One-dimensional(1D, wire-and fiber-shaped)supercapacitors have recently attracted interest due to their roll-up, micrometer size and potential applications in portable or wearable electronics. Herein, a 1D wireshaped ...One-dimensional(1D, wire-and fiber-shaped)supercapacitors have recently attracted interest due to their roll-up, micrometer size and potential applications in portable or wearable electronics. Herein, a 1D wireshaped electrode was developed based on Fe_3O_4 nanosheet arrays connected on the Fe wire, which was prepared via oxidation of Fe wire in 0.1 M KCl solution(pH 3) with O2-rich environment under 70 °C. The obtained Fe_3O_4 nanosheet arrays displayed a high specific capacitance(20.8 m F cm^(-1) at 10 mV s^(-1)) and long cycling lifespan(91.7% retention after 2500 cycles). Theexcellent performance may attribute to the connected nanosheet structure with abundant open spaces and the intimate contact between the Fe_3O_4 and iron substrate. In addition, a wire-shaped asymmetric supercapacitor was fabricated and had excellent capacitive properties with a high energy density(9 l Wh cm^(-2)) at power density of 532.7 l W cm^(-2) and remarkable long-term cycling performance(99% capacitance retention after 2000 cycles).Considering low cost and earth-abundant electrode material, as well as outstanding electrochemical properties, the assembled supercapacitor will possess enormous potential for practical applications in portable electronic device.展开更多
The deposition of active materials directly onto metal wires is a general strategy to prepare wire-shaped electrodes for flexible and wearable energy storage devices. However, it is still a critical challenge to coat ...The deposition of active materials directly onto metal wires is a general strategy to prepare wire-shaped electrodes for flexible and wearable energy storage devices. However, it is still a critical challenge to coat active materials onto the aimed metal wires because of their smooth surface and small specific surface area. In this work, high porous nickel yarns（PNYs） was fabricated using commercial nylon yarns as templates through step-wise electroless plating, electroplating and calcination processes. The PNYs are composed of multiplied fibers with hollow tubular structure of 5–10 μm in diameter, allowing the imbibition of carbon nanotubes（CNTs） solution by a facile capillary action process. The prepared CNTs/PNY electrodes showed a typical electrochemical double layer capacitive performance and the constructed allsolid flexible wire-shaped symmetric supercapacitors provided a specific capacitance of 4.67 F/cm3 with good cycling stability at a current density of 0.6 A/cm3.展开更多
We report a wire-shaped three-dimensional(3D)-hybrid supercapacitor with high volumetric capacitance and high energy density due to an interconnected 3D-configuration of the electrode allowing for large number of elec...We report a wire-shaped three-dimensional(3D)-hybrid supercapacitor with high volumetric capacitance and high energy density due to an interconnected 3D-configuration of the electrode allowing for large number of electrochemical active sites,easy access of electrolyte ions,and facile charge transport for flexible wearable applications.The interconnected and compact electrode delivers a high volumetric capacitance(gravimetric capacitance)of 73 F cm−3(2446 F g−1),excellent rate capability,and cycle stability.The 3D-nickel cobalt-layered double hydroxide onto 3D-nickel wire(NiCo LDH/3D-Ni)//the 3D-manganese oxide onto 3D-nickel wire(Mn3O4/3D-Ni)hybrid supercapacitor exhibits energy density of 153.3 Wh kg−1 and power density of 8810 W kg−1.The red lightemitting diode powered by the as-prepared hybrid supercapacitor can operate for 80 min after being charged for tens of seconds and exhibit excellent electrochemical stability under various deformation conditions.The results verify that such wire-shaped 3D-hybrid supercapacitors are promising alternatives for batteries with long charge–discharge times,for smart wearable and implantable devices.展开更多
AIM: To perform wire-guided cannulation using a newly designed J-shaped tip guidewire, and to verify feasibility and safety for use. METHODS: The study was conducted on endoscopic retrograde cholangiopancreatography (...AIM: To perform wire-guided cannulation using a newly designed J-shaped tip guidewire, and to verify feasibility and safety for use. METHODS: The study was conducted on endoscopic retrograde cholangiopancreatography (ERCP) patients with na ve papilla undergoing diagnosis and treatment of biliary diseases between September 2011 and July 2012. We performed ERCP in a succession of 50 cases with a J-shaped tip guidewire. The first insertion attempt began with a trainee who had 5 min to complete cannulation, followed if necessary by the trainer for another 5 min. We assessed the primary success rate of selective biliary cannulation within 10 min and adverse events such as post-ERCP pancreatitis (PEP), bleeding or perforation.RESULTS: The primary success rate was 90% (45/50) within 10 min, the initial success rate within 5 min by trainee staff was 76% (38/50). The rate of PEP was 6% (3/50), but all 3 cases were mild pancreatitis. All patients were managed successfully with conservative treatment. There was no bleeding or perforation. CONCLUSION: A newly designed J-shaped tip guidewire has the possibility to facilitate selective biliary cannulation for ERCP and appears to be safe.展开更多
Twin-wire indirect arc gas shielded welding is a novel welding method. By recording the arc shape and welding parameters, the effects of welding parameters and included angle on arc characteristics are discussed in th...Twin-wire indirect arc gas shielded welding is a novel welding method. By recording the arc shape and welding parameters, the effects of welding parameters and included angle on arc characteristics are discussed in this paper. The experimental results show increasing welding current can prompt centralized and straight of arc due to increasing plasma force and electric magnetic pinch effect. Increasing arc voltage can increase the size and brightness of the arc, as a result of increasing arc energy. The reducing of included angle increases the electric magnetic pinch effect, the arc becomes slender and supplies higher energy. It is thought the smaller included angle is beneficial to obtain perfect weld bead.展开更多
基金supported by Zhujiang New Stars of Science and Technology (2014J2200061)
文摘One-dimensional(1D, wire-and fiber-shaped)supercapacitors have recently attracted interest due to their roll-up, micrometer size and potential applications in portable or wearable electronics. Herein, a 1D wireshaped electrode was developed based on Fe_3O_4 nanosheet arrays connected on the Fe wire, which was prepared via oxidation of Fe wire in 0.1 M KCl solution(pH 3) with O2-rich environment under 70 °C. The obtained Fe_3O_4 nanosheet arrays displayed a high specific capacitance(20.8 m F cm^(-1) at 10 mV s^(-1)) and long cycling lifespan(91.7% retention after 2500 cycles). Theexcellent performance may attribute to the connected nanosheet structure with abundant open spaces and the intimate contact between the Fe_3O_4 and iron substrate. In addition, a wire-shaped asymmetric supercapacitor was fabricated and had excellent capacitive properties with a high energy density(9 l Wh cm^(-2)) at power density of 532.7 l W cm^(-2) and remarkable long-term cycling performance(99% capacitance retention after 2000 cycles).Considering low cost and earth-abundant electrode material, as well as outstanding electrochemical properties, the assembled supercapacitor will possess enormous potential for practical applications in portable electronic device.
