It is found that when the parity–time symmetry phenomenon is introduced into the resonant optical gyro system and it works near the exceptional point,the sensitivity can in theory be significantly amplified at low an...It is found that when the parity–time symmetry phenomenon is introduced into the resonant optical gyro system and it works near the exceptional point,the sensitivity can in theory be significantly amplified at low angular rate.However,in fact,the exceptional point is easily disturbed by external environmental variables,which means that it depends on harsh experimental environment and strong control ability,so it is difficult to move towards practical application.Here,we propose a new angular rate sensor structure based on exceptional surface,which has the advantages of high sensitivity and high robustness.The system consists of two fiber-optic ring resonators and two optical loop mirrors,and one of the resonators contains a variable ratio coupler and a variable optical attenuator.We theoretically analyze the system response,and the effects of phase and coupling ratio on the system response.Finally,compared with the conventional resonant gyro,the sensitivity of this exceptional surface angular rate sensor can be improved by about 300 times at low speed.In addition,by changing the loss coefficient in the ring resonator,we can achieve a wide range of 600 rad/s.This scheme provides a new approach for the development of ultra-high sensitivity and wide range angular rate sensors in the future.展开更多
To achieve good performance for LiFePO4-based batteries operated at a wide temperature range,mixed salts of LiBF4 LiBOB(lithium bis(oxalato)borate) and LiTFSI(lithium bis(trifluoromethanesulfonyl)imide)-LiBOB ...To achieve good performance for LiFePO4-based batteries operated at a wide temperature range,mixed salts of LiBF4 LiBOB(lithium bis(oxalato)borate) and LiTFSI(lithium bis(trifluoromethanesulfonyl)imide)-LiBOB were investigated as alternative lithium salts to LiPF6 in non-aqueous electrolytes.LiFePO4/Li half cells using LiPF6,LiBF4-LiBOB and LiTFSI-LiBOB slats as lithium salts were investigated by galvanostatic cycling,cyclic voltammetry,thermogravimetric analysis.The results show that LiBF4-LiBOB and LiTFSI-LiBOB mixed salts are much more thermally stable than LiPF6.Corrosion of Al foil in the LiTFSI-based electrolytes can be suppressed successfully by the addition of LiBOB as a co-salt.The electrochemical performance of LiBF4-LiBOB and LiTFSI-LiBOB mixed salts based cells are both better than that of LiPF6-based cell.LiTFSI-LiBOB mixed salt based electrolyte is considered to be a very promising electrolyte candidate for Li-ion batteries that will be used in wide-temperature applications.展开更多
Wheat (Triticum aestivum L.) is a major staple food crop worldwide. It is economically important because it can be grown in a wide range of climates and geographic regions, and it has made an enormous contribution t...Wheat (Triticum aestivum L.) is a major staple food crop worldwide. It is economically important because it can be grown in a wide range of climates and geographic regions, and it has made an enormous contribution to the increase in global food production over the past four decades (Dixon et al., 2009). Wheat is produced on more than 18% of the arable land in the world, and is the most cultivated crop after maize and rice (FAOSTAT data, 2014). Despite its global strategic significance, progress in genomic and genetic engineering research on wheat has lagged behind that on other major crops due to the difficulty of culturing tissues, and the complexity of its hexaploid genome. The first successful wheat trans- formation was achieved by particle bombardment (Vasil et al., 1992). Since then additional transgenic wheat plants have been obtained by various transformation methods (Harwood, 2011). Microprojectile bombardment is considered to be a promising method, since it is robust, versatile and relatively efficient in terms of gene delivery.展开更多
The neutron count rate fluctuation reaches six orders of magnitude between the ohmic plasma scenario and high power of auxiliary heating on an experimental advanced superconducting tokamak(EAST).The measurement result...The neutron count rate fluctuation reaches six orders of magnitude between the ohmic plasma scenario and high power of auxiliary heating on an experimental advanced superconducting tokamak(EAST).The measurement result of neutron flux monitoring(NFM)is a significant feedback parameter related to the acquisition of radiation protection-related information and rapid fluctuations in neutron emission induced by plasma magnetohydrodynamic activity.Therefore,a wide range and high time resolution are required for the NFM system on EAST.To satisfy these requirements,a digital pulse signal acquisition and processing system with a wide dynamic range and fast response time was developed.The present study was conducted using a field-programmable gate array(FPGA)and peripheral component interconnect extension for instrument express(PXIe)platform.The digital dual measurement modes,which are composed of the pulse-counting mode and AC coupled square integral's Campbelling mode,were designed to expand the measurement range of the signal acquisition and processing system.The time resolution of the signal acquisition and processing system was improved from 10 to 1 ms owing to utilizing highspeed analog-to-digital converters(ADCs),a high-speed PXIe communication with a direct memory access(DMA)mode,and online data preprocessing technology of FPGA.The signal acquisition and processing system was tested experimentally in the EAST radiation field.The test results showed that the time resolution of NFM was improved to 1 ms,and the dynamic range of the neutron counts rate was expanded to more than 10^(6) counts per second.The Campbelling mode was calibrated using a multipoint average linear fitting method;subsequently,the fitting coefficient reached 0.9911.Therefore,the newly developed pulse signal acquisition and processing system ensures that the NFM system meets the requirements of high-parameter experiments conducted on EAST more effectively.展开更多
We developed a measuring instrument that had wide range, high precision, small measuring touch force. The instrument for three-dimensional (3D) surface topography measurement was composed of a high precision displacem...We developed a measuring instrument that had wide range, high precision, small measuring touch force. The instrument for three-dimensional (3D) surface topography measurement was composed of a high precision displacement sensor based on the Michelson interference principle, a 3D platform based on vertical scanning, a measuring and control circuit, and an industrial control computer. It was a closed loop control system, which changed the traditional moving stylus scanning style into a moving platform scanning style. When the workpiece was measured, the lever of the displacement sensor returned to the balanced position in every sample interval according to the zero offset of the displacement sensor. The non-linear error caused by the rotation of the lever was, therefore, very small even if the measuring range was wide. The instrument can measure the roughness and the profile size of a curved surface.展开更多
