Elucidation of a reaction mechanism is the most critical aspect for designing electrodes for highperformance secondary batteries.Herein,we investigate the sodium insertion/extraction into an iron fluoride hydrate(FeF_...Elucidation of a reaction mechanism is the most critical aspect for designing electrodes for highperformance secondary batteries.Herein,we investigate the sodium insertion/extraction into an iron fluoride hydrate(FeF_(3)·0.5H_(2)O)electrode for sodium-ion batteries(SIBs).The electrode material is prepared by employing an ionic liquid 1-butyl-3-methylimidazolium-tetrafluoroborate,which serves as a reaction medium and precursor for F^(-)ions.The crystal structure of FeF_(3)·0.5H_(2)O is observed as pyrochlore type with large open 3-D tunnels and a unit cell volume of 1129A^(3).The morphology of FeF_(3)·0.5H_(2)O is spherical shape with a mesoporous structure.The microstructure analysis reveals primary particle size of around 10 nm.The FeF_(3)·0.5H_(2)O cathode exhibits stable discharge capacities of 158,210,and 284 mA h g^(-1) in three different potential ranges of 1.5-4.5,1.2-4.5,and 1.0-4.5 V,respectively at 0.05 C rate.The specific capacities remained stable in over 50 cycles in all three potential ranges,while the rate capability was best in the potential range of 1.5-4.5 V.The electrochemical sodium storage mechanism is studied using X-ray absorption spectroscopy,indicating higher conversion at a more discharged state.Ex-situ M?ssbauer spectroscopy strengthens the results for reversible reduction/oxidation of Fe.These results will be favorable to establish high-performance cathode materials with selective voltage window for SIBs.展开更多
Based on the synchrotron soft X-ray absorption spectroscopy experiments,the fundamental electronic structures of layered Li NixCoyMnzO_(2)(NCM)are investigated systematically and the data of transitionmetal(TM)L-and O...Based on the synchrotron soft X-ray absorption spectroscopy experiments,the fundamental electronic structures of layered Li NixCoyMnzO_(2)(NCM)are investigated systematically and the data of transitionmetal(TM)L-and O K-edges spectra are collected.Distribution of Ni ions under different oxidation states is evaluated according to linear combination fit.It is found that the ratio of Ni^(4+)expands with the increase of Ni since it dominates in charge compensation during charging,and that the existence of Ni^(3+)is nearly negligible in delithiated NCM.The valence state of Co also strongly depends on Ni content,the perceptible position shift of Co L_(3)-edge absorption peak towards higher energy in Ni-rich material agrees well with the small voltage plateau at around 4.2 V.The stability of Mn is verified as no obvious spectral change with the Mn L-edge is observed.Moreover,as Ni content rises,the O 2p holes near the Femi level increases with higher oxidation state of Ni,indicating the enhanced hybridization of O 2p-TM 3 d.Delithiated NCMs with higher Ni content are prior to lose electron existing in highly hybridized Ni3 dO 2 p bands upon heating,which accounts for the pronounced O_(2)release in phase transitions and the deterioration in thermal stability.These detailed observation of the electronic structure evolution is one of the key ingredients to improving the electrochemical and thermal performance of NCM.展开更多
The local structure of an alternative Pb(Zn1/3Nb2/3)O3-based perovskite ceramic is investigated. The 0.07BaTiO33-0.93Pb(Zn1/3Nb2/3)O3 ceramic is synthesized using a combination of Zn3Nb2O8 B-site precursor and BaT...The local structure of an alternative Pb(Zn1/3Nb2/3)O3-based perovskite ceramic is investigated. The 0.07BaTiO33-0.93Pb(Zn1/3Nb2/3)O3 ceramic is synthesized using a combination of Zn3Nb2O8 B-site precursor and BaTiO33 perovskite phase stabilizer. Then, x-ray absorption spectroscopy and density functional theory are employed to calculate the local structure configuration and formation energy of the prepared samples. Ba2+ is found to replace Pb2+ in AA-site with Zn2+ occupying BB-site in Pb(Zn1/3Nb2/3)O3, while in the neighboring structure, Ti4+4+ replaces Nb5+5+ in BB-site with Pb2+2+ occupying AA-site. With the substitution of BaTiO33 in Pb(Zn1/3Nb2/3)O3, the bond length between Zn2+ and Pb2+ is longer than that of the typical perovskite phase of Pb(Zn1/3Nb2/3)O3. This indicates the key role of BaTiO33 in decreasing the steric hindrance of Pb2+ lone pair, and the mutual interactions between Pb2+ lone pair and Zn2+ and the formation energy is seen to decrease. This finding of the formation energy and local structure configuration relationship can further extend a fundamental understanding of the role of BaTiO33 in stabilizing the perovskite phase in PbZn13Nb23O3-based materials, which in turn will lead to an improved preparation technique for desired electrical properties.展开更多
Lead dissolved in water must be removed in order not to cause diseases, especially from high pH aqueous solution. Various oxides having high specific surface area are often applied to remove lead in water media. To im...Lead dissolved in water must be removed in order not to cause diseases, especially from high pH aqueous solution. Various oxides having high specific surface area are often applied to remove lead in water media. To improve removal ability for lead species, it is necessary to understand the adsorbed structure of lead species on oxides. At first, the adsorption behavior of lead from high pH solution in the presence of Ca<sup>2+</sup> and Na+ was compared. Lead and calcium species were adsorbed up to the monolayer, and the adsorption isotherm was analyzed as Langmuir-type adsorption. In the presence of Ca<sup>2+</sup>, the amount of removed lead was reduced. To clarify this influence of Ca<sup>2+</sup>, X-ray absorption spectroscopy was adopted. It was for the first time revealed that lead species at pH > 12 and pH < 10.5 differed, and that lead species adsorbed on various oxides had a similar structure.展开更多
X-Ray Absorption Spectroscopy (XAS) on the carbon K edge of carbon nanostructures (nanotubes, nanofibers, nanowalls) is reported here. They are grown on plain SiO2 (8 nm thick)/Si(100) substrates by a Plasma and Hot F...X-Ray Absorption Spectroscopy (XAS) on the carbon K edge of carbon nanostructures (nanotubes, nanofibers, nanowalls) is reported here. They are grown on plain SiO2 (8 nm thick)/Si(100) substrates by a Plasma and Hot Filaments-enhanced Catalytic Chemical Vapor Deposition (PE HF CCVD) process. The morphology and the nature of these carbon nanostructures are characterized by SEM, TEM and Raman spectroscopy. According to conditions of catalyst preparation and DC HF CCVD process, carbon nanotubes (CNTs), carbon nanofibers (CNFs), carbon nanowalls (CNWs), carbon nanoparticles (CNPs) with different orientation of the graphene plans or shells can be prepared. From the angular dependence of the incident light and geometrical morphology of the nanostructures, wide variations of the C K-edge intensity of the transitions to the empty π* and σ* states occur. A full lineshape analysis of the XAS spectra has been carried out using a home-made software, allowing estimating the relative proportion of π* and σ* transitions. A geometrical model of the angular dependence with the incidence angle of the light and the morphology of the carbon nanostructures is derived. With normalization to the HOPG (Highly Oriented Pyrolytic Graphite graphite) reference case, a degree of alignment can be extracted which is representative of the localized orientation of the graphitic carbon π bonds, accounting not only for the overall orientation, but also for local defects like impurities incorporation, structural defects ... This degree of alignment shows good agreement with SEM observations. Thus CNTs films display degrees of alignment around 50%, depending on the occurrence of defects in the course of the growth, whereas no special alignment can be detected with CNFs and CNPs, and a weak one (about 20%) is detected on CNWs.展开更多
