The occurrence of metallic copper and redistribution of copper in the shocked Suizhou L6 chondrite

Copper possesses very strong chacophile properties,but under the conditions found in meteorites,its behavior is like that of siderophile elements.The Suizhou meteorite is a highly shocked L6 chondrite.Troilite and taenite are considered the main primary carrier of copper in this meteorite,and the post-shock thermal episode is considered the main reason that elemental Cu migrates from its original host phase and forms metallic grains.The Suizhou meteorite contains a few very thin shock melt veins.The occurrence and behavior of metallic copper in this meteorite were studied by optical microscopic examination,electron microprobe analyses,and high-resolution X-ray elemental intensity mapping.Our results show that metallic copper is abundant in the Suizhou chondritic rock.Metallic copper grains adjacent to small troilite grains inside FeNi metal are the most common occurrence,and those at the FeNi metal–troilite interface are the second most common case.The metallic copper grains occurring at the interface of FeNi metal/troililte and silicate are rather rare.Metallic copper grains are not observed within the Suizhou shock veins,Instead,Cu in elemental form is transferred through shock metamorphism into FeNi metal+troilite intergrowths.Four diff erent occurrence types of Cu in the FeNi metal+troilite intergrowths have been identifi ed:the concentrations of Cu in the FeNi+FeS intergrowths for four occurrence types are rather close,we estimate it might be lower than 1 wt%.

The discovery of TiO_(2)-Ⅱ,the α-PbO_(2)-structured high-pressure polymorph of rutile,in the Suizhou L6 chondrite

We report the discovery of TiO_(2)-Ⅱ in the unmelted rock of the shocked Suizhou L6 chondrite.Natural TiO_(2)-Ⅱ was previously found in ultrahigh-pressure metamorphic and mantle-derived rocks,terrestrial impact structures,and tektite.Our microscopic,Raman spectroscopic,electron microprobe and transmission electron microscopic investigations have revealed:(1) All observed TiO_(2)-Ⅱ grains are related with ilmenite and pyrophanite;(2) TiO_(2)-Ⅱ occurs as needle-and leaf-shaped inclusions in llmenite and patch-,tape-shaped body in pyrophanite;(3)The composition of TiO_(2)-Ⅱ is identical with that of its precursor rutile;(4) The Raman spectrum of TiO_(2)-Ⅱ is in good agreement with that of natural and synthesized α-PbO_(2)-type TiO_(2);(5) TiO_(2)-Ⅱ occurs mainly in the form of well-ordered nano-domains and small mis-orientation among the domains can be observed.(6) All electron diffraction reflections from TiO_(2)-Ⅱ can be indexed to α-PbO_(2)structure in space group Pbcn with lattice parameters of a=4.481 ?,b=5.578 A and c=4.921 A;(7) The exsolution inclusions of rutile from host ilmenite are mostly connected with an alternation process along the lamellar twinning plane of ilmenite induced by shockinduced high pressure and high temperature;(8) The P-T regime of 20-25 GPa and 1000 ℃ estimated for the Suizhou unmelted rock is suitable for phase transition of rutile into TiO_(2)-Ⅱ phase.

The breakdown of diopside to(Ca,Mg)SiO_(3)perovskite–(Mg,Ca,Fe)SiO_(3)glass–(Mg,Ca)SiO_(3)glass–(Mg,Ca)SiO_(3)majorite in a melt vein the Suizhou L6 chondrite

The Suizhou meteorite is a heavily shocked and melted vein-containing L6 chondrite.It contains a minor amount of diopside with a(Ca_(0.419)Mg_(0.466)Fe_(0.088))SiO_(3)composition,and a shock-metamorphosed diopside grain associated with ringwoodite and lingunite was found in a melt vein of this meteorite.Our electron microprobe,transmission electron microscopic and Raman spectroscopic analyses revealed four silicate phases with different compositions and structures inside this shock-metamorphosed diopside grain,termed phase A,B,C and D in this paper.Phase A is identified as orthorhombic(Ca_(0.663)-Mg_(0.314))SiO_(3)-perovskite which is closely associated with phase B,the vitrified(Mg_(0.642)Ca_(0.290)Fe_(0.098))SiO_(3)perovskite.Phase D is assigned to be(Mg_(0.578)Ca_(0.414))SiO_(3)majorite which is associated with phase C,the vetrified Carich Mg-perovskite with a(Mg_(0.853)Ca_(0.167))SiO_(3)composition.Based on high-pressure and high-temperature experiments,the diopside grain in the melt vein of the Suizhou meteorite would have experienced a P–T regime of 20–24GPa and 1800–>2000℃.Such P–T conditions are high enough for the decomposition of the diopside and the formation of four different silicate phases.The orthorhombic(Ca_(0.663)Mg_(0.314))SiO_(3)perovskite found in the Suizhou L6 chondrite might be considered as the third lower-mantle silicate mineral after bridgmanite and davemaoite after the detailed analyses of its crystal structure and physical properties being completed.

