 2024年第4期53-66,共14页
Fossil fuels cover around 80% of global energy consumption. However, the problems linked to their use justify the choice of using biofuel. In order to reduce as much as possible, diesel rate, an increase in the number... Fossil fuels cover around 80% of global energy consumption. However, the problems linked to their use justify the choice of using biofuel. In order to reduce as much as possible, diesel rate, an increase in the number of additives may be considered. Thus, in this work, the study of the used frying oil (UFO), bioethanol and diesel ternary system was undertaken. It emerges from this study that the addition of bioethanol reduces the viscosity and the density of the ternary system and permits a 90% substitution rate for diesel between the UFO and bioethanol. Finally, the percentage of oil becomes 40% after adding alcohol compared to the binary diesel crude vegetable oil mixture where this rate is 30%. 展开更多
关键词 Biofuel UFO-Bioethanol-Diesel Ternary Density viscosity
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Molecular composition of naphthenic acids in a Chinese heavy crude oil and their impacts on oil viscosity 被引量:1
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作者 Qian-Hui Zhao Shuai M +7 位作者 Jian-Xun Wu Wei-Feng Chang Sheng-Fei Zhang Xin-Ge Sun Bing Zhou Zeng-Min Lun Keng H.Chung Quan Shi 《Petroleum Science》 SCIE EI CAS CSCD 2023年第2期1225-1230,共6页
Most heavy crude oils underwent biodegradation and generated a significant amount of naphthenic acids. Naphthenic acids are polar compounds with the carboxylic group and are considered as a major factor affecting the ... Most heavy crude oils underwent biodegradation and generated a significant amount of naphthenic acids. Naphthenic acids are polar compounds with the carboxylic group and are considered as a major factor affecting the oil viscosity. However, the relationship between the molecular composition of naphthenic acids and oil viscosity is not well understood. This study examined a “clean” heavy oil with low contents of heteroatoms but had a high content of naphthenic acids. Naphthenic acids were fractionated by distillation and caustic extraction. The molecular composition was characterized by high-resolution Orbitrap mass spectrometry. It was found that the 2- and 3-ring naphthenic monoacids with 15–35 carbon atoms are dominant components of the acid fractions;the caustic extraction is capable of isolating naphthenic acids with less than 35 carbons, which is equivalent to the upper limit of the distillable components, but not those in the residue fraction;the total acid number of the heavy distillates is higher than that of the residue fraction;the viscosity of the distillation fraction increases exponentially with an increased boiling point of the distillates. Blending experiments indicates that there is a strong correlation between the oil viscosity and acids content, although the acid content is only a few percent of the total oil. 展开更多
关键词 Heavy crude oil viscosity High-resolution mass spectrometer Naphthenic acid
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Prediction of the viscosity of natural gas at high temperature and high pressure using free-volume theory and entropy scaling 被引量:1
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作者 Wei Xiong Lie-Hui Zhang +5 位作者 Yu-Long Zhao Qiu-Yun Hu Ye Tian Xiao He Rui-Han Zhang Tao Zhang 《Petroleum Science》 SCIE EI CSCD 2023年第5期3210-3222,共13页
Eighteen models based on two equations of state(EoS),three viscosity models,and four mixing rules were constructed to predict the viscosities of natural gases at high temperature and high pressure(HTHP)conditions.For ... Eighteen models based on two equations of state(EoS),three viscosity models,and four mixing rules were constructed to predict the viscosities of natural gases at high temperature and high pressure(HTHP)conditions.For pure substances,the parameters of free volume(FV)and entropy scaling(ES)models were found to scale with molecular weight,which indicates that the ordered behavior of parameters of Peng-Robinson(PR)and Perturbed-Chain Statistical Associating Fluid Theory(PC-SAFT)propagates to the behavior of parameters of viscosity model.Predicting the viscosities of natural gases showed that the FV and ES models respectively combined with MIX4 and MIX2 mixing rules produced the best accuracy.Moreover,the FV models were more accurate for predicting the viscosities of natural gases than ES models at HTHP conditions,while the ES models were superior to PRFT models.The average absolute relative deviations of the best accurate three models,i.e.,PC-SAFT-FV-MIX4,tPR-FVMIX4,and PC-SAFT-ES-MIX2,were 5.66%,6.27%,and 6.50%,respectively,which was available for industrial production.Compared with the existing industrial models(corresponding states theory and LBC),the proposed three models were more accurate for modeling the viscosity of natural gas,including gas condensate. 展开更多