Nanoscale electrocatalysts have exhibited promising activity and stability,improving the kinetics of numerous electrochemical reactions in renewable energy systems such as electrolyzers,fuel cells,and metal-air batter...Nanoscale electrocatalysts have exhibited promising activity and stability,improving the kinetics of numerous electrochemical reactions in renewable energy systems such as electrolyzers,fuel cells,and metal-air batteries.Due to the size effect,nano particles with extreme small size have high surface areas,complicated morphology,and various surface terminations,which make them different from their bulk phases and often undergo restructuring during the reactions.These restructured materials are hard to probe by conventional ex-situ characterizations,thus leaving the true reaction centers and/or active sites difficult to determine.Nowadays,in situ techniques,particularly X-ray absorption spectroscopy(XAS),have become an important tool to obtain oxidation states,electronic structure,and local bonding environments,which are critical to investigate the electrocatalysts under real reaction conditions.In this review,we go over the basic principles of XAS and highlight recent applications of in situ XAS in studies of nanoscale electrocatalysts.展开更多
In situ quick X-ray absorption spectroscopy(QXAFS) at the Cu and Zn K-edge under operando conditions has been used to unravel the Cu/Zn interaction and identify possible active site of CuO/ZnO/Al_2O_3 catalyst for met...In situ quick X-ray absorption spectroscopy(QXAFS) at the Cu and Zn K-edge under operando conditions has been used to unravel the Cu/Zn interaction and identify possible active site of CuO/ZnO/Al_2O_3 catalyst for methanol synthesis. In this work, the catalyst, whose activity increases with the reaction temperature and pressure, was studied at calcined, reduced, and reacted conditions. TEM and EDX images for the calcined and reduced catalysts showed that copper was distributed uniformly at both conditions. TPR profile revealed two reduction peaks at 165 and 195 °C for copper species in the calcined catalyst. QXAFS results demonstrated that the calcined form consisted mainly of a mixed Cu O and Zn O, and it was progressively transformed into Cu metal particles and dispersed Zn O species as the reduction treatment. It was demonstrated that activation of the catalyst precursor occurred via a Cu^+intermediate, and the active catalyst predominantly consisted of metallic Cu and Zn O evenunder higher pressures. Structure of the active catalyst did not change with the temperature or pressure, indicating that the role of the Zn was mainly to improve Cu dispersion.This indicates the potential of QXAFS method in studying the structure evolutions of catalysts in methanol synthesis.展开更多
Based on the high-energy-resolution fluorescence spectrometer on the BL14W1 beamline at Shanghai Synchrotron Radiation Facility,an in-situ high-energyresolution X-ray absorption spectroscopy technique,with an in-situ ...Based on the high-energy-resolution fluorescence spectrometer on the BL14W1 beamline at Shanghai Synchrotron Radiation Facility,an in-situ high-energyresolution X-ray absorption spectroscopy technique,with an in-situ heating cell,was developed.The high-energyresolution fluorescence detection for X-ray absorption near-edge spectroscopy(HERFD-XANES) was tested in a UO_2 oxidation experiment to measure the UL_3-edge,with higher signal-to-noise ratio and higher-energy-resolution than conventional XANES.The technique has potential application for in-situ study of uranium-based materials.展开更多
As a potential application of titanium-oxide nanoparticles, it is extremely important to investigate a detailed picture of the surface and interior structural properties of nanocrystalline materials, such as rutile an...As a potential application of titanium-oxide nanoparticles, it is extremely important to investigate a detailed picture of the surface and interior structural properties of nanocrystalline materials, such as rutile and anatase with diameters 7.0 and 4.5nm, respectively. X-ray absorption spectroscopy has been used to identify the local Ti environment and related electronic structure. We combine the experimental results at the Ti edge in both bulk and nano-crystals to determine the lattice distortion in terms of differently characteristic preedge features and the variation in the multiple-scattering region of X-ray absorption near-edge structure (XANES) spectra. The relationship between the transition peaks and the surface-to volume ratio is also discussed.展开更多
In this paper we present the state of the art of the theoretical background needed for analyzing X-ray absorption spectra in the whole energy range. The multiple-scattering (MS) theory is presented in detail with some...In this paper we present the state of the art of the theoretical background needed for analyzing X-ray absorption spectra in the whole energy range. The multiple-scattering (MS) theory is presented in detail with some applications on real systems. We also describe recent progress in performing geometrical fitting of the XANES (X-ray absorption near-edge structure) energy region and beyond using a full multiple-scattering approach.展开更多
In order to obtain an in-depth insight into the mechanism of charge compensation and capacity fading in LiCoO2, the evolution of electronic structure of LiCoO2 at different cutoff voltages and after different cycles a...In order to obtain an in-depth insight into the mechanism of charge compensation and capacity fading in LiCoO2, the evolution of electronic structure of LiCoO2 at different cutoff voltages and after different cycles are studied by soft x-ray absorption spectroscopy in total electron(TEY) and fluorescence(TFY) detection modes, which provide surface and bulk information, respectively. The spectra of Co L2,3-edge indicate that Co contributes to charge compensation below 4.4 V.Combining with the spectra of O K-edge, it manifests that only O contributes to electron compensation above 4.4 V with the formation of local O 2 p holes both on the surface and in the bulk, where the surficial O evolves more remarkably. The evolution of the O 2 p holes gives an explanation to the origin of O2^-or even O2. A comparison between the TEY and TFY of O K-edge spectra of LiCoO2 cycled in a range from 3 V to 4.6 V indicates both the structural change in the bulk and aggregation of lithium salts on the electrode surface are responsible for the capacity fading. However, the latter is found to play a more important role after many cycles.展开更多