Redistribution of Trace Elements During Shock-inducd Melting and Phase Tranzition of Minerals in the Suizhou l6 Chondrite

The Suizhou meteorite is an L6 chondrite. This meteorite is consisted of olivine, low-Ca pyroxene, plagioclase, FeNi metal, troilite, whitlockite, chlorapatite, chromite and ilmenite. Olivine and pyroxene grains display shock-induced mosaic texture, and most plagioclase grains were melted and transformed to maskelynite. This meteorite contains a few very thin shock-produced melt veins ranging from 20 to 100 μm in width. They are chondritic in composition and contain abundant high-pressure minerals in two assemblages. One is the coarse-grained assemblage of ringwoodite, majorite, lingunite with minor amount of tuite, xieite, the CF-phase, akimotoite and amorphized perovskite, and the fine-grained assemblage (the melt vein matrix) composed of majorite-pyrope garnet, magnesiowüstite. FeNi metal and troilite in the Suizhou shock veins were molten and occur as small intergrowth grains or veinlets filling the interstices of garnet crystals or cracks in the vein matrix. It was revealed that olivine, pyroxene and plagioclase in the Suizhou shock veins have transformed in solid state to their high-pressure polymorphs ringwoodite, majorite, and lingunite, respectively, without change in their chemical compositions.

Transmission electron microscopic study of the fine-grained vein matrix in the Suizhou L6 meteorite

The mineralogy of shock vein matrix in the Suizhou meteorite has been investigated by optical and transmission electron microscopy. It was revealed that the vein matrix is composed of majorite-pyrope garnet, mag- aesiowtistite, and ringwoodite, with FeNi-FeS inter- growths. The observation and character of ring-like selected electron diffraction （SAED） patterns indicate that Lhe idiomorphic garnet crystals in the vein matrix have different orientations. The polycrystalline nature of magnesiowtistite is also confirmed by a ring-like SAED pattern. Both garnet and magnesiowtistite crystals showed sharp Jiffraction spots, signifying the good crystallinity of these ：wo minerals. The SAED pattern of cryptocrystalline 5ngwoodite shows only diffuse concentric diffraction tings. FeNi metal and troilite （FeS）, which were molten during the shock event, occur in the matrix as fine eutectic FeNi-FeS intergrowths filling the interstices between garaet and magnesiowiistite grains. Based on the phase dia- gram of the Allende chondrite and the results of this TEM study, it is inferred that majorite-pyrope garnet first crystallized from the Suizhou chondritic melt at 22-26 GPa, Followed by crystallization of magnesiowtistite at 20-24 GPa, and then ringwoodite at 18-20 GPa. The eutectic intergrowths of FeNi-metal and troilite are proposed to have crystallized during meteorite cooling and solidified at the last stage of vein formation.

襄阳都市圈旅游一体化发展路径研究

中国式现代化和新发展格局对区域旅游一体化提出了新的要求。旅游一体化是城市一体化的重要组成部分,襄阳都市圈旅游一体化发展问题要立足汉江流域、南襄盆地、中西部新通道的大格局来分析,最为关键的就是“襄十随神”城市群旅游一体化。襄阳都市圈各城市地域相接、交通相连、文脉相通,共饮一江汉水,旅游一体化基础良好。围绕五大主题游线,重点做好增加旅游一体化合作收益、拓展襄阳旅游中心城市功能、谋划城市群旅游新格局、丰富城市群旅游形象和业态等方面的工作。

Synchrotron radiation X-ray diffraction in situ study of fine-grained minerals in shock veins of Suizhou meteorite