关键词 viscosity Friction theory Free volume theory Entropy scaling PC-SAFT Equation of state
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Influence of substituting B_(2)O_(3) with Li_(2)O on the viscosity,structure and crystalline phase of low-reactivity mold flux
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作者 Rongzhen Mo Xubin Zhang +2 位作者 Ying Ren Junjie Hu Lifeng Zhang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第7期1320-1328,共9页
The low-reactivity mold flux with low SiO_(2)content is considered suitable for the continuous casting of high-aluminum steel since it can significantly reduce the reaction between Al in steel and SiO_(2)in mold flux.... The low-reactivity mold flux with low SiO_(2)content is considered suitable for the continuous casting of high-aluminum steel since it can significantly reduce the reaction between Al in steel and SiO_(2)in mold flux.However,the traditional low-reactivity mold flux still presents some problems such as high viscosity and strong crystallization tendency.In this study,the co-addition of Li_(2)O and B_(2)O_(3)in CaO–Al_(2)O_(3)–10wt%Si O_(2)based low-reactivity mold flux was proposed to improve properties of mold flux for high-aluminum steel,and the effect of Li_(2)O replacing B_(2)O_(3)on properties of mold flux was investigated.The viscosity of the mold flux with 2wt%Li_(2)O and 6wt%B_(2)O_(3)reached a minimum value of 0.07 Pa·s.The break temperature and melting point showed a similar trend with the viscosity.Besides,the melt structure and precipitation of the crystalline phase were studied using Raman and X-ray diffraction spectra to better understand the evolution of viscosity.It demonstrated that with increasing Li_(2)O content in the mold flux from 0 to 6 wt%,the degree of polymerization of aluminate and the aluminosilicate network structure increased because of increasing Li+released by Li_(2)O,indicating the added Li_(2)O was preferentially associated with Al^(3+)as a charge compensator.The precipitation of LiAlO_(2)crystalline phase gradually increased with the replacement of B_(2)O_(3)by Li_(2)O.Therefore,Li_(2)O content should be controlled below 2wt%to avoid LiAlO_(2)precipitation,which was harmful to the continuous casting of highaluminum steels. 展开更多
关键词 low-reactivity mold flux viscosity STRUCTURE crystalline phase
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Lipschitz Regularity of Viscosity Solutions to the Infinity Laplace Equation
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作者 Xiao Han Fang Liu 《Journal of Applied Mathematics and Physics》 2023年第10期2982-2996,共15页
In this paper, we study the viscosity solutions of the Neumann problem in a bounded C<sup>2</sup> domain Ω, where Δ<sup>N</sup>∞</sub> is called the normalized infinity Laplacian. The ... In this paper, we study the viscosity solutions of the Neumann problem in a bounded C<sup>2</sup> domain Ω, where Δ<sup>N</sup>∞</sub> is called the normalized infinity Laplacian. The normalized infinity Laplacian was first studied by Peres, Shramm, Sheffield and Wilson from the point of randomized theory named tug-of-war, which has wide applications in optimal mass transportation, financial option price problems, digital image processing, physical engineering, etc. We give the Lipschitz regularity of the viscosity solutions of the Neumann problem. The method we adopt is to choose suitable auxiliary functions as barrier functions and combine the perturbation method and viscosity solutions theory. . 展开更多
关键词 Normalized Infinity Laplacian viscosity Solution Lipschitz Regularity
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Enhancing Heavy Crude Oil Flow in Pipelines through Heating-Induced Viscosity Reduction in the Petroleum Industry