Breakthroughs in energy storage and conversion devices depend heavily on the exploration of low-cost and high-performance materials.Carbon-supported electrocatalysts with dimensional varieties have recently attracted ...Breakthroughs in energy storage and conversion devices depend heavily on the exploration of low-cost and high-performance materials.Carbon-supported electrocatalysts with dimensional varieties have recently attracted significant attention due to their strong structural flexibility and easy accessibility.Nevertheless,understanding the connection between their electronic,structural properties,and catalytic performance must remain a top priority.Synchrotron radiation(SR)X-ray absorption spectroscopy(XAS)techniques,including hard XAS and soft XAS,are recognized as efficient and comprehensive platforms for probing the surface,interface,and bulk electronic structure of elements of interest in the materials community.In the past decade,the flourishing development of materials science and advanced characterization technologies have led to a deeper understanding at different temporal,longitudinal,and spatial scales.In this review,we briefly describe the concept of XAS techniques and summarize their recent progress in addressing scientific questions on carbon-supported electrocatalysts through the development of advanced instruments and experimental methods.We then discuss the remaining challenges and potential research directions in nextgeneration materials frontiers,and suggest challenges and perspectives for shedding light on the structure–activity relationship.展开更多
Chalcopyrite and bornite are the main Au-bearing minerals at Cu porphyry deposits,volcanogenic massive sulfide(VMS)deposits,Cu-Ni deposits of the mafic magmatic complexes,and ores of submarine sulfide edifices.Bornite...Chalcopyrite and bornite are the main Au-bearing minerals at Cu porphyry deposits,volcanogenic massive sulfide(VMS)deposits,Cu-Ni deposits of the mafic magmatic complexes,and ores of submarine sulfide edifices.Bornite and intermediate solid solutions with wide compositional variations(bnss and iss–high-temperature chalcopyrite,correspondingly),which can scavenge economic concentrations of Au,appear in the Cu-Fe-S system at ore-forming conditions.However,the state of Au in bnss and iss is yet unknown.To solve this conundrum,we synthesized samples with net chemical composition of bnss and iss,studied them by in situ X–ray absorption spectroscopy(XAS),and used the experimental data to explain the Au distribution among natural ore-forming minerals.The sulfide samples were obtained at 495–700℃ in Au-saturated system by means of salt flux method.The bnss contained1.2–1.6 log units more Au than iss:up to 18 wt.%Au in bnss vs 0.4 wt.%Au in iss at 700C.An increase of temperature resulted in the sharp increase of Au concentration in both phases,1 log unit per 100℃ at f(S2)close to S_((l)) saturation.Analysis of Au L_(3)-edge spectra recorded at 25–675℃ revealed that at 25℃ Au exists mainly in the metallic state.At t>500℃ the spectral features of Audisappear,and “chemically bound”Au predominates.The Au form of occurrence in the iss field is interpreted as Au-bearing clusters with a stromeyerite-like(CuAgS)structure.Digenite Cu_(2–x)S and bnss contain Au in a mixture of stromeyeritelike and petrovskaite-like(Au_(0.8)Ag_(1.2)S)clusters.The chemical composition of both forms is close to CuAuS,where the nearest Au neighbors are two S atoms at R_(Au-S)=2.34–2.36Å.Results of the present study allow to determine the state of Au and its concentration in the main Cu-bearing minerals of sulfide ores as a function of the T-f(S_(2))-compositional parameters.Due to the sharp increase of the CuAuS clusters stability with increasing temperature,in high-temperature ores formed at t>350℃ Au enriches Cubearing minerals in comparison with Cu-free or Cu-deficient ones.As a result,in these ores native gold,being a product of decomposition of the Au-bearing clusters,is associated with Cu-rich minerals–chalcopyrite,bornite,digenite,chalcocite.展开更多
This compendium review focuses on the spatial distribution of sensitivity to localized absorption changes in optically diffuse media,particularly for measurements relevant to near-infrared spectroscopy.The three tempo...This compendium review focuses on the spatial distribution of sensitivity to localized absorption changes in optically diffuse media,particularly for measurements relevant to near-infrared spectroscopy.The three temporal domains,continuous wave,frequency domain,and time domain,each obtain different optical data types whose changes may be related to effective homogeneous changes in the absorption coefficient.Sensitivity is the relationship between a localized perturbation and the recovered effective homogeneous absorption change.Therefore,spatial sensitivity maps representing the perturbation location can be generated for the numerous optical data types in the three temporal domains.The review first presents a history of the past 30 years of work investigating this sensitivity in optically diffuse media.These works are experimental and theoretical,presenting one-,two-,and three-dimensional sensitivity maps for different Near-Infrared Spectroscopy methods,domains,and data types.Following this history,we present a compendium of sensitivity maps organized by temporal domain and then data type.This compendium provides a valuable tool to compare the spatial sensitivity of various measurement methods and parameters in one document.Methods for one to generate these maps are provided in Appendix A,including the code.This historical review and comprehensive sensitivity map compendium provides a single source researchers may use to visualize,investigate,compare,and generate sensitivity to localized absorption change maps.展开更多
The layout and characteristics of the hard X-ray spectroscopy beamline(BL11B)at the Shanghai synchrotron radiation facility are described herein.BL11B is a bending-magnet beamline dedicated to conventional and millise...The layout and characteristics of the hard X-ray spectroscopy beamline(BL11B)at the Shanghai synchrotron radiation facility are described herein.BL11B is a bending-magnet beamline dedicated to conventional and millisecond-scale quick-scanning X-ray absorption fine structures.It is equipped with a cylindrical collimating mirror,a double-crystal monochromator comprising Si(111)and Si(311),a channel-cut quick-scanning Si(111)monochromator,a toroidal focusing mirror,and a high harmonics rejection mirror.It can provide 5-30 keV of X-rays with a photon flux of~5×10^(11)photons/s and an energy resolution of~1.31×10^(-4)at 10 keV.The performance of the beamline can satisfy the demands of users in the fields of catalysis,materials,and environmental science.This paper presents an overview of the beamline design and a detailed description of its performance and capabilities.展开更多
Hydrogen production by water reduction reactions has received considerable attention because hydrogen is considered a clean-energy carrier,key for a sustainable energy future.Computational methods have been widely use...Hydrogen production by water reduction reactions has received considerable attention because hydrogen is considered a clean-energy carrier,key for a sustainable energy future.Computational methods have been widely used to study the reaction mechanism of the hydrogen evolution reaction(HER),but the calculation results need to be supported by experimental results and direct evidence to confirm the mechanistic insights.In this review,we discuss the fundamental principles of the in situ spectroscopic strategy and a theoretical model for a mechanistic understanding of the HER.In addition,we investigate recent studies by in situ Fourier transform infrared(FTIR),Raman spectroscopy,and X-ray absorption spectroscopy(XAS) and cover new findings that occur at the catalyst-electrolyte interface during HER.These spectroscopic strategies provide practical ways to elucidate catalyst phase,reaction intermediate,catalyst-electrolyte interface,intermediate binding energy,metal valency state,and coordination environment during HER.展开更多