The synchrotron radiation X-ray diffraction technique developed for in situ study ahigh pressure and temperature has also been used to investigate microscopic mineral inclusionsin ultrahigh-pressure metamorphic rocks and deep-mantle samples. Present study added twomore examples of successful utilization of synchrotron radiation X-ray diffraction technique for insitu investigations of fine-grained (0.5―30 μm in size) minerals in very thin shock melt veins othe Suizhou meteorite: ( i ) X-ray diffraction measurement of extremely small-sized vein matrixminerals, and (ii) identification of the micron-sized new mineral tuite embedded in the vein matrixIt has been revealed that the fine-grained vein matrix consists of well crystallized garnet, kamacite and troilite, and the powder diffraction pattern consisting of 17 lines with d-values, intensities( I ), relative intensities (I/Io) and Miller indices, as well as the cell parameters for the new mineratuite has also been successfully obtained. The result of present investigations has enriched thecontent of dynamic high-pressure mineralogy and that of Earth’s mantle geochemistry.

湖北随州叶家山墓地M126出土铜器科学分析

本文通过科技检测手段对叶家山M126出土铜器进行了分析。结果表明,经分析的10件器物中,有7件为铅锡青铜制成,包括6件容器和1件兵器,有3件锡青铜,全部为容器。这批铜器制作采用块范铸造工艺。祖己爵M126:16为一件商代器物。其他器物分属A类和C类普通铅的范畴。其他族属铭文铜器中,一部分器物使用了与曾国铜器相同或相似的矿料,另一部分器物与曾国铜器使用的矿料不同,体现了西周早中期青铜物料流通信息,部分以器物组的形式流通。

NaAlSi_3O_8-hollandite and other high-pressure minerals in the shock melt veins of the Suizhou meteorite

The Suizhou L6 chondrite contains a few very thin shock melt veins of 0.02-0.09 mm in width. In spite of small width of the veins, shock-induced high-pressure phases, such as coarse-grained NaAlSi3O8-hollandite, ringwoodite, majorite and fine-grained matrix majorite-pyropess have been discovered in these veins. NaAlSi3O8-hollandite, the high-pressure phase of plagioclase, in Suizhou shock veins occurs as a single phase mineral, no silicate glassy phase, such as albitic glass, was incorporated with it. The presence of above-mentioned high-pressure phases constrains the high pressure (up to 23-24 GPa) and high temperature (up to 1900-2000℃) regime in Suizhou shock veins, and indicates that the duration of high-pressure regime in the veins should be long enough (a few seconds) for phase transformation and crystallization of minerals under pressure. The discovery of the first natural single-phase crystalline NaAlSi3O8- holland-ite in Suizhou meteorite is of important significance in understanding the Earth’

Shock-produced akimotoite in the Suizhou L6 chondrite

Shock-produced akimotoite was identified in the Suizhou chondritic meteorite, which occurs in two kinds of occurrence. The first is the irregular layers of akimotoite up to 4 ?m in thickness occurring in fractures and cracks of low-Ca pyroxene enclosed in the shock veins. The second is the zonal polycrystalline aggregates of akimotoite in shocked pyroxene grains close to the shock vein, where akimotoite occurs in a zonal area in between pyroxene and Mg Si O3-glass as irregular small clumps up to 5 ?m in size. This investigation suggests a solid-state transformation mechanism of pyroxene to akimotoite, and that akimotoite should have nucleated and grew in the area with abundant defects caused by shock deformation because the defect significantly enhances the solid-state reactivity and the kinetics of nucleation of high-pressure phase. The spatial relationship among the composed grains of pyroxene, akimotoite and Mg Si O3-glass(possibly vitrified perovskite) demonstrates a temperature gradient from the vein wall to the unmelted chondritic meteorite.

Petrogenesis and Tectonic Implications of Peralkaline A-Type Granites and Syenites from the Suizhou-Zaoyang Region,Central China

