To find a novel counter electrode(CE)material for quantum dot-sensitized solar cells(QDSSCs),pompon-like NiCo_(2)O_(4) nanospheres are synthesized by a facile solvothermal and post-calcination method and we attempt to...To find a novel counter electrode(CE)material for quantum dot-sensitized solar cells(QDSSCs),pompon-like NiCo_(2)O_(4) nanospheres are synthesized by a facile solvothermal and post-calcination method and we attempt to apply it as a CE material for QDS SC.The catalytic performance of NiCo_(2)O_(4) counter electrode is investigated in detail through electrochemical impedance spectroscopy,Tafel test and cyclic voltammetry.The catalytic activity of NiCo_(2)O_(4) CE is superior to that of nanoflower-like Cu2S CE and traditional Cu2S/brass CE,which is mainly attributed to the large specific surface area,outstanding electrical conductivity of bimetallic oxides and the synergistic promotion effect of metals with different valence states.Under standard sunlight(air mass AM 1.5G 100 mW·cm^(-2)),the CdS/CdSe/ZnS-sensitized solar cell assembled with NiCo_(2)O_(4) CE achieved a photoelectric conversion efficiency of 5.55%,with a short current density of 22.49 mA·cm^(-2),an open circuit voltage of 0.574 V,and a fill factor of 0.43,which is slightly higher than the QDSSCs with nanoflower-like Cu_(2)S CE(4.75%)and traditional Cu_(2)S/brass CE(4.69%).This research provides ideas for discovering innovative and efficient CE materials for QDSSCs.展开更多
In this study, down-conversion fluorescent powder of Sr2ZnSi2O7：Eu-（2＋）,Dy-（3＋）, SrAl2O4：Eu-（2＋）,Dy-（3＋） and Y2O2S：Eu-（3＋）,Mg-（2＋）,Ti-（4＋）, which were the common three primary colors materials ...In this study, down-conversion fluorescent powder of Sr2ZnSi2O7：Eu-（2＋）,Dy-（3＋）, SrAl2O4：Eu-（2＋）,Dy-（3＋） and Y2O2S：Eu-（3＋）,Mg-（2＋）,Ti-（4＋）, which were the common three primary colors materials with long afterglow, were synthesized by high temperature solid state method. The blends of rare earth（RE） luminescent materials have been of interest to reinvest the luminescent characteristics of polyethylene terephtahalate（PET） luminous fiber. The scanning electron microscopy（SEM） and an inversion fluorescence microscope were used to characterize the surface morphology and the dispersion of inclusion. Through analysis of microcosmic morphology, three typical dispersions of luminescent particles were summarized. The X-ray diffraction indicated that the phase structure of fiber samples and crystal structure of luminescence materials kept complete after prilling and spinning. From the fluorescence spectra and CIE 1931 coordinates, it could be found that different combinations of luminous fibers were desired to obtain divers colors emission luminous fiber. And the fiber samples were a light sensation which could induct different excitation wavelengths and convert it down to different colors. The afterglow decay curve and its differential curve were summarized indicating the three decay stages. The decay curve and decay rate curve showed that the contents of Sr2ZnSi2O7：Eu-（2＋）,Dy-（3＋）, SrAl2O4：Eu-（2＋）,Dy-（3＋） and Y2O2S：Eu-（3＋）,Mg-（2＋）,Ti-（4＋） had obvious influence on the afterglow of fiber samples.展开更多
As a kind of non-destructive testing method,magnetic particle inspection is widely used in the fields of aviation and high-speed rail.The properties of magnetic fluorescent bifunctional composites,such as fluorescence...As a kind of non-destructive testing method,magnetic particle inspection is widely used in the fields of aviation and high-speed rail.The properties of magnetic fluorescent bifunctional composites,such as fluorescence intensity and magnetic properties,have increasing demands in magnetic particle inspection.Rare earth compounds offer potential as novel materials for fluorescent magnetic bifunctional composites due to their excellent optical properties and extremely narrow emission spectra.In this work,the rare earth fluorescent material Y_(2)O_(2)S:Eu^(3+) was synthesized by solid-state reaction method.Fe_(3)O_(4)nanoparticles prepared by hydrothermal method were uniformly coated on the Y_(2)O_(2)S:Eu^(3+) particles through physical adsorption of surfactants.The obtained Fe_(3)O_(4)@Y_(2)O_(2)S:Eu^(3+) exhibits dark red color under the ultraviolet light.In additio n,X-ray diffractio n,morphology,photoluminescence and hyste resis loop of Fe_(3)O_(4)@Y_(2)O_(2)S:Cu^(3+) were investigated.The luminescence mechanism of Y_(2)O_(2)S:Eu^(3+) is described in detail Fe_(3)O_(4)@Y_(2)O_(2)S:Cu^(3+) displays good paramagnetism and has a good controllability under a magnetic field.The magnetic particle inspection of Fe_(3)O_(4)@Y_(2)O_(2)S:Eu^(3+) was performed using a 4-pole electromagnet and a test piece shim.The magnetic fluorescent bifunctional composite presented in this work can be applied for non-destructive testing.展开更多