Nickel based magnetic nanocrystals have been widely applied in magnetic and catalytic facilities.Tunable magnetic properties of nickel can be easily obtained via non-magnetic doping or phase transformation.However,pha...Nickel based magnetic nanocrystals have been widely applied in magnetic and catalytic facilities.Tunable magnetic properties of nickel can be easily obtained via non-magnetic doping or phase transformation.However,phase transformation from face centered cubic(fcc)to hexagonal close packed(hcp)induced magnetism adjustment of Ni are always confused with nickel carbide(Ni_(3)C),due to the similar atomic structures of hcp-Ni and Ni3C.Here,we present series of Au@Ni-carbide magnetic materials achieved from the controlled carbonation of Au@Ni core-shell structures,whose magnetism is tunable by adjusting the amount of carbon in the Ni layer.Ex-situ hard X-ray absorption spectroscopy(XAS)at the metal K edge and soft XAS at both metal L edge and carbon K edge provide solid evidence for the carbonation process from fcc-Ni to Ni_(x)C,rather than phase transformation to hcp-Ni.Further investigation reveals that the magnetism of the hybrids is mainly contributed from the residual fcc-Ni.The result represents an accurate and effective way to distinguish hexagonal Ni_(3)C from hcp-Ni,and provides the pathway to control magnetism of Ni-based materials for applications.展开更多
The polysulfides shuttle effect represents a great challenge in achieving high capacity and long lifespan of lithium/sulfur(Li/S)cells.A comprehensive understanding of the shuttle-related sulfur speciation and diffusi...The polysulfides shuttle effect represents a great challenge in achieving high capacity and long lifespan of lithium/sulfur(Li/S)cells.A comprehensive understanding of the shuttle-related sulfur speciation and diffusion process is vital for addressing this issue.Herein,we employed in situ/operando X-ray absorption spectroscopy(XAS)to trace the migration of polysulfides across the Li/S cells by precisely monitoring the sulfur chemical speciation at the cathodic electrolyte-separator and electrolyte-anode interfaces,respectively,in a real-time condition.After we adopted a shuttle-suppressing strategy by introducing an electrocatalytic layer of twinborn bismuth sulfide/bismuth oxide nanoclusters in a carbon matrix(BSOC),we found the Li/S cell showed greatly improved sulfur utilization and longer life span.The operando S Kedge XAS results revealed that the BSOC modification was bi-functional:trapping polysulfides and catalyzing conversion of sulfur species simultaneously.We elucidated that the polysulfide trapping-and-catalyzing effect of the BSOC electrocatalytic layer resulted in an effective lithium anode protection.Our results could offer potential stratagem for designing more advanced Li/S cells.展开更多
The possible configurations of pyrrole absorbed on a Si(100)surface have been investigated by x-ray photoelectron spectroscopy(XPS)and near-edge x-ray absorption fine structure(NEXAFS)spectra.The C-1s XPS and NEXAFS s...The possible configurations of pyrrole absorbed on a Si(100)surface have been investigated by x-ray photoelectron spectroscopy(XPS)and near-edge x-ray absorption fine structure(NEXAFS)spectra.The C-1s XPS and NEXAFS spectra of these adsorption configurations have been calculated by using the density functional theory(DFT)method and fullcore hole(FCH)approximation to investigate the relationship between the adsorption configurations and the spectra.The result shows that the XPS and NEXAFS spectra are structurally dependent on the configurations of pyrrole absorbed on the Si(100)surface.Compared with the XPS,the NEXAFS spectra are relatively sensitive to the adsorption configurations and can accurately identify them.The NEXAFS decomposition spectra produced by non-equivalent carbon atoms have also been calculated and show that the spectral features vary with the diverse types of carbon atoms and their structural environments.展开更多
A method is described to determine the internal structure of electrocatalyst nanoparticles by in situ X-ray absorption spectroscopy (XAS). The nondestructive spec- troscopic technique typically utilizing synchrotron...A method is described to determine the internal structure of electrocatalyst nanoparticles by in situ X-ray absorption spectroscopy (XAS). The nondestructive spec- troscopic technique typically utilizing synchrotron radiation as the source measures changes in the X-ray absorption coefficient as a function of energy. The bulk technique has found its use for materials characterization in all scientific areas, including nanomaterials. The analysis of the internal structure of nanoparticles reveals intera- tomic distances and coordination numbers for each element, and their values and mutual relations indicate whether the elements form a homogeneous or hetero- geneous mixture. The core-shell heterogeneous structure in which certain elements are predominantly located in the core, and others form the encapsulating shell is of particular importance in catalysis and electrocatalysis because it may reduce the amount of precious metals in nanoparticles by replacing the atoms in the core of nanoparticles with more abundant and cheaper alternatives. The examples of nanoparticle structures designed in the laboratory and the approach to model efficient catalysts through systematic analysis of XAS data in electrochemical systems consisting of two and three metals are also demonstrated.展开更多
基金supported by the Basic Science Research Program of the National Research Foundation(NRF)of South Koreafunded by the Ministry of Science&ICT and Future Planning(NRF-2020M3H4A3081889)KIST Institutional Program of South Korea(Project Nos.2E31860)。
文摘Elucidation of a reaction mechanism is the most critical aspect for designing electrodes for highperformance secondary batteries.Herein,we investigate the sodium insertion/extraction into an iron fluoride hydrate(FeF_(3)·0.5H_(2)O)electrode for sodium-ion batteries(SIBs).The electrode material is prepared by employing an ionic liquid 1-butyl-3-methylimidazolium-tetrafluoroborate,which serves as a reaction medium and precursor for F^(-)ions.The crystal structure of FeF_(3)·0.5H_(2)O is observed as pyrochlore type with large open 3-D tunnels and a unit cell volume of 1129A^(3).The morphology of FeF_(3)·0.5H_(2)O is spherical shape with a mesoporous structure.The microstructure analysis reveals primary particle size of around 10 nm.The FeF_(3)·0.5H_(2)O cathode exhibits stable discharge capacities of 158,210,and 284 mA h g^(-1) in three different potential ranges of 1.5-4.5,1.2-4.5,and 1.0-4.5 V,respectively at 0.05 C rate.The specific capacities remained stable in over 50 cycles in all three potential ranges,while the rate capability was best in the potential range of 1.5-4.5 V.The electrochemical sodium storage mechanism is studied using X-ray absorption spectroscopy,indicating higher conversion at a more discharged state.Ex-situ M?ssbauer spectroscopy strengthens the results for reversible reduction/oxidation of Fe.These results will be favorable to establish high-performance cathode materials with selective voltage window for SIBs.