In this study, we present systematic petrological, geochemical, LA-ICP-MS zircon U-Pb ages and Nd isotopic data for the A-type granites and syenites from Suizhou-Zaoyang region. The results show that the peralkaline A-type granites and syenites were episodically emplaced in Suizhou-Zaoyang region between 450±3 and 441±7 Ma which corresponds to Late Ordovician and Early Silurian periods, respectively. Petrologically, the syenite-peralkaline granite association comprises of nephefine normative-syenite and alkaline granite in Guanzishan and quartz normative syenite and alkafine granite in Huangyangshan. The syenite-granite associations are ferroan to alkali in composition. They depict characteristics of typical OIB （oceanic island basalts） derived A-type granites in multi-elements primitive normalized diagram and Ybffa vs. Y/Nb as well as Ce/Nb vs. Y/Nb binary plots. Significant depletion in Ba, Sr, P, Ti and Eu indicates fractionation of feldspars, biotite, amphiboles and Ti-rich augite. The values of eNd（t） in Guanzishan nepheline syenite and alkaline granite are ＋1.81 and ＋2.26, respectively and the calculated two-stage model age for these rocks are 1 040 and 1 003 Ma, respectively. On the other hand, the Huangyangshan alkaline granite has eNd（t） values ranging from ＋2.61 to ＋3.46 and a relatively younger two-stage Nd model age values ranging from 906 to 975 Ma, respectively. Based on these data, we inferred that the Guanzishan nepheline syenites and granites were formed from fractional crystallization of OIB-like basic magmas derived from upweliing of metasomatized lithospheric mantle. The Huangyangshan quartz syenite and granite on the other hand, were formed from similar magmas through fractional crystallization with low input from the ancient crustal rocks. Typically, the rocks exhibit Al-type granite affinity and classified as within plate granites associated with the Ordovician crustal extension and the Silurian rifting.

FISSION-TRACK AGE OF SUIZHOU METEORITE

An average ancient track density of(7.6±1.1)×10~3/cm^2 has been obtained for pyroxene in Suizhou meteorite based on ancient and neutron-induced fission-track density measurements. The result is consistent with the ancient track density of 8.4×10~3/cm^2

基于测雨雷达与地面雨量站的山洪模拟及灾害预警时效分析

传统暴雨山洪预警主要依靠地面雨量站降雨数据,易出现虚警漏警或难以满足预警时效的情况。流域面雨量实时监测和前移山洪预警响应时间是满足山洪灾害防御目标的重要技术手段,测雨雷达技术的应用也为山洪灾害防治提供了新的预警思路。以湖北柳林镇2021年8月12日暴雨山洪事件为例,采用模块化分布式水文模型(MDHM)模拟山洪过程并进行预警分析,对比基于测雨雷达、地面雨量站降雨输入条件下的灾害预警时效,评估两种降雨数据源下山洪预警的有效性和可靠性,结果表明测雨雷达预报降雨结合水位陡涨率预警法能显著提高预警效果,可为暴雨山洪防灾减灾提供技术支撑。

西周鄂国史二题

从西周鄂国史来看,疑尊、疑卣二器铭文“于卜噩(鄂)侯,于盩(盭)城”句,说明西周早期将鄂国封在随州附近的盩(即“盭”“厉”“赖”)。这可与随州安居的西周早期鄂国考古发现相印证,表明西周早中期鄂在随州地区。而《史记·楚世家》所记西周晚期楚熊渠“乃兴兵伐庸、杨粤,至于鄂”的路线,可理解成“乃兴兵伐庸、杨,粤(越)至于鄂”,即其历程是从庸(湖北竹山)经杨(唐,随州西北),再到鄂(随州),行军路线一路东进。

A SURVEY OF SUIZHOU METEORITE SHOWER

A chondrite shower occurred on April 15, 1986 in the vicinity of Dayianpo Village, Suizhou City, Hubei Province. It is the second large scale meteorite shower following the Jilin Meteorite Shower.

Occurrence andmineral chemistry of chromite and xieite in the Suizhou L6 chondrite