This paper presents a novel adaptive-bandwidth charge pump PLL with low jitter and a wide tuning range. With an adaptive bandwidth,the proposed PLL can scale its loop dynamics proportional to the output frequency and ...This paper presents a novel adaptive-bandwidth charge pump PLL with low jitter and a wide tuning range. With an adaptive bandwidth,the proposed PLL can scale its loop dynamics proportional to the output frequency and maintain optimal performance over its entire output range. In order to improve the jitter performance of the PLL,a matching tech- nique is employed in the charge pump,and a voltage-to-voltage converter is used to achieve a low gain VCO. The experimental chip was fabricated in a 0. 35μm CMOS process. The measured results show that the PLL has perfect jitter performance within its operating range from 200MHz to 1.1GHz.展开更多
An on-chip voltage reference with a wide supply voltage range is required by some applications,especially that of power management (PM) controller chips applied to telecommunication, automotive, lighting equipment, ...An on-chip voltage reference with a wide supply voltage range is required by some applications,especially that of power management (PM) controller chips applied to telecommunication, automotive, lighting equipment, etc., when high power supply voltage is needed. Accordingly,a new bandgap reference with a wide supply voltage range is proposed. Due to the improved structure,it features a high power supply rejection ratio (PSRR) and high temperature stability. In addition, an auxiliary micro-power reference is introduced to support the sleep mode of the PM chip and reduce its standby power consumption. The auxiliary reference provides bias currents in normal mode and a 1.28V reference voltage in sleep mode to replace the main reference and save power. Simulation results show that the reference provides a reference volt- age of 1.27V,which has a 3.5mV drift over the temperature range from -20 to 120~C and 56t^V deviation over a supply voltage range from 3 to 40V. The PSRR is higher than 100dB for frequency below 10kHz. The circuit was completed in 1.5tzm BCD (Bipolar-CMOS-DMOS) technology. The experimental results show that all main expectations are achieved.展开更多
We present a design for an adaptive gain phase-locked loop (PLL) that features fast acquisition,low jitter,and wide tuning range. A dual-edge-triggered phase frequency detector (PFD) and a self-regulated voltage c...We present a design for an adaptive gain phase-locked loop (PLL) that features fast acquisition,low jitter,and wide tuning range. A dual-edge-triggered phase frequency detector (PFD) and a self-regulated voltage controlled oscillator (VCO) are employed in this design to realize the aforementioned properties. Measured results show that the experimental chip, implemented in a standard 0.5μm 5V CMOS logic process, has an acquisition time of about 150ns at 37% frequency variation and an output RMS jitter of 39ps at 640MHz.(dual-edge-triggered phase frequency detector)展开更多
Earth-abundant and nontoxic Sn-based materials have been regarded as promising catalysts for the electrochemical conversion of CO_(2)to C1 products,e.g.,CO and formate.However,it is still difficult for Snbased materia...Earth-abundant and nontoxic Sn-based materials have been regarded as promising catalysts for the electrochemical conversion of CO_(2)to C1 products,e.g.,CO and formate.However,it is still difficult for Snbased materials to obtain satisfactory performance at low-to-moderate overpotentials.Herein,a simple and facile electrospinning technique is utilized to prepare a composite of a bimetallic Sn-Co oxide/carbon matrix with a hollow nanotube structure(Sn Co-HNT).Sn Co-HNT can maintain>90%faradaic efficiencies for C1 products within a wide potential range from-0.6 VRHE to-1.2 VRHE,and a highest 94.1%selectivity towards CO in an H-type cell.Moreover,a 91.2%faradaic efficiency with a 241.3 m A cm^(-2)partial current density for C1 products could be achieved using a flow cell.According to theoretical calculations,the fusing of Sn/Co oxides on the carbon matrix accelerates electron transfer at the atomic level,causing electron deficiency of Sn centers and reversible variation between Co^(2+)and Co^(3+)centers.The synergistic effect of the Sn/Co composition improves the electron affinity of the catalyst surface,which is conducive to the adsorption and stabilization of key intermediates and eventually increases the catalytic activity in CO_(2)electroreduction.This study could provide a new strategy for the construction of oxide-derived catalysts for CO_(2)electroreduction.展开更多
A vehicle stopping method using an electric brake until a traction motor is stopped is studied. At the moment of vehicle stop, electric brake is changed to control mode where torque is reduced at a low speed. Gradient...A vehicle stopping method using an electric brake until a traction motor is stopped is studied. At the moment of vehicle stop, electric brake is changed to control mode where torque is reduced at a low speed. Gradient is controlled by estimating the load torque of motor, thereby traction motor is not rotated after stop. In addition, coasting operation and brake test are performed from normal-opposite operation and start using a small-scale model comprising the inertial load equipment and the power converter. Further, traction motor is made to be equipped with a suspension torque. Pure electric braking that makes traction motor stop by an air brake at the time of stop is also implemented. Constant torque range and constant power range are expanded during braking so that braking force is secured with the electric brakes even in high speed region. Therefore, vehicle reduction effect can be expected by reducing parts related with an air brake which is not used frequently by using a pure electric brake in the M car in wide speed region. Further, maintenance of brake system can be reduced. Besides, ride comfort of passenger in the electric rail car, energy efficiency improvement, and noise reduction effect can be additionally expected. Further, an improved brake method that uses only an electric brake till motor stop is proposed by comparing those in the blending brake that uses an air brake while reducing brake torque at vehicle stop.展开更多
