HPMo-loaded Y-zeolites were prepared for the removal of trace olefins from aromatic hydrocarbons. The temperature of calcination and the proportion of phospho-molybdic acid in the catalyst were studied. The catalytic ...HPMo-loaded Y-zeolites were prepared for the removal of trace olefins from aromatic hydrocarbons. The temperature of calcination and the proportion of phospho-molybdic acid in the catalyst were studied. The catalytic activity for olefins removal and the service life of the catalyst were tested in a fixed bed microreactor. The results showed that the catalyst containing 3% phospho-molybdic acid, which was calcined at 550℃, demonstrated the best activity for olefins removal. The catalyst could be regenerated and could perform still very well. Catalyst characterization was performed by XRD and measured by pyridine-FTIR spectrometry. The test results indicated that the activity of the catalyst was related with the effect of acid concentration and acid strength. Besides, the deactivation of the catalyst was associated with the formation of coke deposits and the deactivated catalyst could recover its activity by oxidation with air under a proper temperature.展开更多
文摘HPMo-loaded Y-zeolites were prepared for the removal of trace olefins from aromatic hydrocarbons. The temperature of calcination and the proportion of phospho-molybdic acid in the catalyst were studied. The catalytic activity for olefins removal and the service life of the catalyst were tested in a fixed bed microreactor. The results showed that the catalyst containing 3% phospho-molybdic acid, which was calcined at 550℃, demonstrated the best activity for olefins removal. The catalyst could be regenerated and could perform still very well. Catalyst characterization was performed by XRD and measured by pyridine-FTIR spectrometry. The test results indicated that the activity of the catalyst was related with the effect of acid concentration and acid strength. Besides, the deactivation of the catalyst was associated with the formation of coke deposits and the deactivated catalyst could recover its activity by oxidation with air under a proper temperature.