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作者 Ramzy S.Hamied Anwar N.Mohammed Ali Khalid A.Sukkar 《Fluid Dynamics & Materials Processing》 EI 2023年第8期2027-2039,共13页
The process of transporting crude oil across pipelines is one of the most critical aspects of the midstream petroleum industry.In the present experimental work,the effect of temperature,pressure drop,and pipe diameter... The process of transporting crude oil across pipelines is one of the most critical aspects of the midstream petroleum industry.In the present experimental work,the effect of temperature,pressure drop,and pipe diameter on the flow rate of heavy crude oil have been assessed.Moreover,the total discharge and energy losses have been evaluated in order to demonstrate the improvements potentially achievable by using solar heating method replacing pipe,and adjusting the value of the initial pressure difference.Crude oil of API=20 has been used for the experiments,with the studied pipelines sections connecting the separator unit to the storage tank operating at a temperature of 25℃-100℃,pressure drop of 3,4,5,and 6 kg/cm^(2),and with pipe diameter of 4,6,and 8 in.The results show that on increasing the temperature and/or the pressure drop,the flow rate through the pipeline becomes higher,thus raising the total pumping energy(as the pipe diameter increase),while energy losses increase from the last separator to the storage tank in the field.A pipe diameter increase can also produce a growth of the total pumping energy(i.e.,energy losses increase).The results of the present analysis suggest that employing an optimal temperature(50℃)is needed to ensure good performance. 展开更多
关键词 Petroleum industry heavy crude oil horizontal flow viscosity reduction
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Incompressible Limit of the Oldroyd-B Model with Density-Dependent Viscosity
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作者 Qingliu Li Dandan Ren 《Journal of Applied Mathematics and Physics》 2023年第4期949-971,共23页
This paper studies the existence and uniqueness of local strong solutions to an Oldroyd-B model with density-dependent viscosity in a bounded domain Ω ⊂ R<sup>d</sup>, d = 2 or 3 via incompressible limit,... This paper studies the existence and uniqueness of local strong solutions to an Oldroyd-B model with density-dependent viscosity in a bounded domain Ω ⊂ R<sup>d</sup>, d = 2 or 3 via incompressible limit, in which the initial data is “well-prepared” and the velocity field enjoys the slip boundary conditions. The main idea is to derive the uniform energy estimates for nonlinear systems and corresponding incompressible limit. 展开更多
关键词 Incompressible Limit Oldroyd-B Model Slip Boundary Condition Density-Dependent viscosity
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An artificial viscosity augmented physics-informed neural network for incompressible flow
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作者 Yichuan HE Zhicheng WANG +2 位作者 Hui XIANG Xiaomo JIANG Dawei TANG 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2023年第7期1101-1110,共10页
Physics-informed neural networks(PINNs)are proved methods that are effective in solving some strongly nonlinear partial differential equations(PDEs),e.g.,Navier-Stokes equations,with a small amount of boundary or inte... Physics-informed neural networks(PINNs)are proved methods that are effective in solving some strongly nonlinear partial differential equations(PDEs),e.g.,Navier-Stokes equations,with a small amount of boundary or interior data.However,the feasibility of applying PINNs to the flow at moderate or high Reynolds numbers has rarely been reported.The present paper proposes an artificial viscosity(AV)-based PINN for solving the forward and inverse flow problems.Specifically,the AV used in PINNs is inspired by the entropy viscosity method developed in conventional computational fluid dynamics(CFD)to stabilize the simulation of flow at high Reynolds numbers.The newly developed PINN is used to solve the forward problem of the two-dimensional steady cavity flow at Re=1000 and the inverse problem derived from two-dimensional film boiling.The results show that the AV augmented PINN can solve both problems with good accuracy and substantially reduce the inference errors in the forward problem. 展开更多