High-temperature proton exchange membrane fuel cells(HT-PEMFC) possess distinct technical advantages of high output power, simplified water/heat management, increased tolerance to fuel impurities and diverse fuel sour...High-temperature proton exchange membrane fuel cells(HT-PEMFC) possess distinct technical advantages of high output power, simplified water/heat management, increased tolerance to fuel impurities and diverse fuel sources, within the temperature range of 120–200 ℃. However, for practical automobile applications, it was crucial to broaden their low-temperature operating window and enable cold start-up capability. Herein, gel-state phosphoric acid(PA) doped sulfonated polybenzimidazole(PBI) proton exchange membranes(PEMs) were designed and synthesized via PPA sol-gel process and in-situ sultone ring-opening reactions with various proton transport pathways based on absorbed PA, flexible alkyl chain connected sulfonic acid groups and imidazole sites. The effects of flexible alkyl sulfonic acid side chain length and content on PA doping level, proton conductivity, and membrane stability under different temperature and relative humidity(RH) were thoroughly investigated. The prepared gel-state membranes contained a self-assembled lamellar and porous structure that facilitated the absorption of a large amount of PA with rapid proton transporting mechanisms. At room temperature, the optimized membrane exhibited a proton conductivity of 0.069 S cm^(-1), which was further increased to 0.162 and 0.358 S cm^(-1)at 80 and 200 ℃, respectively, without additional humidification. The most significant contribution of this work was demonstrating the feasibility of gel-state sulfonated PBI membranes in expanding HT-PEMFC application opportunities over a wider operating range of 25 to 240 ℃.展开更多
To implement the multi-way phase shifting maintaining the compact size and simplicity in structure,the uniform reference line concept was proposed for the differential phase shifter.However,the performance in bandwidt...To implement the multi-way phase shifting maintaining the compact size and simplicity in structure,the uniform reference line concept was proposed for the differential phase shifter.However,the performance in bandwidth and phase range deteriorates with the additional requirements considered.To solve this problem,a quarter wavelength coupled line section loaded with open/short stubs is proposed as the basic element to implement the main line and also reference line.According to the theoretical analysis on this basic element,the loading stubs can be used to control the phase shift and also the phase slope of the basic element without affecting the amplitude property.With the predetermined parameters of the uniform reference line,only two parameters are required for the implementation of different differential phase shifts.This demonstrates the high simplicity of the proposed structure.For demonstration,an eight-way differential phase shifter operating at 3.5 GHz was implemented using the vertically installed planar structure.The prototype was further fabricated and measured.Good agreement between simulation and measurement can be observed.The implemented phase shifter can provide a wide range of phase shifting values from 45°to 315°with reference to the uniform reference line over a relative bandwidth of 62.3%.展开更多
The electrolyte integrated with lithium metal anodes is subjected to the issues of interfacial compatibility and stability,which strongly influence the performances of high-energy lithium metal batteries.Here,we repor...The electrolyte integrated with lithium metal anodes is subjected to the issues of interfacial compatibility and stability,which strongly influence the performances of high-energy lithium metal batteries.Here,we report a new electrolyte recipe viz.a moderately concentrated electrolyte comprising of 2.4 M lithium bis(fluorosulfonyl)imide(LiFSI)in a cosolvent mixture of fluorinated ethylene carbonate(FEC)and dimethyl carbonate(DMC)with relatively high ion conductivity.Owing to the preferential decomposition of LiFSI and FEC,an inorganic-rich interphase with abundant Li_(2)O and LiF nanocrystals is formed on lithium metal with improved robustness and ion transfer kinetics,enabling lithium plating/stripping with an extremely low overpotential of~8 mV and the average CE of 97%.When tested in Li||LiFePO_(4) cell,this electrolyte provides long-term cycling with a capacity retention of 98.3%after 1000 cycles at 1 C and an excellent rate performance of 20 C,as well as an areal capacity of 1.35 mA h cm^(-2)at the cathode areal loading of 9 mg cm^(-2).Moreover,the Li||LiFePO_(4) cell exhibits excellent wide-temperature performances(-40~60℃),including long-term cycling stability over 2600 cycles without visible capacity fading at 0℃,as well as extremely high average CEs of 99.6%and 99.8% over 400 cycles under-20℃ and 45℃.展开更多
A new solvent polymeric membrane (SPM)pH2sensor based on 4,4'-bis (N, N-didecylamino)methyl)azobenzene as neutral carricr has been reported. It has excellent pH response characteristics with the linear response ra...A new solvent polymeric membrane (SPM)pH2sensor based on 4,4'-bis (N, N-didecylamino)methyl)azobenzene as neutral carricr has been reported. It has excellent pH response characteristics with the linear response range (1.7—13.2)much wider than that of similar SPM pH sensors reported so far. The sensor has a theoretical Nernstian response of 57.4+0.2V/pH(at 20℃)without super—Nernstian response phenomenon.展开更多
Wide-size-range medium-solids are used in a modularized coal beneficiation demonstration system with a gas-solid fluidized bed. The characteristics of fluidization and dry-beneficiation of the medium solids were studi...Wide-size-range medium-solids are used in a modularized coal beneficiation demonstration system with a gas-solid fluidized bed. The characteristics of fluidization and dry-beneficiation of the medium solids were studied. The numerical simulation results show that 0.15–0.06 mm fine magnetite powder can decrease the disturbances caused by the bubbles. This is beneficial to the uniformity of the gas-solid interactions and thus to the uniformity and stability of the bed density and height. The experimental results show that, with an increase in the fine coal content in medium solids, both the fluidization quality and the beneficiation performance of the bed decreased gradually. When the fine coal content was no more than 13%, a relatively high superficial gas velocity increased the beneficiation efficiency. When the content was more than 13%, part of the fine coal was separated, leading to product layers. The separation efficiency was therefore gradually decreased. The models for predicting the bed density standard deviation and the probable error, E, value were both proposed. The E value can reach to 0.04–0.07 g/cm^3 under the optimized experimental parameters. This work provides a foundation for the adjustment of the bed density and the separation performance of the modularized 40–60 ton per hour dry coalbeneficiation industrial system.展开更多