基金supported by the National Natural Science Foundation of China(No.51976209)the Fundamental Research Funds for the Central Universities(No.WK2320000040)supported by the Youth Innovation Promotion Association CAS(No.Y201768)。
文摘Based on the synchrotron soft X-ray absorption spectroscopy experiments,the fundamental electronic structures of layered Li NixCoyMnzO_(2)(NCM)are investigated systematically and the data of transitionmetal(TM)L-and O K-edges spectra are collected.Distribution of Ni ions under different oxidation states is evaluated according to linear combination fit.It is found that the ratio of Ni^(4+)expands with the increase of Ni since it dominates in charge compensation during charging,and that the existence of Ni^(3+)is nearly negligible in delithiated NCM.The valence state of Co also strongly depends on Ni content,the perceptible position shift of Co L_(3)-edge absorption peak towards higher energy in Ni-rich material agrees well with the small voltage plateau at around 4.2 V.The stability of Mn is verified as no obvious spectral change with the Mn L-edge is observed.Moreover,as Ni content rises,the O 2p holes near the Femi level increases with higher oxidation state of Ni,indicating the enhanced hybridization of O 2p-TM 3 d.Delithiated NCMs with higher Ni content are prior to lose electron existing in highly hybridized Ni3 dO 2 p bands upon heating,which accounts for the pronounced O_(2)release in phase transitions and the deterioration in thermal stability.These detailed observation of the electronic structure evolution is one of the key ingredients to improving the electrochemical and thermal performance of NCM.
基金Supported by the Thailand Research Fund under Grant No TRG5880097
文摘The local structure of an alternative Pb(Zn1/3Nb2/3)O3-based perovskite ceramic is investigated. The 0.07BaTiO33-0.93Pb(Zn1/3Nb2/3)O3 ceramic is synthesized using a combination of Zn3Nb2O8 B-site precursor and BaTiO33 perovskite phase stabilizer. Then, x-ray absorption spectroscopy and density functional theory are employed to calculate the local structure configuration and formation energy of the prepared samples. Ba2+ is found to replace Pb2+ in AA-site with Zn2+ occupying BB-site in Pb(Zn1/3Nb2/3)O3, while in the neighboring structure, Ti4+4+ replaces Nb5+5+ in BB-site with Pb2+2+ occupying AA-site. With the substitution of BaTiO33 in Pb(Zn1/3Nb2/3)O3, the bond length between Zn2+ and Pb2+ is longer than that of the typical perovskite phase of Pb(Zn1/3Nb2/3)O3. This indicates the key role of BaTiO33 in decreasing the steric hindrance of Pb2+ lone pair, and the mutual interactions between Pb2+ lone pair and Zn2+ and the formation energy is seen to decrease. This finding of the formation energy and local structure configuration relationship can further extend a fundamental understanding of the role of BaTiO33 in stabilizing the perovskite phase in PbZn13Nb23O3-based materials, which in turn will lead to an improved preparation technique for desired electrical properties.
文摘Lead dissolved in water must be removed in order not to cause diseases, especially from high pH aqueous solution. Various oxides having high specific surface area are often applied to remove lead in water media. To improve removal ability for lead species, it is necessary to understand the adsorbed structure of lead species on oxides. At first, the adsorption behavior of lead from high pH solution in the presence of Ca<sup>2+</sup> and Na+ was compared. Lead and calcium species were adsorbed up to the monolayer, and the adsorption isotherm was analyzed as Langmuir-type adsorption. In the presence of Ca<sup>2+</sup>, the amount of removed lead was reduced. To clarify this influence of Ca<sup>2+</sup>, X-ray absorption spectroscopy was adopted. It was for the first time revealed that lead species at pH > 12 and pH < 10.5 differed, and that lead species adsorbed on various oxides had a similar structure.