关键词 physics-informed neural network(PINN) artificial viscosity(AV) cavity driven flow high Reynolds number
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Influences of across-strike heterogeneous viscosity on the earthquake cycle in a three-dimensional strike-slip fault model
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作者 Peng Zhai Feng Li Jinshui Huang 《Earthquake Research Advances》 CSCD 2023年第3期30-41,共12页
Geodetic observations have shown that there exist large differences in the viscosity of the deep lithosphere across many large strike-slip faults.Heterogeneity in lithospheric viscosity structure can influence the eff... Geodetic observations have shown that there exist large differences in the viscosity of the deep lithosphere across many large strike-slip faults.Heterogeneity in lithospheric viscosity structure can influence the efficiency of stress transfer and thus may have a significant effect on the earthquake cycle.Until now,how the lateral viscosity variation across strike-slip faults affects the earthquake cycles is still not well understood.Here,we investigate the effects of across-strike viscosity variation on long-term earthquake behaviors with a three-dimensional strike-slip fault model.Our model is a quasi-static model which is controlled by the slip-weakening friction law and powerlaw rheology.By comparing with the reference case,we find that low viscosity on one side of the fault results in a smaller rupture area but with a higher Coulomb stress drop on the ruptured fault region.In addition,low viscosity also leads to a small Coulomb stress accumulation rate.These combined effects increase the earthquake recurrence interval by approximately 10%and the earthquake moments by about 30%when the low viscosity is related to a geothermal gradient of 30 K/km.In addition,across-strike viscosity variation causes asymmetric interseismic ground surface deformation rate.As the viscosity contrast increases,the difference in the interseismic ground surface deformation rate between the two sides of the fault gradually increases,although the asymmetric feature is not pronounced.This asymmetry of interseismic ground deformation rate across a strike-slip fault is supposed to result in asymmetric coseismic deformation if the long-term plate motion velocity is invariant.As a result,this kind of asymmetry of interseismic deformation may influence the evaluation of potential earthquake hazards along large strike-slip faults with lateral viscosity contrast. 展开更多
关键词 Across-strike viscosity variation Friction law Power-law rheology Earthquake cycle Asymmetric interseismic deformation
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Study on the in situ desulfurization and viscosity reduction of heavy oil over MoO_(3)–ZrO_(2)/HZSM-5 catalyst
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作者 Rui-Qi Liu Li-Qiang Zhang +6 位作者 Hui-Da Pan Yi-Ya Wang Jin-Yu Li Xin-Wei Wang Zheng-Da Yang Xin-Lu Han Ri-Yi Lin 《Petroleum Science》 SCIE EI CAS CSCD 2023年第6期3887-3896,共10页
Heavy oil is characterized by high viscosity.High viscosity makes it challenging to recover and transport.HZSM-5,MoO_(3)/HZSM-5,ZrO_(2)/HZSM-5 and MoO_(3)–ZrO_(2)/HZSM-5 catalysts were developed to promote in situ de... Heavy oil is characterized by high viscosity.High viscosity makes it challenging to recover and transport.HZSM-5,MoO_(3)/HZSM-5,ZrO_(2)/HZSM-5 and MoO_(3)–ZrO_(2)/HZSM-5 catalysts were developed to promote in situ desulfurization and viscosity reduction of heavy oil.The physical and chemical properties of catalysts were characterized by XPS,XRD,TEM,NH3-TPD,etc.The effects of temperature,catalyst type and addition amount on viscosity and composition of heavy oil were evaluated.The results showed that the presence of MoO_(3)–ZrO_(2)/HZSM-5 nanoparticles during aquathermolysis could improve the oil quality by reducing the heavy fractions.It reduced viscosity by 82.56%after the reaction at 280℃ and catalyst addition of 1 wt%.The contents of resins and asphaltic in the oil samples were 5.69%lower than that in the crude oil.Sulfur content decreased from 1.45%to 1.03%.The concentration of H2S produced by the reaction was 2225 ppm.The contents of sulfur-containing functional groups sulfoxide and sulfone sulfur in the oil samples decreased by 19.92%after the catalytic reaction.The content of stable thiophene sulfur increased by 5.71%.This study provided a basis for understanding the mechanism of heavy oil desulfurization and viscosity reduction. 展开更多
