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Petrogenesis and Physicochemical Conditions of Fertile Porphyry in Non-arc Porphyry Mineralization:A Case from Habo Porphyry Cu-Mo Deposits,SW China
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作者 ZHANG Aiping ZHENG Yuanchuan +4 位作者 SHEN Yang Qi Qunjia WANG Zixuan WU Changda WANG Lu 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2023年第2期469-485,共17页
The Habo deposit is a typical porphyry Cu-Mo deposit in the Ailaoshan–Red River metallogenic belt.Ore minerals in the Habo deposit typically occur as veins in the monzonite porphyry.Zircon U-Pb dating suggests that t... The Habo deposit is a typical porphyry Cu-Mo deposit in the Ailaoshan–Red River metallogenic belt.Ore minerals in the Habo deposit typically occur as veins in the monzonite porphyry.Zircon U-Pb dating suggests that the monzonite porphyry formed at 35.07±0.38 Ma.The monzonite porphyry is characterized by high SiO_(2),Al_(2)O_(3),K_(2)O and Na_(2)O contents,with A/CNK ratios ranging from 0.97 to 1.02.All samples exhibit fractionated REE patterns,characterized by high(La/Yb)N ratios(9.4–13.6,average of 11.2).They show adakite-like geochemical features,high Sr concentrations(627–751 ppm,average of 700 ppm),low Y concentrations(15.13–16.86 ppm,average of 15.81 ppm)and high Sr/Y values(39.5–47.4,average of 44.3).These samples have high initial^(87)Sr/^(86)Sr ratios(0.7074–0.7076)and negativeεNd(t)values(-5.1 to-3.7),whereas the zirconεHf(t)values range from-2.2 to+0.4,suggesting that the monzonite porphyry was derived from the partial melting of a thickened juvenile lower crust.The oxygen fugacity,calculated on the basis of the chemical composition of the amphiboles,shows?NNO values ranging from+1.65 to+2.16(average of 1.94)and lg(fO_(2))ranging from-12.72 to-11.99(average of-12.25),indicating that the monzonite porphyry has high oxygen fugacity.Zircons have high Ce^(4+)/Ce^(3+)ratios(29.29–164.24,average of 84.92),with high?FMQ values ranging from+0.50 to+1.51(average of 0.87)and high lg(fO_(2))values ranging from-14.72 to-12.85(average of-14.07),which also indicates that the oxygen fugacity of the magma was high.The dissolved water content of the Habo monzonite porphyry is 9.5–11.5 wt%,according to the geochemical characteristics,zircon-saturation thermometry(692–794°C)and the mineral phases(amphibole,no plagioclase)in the deep magma chamber.Combined with previous studies,we propose that the high oxygen fugacity and high water content of magma played key roles in controlling the formation of the Habo and other Cu-Mo-Au deposits in the Ailaoshan–Red River metallogenic belt. 展开更多
关键词 magmatic oxidation state water content monzonite porphyry Habo porphyry cu-mo deposit Ailaoshan-Red River metallogenic belt
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Geochemical Characteristics and Significance of Major Elements, Trace Elements and REE in Mineralized Altered Rocks of Large-Scale Tsagaan Suvarga Cu-Mo Porphyry Deposit in Mongolia 被引量:3
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作者 方维萱 杨社锋 +2 位作者 刘正桃 韦星林 张宝琛 《Journal of Rare Earths》 SCIE EI CAS CSCD 2007年第6期759-769,共11页
The alteration types of the large-scale Tsagaan Suvarga Cu-Mo porphyry deposit mostly comprise stockwork silicification, argillization, quartz-sericite alteration, K-silicate alteration, and propylitization. The miner... The alteration types of the large-scale Tsagaan Suvarga Cu-Mo porphyry deposit mostly comprise stockwork silicification, argillization, quartz-sericite alteration, K-silicate alteration, and propylitization. The mineralized and altered zones from hydrothermal metallogenic center to the outside successively are Cu-bearing stockwork silicification zone, Cu-beating argillized zone, Cu-Mo-bearing quartz-sericite alteration zone, Cu-Mo-bearing K-silicate alteration zone, and pro- pylitization zone. The K-silicate alteration occurred in the early phase, quartz-sericite alteration in the medium phase, and argillization and carbonatization (calcite) in the later phase. Ore-bearing-altered rocks are significantly controlled by the structure and fissure zones of different scales, and NE- and NW-trending fissure zones could probably be the migration pathways of the porphyry hydrothermal system. Results in this study indicated that the less the concentrations of REE, LREE, and HREE and the more the extensive fractionation between LREE and HREE, the closer it is to the center circulatory hydrothermal ore-forming and the more extensive silicification. The exponential relationship between the fractionation of LREE and HREE and the intensity of silicification and K-silicate alteration was found in the Cu-Mo deposit studied. The negative Eu anomaly, normal Eu, positive Eu anomaly and obviously positive Eu anomaly are coincident with the enhancement of Na2O and K2O concentrations gradually, which indicated that Eu anomaly would be significantly controlled by the alkaline metasomatism of the circulatory hydrothermal ore-forming system. Therefore, such characteristics as the positive Eu anomaly, the obvious fractionation between LREE and HREE and their related special alteration lithofacies are suggested to be metallogenic prognostic and exploration indications for Tsagaan Suvarga-style porphyry Cu-Mo deposits in Mongolia and China. 展开更多