文摘X-Ray Absorption Spectroscopy (XAS) on the carbon K edge of carbon nanostructures (nanotubes, nanofibers, nanowalls) is reported here. They are grown on plain SiO2 (8 nm thick)/Si(100) substrates by a Plasma and Hot Filaments-enhanced Catalytic Chemical Vapor Deposition (PE HF CCVD) process. The morphology and the nature of these carbon nanostructures are characterized by SEM, TEM and Raman spectroscopy. According to conditions of catalyst preparation and DC HF CCVD process, carbon nanotubes (CNTs), carbon nanofibers (CNFs), carbon nanowalls (CNWs), carbon nanoparticles (CNPs) with different orientation of the graphene plans or shells can be prepared. From the angular dependence of the incident light and geometrical morphology of the nanostructures, wide variations of the C K-edge intensity of the transitions to the empty π* and σ* states occur. A full lineshape analysis of the XAS spectra has been carried out using a home-made software, allowing estimating the relative proportion of π* and σ* transitions. A geometrical model of the angular dependence with the incidence angle of the light and the morphology of the carbon nanostructures is derived. With normalization to the HOPG (Highly Oriented Pyrolytic Graphite graphite) reference case, a degree of alignment can be extracted which is representative of the localized orientation of the graphitic carbon π bonds, accounting not only for the overall orientation, but also for local defects like impurities incorporation, structural defects ... This degree of alignment shows good agreement with SEM observations. Thus CNTs films display degrees of alignment around 50%, depending on the occurrence of defects in the course of the growth, whereas no special alignment can be detected with CNFs and CNPs, and a weak one (about 20%) is detected on CNWs.
基金financially supported by start-up funds from Oregon State UniversityPart of authors’ work using soft X-ray absorption spectroscopy was performed at beamline 6.3.1 of Advanced Light Source, which is an Office of Science User Facility operated for the U.S.DOE Office of Science by Lawrence Berkeley National Laboratory and supported by the DOE under Contract No. DEAC02-05CH11231
文摘Nanoscale electrocatalysts have exhibited promising activity and stability,improving the kinetics of numerous electrochemical reactions in renewable energy systems such as electrolyzers,fuel cells,and metal-air batteries.Due to the size effect,nano particles with extreme small size have high surface areas,complicated morphology,and various surface terminations,which make them different from their bulk phases and often undergo restructuring during the reactions.These restructured materials are hard to probe by conventional ex-situ characterizations,thus leaving the true reaction centers and/or active sites difficult to determine.Nowadays,in situ techniques,particularly X-ray absorption spectroscopy(XAS),have become an important tool to obtain oxidation states,electronic structure,and local bonding environments,which are critical to investigate the electrocatalysts under real reaction conditions.In this review,we go over the basic principles of XAS and highlight recent applications of in situ XAS in studies of nanoscale electrocatalysts.
基金supported by the National Basic Research Program of China(973 Program,2013CB933104)the National Natural Science Foundation of China(Nos.11275258 and 11135008)
文摘In situ quick X-ray absorption spectroscopy(QXAFS) at the Cu and Zn K-edge under operando conditions has been used to unravel the Cu/Zn interaction and identify possible active site of CuO/ZnO/Al_2O_3 catalyst for methanol synthesis. In this work, the catalyst, whose activity increases with the reaction temperature and pressure, was studied at calcined, reduced, and reacted conditions. TEM and EDX images for the calcined and reduced catalysts showed that copper was distributed uniformly at both conditions. TPR profile revealed two reduction peaks at 165 and 195 °C for copper species in the calcined catalyst. QXAFS results demonstrated that the calcined form consisted mainly of a mixed Cu O and Zn O, and it was progressively transformed into Cu metal particles and dispersed Zn O species as the reduction treatment. It was demonstrated that activation of the catalyst precursor occurred via a Cu^+intermediate, and the active catalyst predominantly consisted of metallic Cu and Zn O evenunder higher pressures. Structure of the active catalyst did not change with the temperature or pressure, indicating that the role of the Zn was mainly to improve Cu dispersion.This indicates the potential of QXAFS method in studying the structure evolutions of catalysts in methanol synthesis.
基金supported by the National Nature Science Foundation of China(Nos.11175244 and U1532259)
文摘Based on the high-energy-resolution fluorescence spectrometer on the BL14W1 beamline at Shanghai Synchrotron Radiation Facility,an in-situ high-energyresolution X-ray absorption spectroscopy technique,with an in-situ heating cell,was developed.The high-energyresolution fluorescence detection for X-ray absorption near-edge spectroscopy(HERFD-XANES) was tested in a UO_2 oxidation experiment to measure the UL_3-edge,with higher signal-to-noise ratio and higher-energy-resolution than conventional XANES.The technique has potential application for in-situ study of uranium-based materials.
基金One of us (Z.Y. Wu) was supported by 100-Talent Research Program of The Chinese Academy of Sciences. One of the authors (K. Ibrahim) is grateful to the National Natural Science Foundation of China (NSFC) for financial support (Grant No. 10074063) The
文摘As a potential application of titanium-oxide nanoparticles, it is extremely important to investigate a detailed picture of the surface and interior structural properties of nanocrystalline materials, such as rutile and anatase with diameters 7.0 and 4.5nm, respectively. X-ray absorption spectroscopy has been used to identify the local Ti environment and related electronic structure. We combine the experimental results at the Ti edge in both bulk and nano-crystals to determine the lattice distortion in terms of differently characteristic preedge features and the variation in the multiple-scattering region of X-ray absorption near-edge structure (XANES) spectra. The relationship between the transition peaks and the surface-to volume ratio is also discussed.
基金We would like to thank C.R.Natoli for iluminating discussion.Zi-Yu WU acknowledges the financial support of the 100-Talent Research Program of the Chinese Academy of Sciencesof the Outstanding Youth Fund(10125523)Key Important Nano-Research Project(90206032)of the National Natural Science Foundation of China.
文摘In this paper we present the state of the art of the theoretical background needed for analyzing X-ray absorption spectra in the whole energy range. The multiple-scattering (MS) theory is presented in detail with some applications on real systems. We also describe recent progress in performing geometrical fitting of the XANES (X-ray absorption near-edge structure) energy region and beyond using a full multiple-scattering approach.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.21503263,U1632269,21473235,and 11227902)
文摘In order to obtain an in-depth insight into the mechanism of charge compensation and capacity fading in LiCoO2, the evolution of electronic structure of LiCoO2 at different cutoff voltages and after different cycles are studied by soft x-ray absorption spectroscopy in total electron(TEY) and fluorescence(TFY) detection modes, which provide surface and bulk information, respectively. The spectra of Co L2,3-edge indicate that Co contributes to charge compensation below 4.4 V.Combining with the spectra of O K-edge, it manifests that only O contributes to electron compensation above 4.4 V with the formation of local O 2 p holes both on the surface and in the bulk, where the surficial O evolves more remarkably. The evolution of the O 2 p holes gives an explanation to the origin of O2^-or even O2. A comparison between the TEY and TFY of O K-edge spectra of LiCoO2 cycled in a range from 3 V to 4.6 V indicates both the structural change in the bulk and aggregation of lithium salts on the electrode surface are responsible for the capacity fading. However, the latter is found to play a more important role after many cycles.