关键词 Heavy oil Hydrothermal cracking MoO_(3)-ZrO_(2)/HZSM-5 catalyst DESULFURIZATION viscosity reduction
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Efficient and reversible separation of NH_(3) by deep eutectic solvents with multiple active sites and low viscosities
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作者 Jiayin Zhang Lu Zheng +4 位作者 Siqi Fang Hongwei Zhang Zhenping Cai Kuan Huang Lilong Jiang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第3期97-105,共9页
The efficient separation and collection of ammonia(NH_(3))during NH_(3) synthesis process is essential to improve the economic efficiency and protect the environment.In this work,ethanolammonium hydrochloride(EtOHACl)... The efficient separation and collection of ammonia(NH_(3))during NH_(3) synthesis process is essential to improve the economic efficiency and protect the environment.In this work,ethanolammonium hydrochloride(EtOHACl)and phenol(PhOH)were used to prepare a novel class of deep eutectic solvents(DESs)with multiple active sites and low viscosities.The NH_(3) separation performance of EtOHACl+PhOH DESs was analyzed completely.It is figured out that the NH_(3) absorption rates in EtOHACl+PhOH DESs are very fast.The NH_(3) absorption capacities are very high and reach up to 5.52 and 10.74 mol·kg1 at 11.2 and 100.4 kPa under 298.2 K,respectively.In addition,the EtOHACl+PhOH DESs present highly selective absorption of NH_(3) over N_(2) and H_(2) and good regenerative properties after seven cycles of absorption/desorption.The intrinsic separation mechanism of NH_(3) by EtOHACl+PhOH DESs was further revealed by spectroscopic analysis and quantum chemistry calculations. 展开更多
关键词 SEPARATION Absorption Ionic liquid Deep eutectic solvent Multiple active site Low viscosity
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Synthesis and evaluation of an oil-soluble viscosity reducer for heavy oil 被引量:26
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作者 Guo Jixiang Wang Heyi +2 位作者 Chen Chaogang Chen Yun Xie Xiaohai 《Petroleum Science》 SCIE CAS CSCD 2010年第4期536-540,共5页
To reduce the viscosity of highly-viscous oil of the Tahe oilfield (Xinjiang,China),an oilsoluble polybasic copolymer viscosity reducer for heavy oil was synthesized using the orthogonal method.The optimum reaction ... To reduce the viscosity of highly-viscous oil of the Tahe oilfield (Xinjiang,China),an oilsoluble polybasic copolymer viscosity reducer for heavy oil was synthesized using the orthogonal method.The optimum reaction conditions are obtained as follows:under the protection of nitrogen,a reaction time of 9 h,monomer mole ratio of reaction materials of 3:2:2 (The monomers are 2-propenoic acid,docosyl ester,maleic anhydride and styrene,respectively),initiator amount of 0.8% (mass percent of the sum of all the monomers) and reaction temperature of 80 oC.This synthesized viscosity reducer is more effective than commercial viscosity reducers.The rate of viscosity reduction reached 95.5% at 50 oC.Infrared spectra (IR) and interfacial tensions of heavy oil with and without viscosity reducer were investigated to understand the viscosity reduction mechanism.When viscosity reducer is added,the molecules of the viscosity reducer are inserted amongst the molecules of crude oil,altering the original intermolecular structure of crude oil and weakening its ability to form hydrogen bonds with hydroxyl or carboxyl groups,so the viscosity of crude oil is reduced.Field tests of the newly developed oil-soluble viscosity reducer was carried out in the Tahe Oilfield,and the results showed that 44.5% less light oil was needed to dilute the heavy oil to achieve the needed viscosity. 展开更多
关键词 OIL-SOLUBLE viscosity reducer heavy oil SYNTHESIS EVALUATION
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THE APPARENT VISCOSITY OF SEMI-SOLID AZ91D ALLOY AT STEADY STATE 被引量:10
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作者 Z.S. Zhen, W.M. Mao, S.J. Van, A.M. Zhao, C.L. Cui and X.Y. ZhongSchool of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2002年第6期505-510,共6页