The occurrence and mineral chemistry of chromite and its high-pressure phase xieite in the Suizhou meteorite were studied by different modem micromineralogical techniques. Three types of occurrences for chromite were observed in the Suizhou L6 chondrite： coarse chromite grains, cluster of chromite fragments in molten plagioclase, and exsolution lamellar chromite in oli- vine. All the chromite grains of the first two types are remarkably similar in chemical compositions, but the composition of exsolution chromite is inhomogeneous and variable in A1203 content. Xieite is a post-spinel CT-phase of chromite firstly found in the Suizhou meteorite. Three types of occurrences of xieite have also been revealed in this meteorite： coarse xieite grains, complex three-zone-grains consisting of the inner xieite, the intermediate lamellae-like CF-phase and the outer chromite phase, and two-phase-grains consisting of xieite and one of the high-pressure silicate minerals lingunite, ringwoodite or majorite. The curved boundary between xieite and the silicate half in two-phase grains is indicative of some partial or even full melting of the silicate phase. EPMA and EDS results show that the compositions of xieite inside/contacting the shock veins are also identical to that of chromite outside the veins. However, some element diffusion appeared in between the xieite and the silicate half in the two-phase grains, namely, some of Al^3＋ from lingunite, or Fe^2＋ from ringwoodite migrated to xieite, and some of Cr^3＋ migrated from xieite to lingunite or ringwoodite. Majorite in two-phase grains shows remarkable decrease of SiO2 and MgO, and notable increase of Al2O3 and CaO, indicating that its host mineral pyroxene was fully molten and mixed with the surrounding silicate melt of the vein matrix. The complexity in mineral chemistry of these two-phase grains in shock veins can be explained by the much higher shock peak temperature in shock veins （1800-2000℃） than in unmelted main body （-1000℃）, and by the much lower density of the silicate minerals （2.6-3.3 g/cm3） than that of chromite （4.43 g/cm^3）. Being a refractory and a rela-tively high-impedance material, chromite is chemically more stable and easier to reflect shock wave into the silicate half causing the partial or even full melting of silicate phases, upon which some diffusion of elements between the two phases them-selves, or even mixing of molten pyroxene and the surrounding silicate melt.

旅游发展、交通基础设施与农民增收的动态关联研究——以湖北省“襄十随神”区域为例

探索旅游发展、交通基础设施与农民增收三者之间的动态关系,对于推进区域协同发展具有重要的启示意义。文章基于湖北省“襄十随神”四市(区)2004—2021年面板数据,运用向量自回归模型,讨论了四地旅游发展、交通基础设施和农民增收三者之间的动态关系。结果表明:“襄十随神”四市(区)旅游发展、交通基础设施与农民增收之间存在长期均衡关系;旅游发展明显促进了交通基础设施的完善,旅游发展与交通基础设置完善对农民增收具有较强的推动作用;农民增收对旅游发展和交通基础设施完善的影响较弱。在实证分析和考虑地区差异与关联性的基础上,提出了协调、共生、一体化的发展建议,以期为“襄十随神”区域协同发展提供一定借鉴。

试论随州吴山铜钼多金属矿地质特征及找矿方向

吴山铜钼多金属矿主要分布在桐柏-大别山钼多金属成矿带西南部的区段上,区内有着较为复杂的地层产出,并有着频繁而又强烈的构造岩浆活动,成矿地质条件优越。下文中主要对该矿成矿地质特征进行详细分析和阐述,在此基础上,探究分析该矿矿床成因,并对找矿标志进行总结指出今后的找矿方向,希望能对区内地质找矿工作提供一些指示作用。

“襄十随神”区域经济特征及发展战略调整——以十堰市为例

“襄十随神”作为湖北省发展战略的一个重要组成部分,是“一主引领、两翼驱动”中的重要一“翼”。随着国家新的经济发展格局的调整,湖北省及“襄十随神”各市县均对其发展战略进行了重大调整。在国家将湖北建成“建设全国构建新发展格局先行区”的大战略下,“襄十随神”各地须适当优化发展战略和规划,实行错位发展。十堰市主要应突破性发展“一主四优多支撑”产业。

随州南站屋盖结构设计和分析

随州南站站房采用24个伞状单元体呈现银杏叶的造型,结构设计时以H形截面弦杆形成的异形钢桁架作为主受力骨架,结合分叉圆钢管、吊杆、水平圆管桁架等形成完整单元体结构。单元体结构与顶部波浪形正交钢梁体系连接,形成了站房屋盖整体结构。屋盖结构体系复杂,单元体根部尺寸收缩,采用屈曲分析得到了结构的屈曲模态及屈曲因子,第一阶屈曲模态位于伞状单元体结构根部位置,并进一步对屋盖结构进行了荷载-位移全过程分析,以保证屋盖结构的整体承载力。设计时在单元体结构中采用了十字工形组合钢柱及鼓形节点,利用有限元分析和试验的手段对此两种特殊结构构造进行了验证,以确保关键部位的承载力。单元体结构外表皮采用张拉索-膜结构形成的金黄色ETFE膜完整呈现了建筑效果。