Sulfur is one of the hazardous elements in coal. The concentrations of sulfur are relatively high in coal. The major forms of sulfur in coal are pyritic, organic and sulfate. Pyritic and organic sulfur generally accou...Sulfur is one of the hazardous elements in coal. The concentrations of sulfur are relatively high in coal. The major forms of sulfur in coal are pyritic, organic and sulfate. Pyritic and organic sulfur generally account for the bulk of sulfur in coal. Elemental sulfur also occurs in coal, but only in trace to minor amounts. When coals are burned, leached and washed, sulfur will be released in the form of sulfide and H\-2S, which then react with O\-2, water and other substances to change into vitriol, and in some places it may form acid rain. And they will impact water environment, acidify the soil and do great harm to plants and human health. In this paper, on the basis of the data from the Yanzhou mining district, the distribution and concentrations of sulfur are analyzed and the existing forms of sulfur are studied. The variation of sulfur and its impact on the environments also are described when coal is used.展开更多
In the process of combustion of coal organic and inorganic materials in it will undergo a complex variation. Part of them will become volatiles and, together with coal smoke, enter into atmosphere, some will remain in...In the process of combustion of coal organic and inorganic materials in it will undergo a complex variation. Part of them will become volatiles and, together with coal smoke, enter into atmosphere, some will remain in micro-particulates such as ash and dust and find their way into atmosphere in the form of solid particles, and the rest will be retained in ash and slag. Coal ashes are the residues of organic and inorganic substances in coal left after coal combustion and the composition of coal ashes is dependent on that of minerals and organic matter in coal. This paper deals with the chemical composition of coal ashes, the distribution of trace elements in them and their petrological characteristics, and also studies the relationship between the yield of coal ashes and the distribution of trace elements. In addition, a preliminary study is also undertaken on the factors that affect the chemical composition of coal ashes. As viewed from the analyses of coal ash samples collected from the Yanzhou mining district, it can be seen clearly that coal ashes from the region studied are composed chiefly of crystalline materials, glassy materials and uncombusted organic matter and the major chemical compositions are SiO 2, Al 2O 3, Fe 2O 3, and CaO, as well as minor amounts of SO 3, P 2O 5, Na 2O, K 2O and TiO 2. During the combustion of coal, its trace elements will be redistributed and most of them are enriched in coal ashes. At the same time, the concentrations of the trace elements in flying ash are much higher than those of bottom ash, i.e., with decreasing particle-size of coal ashes their concentrations will become higher and higher. So the contents of trace elements are negatively proportional to the particle-size of coal ashes. There has been found a positive correlation between the trace elements Th, V, Zn, Cu and Pb and the yield of coal ashes while a negative correlation between Cl and the yield of coal ashes.展开更多
文摘Sulfur is one of the hazardous elements in coal. The concentrations of sulfur are relatively high in coal. The major forms of sulfur in coal are pyritic, organic and sulfate. Pyritic and organic sulfur generally account for the bulk of sulfur in coal. Elemental sulfur also occurs in coal, but only in trace to minor amounts. When coals are burned, leached and washed, sulfur will be released in the form of sulfide and H\-2S, which then react with O\-2, water and other substances to change into vitriol, and in some places it may form acid rain. And they will impact water environment, acidify the soil and do great harm to plants and human health. In this paper, on the basis of the data from the Yanzhou mining district, the distribution and concentrations of sulfur are analyzed and the existing forms of sulfur are studied. The variation of sulfur and its impact on the environments also are described when coal is used.
文摘In the process of combustion of coal organic and inorganic materials in it will undergo a complex variation. Part of them will become volatiles and, together with coal smoke, enter into atmosphere, some will remain in micro-particulates such as ash and dust and find their way into atmosphere in the form of solid particles, and the rest will be retained in ash and slag. Coal ashes are the residues of organic and inorganic substances in coal left after coal combustion and the composition of coal ashes is dependent on that of minerals and organic matter in coal. This paper deals with the chemical composition of coal ashes, the distribution of trace elements in them and their petrological characteristics, and also studies the relationship between the yield of coal ashes and the distribution of trace elements. In addition, a preliminary study is also undertaken on the factors that affect the chemical composition of coal ashes. As viewed from the analyses of coal ash samples collected from the Yanzhou mining district, it can be seen clearly that coal ashes from the region studied are composed chiefly of crystalline materials, glassy materials and uncombusted organic matter and the major chemical compositions are SiO 2, Al 2O 3, Fe 2O 3, and CaO, as well as minor amounts of SO 3, P 2O 5, Na 2O, K 2O and TiO 2. During the combustion of coal, its trace elements will be redistributed and most of them are enriched in coal ashes. At the same time, the concentrations of the trace elements in flying ash are much higher than those of bottom ash, i.e., with decreasing particle-size of coal ashes their concentrations will become higher and higher. So the contents of trace elements are negatively proportional to the particle-size of coal ashes. There has been found a positive correlation between the trace elements Th, V, Zn, Cu and Pb and the yield of coal ashes while a negative correlation between Cl and the yield of coal ashes.