基金supported by Priority Academic Program Development of Jiangsu Higher Education Institutions (YX03001)Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM)+3 种基金Synergistic Innovation Center for Organic Electronics and Information Displays, Jiangsu Provincial NSF (BK20160890, BK20141424, BK20150863)Jiangsu Province "Six Talent Peak" (2014-XCL-014)Qing Lan Project of Jiangsu ProvinceScientific Research Foundation of NUPT (NY214183, NY215014, NY215152)
文摘The deposition of active materials directly onto metal wires is a general strategy to prepare wire-shaped electrodes for flexible and wearable energy storage devices. However, it is still a critical challenge to coat active materials onto the aimed metal wires because of their smooth surface and small specific surface area. In this work, high porous nickel yarns（PNYs） was fabricated using commercial nylon yarns as templates through step-wise electroless plating, electroplating and calcination processes. The PNYs are composed of multiplied fibers with hollow tubular structure of 5–10 μm in diameter, allowing the imbibition of carbon nanotubes（CNTs） solution by a facile capillary action process. The prepared CNTs/PNY electrodes showed a typical electrochemical double layer capacitive performance and the constructed allsolid flexible wire-shaped symmetric supercapacitors provided a specific capacitance of 4.67 F/cm3 with good cycling stability at a current density of 0.6 A/cm3.
基金supported by national research foundation of Korea(NRF)(No.NRF-2019R1H1A2039743)S-Oil corporation,and “Human Resources Program in Energy Technology” of the Korea Institute of Energy Technology Evaluation and Planning(KETEP)granted financial resource from the Ministry of Trade,Industry and Energy,Republic of Korea(No.20194010201890)
文摘We report a wire-shaped three-dimensional(3D)-hybrid supercapacitor with high volumetric capacitance and high energy density due to an interconnected 3D-configuration of the electrode allowing for large number of electrochemical active sites,easy access of electrolyte ions,and facile charge transport for flexible wearable applications.The interconnected and compact electrode delivers a high volumetric capacitance(gravimetric capacitance)of 73 F cm−3(2446 F g−1),excellent rate capability,and cycle stability.The 3D-nickel cobalt-layered double hydroxide onto 3D-nickel wire(NiCo LDH/3D-Ni)//the 3D-manganese oxide onto 3D-nickel wire(Mn3O4/3D-Ni)hybrid supercapacitor exhibits energy density of 153.3 Wh kg−1 and power density of 8810 W kg−1.The red lightemitting diode powered by the as-prepared hybrid supercapacitor can operate for 80 min after being charged for tens of seconds and exhibit excellent electrochemical stability under various deformation conditions.The results verify that such wire-shaped 3D-hybrid supercapacitors are promising alternatives for batteries with long charge–discharge times,for smart wearable and implantable devices.
基金Supported by Toho University Ohashi Medical Center
文摘AIM: To perform wire-guided cannulation using a newly designed J-shaped tip guidewire, and to verify feasibility and safety for use. METHODS: The study was conducted on endoscopic retrograde cholangiopancreatography (ERCP) patients with na ve papilla undergoing diagnosis and treatment of biliary diseases between September 2011 and July 2012. We performed ERCP in a succession of 50 cases with a J-shaped tip guidewire. The first insertion attempt began with a trainee who had 5 min to complete cannulation, followed if necessary by the trainer for another 5 min. We assessed the primary success rate of selective biliary cannulation within 10 min and adverse events such as post-ERCP pancreatitis (PEP), bleeding or perforation.RESULTS: The primary success rate was 90% (45/50) within 10 min, the initial success rate within 5 min by trainee staff was 76% (38/50). The rate of PEP was 6% (3/50), but all 3 cases were mild pancreatitis. All patients were managed successfully with conservative treatment. There was no bleeding or perforation. CONCLUSION: A newly designed J-shaped tip guidewire has the possibility to facilitate selective biliary cannulation for ERCP and appears to be safe.
文摘Twin-wire indirect arc gas shielded welding is a novel welding method. By recording the arc shape and welding parameters, the effects of welding parameters and included angle on arc characteristics are discussed in this paper. The experimental results show increasing welding current can prompt centralized and straight of arc due to increasing plasma force and electric magnetic pinch effect. Increasing arc voltage can increase the size and brightness of the arc, as a result of increasing arc energy. The reducing of included angle increases the electric magnetic pinch effect, the arc becomes slender and supplies higher energy. It is thought the smaller included angle is beneficial to obtain perfect weld bead.