In this paper,a novel intensifying-flux variable flux-leakage interior permanent magnet(IFVF-IPM)machine is proposed,in which flux barriers were designed deliberately between the adjacent poles to obtain intensifying-...In this paper,a novel intensifying-flux variable flux-leakage interior permanent magnet(IFVF-IPM)machine is proposed,in which flux barriers were designed deliberately between the adjacent poles to obtain intensifying-flux effect and variable flux-leakage property.The rotor topology and design principles of the proposed machine are also introduced.Then,a multi-objective optimization method is adopted based on the sensitivity analysis,and some design variables of IFVF-IPM machine with strong sensitivity are selected to optimization progress by using the non-dominated sorting genetic algorithm-Ⅱ(NSGA-Ⅱ).Moreover,the electromagnetic characteristics of conventional IPM machine,conventional IFVF-IPM machine(CIFVF-IPM)and the novel IFVF-IPM machine are compared based on the finite element analysis(FEA)method which includes flux linkage,inductances characteristic,torque-speed envelops and power characteristic,as well as evaluation of the risk of irreversible demagnetization.Finally,the experiment results show that the IFVF-IPM machine has a better performance in flux weakening capability for wide speed range and a lower risk of irreversible demagnetization,which indicates the validity and feasibility of the proposed machine.展开更多
Lysosomal polarity is considered a key indicator of lysosomal function due to its significant impact on membrane fluidity and enzymatic reactions in lysosomes. Monitoring lysosomal polarity can gain insight into the r...Lysosomal polarity is considered a key indicator of lysosomal function due to its significant impact on membrane fluidity and enzymatic reactions in lysosomes. Monitoring lysosomal polarity can gain insight into the related physiological and pathological processes and develop new diagnostic methods. However, current fluorescent probes with lysosomal polarity response suffer from narrow linear range, photobleaching and complicated preparation. Herein, a ratiometric fluorescent probe(r-b CDs) for intracellular lysosomal polarity imaging is designed and constructed by amide bond assembly of polarity-sensitive red fluorescent carbon dots(r CDs) and referenced blue fluorescent carbon dots(b CDs). r-b CDs show a much wider linear range of polarity response(orientation polarizability Δf from 0.020 to 0.315) than other probes, and the interference of uneven distribution and instrument factors can be effectively eliminated by ratiometric fluorescent sensing. Imaging of intracellular lysosomal polarity with r-b CDs is implemented to observe the polarity variation caused by the change of cell state and the difference between cancer cells and normal cells. This work provides a promising tool for studying the related physiological and pathological processes and developing new diagnostic methods.展开更多
In order to design the scale model in a wide frequency range,a method based on the reflective loss is proposed according to the high-frequency approximation algorithm,and an example of designing the scale model of a p...In order to design the scale model in a wide frequency range,a method based on the reflective loss is proposed according to the high-frequency approximation algorithm,and an example of designing the scale model of a plate-shaped absorber is given in this paper.In the example,the frequency of the full-size measurement ranges from 2.0 GHz to 2.4 GHz,the thickness of the full-size absorber is 1 mm and the scale ratio is 1/5.A two-layer scale absorber is obtained by the proposed method.The thickness values of the bottom and top layer are 0.4 mm and 0.5 mm,respectively.Furthermore,the scattering properties of a plate model and an SLICY model are studied by FEKO to verify the effectiveness of the designed scale absorber.Compared with the corresponding values from the theoretical scale model,the average values of the absolute deviations in 10 GHz~12 GHz are 0.53 d Bm^2,0.65 d Bm^2,0.76 d Bm^2 for the plate model and 0.20 d Bm^2,0.95 d Bm^2,0.77 d Bm^2 for the SLICY model while the incident angles are 0°,30°,and 60°,respectively.These deviations fall within the Radar cross section(RCS) measurement tolerance.Thus,the work in this paper has important theoretical and practical significance.展开更多
A membrane with high stability and ion conductivity in wide pH range is essential for energy storage devices.Here,we report a novel membrane with hierarchical core-shell structure,which demonstrates high stability and...A membrane with high stability and ion conductivity in wide pH range is essential for energy storage devices.Here,we report a novel membrane with hierarchical core-shell structure,which demonstrates high stability and ion conductivity,simultaneously under a wide pH range applications.Spectral characterizations and theoretical calculation indicate that the non-solvent induces the chain segment configuration and eventually leads to polymer-polymer phase separation,thus forming hierarchical porous core-shell structure.Benefiting from this structure,an acidic vanadium flow battery(VFB)with such a membrane shows excellent performance over 400 cycles with an energy efficiency(EE)of above 81%at current density of 120 mA cm^(-2) and an alkaline zinc-iron flow battery(AZIFB)delivers a cycling stability for more than 200 cycles at 160 mA cm^(-2),along with an EE of above 82%.This paper provides a cost-effective and simple way to fabricate membranes with high performance for variety of energyrelated devices.展开更多
Aqueous rechargeable batteries are safe and environmentally friendly and can be made at a low cost;as such,they are attracting attention in the field of energy storage.However,the temperature sensitivity of aqueous ba...Aqueous rechargeable batteries are safe and environmentally friendly and can be made at a low cost;as such,they are attracting attention in the field of energy storage.However,the temperature sensitivity of aqueous batteries hinders their practical application.The solvent water freezes at low temperatures,and there is a reduction in ionic conductivity,whereas it evaporates rapidly at high temperatures,which causes increased side reactions.This review discusses recent progress in improving the performance of aqueous batteries,mainly with respect to electrolyte engineering and the associated strategies employed to achieve such improvements over a wide temperature domain.The review focuses on fi ve electrolyte engineer-ing(aqueous high-concentration electrolytes,organic electrolytes,quasi-solid/solid electrolytes,hybrid electrolytes,and eutectic electrolytes)and investigates the mechanisms involved in reducing the solidifi cation point and boiling point of the electrolyte and enhancing the extreme-temperature electrochemical performance.Finally,the prospect of further improving the wide temperature range performance of aqueous rechargeable batteries is presented.展开更多
基金supported in part by the National Natural Science Foundation of China (Grant Nos.62273314,U21A20141,and 51821003)Fundamental Research Program of Shanxi Province (Grant No.202303021224008)Shanxi Province Key Laboratory of Quantum Sensing and Precision Measure-ment (Grant No.201905D121001).
