Thermal fatigue checking is the general failure of hot work die steels, which is relative with the structures and properties of the steels and the stress alternated during the employment. The Uddeholm test method on t...Thermal fatigue checking is the general failure of hot work die steels, which is relative with the structures and properties of the steels and the stress alternated during the employment. The Uddeholm test method on thermal fatigue is used to compare the behaviors of different samples, which are treated with plasma nitriding、plasma sulfur carbon nitriding、boronizing or not treated. The results show that the nitriding improves the thermal fatigue property of the tool steel, while the plasma sulfur carbon nitriding and the boronizing impair the property. The mechanisms are induced as follows. By increasing the hardness and changing the stress distribution in the surface layer, surface treatment can decrease the plastic deformation and the tensile stress during the cycling. Therefore, the generation and growth of the cracks are restrained. On the other hand, as results of surface treating, in the surface layer the toughness declines and the expanding coefficient ascendes; the latter change caused the strengthening of the tensile and compressive stress during the cycling. Thus the resistance to thermal fatigue is weakened. Whether or not the surface treatment is favor to thermal fatigue of tool steels relies on which factor is dominant.展开更多
With the rapid development of the automobile industry in China, there is an ever-increasing demand for long-life cold working dies used for punching automobile components. However, the full potential of such advanced ...With the rapid development of the automobile industry in China, there is an ever-increasing demand for long-life cold working dies used for punching automobile components. However, the full potential of such advanced surface engineering technologies as PVD coatings and duplex surface treatments in cold work dies has not been realized. In the present study, Crl2MoV steel has been surface engineered by single PVD Ti/TiN coating and duplex treatment combining low temperature plasma nitriding (LTPN) with PVD Ti/TiN coatings. The properties of Ti/TiN coatings in terms of surface morphology, microhardness, load bearing capacity, bonding strength and wear resistance were evaluated by microhardness, scratch and wear tests. The experimental results show that PVD Ti/TiN coatings can significantly enhance the surface load bearing capacity (especially for duplex treatments) and wear resistance of Crl2MoV steel by more than one order of magnitude. This can be mainly attributed to the hard and well-adherent PVD Ti/TiN surface coatings and strong mechanical support of the LTPN sublayer. While two-body abrasive wear prevails for uncoated Crl2MoV, the micropolishing action of the counterface dominates in surface engineered material.展开更多
This paper studies a compound treatment. i. e. liquid S , N,C co-diffusing with rare earth (RE) and then oxidization , for hot-working die steels , and the effect of RE on thermal fatigue behavior of the diffused laye...This paper studies a compound treatment. i. e. liquid S , N,C co-diffusing with rare earth (RE) and then oxidization , for hot-working die steels , and the effect of RE on thermal fatigue behavior of the diffused layer. XRD and SEM energy spectrum prove that trace RE element actually penetrates into the surface layer of steels. The result shows that RE can reduce the gradient of change of hardness in diffused layer, improve the morphology and distribution of compounds , and reduce the degree of surface alligator crack for thermal fatigue. The behavior of thermal fatigue of hot-working die steels is raised by 70% or so after the application of RE. The effect of RE is analysed according to the theory.展开更多
The estrogenic activity of influents and effluents of five municipal sewage treatment works (STWs) in Nanjing was investigated. The water samples were enriched by solid phase extraction, then eluted with different p...The estrogenic activity of influents and effluents of five municipal sewage treatment works (STWs) in Nanjing was investigated. The water samples were enriched by solid phase extraction, then eluted with different polar solvents, and f'mally three fractionated extracts were obtained. Estrogen receptor recombinant yeast screen was used to evaluate the estrogenic activity of individual fractionated extracts and their mixture. The results show that the influents and effluents of the two STWs mainly receiving industrial wastewater have no obvious estrogenic activity, and the water samples from the other three STWs mainly receiving domestic wastewater show different degrees of estrogenic activity. The total estrogenic concentration ranged from 171. 52 ng/L EEQ (E2 - equivalent concentration) to 1 008.37 ng/L EEQ in the influents, and from ND (not detected) to 36.3 ng/L EEQ in the effluents. By comparing the results of different fractionated extracts, the methanol and dichloromethane extracts of the water samples show higher estrogenic activity, while the hexane extracts very low. The (xeno)estrogens from domestic wastewater could be removed obviously by activated sludge treatment units. However, the effluents of STWs in Nanjing still have chemical contaminants capable of binding to estrogen receptors.展开更多