The rheological behavior of semi-solid AZ91D at steady state is studied usinga Couette type viscometer in the present paper. The results show that the apparent viscosity ofsemi-solid AZ91D at the steady state increase... The rheological behavior of semi-solid AZ91D at steady state is studied usinga Couette type viscometer in the present paper. The results show that the apparent viscosity ofsemi-solid AZ91D at the steady state increases with the solid fraction increasing, and goes upsharply when the solid fraction reaches a certain value, which is called critical fraction. Inaddition, the apparent viscosity of semi-solid AZ91D at the steady state takes on a distinctdowntrend with the shearing rate increasing, which indicates a strong shear thinning property. Inaddition, the critical solid fraction becomes higher under larger shearing rate, owing to the moreglobular shape of the solid particles. Based on the present experiment results, an empiricalequation is built as that, relating the steady state apparent viscosity of semi-solid AZ91D with thesolid fraction f_s and shearing rate gamma at the same time: eta_(app)=10.74 exp (6.95 f_s)gamma^(-0.86). 展开更多
关键词 rheological behavior magnesium alloy SEMI-SOLID viscosity VISCOMETER
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Effects of basicity and MgO content on the viscosity of the SiO_2-CaO-MgO-9wt%Al_2O_3 slag system 被引量:9
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作者 Yun-ming Gao Shao-bo Wang +2 位作者 Chuan Hong Xiu-juan Ma Fu Yang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2014年第4期353-362,共10页
The effects of basicity and MgO content on the viscosity of SiO2-CaO-MgO-9wt%Al2O3 slags with basicity from 0.4 to 1.0 and MgO content from 13wt%to 19wt%were investigated using the rotating cylinder method. A correlat... The effects of basicity and MgO content on the viscosity of SiO2-CaO-MgO-9wt%Al2O3 slags with basicity from 0.4 to 1.0 and MgO content from 13wt%to 19wt%were investigated using the rotating cylinder method. A correlation between the viscosity and the slag structure was determined by Fourier transform infrared (FTIR) spectroscopy. It is indicated that the complex network structure of the slag melt is depolymerized into simpler network units with increasing basicity or MgO content, resulting in a continuous decrease in viscosity of the slag. The viscosity is strongly dependent on the combined action of basic oxide components in the slag. Under the present experimental conditions, increasing the basicity is found to be more effective than increasing the MgO content in decreasing the viscosity of the slag. At higher temperatures, the increase of basicity or MgO content does not appreciably decrease the viscosity of the slag, as it does at lower tem-peratures. The calculated activation energy of viscous flow is between 154 and 200 kJ&#183;mol-1, which decreases with an increase in basicity from 0.4 to 1.0 at a fixed MgO content in the range of 13wt%to 19wt%. 展开更多
关键词 SLAGS viscosity BASICITY MAGNESIA activation energy Fourier transform infrared spectroscopy
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Dynamics Study of the Influence of Temperature on Konjac Glucomannan Saline Solution’s Viscosity 被引量:10
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作者 庞杰 孙玉敬 +2 位作者 庄昱 叶炳鸿 孙远明 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2008年第4期394-398,共5页
Molecular dynamics (MD) method is adopted to simulate the conformation variations of konjac glucomannan (KGM) saline solution at different temperatures, and structurally analyze the trends and reasons of viscosity... Molecular dynamics (MD) method is adopted to simulate the conformation variations of konjac glucomannan (KGM) saline solution at different temperatures, and structurally analyze the trends and reasons of viscosity change in KGM saline solution with temperature. The experimental results have been analyzed to find out that the sum of formative hydrogen bonds decreases with the rise of temperature and the amount of intramolecular hydrogen bonds suddenly increases at 323 K. Besides, in terms of molecular orbital data obtained from simulation, we can know that hydrogen bonding energy also decreases with the rise of temperature. Therefore, we can predict the viscosity of KGM saline solution decreases gradually when rising the temperature. 展开更多
关键词 konjac glucomannan molecular dynamics simulation viscosity
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