基金supported in part by the National Key R&D Program of China(Nos.2020YFA0405800,2022YFA1504104,and 2022YFA1605400)the National Natural Science Foundation of China(Nos.12225508,12322515,U1932201,U2032113,and 22075264)+5 种基金the Youth Innovation Promotion Association of CAS(No.2022457)the Institute of Energy,Hefei Comprehensive National Science Center,University Synergy Innovation Program of Anhui Province(No.GXXT-2020-002)and the CAS Iterdisciplinary Innovation Team.We thank the Shanghai Synchrotron Radiation Facility(BL14W1,BL14B1,and SSRF)the Beijing Synchrotron Radiation Facility(1W1B,4B7A,and BSRF)the Hefei Synchrotron Radiation Facility(Infrared Spectroscopy and Microspectroscopy,MCD-A and MCD-B Soochow Beamline for Energy Materials at NSRL)and the USTC Center for Micro and Nanoscale Research and Fabrication for helps in characterizations.
文摘Breakthroughs in energy storage and conversion devices depend heavily on the exploration of low-cost and high-performance materials.Carbon-supported electrocatalysts with dimensional varieties have recently attracted significant attention due to their strong structural flexibility and easy accessibility.Nevertheless,understanding the connection between their electronic,structural properties,and catalytic performance must remain a top priority.Synchrotron radiation(SR)X-ray absorption spectroscopy(XAS)techniques,including hard XAS and soft XAS,are recognized as efficient and comprehensive platforms for probing the surface,interface,and bulk electronic structure of elements of interest in the materials community.In the past decade,the flourishing development of materials science and advanced characterization technologies have led to a deeper understanding at different temporal,longitudinal,and spatial scales.In this review,we briefly describe the concept of XAS techniques and summarize their recent progress in addressing scientific questions on carbon-supported electrocatalysts through the development of advanced instruments and experimental methods.We then discuss the remaining challenges and potential research directions in nextgeneration materials frontiers,and suggest challenges and perspectives for shedding light on the structure–activity relationship.
基金the ESRF for the beamtime allocation under proposals No.ES-184(ID26 beamline)and ES-703(BM20 beamline)study was supported by the Russian Science Foundation grant No.20-17-00184(XAS experiment,interpretation,geological application)Grant of the President of the Russian Federation for the state support of the leading scientific schools of the Russian Federation No.NSh-2394.2022.1.5(synthesis experiments,analysis of the synthesis products)support by the Russian Ministry of Science and Education under grant No 075-15-2022-1107(XAS experimental setup).
文摘Chalcopyrite and bornite are the main Au-bearing minerals at Cu porphyry deposits,volcanogenic massive sulfide(VMS)deposits,Cu-Ni deposits of the mafic magmatic complexes,and ores of submarine sulfide edifices.Bornite and intermediate solid solutions with wide compositional variations(bnss and iss–high-temperature chalcopyrite,correspondingly),which can scavenge economic concentrations of Au,appear in the Cu-Fe-S system at ore-forming conditions.However,the state of Au in bnss and iss is yet unknown.To solve this conundrum,we synthesized samples with net chemical composition of bnss and iss,studied them by in situ X–ray absorption spectroscopy(XAS),and used the experimental data to explain the Au distribution among natural ore-forming minerals.The sulfide samples were obtained at 495–700℃ in Au-saturated system by means of salt flux method.The bnss contained1.2–1.6 log units more Au than iss:up to 18 wt.%Au in bnss vs 0.4 wt.%Au in iss at 700C.An increase of temperature resulted in the sharp increase of Au concentration in both phases,1 log unit per 100℃ at f(S2)close to S_((l)) saturation.Analysis of Au L_(3)-edge spectra recorded at 25–675℃ revealed that at 25℃ Au exists mainly in the metallic state.At t>500℃ the spectral features of Audisappear,and “chemically bound”Au predominates.The Au form of occurrence in the iss field is interpreted as Au-bearing clusters with a stromeyerite-like(CuAgS)structure.Digenite Cu_(2–x)S and bnss contain Au in a mixture of stromeyeritelike and petrovskaite-like(Au_(0.8)Ag_(1.2)S)clusters.The chemical composition of both forms is close to CuAuS,where the nearest Au neighbors are two S atoms at R_(Au-S)=2.34–2.36Å.Results of the present study allow to determine the state of Au and its concentration in the main Cu-bearing minerals of sulfide ores as a function of the T-f(S_(2))-compositional parameters.Due to the sharp increase of the CuAuS clusters stability with increasing temperature,in high-temperature ores formed at t>350℃ Au enriches Cubearing minerals in comparison with Cu-free or Cu-deficient ones.As a result,in these ores native gold,being a product of decomposition of the Au-bearing clusters,is associated with Cu-rich minerals–chalcopyrite,bornite,digenite,chalcocite.
文摘This compendium review focuses on the spatial distribution of sensitivity to localized absorption changes in optically diffuse media,particularly for measurements relevant to near-infrared spectroscopy.The three temporal domains,continuous wave,frequency domain,and time domain,each obtain different optical data types whose changes may be related to effective homogeneous changes in the absorption coefficient.Sensitivity is the relationship between a localized perturbation and the recovered effective homogeneous absorption change.Therefore,spatial sensitivity maps representing the perturbation location can be generated for the numerous optical data types in the three temporal domains.The review first presents a history of the past 30 years of work investigating this sensitivity in optically diffuse media.These works are experimental and theoretical,presenting one-,two-,and three-dimensional sensitivity maps for different Near-Infrared Spectroscopy methods,domains,and data types.Following this history,we present a compendium of sensitivity maps organized by temporal domain and then data type.This compendium provides a valuable tool to compare the spatial sensitivity of various measurement methods and parameters in one document.Methods for one to generate these maps are provided in Appendix A,including the code.This historical review and comprehensive sensitivity map compendium provides a single source researchers may use to visualize,investigate,compare,and generate sensitivity to localized absorption change maps.