Despite years of interventions in the United States, substance abuse continues to be a major national problem in our society. For individuals affected, it can constitute a major disability and a decrease in quality of...Despite years of interventions in the United States, substance abuse continues to be a major national problem in our society. For individuals affected, it can constitute a major disability and a decrease in quality of life. Current American societal expectations are that individuals who identify!they are involved in substance abuse will go to treatment, eventually recover, get off public assistance straightaway, and return to work. Most rehabilitation professionals also maintain the same expectations. The reality is that efforts of prevention do not appear to diminish the number of people with substance abuse. Traditional treatment appears to have minimal, if any, influence upon the cessation of substance abuse, and traditional vocational rehabilitation practices appear unsuited for the unique problems and types of symptoms experienced by substance abusers. Creative, yet sound, alternatives that combine effective treatment strategies and non-traditional vocational rehabilitation methods need to be exqlored and tested for effectiveness, and applied.展开更多
These days, water and wastewater treatment are one of the most important issues regarding to the human health. Wastewaters are one of the most environmental pollutants and a wide range of adverse effects linked to the...These days, water and wastewater treatment are one of the most important issues regarding to the human health. Wastewaters are one of the most environmental pollutants and a wide range of adverse effects linked to the effect of untreated wastewaters or wastewaters that treat improperly. The aim of this present study was to evaluate performance of the wastewater treatment plant at Al-Diwaniyah City according to the national standards. Therefore, data of the most common parameters (PH, BOD<sub>5</sub>, COD, TSS, PO<sub>4</sub>, NO<sub>3</sub>, Cl, and Oil and Grease) were collected from the wastewater treatment plant. The study revealed that the wastewater treatment plant was receiving medium to strong influent with a BOD<sub>5</sub>/COD ratio of between (0.4 - 0.7). Regression analysis was achieved to approximate the influent of BOD<sub>5</sub> and TSS. While the effluent quality was exceeded the Iraq standards for disposing treated wastewater to the water bodies with a fluctuation in the ratio of BOD5to COD as a consequence of the operational problems. Therefore, these results would be of help to planners and policy makers in the City to combat such this problem and to take the necessary actions to reduce the impact of these pollutants.展开更多
文摘Thermal fatigue checking is the general failure of hot work die steels, which is relative with the structures and properties of the steels and the stress alternated during the employment. The Uddeholm test method on thermal fatigue is used to compare the behaviors of different samples, which are treated with plasma nitriding、plasma sulfur carbon nitriding、boronizing or not treated. The results show that the nitriding improves the thermal fatigue property of the tool steel, while the plasma sulfur carbon nitriding and the boronizing impair the property. The mechanisms are induced as follows. By increasing the hardness and changing the stress distribution in the surface layer, surface treatment can decrease the plastic deformation and the tensile stress during the cycling. Therefore, the generation and growth of the cracks are restrained. On the other hand, as results of surface treating, in the surface layer the toughness declines and the expanding coefficient ascendes; the latter change caused the strengthening of the tensile and compressive stress during the cycling. Thus the resistance to thermal fatigue is weakened. Whether or not the surface treatment is favor to thermal fatigue of tool steels relies on which factor is dominant.
文摘With the rapid development of the automobile industry in China, there is an ever-increasing demand for long-life cold working dies used for punching automobile components. However, the full potential of such advanced surface engineering technologies as PVD coatings and duplex surface treatments in cold work dies has not been realized. In the present study, Crl2MoV steel has been surface engineered by single PVD Ti/TiN coating and duplex treatment combining low temperature plasma nitriding (LTPN) with PVD Ti/TiN coatings. The properties of Ti/TiN coatings in terms of surface morphology, microhardness, load bearing capacity, bonding strength and wear resistance were evaluated by microhardness, scratch and wear tests. The experimental results show that PVD Ti/TiN coatings can significantly enhance the surface load bearing capacity (especially for duplex treatments) and wear resistance of Crl2MoV steel by more than one order of magnitude. This can be mainly attributed to the hard and well-adherent PVD Ti/TiN surface coatings and strong mechanical support of the LTPN sublayer. While two-body abrasive wear prevails for uncoated Crl2MoV, the micropolishing action of the counterface dominates in surface engineered material.