文摘It is found that when the parity–time symmetry phenomenon is introduced into the resonant optical gyro system and it works near the exceptional point,the sensitivity can in theory be significantly amplified at low angular rate.However,in fact,the exceptional point is easily disturbed by external environmental variables,which means that it depends on harsh experimental environment and strong control ability,so it is difficult to move towards practical application.Here,we propose a new angular rate sensor structure based on exceptional surface,which has the advantages of high sensitivity and high robustness.The system consists of two fiber-optic ring resonators and two optical loop mirrors,and one of the resonators contains a variable ratio coupler and a variable optical attenuator.We theoretically analyze the system response,and the effects of phase and coupling ratio on the system response.Finally,compared with the conventional resonant gyro,the sensitivity of this exceptional surface angular rate sensor can be improved by about 300 times at low speed.In addition,by changing the loss coefficient in the ring resonator,we can achieve a wide range of 600 rad/s.This scheme provides a new approach for the development of ultra-high sensitivity and wide range angular rate sensors in the future.
基金Project(2013JSJJ027)supported by the Teacher Research Fund of Central South University,China
文摘To achieve good performance for LiFePO4-based batteries operated at a wide temperature range,mixed salts of LiBF4 LiBOB(lithium bis(oxalato)borate) and LiTFSI(lithium bis(trifluoromethanesulfonyl)imide)-LiBOB were investigated as alternative lithium salts to LiPF6 in non-aqueous electrolytes.LiFePO4/Li half cells using LiPF6,LiBF4-LiBOB and LiTFSI-LiBOB slats as lithium salts were investigated by galvanostatic cycling,cyclic voltammetry,thermogravimetric analysis.The results show that LiBF4-LiBOB and LiTFSI-LiBOB mixed salts are much more thermally stable than LiPF6.Corrosion of Al foil in the LiTFSI-based electrolytes can be suppressed successfully by the addition of LiBOB as a co-salt.The electrochemical performance of LiBF4-LiBOB and LiTFSI-LiBOB mixed salts based cells are both better than that of LiPF6-based cell.LiTFSI-LiBOB mixed salt based electrolyte is considered to be a very promising electrolyte candidate for Li-ion batteries that will be used in wide-temperature applications.
基金funded by the Ministry of Agriculture of China(Nos.2014ZX0801003B and 2013ZX08002-004)
文摘Wheat (Triticum aestivum L.) is a major staple food crop worldwide. It is economically important because it can be grown in a wide range of climates and geographic regions, and it has made an enormous contribution to the increase in global food production over the past four decades (Dixon et al., 2009). Wheat is produced on more than 18% of the arable land in the world, and is the most cultivated crop after maize and rice (FAOSTAT data, 2014). Despite its global strategic significance, progress in genomic and genetic engineering research on wheat has lagged behind that on other major crops due to the difficulty of culturing tissues, and the complexity of its hexaploid genome. The first successful wheat trans- formation was achieved by particle bombardment (Vasil et al., 1992). Since then additional transgenic wheat plants have been obtained by various transformation methods (Harwood, 2011). Microprojectile bombardment is considered to be a promising method, since it is robust, versatile and relatively efficient in terms of gene delivery.
基金supported by the Users with Excellence Program of the Hefei Science Center CAS (No. 2020HSC-UE012)
文摘The neutron count rate fluctuation reaches six orders of magnitude between the ohmic plasma scenario and high power of auxiliary heating on an experimental advanced superconducting tokamak(EAST).The measurement result of neutron flux monitoring(NFM)is a significant feedback parameter related to the acquisition of radiation protection-related information and rapid fluctuations in neutron emission induced by plasma magnetohydrodynamic activity.Therefore,a wide range and high time resolution are required for the NFM system on EAST.To satisfy these requirements,a digital pulse signal acquisition and processing system with a wide dynamic range and fast response time was developed.The present study was conducted using a field-programmable gate array(FPGA)and peripheral component interconnect extension for instrument express(PXIe)platform.The digital dual measurement modes,which are composed of the pulse-counting mode and AC coupled square integral's Campbelling mode,were designed to expand the measurement range of the signal acquisition and processing system.The time resolution of the signal acquisition and processing system was improved from 10 to 1 ms owing to utilizing highspeed analog-to-digital converters(ADCs),a high-speed PXIe communication with a direct memory access(DMA)mode,and online data preprocessing technology of FPGA.The signal acquisition and processing system was tested experimentally in the EAST radiation field.The test results showed that the time resolution of NFM was improved to 1 ms,and the dynamic range of the neutron counts rate was expanded to more than 10^(6) counts per second.The Campbelling mode was calibrated using a multipoint average linear fitting method;subsequently,the fitting coefficient reached 0.9911.Therefore,the newly developed pulse signal acquisition and processing system ensures that the NFM system meets the requirements of high-parameter experiments conducted on EAST more effectively.
基金the National Science Foundation of China (No.50745020).