文摘The layout and characteristics of the hard X-ray spectroscopy beamline(BL11B)at the Shanghai synchrotron radiation facility are described herein.BL11B is a bending-magnet beamline dedicated to conventional and millisecond-scale quick-scanning X-ray absorption fine structures.It is equipped with a cylindrical collimating mirror,a double-crystal monochromator comprising Si(111)and Si(311),a channel-cut quick-scanning Si(111)monochromator,a toroidal focusing mirror,and a high harmonics rejection mirror.It can provide 5-30 keV of X-rays with a photon flux of~5×10^(11)photons/s and an energy resolution of~1.31×10^(-4)at 10 keV.The performance of the beamline can satisfy the demands of users in the fields of catalysis,materials,and environmental science.This paper presents an overview of the beamline design and a detailed description of its performance and capabilities.
基金the immense support provided by the National Research Foundation of Korea(NRF)Grant funded by the Korean Government(MSIT)(RS-2023–00210114)the National R&D Program through the National Research Foundation of Korea(NRF)funded by Ministry of Science and ICT(2021M3D1A2051636)。
文摘Hydrogen production by water reduction reactions has received considerable attention because hydrogen is considered a clean-energy carrier,key for a sustainable energy future.Computational methods have been widely used to study the reaction mechanism of the hydrogen evolution reaction(HER),but the calculation results need to be supported by experimental results and direct evidence to confirm the mechanistic insights.In this review,we discuss the fundamental principles of the in situ spectroscopic strategy and a theoretical model for a mechanistic understanding of the HER.In addition,we investigate recent studies by in situ Fourier transform infrared(FTIR),Raman spectroscopy,and X-ray absorption spectroscopy(XAS) and cover new findings that occur at the catalyst-electrolyte interface during HER.These spectroscopic strategies provide practical ways to elucidate catalyst phase,reaction intermediate,catalyst-electrolyte interface,intermediate binding energy,metal valency state,and coordination environment during HER.
基金This work was supported by the National Natural Science Foundation of China(NSFC,Nos.21801140,51532001,51667009,21771014,and 52002010)。
文摘Nickel based magnetic nanocrystals have been widely applied in magnetic and catalytic facilities.Tunable magnetic properties of nickel can be easily obtained via non-magnetic doping or phase transformation.However,phase transformation from face centered cubic(fcc)to hexagonal close packed(hcp)induced magnetism adjustment of Ni are always confused with nickel carbide(Ni_(3)C),due to the similar atomic structures of hcp-Ni and Ni3C.Here,we present series of Au@Ni-carbide magnetic materials achieved from the controlled carbonation of Au@Ni core-shell structures,whose magnetism is tunable by adjusting the amount of carbon in the Ni layer.Ex-situ hard X-ray absorption spectroscopy(XAS)at the metal K edge and soft XAS at both metal L edge and carbon K edge provide solid evidence for the carbonation process from fcc-Ni to Ni_(x)C,rather than phase transformation to hcp-Ni.Further investigation reveals that the magnetism of the hybrids is mainly contributed from the residual fcc-Ni.The result represents an accurate and effective way to distinguish hexagonal Ni_(3)C from hcp-Ni,and provides the pathway to control magnetism of Ni-based materials for applications.
基金financially supported by the National Key R&D Program of China(2016YFB0100100)the National Natural Science Foundation of China(Nos.21433013,U1832218)the support from China Scholarship Council
文摘The polysulfides shuttle effect represents a great challenge in achieving high capacity and long lifespan of lithium/sulfur(Li/S)cells.A comprehensive understanding of the shuttle-related sulfur speciation and diffusion process is vital for addressing this issue.Herein,we employed in situ/operando X-ray absorption spectroscopy(XAS)to trace the migration of polysulfides across the Li/S cells by precisely monitoring the sulfur chemical speciation at the cathodic electrolyte-separator and electrolyte-anode interfaces,respectively,in a real-time condition.After we adopted a shuttle-suppressing strategy by introducing an electrocatalytic layer of twinborn bismuth sulfide/bismuth oxide nanoclusters in a carbon matrix(BSOC),we found the Li/S cell showed greatly improved sulfur utilization and longer life span.The operando S Kedge XAS results revealed that the BSOC modification was bi-functional:trapping polysulfides and catalyzing conversion of sulfur species simultaneously.We elucidated that the polysulfide trapping-and-catalyzing effect of the BSOC electrocatalytic layer resulted in an effective lithium anode protection.Our results could offer potential stratagem for designing more advanced Li/S cells.
基金Project supported by the Shandong Provincial Natural Science Foundation,China(Grant Nos.ZR2022MA025 and ZR2020MA077).
文摘The possible configurations of pyrrole absorbed on a Si(100)surface have been investigated by x-ray photoelectron spectroscopy(XPS)and near-edge x-ray absorption fine structure(NEXAFS)spectra.The C-1s XPS and NEXAFS spectra of these adsorption configurations have been calculated by using the density functional theory(DFT)method and fullcore hole(FCH)approximation to investigate the relationship between the adsorption configurations and the spectra.The result shows that the XPS and NEXAFS spectra are structurally dependent on the configurations of pyrrole absorbed on the Si(100)surface.Compared with the XPS,the NEXAFS spectra are relatively sensitive to the adsorption configurations and can accurately identify them.The NEXAFS decomposition spectra produced by non-equivalent carbon atoms have also been calculated and show that the spectral features vary with the diverse types of carbon atoms and their structural environments.
文摘A method is described to determine the internal structure of electrocatalyst nanoparticles by in situ X-ray absorption spectroscopy (XAS). The nondestructive spec- troscopic technique typically utilizing synchrotron radiation as the source measures changes in the X-ray absorption coefficient as a function of energy. The bulk technique has found its use for materials characterization in all scientific areas, including nanomaterials. The analysis of the internal structure of nanoparticles reveals intera- tomic distances and coordination numbers for each element, and their values and mutual relations indicate whether the elements form a homogeneous or hetero- geneous mixture. The core-shell heterogeneous structure in which certain elements are predominantly located in the core, and others form the encapsulating shell is of particular importance in catalysis and electrocatalysis because it may reduce the amount of precious metals in nanoparticles by replacing the atoms in the core of nanoparticles with more abundant and cheaper alternatives. The examples of nanoparticle structures designed in the laboratory and the approach to model efficient catalysts through systematic analysis of XAS data in electrochemical systems consisting of two and three metals are also demonstrated.