文摘This paper studies a compound treatment. i. e. liquid S , N,C co-diffusing with rare earth (RE) and then oxidization , for hot-working die steels , and the effect of RE on thermal fatigue behavior of the diffused layer. XRD and SEM energy spectrum prove that trace RE element actually penetrates into the surface layer of steels. The result shows that RE can reduce the gradient of change of hardness in diffused layer, improve the morphology and distribution of compounds , and reduce the degree of surface alligator crack for thermal fatigue. The behavior of thermal fatigue of hot-working die steels is raised by 70% or so after the application of RE. The effect of RE is analysed according to the theory.
基金Program for New Century Excellent Talents in University of China(No.05-0481)
文摘The estrogenic activity of influents and effluents of five municipal sewage treatment works (STWs) in Nanjing was investigated. The water samples were enriched by solid phase extraction, then eluted with different polar solvents, and f'mally three fractionated extracts were obtained. Estrogen receptor recombinant yeast screen was used to evaluate the estrogenic activity of individual fractionated extracts and their mixture. The results show that the influents and effluents of the two STWs mainly receiving industrial wastewater have no obvious estrogenic activity, and the water samples from the other three STWs mainly receiving domestic wastewater show different degrees of estrogenic activity. The total estrogenic concentration ranged from 171. 52 ng/L EEQ (E2 - equivalent concentration) to 1 008.37 ng/L EEQ in the influents, and from ND (not detected) to 36.3 ng/L EEQ in the effluents. By comparing the results of different fractionated extracts, the methanol and dichloromethane extracts of the water samples show higher estrogenic activity, while the hexane extracts very low. The (xeno)estrogens from domestic wastewater could be removed obviously by activated sludge treatment units. However, the effluents of STWs in Nanjing still have chemical contaminants capable of binding to estrogen receptors.
文摘Despite years of interventions in the United States, substance abuse continues to be a major national problem in our society. For individuals affected, it can constitute a major disability and a decrease in quality of life. Current American societal expectations are that individuals who identify!they are involved in substance abuse will go to treatment, eventually recover, get off public assistance straightaway, and return to work. Most rehabilitation professionals also maintain the same expectations. The reality is that efforts of prevention do not appear to diminish the number of people with substance abuse. Traditional treatment appears to have minimal, if any, influence upon the cessation of substance abuse, and traditional vocational rehabilitation practices appear unsuited for the unique problems and types of symptoms experienced by substance abusers. Creative, yet sound, alternatives that combine effective treatment strategies and non-traditional vocational rehabilitation methods need to be exqlored and tested for effectiveness, and applied.
文摘These days, water and wastewater treatment are one of the most important issues regarding to the human health. Wastewaters are one of the most environmental pollutants and a wide range of adverse effects linked to the effect of untreated wastewaters or wastewaters that treat improperly. The aim of this present study was to evaluate performance of the wastewater treatment plant at Al-Diwaniyah City according to the national standards. Therefore, data of the most common parameters (PH, BOD<sub>5</sub>, COD, TSS, PO<sub>4</sub>, NO<sub>3</sub>, Cl, and Oil and Grease) were collected from the wastewater treatment plant. The study revealed that the wastewater treatment plant was receiving medium to strong influent with a BOD<sub>5</sub>/COD ratio of between (0.4 - 0.7). Regression analysis was achieved to approximate the influent of BOD<sub>5</sub> and TSS. While the effluent quality was exceeded the Iraq standards for disposing treated wastewater to the water bodies with a fluctuation in the ratio of BOD5to COD as a consequence of the operational problems. Therefore, these results would be of help to planners and policy makers in the City to combat such this problem and to take the necessary actions to reduce the impact of these pollutants.