文摘We developed a measuring instrument that had wide range, high precision, small measuring touch force. The instrument for three-dimensional (3D) surface topography measurement was composed of a high precision displacement sensor based on the Michelson interference principle, a 3D platform based on vertical scanning, a measuring and control circuit, and an industrial control computer. It was a closed loop control system, which changed the traditional moving stylus scanning style into a moving platform scanning style. When the workpiece was measured, the lever of the displacement sensor returned to the balanced position in every sample interval according to the zero offset of the displacement sensor. The non-linear error caused by the rotation of the lever was, therefore, very small even if the measuring range was wide. The instrument can measure the roughness and the profile size of a curved surface.
文摘This paper presents a novel adaptive-bandwidth charge pump PLL with low jitter and a wide tuning range. With an adaptive bandwidth,the proposed PLL can scale its loop dynamics proportional to the output frequency and maintain optimal performance over its entire output range. In order to improve the jitter performance of the PLL,a matching tech- nique is employed in the charge pump,and a voltage-to-voltage converter is used to achieve a low gain VCO. The experimental chip was fabricated in a 0. 35μm CMOS process. The measured results show that the PLL has perfect jitter performance within its operating range from 200MHz to 1.1GHz.
文摘An on-chip voltage reference with a wide supply voltage range is required by some applications,especially that of power management (PM) controller chips applied to telecommunication, automotive, lighting equipment, etc., when high power supply voltage is needed. Accordingly,a new bandgap reference with a wide supply voltage range is proposed. Due to the improved structure,it features a high power supply rejection ratio (PSRR) and high temperature stability. In addition, an auxiliary micro-power reference is introduced to support the sleep mode of the PM chip and reduce its standby power consumption. The auxiliary reference provides bias currents in normal mode and a 1.28V reference voltage in sleep mode to replace the main reference and save power. Simulation results show that the reference provides a reference volt- age of 1.27V,which has a 3.5mV drift over the temperature range from -20 to 120~C and 56t^V deviation over a supply voltage range from 3 to 40V. The PSRR is higher than 100dB for frequency below 10kHz. The circuit was completed in 1.5tzm BCD (Bipolar-CMOS-DMOS) technology. The experimental results show that all main expectations are achieved.
文摘We present a design for an adaptive gain phase-locked loop (PLL) that features fast acquisition,low jitter,and wide tuning range. A dual-edge-triggered phase frequency detector (PFD) and a self-regulated voltage controlled oscillator (VCO) are employed in this design to realize the aforementioned properties. Measured results show that the experimental chip, implemented in a standard 0.5μm 5V CMOS logic process, has an acquisition time of about 150ns at 37% frequency variation and an output RMS jitter of 39ps at 640MHz.(dual-edge-triggered phase frequency detector)
基金supported by the National Natural Science Foundation of China(U21A20312,22172099,21975162,51902209)the Natural Science Foundation of Guangdong(2020A1515010840)the Shenzhen Science and Technology Program(SGDX20201103095802006,RCBS20200714114819161,JCYJ20190808111801674,JCYJ20200109105803806,RCYX20200714114535052)。
文摘Earth-abundant and nontoxic Sn-based materials have been regarded as promising catalysts for the electrochemical conversion of CO_(2)to C1 products,e.g.,CO and formate.However,it is still difficult for Snbased materials to obtain satisfactory performance at low-to-moderate overpotentials.Herein,a simple and facile electrospinning technique is utilized to prepare a composite of a bimetallic Sn-Co oxide/carbon matrix with a hollow nanotube structure(Sn Co-HNT).Sn Co-HNT can maintain>90%faradaic efficiencies for C1 products within a wide potential range from-0.6 VRHE to-1.2 VRHE,and a highest 94.1%selectivity towards CO in an H-type cell.Moreover,a 91.2%faradaic efficiency with a 241.3 m A cm^(-2)partial current density for C1 products could be achieved using a flow cell.According to theoretical calculations,the fusing of Sn/Co oxides on the carbon matrix accelerates electron transfer at the atomic level,causing electron deficiency of Sn centers and reversible variation between Co^(2+)and Co^(3+)centers.The synergistic effect of the Sn/Co composition improves the electron affinity of the catalyst surface,which is conducive to the adsorption and stabilization of key intermediates and eventually increases the catalytic activity in CO_(2)electroreduction.This study could provide a new strategy for the construction of oxide-derived catalysts for CO_(2)electroreduction.
文摘A vehicle stopping method using an electric brake until a traction motor is stopped is studied. At the moment of vehicle stop, electric brake is changed to control mode where torque is reduced at a low speed. Gradient is controlled by estimating the load torque of motor, thereby traction motor is not rotated after stop. In addition, coasting operation and brake test are performed from normal-opposite operation and start using a small-scale model comprising the inertial load equipment and the power converter. Further, traction motor is made to be equipped with a suspension torque. Pure electric braking that makes traction motor stop by an air brake at the time of stop is also implemented. Constant torque range and constant power range are expanded during braking so that braking force is secured with the electric brakes even in high speed region. Therefore, vehicle reduction effect can be expected by reducing parts related with an air brake which is not used frequently by using a pure electric brake in the M car in wide speed region. Further, maintenance of brake system can be reduced. Besides, ride comfort of passenger in the electric rail car, energy efficiency improvement, and noise reduction effect can be additionally expected. Further, an improved brake method that uses only an electric brake till motor stop is proposed by comparing those in the blending brake that uses an air brake while reducing brake torque at vehicle stop.