基金financially supported by the Natural Science Foundation of China(Grant Nos.22071018 and 21671035)。
文摘To find a novel counter electrode(CE)material for quantum dot-sensitized solar cells(QDSSCs),pompon-like NiCo_(2)O_(4) nanospheres are synthesized by a facile solvothermal and post-calcination method and we attempt to apply it as a CE material for QDS SC.The catalytic performance of NiCo_(2)O_(4) counter electrode is investigated in detail through electrochemical impedance spectroscopy,Tafel test and cyclic voltammetry.The catalytic activity of NiCo_(2)O_(4) CE is superior to that of nanoflower-like Cu2S CE and traditional Cu2S/brass CE,which is mainly attributed to the large specific surface area,outstanding electrical conductivity of bimetallic oxides and the synergistic promotion effect of metals with different valence states.Under standard sunlight(air mass AM 1.5G 100 mW·cm^(-2)),the CdS/CdSe/ZnS-sensitized solar cell assembled with NiCo_(2)O_(4) CE achieved a photoelectric conversion efficiency of 5.55%,with a short current density of 22.49 mA·cm^(-2),an open circuit voltage of 0.574 V,and a fill factor of 0.43,which is slightly higher than the QDSSCs with nanoflower-like Cu_(2)S CE(4.75%)and traditional Cu_(2)S/brass CE(4.69%).This research provides ideas for discovering innovative and efficient CE materials for QDSSCs.
基金Project supported by the National Natural Science Foundation of China(51503082)the Fundamental Research Funds for the Central Universities(JUSRP51505,JUSRP116020)Jiangsu Province Ordinary University Academic Degree Graduate Student Scientific Research Innovation Projects(KYLX16-0791)
文摘In this study, down-conversion fluorescent powder of Sr2ZnSi2O7：Eu-（2＋）,Dy-（3＋）, SrAl2O4：Eu-（2＋）,Dy-（3＋） and Y2O2S：Eu-（3＋）,Mg-（2＋）,Ti-（4＋）, which were the common three primary colors materials with long afterglow, were synthesized by high temperature solid state method. The blends of rare earth（RE） luminescent materials have been of interest to reinvest the luminescent characteristics of polyethylene terephtahalate（PET） luminous fiber. The scanning electron microscopy（SEM） and an inversion fluorescence microscope were used to characterize the surface morphology and the dispersion of inclusion. Through analysis of microcosmic morphology, three typical dispersions of luminescent particles were summarized. The X-ray diffraction indicated that the phase structure of fiber samples and crystal structure of luminescence materials kept complete after prilling and spinning. From the fluorescence spectra and CIE 1931 coordinates, it could be found that different combinations of luminous fibers were desired to obtain divers colors emission luminous fiber. And the fiber samples were a light sensation which could induct different excitation wavelengths and convert it down to different colors. The afterglow decay curve and its differential curve were summarized indicating the three decay stages. The decay curve and decay rate curve showed that the contents of Sr2ZnSi2O7：Eu-（2＋）,Dy-（3＋）, SrAl2O4：Eu-（2＋）,Dy-（3＋） and Y2O2S：Eu-（3＋）,Mg-（2＋）,Ti-（4＋） had obvious influence on the afterglow of fiber samples.
基金supported by the National Natural Science Foundation of China (51927810)。
文摘As a kind of non-destructive testing method,magnetic particle inspection is widely used in the fields of aviation and high-speed rail.The properties of magnetic fluorescent bifunctional composites,such as fluorescence intensity and magnetic properties,have increasing demands in magnetic particle inspection.Rare earth compounds offer potential as novel materials for fluorescent magnetic bifunctional composites due to their excellent optical properties and extremely narrow emission spectra.In this work,the rare earth fluorescent material Y_(2)O_(2)S:Eu^(3+) was synthesized by solid-state reaction method.Fe_(3)O_(4)nanoparticles prepared by hydrothermal method were uniformly coated on the Y_(2)O_(2)S:Eu^(3+) particles through physical adsorption of surfactants.The obtained Fe_(3)O_(4)@Y_(2)O_(2)S:Eu^(3+) exhibits dark red color under the ultraviolet light.In additio n,X-ray diffractio n,morphology,photoluminescence and hyste resis loop of Fe_(3)O_(4)@Y_(2)O_(2)S:Cu^(3+) were investigated.The luminescence mechanism of Y_(2)O_(2)S:Eu^(3+) is described in detail Fe_(3)O_(4)@Y_(2)O_(2)S:Cu^(3+) displays good paramagnetism and has a good controllability under a magnetic field.The magnetic particle inspection of Fe_(3)O_(4)@Y_(2)O_(2)S:Eu^(3+) was performed using a 4-pole electromagnet and a test piece shim.The magnetic fluorescent bifunctional composite presented in this work can be applied for non-destructive testing.