基金supported by the National Natural Science Foundation of China (NSFC-22209147)。
文摘High-temperature proton exchange membrane fuel cells(HT-PEMFC) possess distinct technical advantages of high output power, simplified water/heat management, increased tolerance to fuel impurities and diverse fuel sources, within the temperature range of 120–200 ℃. However, for practical automobile applications, it was crucial to broaden their low-temperature operating window and enable cold start-up capability. Herein, gel-state phosphoric acid(PA) doped sulfonated polybenzimidazole(PBI) proton exchange membranes(PEMs) were designed and synthesized via PPA sol-gel process and in-situ sultone ring-opening reactions with various proton transport pathways based on absorbed PA, flexible alkyl chain connected sulfonic acid groups and imidazole sites. The effects of flexible alkyl sulfonic acid side chain length and content on PA doping level, proton conductivity, and membrane stability under different temperature and relative humidity(RH) were thoroughly investigated. The prepared gel-state membranes contained a self-assembled lamellar and porous structure that facilitated the absorption of a large amount of PA with rapid proton transporting mechanisms. At room temperature, the optimized membrane exhibited a proton conductivity of 0.069 S cm^(-1), which was further increased to 0.162 and 0.358 S cm^(-1)at 80 and 200 ℃, respectively, without additional humidification. The most significant contribution of this work was demonstrating the feasibility of gel-state sulfonated PBI membranes in expanding HT-PEMFC application opportunities over a wider operating range of 25 to 240 ℃.
基金The work described in this paper was supported by the National Natural Science Foundation of China(No.62071503).
文摘To implement the multi-way phase shifting maintaining the compact size and simplicity in structure,the uniform reference line concept was proposed for the differential phase shifter.However,the performance in bandwidth and phase range deteriorates with the additional requirements considered.To solve this problem,a quarter wavelength coupled line section loaded with open/short stubs is proposed as the basic element to implement the main line and also reference line.According to the theoretical analysis on this basic element,the loading stubs can be used to control the phase shift and also the phase slope of the basic element without affecting the amplitude property.With the predetermined parameters of the uniform reference line,only two parameters are required for the implementation of different differential phase shifts.This demonstrates the high simplicity of the proposed structure.For demonstration,an eight-way differential phase shifter operating at 3.5 GHz was implemented using the vertically installed planar structure.The prototype was further fabricated and measured.Good agreement between simulation and measurement can be observed.The implemented phase shifter can provide a wide range of phase shifting values from 45°to 315°with reference to the uniform reference line over a relative bandwidth of 62.3%.
基金the Innovation-Driven Project of Central South University(2019CX033)the National Natural Science Foundation of China(51904344 and 52172264)the Natural Science Foundation of Hunan Province of China(2021JJ10060 and 2022GK2033)。
文摘The electrolyte integrated with lithium metal anodes is subjected to the issues of interfacial compatibility and stability,which strongly influence the performances of high-energy lithium metal batteries.Here,we report a new electrolyte recipe viz.a moderately concentrated electrolyte comprising of 2.4 M lithium bis(fluorosulfonyl)imide(LiFSI)in a cosolvent mixture of fluorinated ethylene carbonate(FEC)and dimethyl carbonate(DMC)with relatively high ion conductivity.Owing to the preferential decomposition of LiFSI and FEC,an inorganic-rich interphase with abundant Li_(2)O and LiF nanocrystals is formed on lithium metal with improved robustness and ion transfer kinetics,enabling lithium plating/stripping with an extremely low overpotential of~8 mV and the average CE of 97%.When tested in Li||LiFePO_(4) cell,this electrolyte provides long-term cycling with a capacity retention of 98.3%after 1000 cycles at 1 C and an excellent rate performance of 20 C,as well as an areal capacity of 1.35 mA h cm^(-2)at the cathode areal loading of 9 mg cm^(-2).Moreover,the Li||LiFePO_(4) cell exhibits excellent wide-temperature performances(-40~60℃),including long-term cycling stability over 2600 cycles without visible capacity fading at 0℃,as well as extremely high average CEs of 99.6%and 99.8% over 400 cycles under-20℃ and 45℃.
基金Project supported by the National Natural Science Foundation of China partially by Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Academia Sinica.
文摘A new solvent polymeric membrane (SPM)pH2sensor based on 4,4'-bis (N, N-didecylamino)methyl)azobenzene as neutral carricr has been reported. It has excellent pH response characteristics with the linear response range (1.7—13.2)much wider than that of similar SPM pH sensors reported so far. The sensor has a theoretical Nernstian response of 57.4+0.2V/pH(at 20℃)without super—Nernstian response phenomenon.
基金financially supported by the National Program on Key Basic Research Project of China (No.2012CB214904)the National Natural Science Foundation of China (Nos.51221462,51134022 and 51174203)
文摘Wide-size-range medium-solids are used in a modularized coal beneficiation demonstration system with a gas-solid fluidized bed. The characteristics of fluidization and dry-beneficiation of the medium solids were studied. The numerical simulation results show that 0.15–0.06 mm fine magnetite powder can decrease the disturbances caused by the bubbles. This is beneficial to the uniformity of the gas-solid interactions and thus to the uniformity and stability of the bed density and height. The experimental results show that, with an increase in the fine coal content in medium solids, both the fluidization quality and the beneficiation performance of the bed decreased gradually. When the fine coal content was no more than 13%, a relatively high superficial gas velocity increased the beneficiation efficiency. When the content was more than 13%, part of the fine coal was separated, leading to product layers. The separation efficiency was therefore gradually decreased. The models for predicting the bed density standard deviation and the probable error, E, value were both proposed. The E value can reach to 0.04–0.07 g/cm^3 under the optimized experimental parameters. This work provides a foundation for the adjustment of the bed density and the separation performance of the modularized 40–60 ton per hour dry coalbeneficiation industrial system.
基金This work was supported in part by the National Natural Science Foundation of China under grant no.52067008.
文摘In this paper,a novel intensifying-flux variable flux-leakage interior permanent magnet(IFVF-IPM)machine is proposed,in which flux barriers were designed deliberately between the adjacent poles to obtain intensifying-flux effect and variable flux-leakage property.The rotor topology and design principles of the proposed machine are also introduced.Then,a multi-objective optimization method is adopted based on the sensitivity analysis,and some design variables of IFVF-IPM machine with strong sensitivity are selected to optimization progress by using the non-dominated sorting genetic algorithm-Ⅱ(NSGA-Ⅱ).Moreover,the electromagnetic characteristics of conventional IPM machine,conventional IFVF-IPM machine(CIFVF-IPM)and the novel IFVF-IPM machine are compared based on the finite element analysis(FEA)method which includes flux linkage,inductances characteristic,torque-speed envelops and power characteristic,as well as evaluation of the risk of irreversible demagnetization.Finally,the experiment results show that the IFVF-IPM machine has a better performance in flux weakening capability for wide speed range and a lower risk of irreversible demagnetization,which indicates the validity and feasibility of the proposed machine.
基金financially supported by the National Natural Science Foundation of China (Nos.21922402,21874017 and 21727811)the Fundamental Research Funds for the Central Universities (No.N2005027)。
文摘Lysosomal polarity is considered a key indicator of lysosomal function due to its significant impact on membrane fluidity and enzymatic reactions in lysosomes. Monitoring lysosomal polarity can gain insight into the related physiological and pathological processes and develop new diagnostic methods. However, current fluorescent probes with lysosomal polarity response suffer from narrow linear range, photobleaching and complicated preparation. Herein, a ratiometric fluorescent probe(r-b CDs) for intracellular lysosomal polarity imaging is designed and constructed by amide bond assembly of polarity-sensitive red fluorescent carbon dots(r CDs) and referenced blue fluorescent carbon dots(b CDs). r-b CDs show a much wider linear range of polarity response(orientation polarizability Δf from 0.020 to 0.315) than other probes, and the interference of uneven distribution and instrument factors can be effectively eliminated by ratiometric fluorescent sensing. Imaging of intracellular lysosomal polarity with r-b CDs is implemented to observe the polarity variation caused by the change of cell state and the difference between cancer cells and normal cells. This work provides a promising tool for studying the related physiological and pathological processes and developing new diagnostic methods.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61601299 and 11404213)the Shanghai Municipal Science and Technology Commission,China(Grant Nos.17210730900 and 15ZR1439600)the Defense Industrial Technology,China(Grant No.B2120132001)
文摘In order to design the scale model in a wide frequency range,a method based on the reflective loss is proposed according to the high-frequency approximation algorithm,and an example of designing the scale model of a plate-shaped absorber is given in this paper.In the example,the frequency of the full-size measurement ranges from 2.0 GHz to 2.4 GHz,the thickness of the full-size absorber is 1 mm and the scale ratio is 1/5.A two-layer scale absorber is obtained by the proposed method.The thickness values of the bottom and top layer are 0.4 mm and 0.5 mm,respectively.Furthermore,the scattering properties of a plate model and an SLICY model are studied by FEKO to verify the effectiveness of the designed scale absorber.Compared with the corresponding values from the theoretical scale model,the average values of the absolute deviations in 10 GHz~12 GHz are 0.53 d Bm^2,0.65 d Bm^2,0.76 d Bm^2 for the plate model and 0.20 d Bm^2,0.95 d Bm^2,0.77 d Bm^2 for the SLICY model while the incident angles are 0°,30°,and 60°,respectively.These deviations fall within the Radar cross section(RCS) measurement tolerance.Thus,the work in this paper has important theoretical and practical significance.
基金the financial support from NSFC(21925804,U1808209 and 21908214)CAS Engineering Laboratory for Electrochemical Energy Storage,CAS,STS program.Major scientific and technological innovation project of Shandong(2018YFJH0106)+1 种基金the CAS(DNL201910)Youth Innovation Promotion Association CAS。
文摘A membrane with high stability and ion conductivity in wide pH range is essential for energy storage devices.Here,we report a novel membrane with hierarchical core-shell structure,which demonstrates high stability and ion conductivity,simultaneously under a wide pH range applications.Spectral characterizations and theoretical calculation indicate that the non-solvent induces the chain segment configuration and eventually leads to polymer-polymer phase separation,thus forming hierarchical porous core-shell structure.Benefiting from this structure,an acidic vanadium flow battery(VFB)with such a membrane shows excellent performance over 400 cycles with an energy efficiency(EE)of above 81%at current density of 120 mA cm^(-2) and an alkaline zinc-iron flow battery(AZIFB)delivers a cycling stability for more than 200 cycles at 160 mA cm^(-2),along with an EE of above 82%.This paper provides a cost-effective and simple way to fabricate membranes with high performance for variety of energyrelated devices.
基金supported by the National Key Research and Development Program of China(2019YFC1904500)National Natural Science Foundation of China(Nos.21801251,51502036,and 21875037)+2 种基金Young Top Talent of Fujian Young Eagle Program of Fujian Province,Educational Commis-sion of Fujian Province(2022G02022)Natural Science Foundation of Fuzhou City(2022-Y-004)Natural Science Foundation of Fujian Province(2023J02013).
文摘Aqueous rechargeable batteries are safe and environmentally friendly and can be made at a low cost;as such,they are attracting attention in the field of energy storage.However,the temperature sensitivity of aqueous batteries hinders their practical application.The solvent water freezes at low temperatures,and there is a reduction in ionic conductivity,whereas it evaporates rapidly at high temperatures,which causes increased side reactions.This review discusses recent progress in improving the performance of aqueous batteries,mainly with respect to electrolyte engineering and the associated strategies employed to achieve such improvements over a wide temperature domain.The review focuses on fi ve electrolyte engineer-ing(aqueous high-concentration electrolytes,organic electrolytes,quasi-solid/solid electrolytes,hybrid electrolytes,and eutectic electrolytes)and investigates the mechanisms involved in reducing the solidifi cation point and boiling point of the electrolyte and enhancing the extreme-temperature electrochemical performance.Finally,the prospect of further improving the wide temperature range performance of aqueous rechargeable batteries is presented.