关键词 mongolia tsagaan suvarga porphyry cu-mo deposit wall rock alteration fractionation mode positive Eu anomaly rare earths
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Geochronological Constraints on the Haftcheshmeh Porphyry Cu-Mo-Au Ore Deposit, Central Qaradagh Batholith, Arasbaran Metallogenic Belt, Northwest Iran
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作者 Shohreh HASSANPOUR Mohsen MOAZZEN 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2017年第6期2109-2125,共17页
The Haftcheshmeh porphyry Cu-Mo-Au deposit in the Arasbaran metallogenic belt (AMB) of NW Iran contains more than 185 Mt of ore, with a grade ranging from 0.3% to 0.4%. It is hosted within a porphyritic diorite to g... The Haftcheshmeh porphyry Cu-Mo-Au deposit in the Arasbaran metallogenic belt (AMB) of NW Iran contains more than 185 Mt of ore, with a grade ranging from 0.3% to 0.4%. It is hosted within a porphyritic diorite to granodiorite intruded into an older gabbro - diorite intrusion. 40Ar/39Ar analyses of primary magmatic hornblende from the granodiorite porphyry and gabbro - diorite show plateau ages of 26.41 ± 0.59 Ma, with an inverse isochron age of 25.9 ± 1.0 Ma and a plateau age of 27.47 ± 0.17 Ma, with an inverse isochron age of 27.48 ± 0.35 Ma for these two rock types, respectively. Comparing these new age data with those from the nearby Sungun (20.69 ± 0.35 Ma) and Kighal porphyry deposits defines a northwest-southeast Cu-Mo-Au mineralization zone extending for 20 km over the time span of-27 to 20 Ma. Geochemically, Haftcheshmeh rocks are calc-alkaline with high potassium affinities with tectonic setting in relation to volcanic arc setting. Large ion lithophile elements (LILE) such as Th, U and K show enrichment on a primitive mantle normalized diagram (specially Pb), and are depleted in high field strength elements (HFSE) such as Ti and Nb, pointing to a mantle magma source contamination with crustal materials by subducted oceanic crust. 展开更多
关键词 40Ar/39Ar dating Haftcheshmeh porphyry cu-mo deposit Arasbaran Metallogenic Belt Northwest Iran
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Re-Os geochronology of Cu and W-Mo deposits in the Balkhash metallogenic belt,Kazakhstan and its geological significance 被引量:10
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作者 Xuanhua Chen Wenjun Qu +6 位作者 Shuqin Han Seitmuratova Eleonora Nong Yang Zhengle Chen Fagang Zeng Andao Du Zhihong Wang 《Geoscience Frontiers》 SCIE CAS 2010年第1期115-124,共10页
The Central Asian metallogenic domain (CAMD) is a multi-core metallogenic system controlled by boundary strike-slip fault systems. The Balkhash metallogenic belt in Kazakhstan, in which occur many large and super-la... The Central Asian metallogenic domain (CAMD) is a multi-core metallogenic system controlled by boundary strike-slip fault systems. The Balkhash metallogenic belt in Kazakhstan, in which occur many large and super-large porphyritic Cu--Mo deposits and some quartz vein- and greisen-type W-Mo deposits, is a well-known porphyritic Cu--Mo metallogenic belt in the CAMD. In this paper 11 molybdenite samples from the western segment of the Balkhash metallogenic belt are selected for Re--Os compositional analyses and Re--Os isotopic dating. Molybdenites from the Borly porphyry Cu deposit and the three quartz vein-greisen W--Mo deposits--East Kounrad, Akshatau and Zhanet--all have relatively high Re contents (2712--2772 μg/g for Borly and 2.267--31.50 μg/g for the other three W-Mo deposits), and lower common Os contents (0.670-2.696 ng/g for Borly and 0.0051--0.056 ng/g for the other three). The molybdenites from the Borly porphyry Cu--Mo deposit and the East Kounrad, Zhanet, and Akshatau quartz vein- and greisen-type W-Mo deposits give average model Re--Os ages of 315.9 Ma, 298.0 Ma, 295.0 Ma, and 289.3 Ma respectively. Meanwhile, molybde- nites from the East Kounrad, Zhanet, and Akshatan W-Mo deposits give a Re--Os isochron age of 297.9 Ma, with an MSWD value of 0.97. Re--Os dating of the molybdenites indicates that Cu-W-Mo metallogenesis in the western Balkhash metallogeuic belt occurred during Late Carboniferous to Early Permian (315.9--289.3 Ma), while the porphyry Cu--Mo deposits formed at ~316 Ma, and the quartz vein-greisen W--Mo deposits formed at ~298 Ma. The Re--Os model and isochron ages thus suggest that Late Carboniferous porphyry granitoid and pegmatite magmatism took place during the late Hercy- nian movement. Compared to the Junggar-East Tianshan porphyry Cu metallogenic belt in northwestern China, the formation of the Cu-Mo metallogenesis in the Balkhash rnetallogenic belt occurred between that of the Tuwu-Yandong in East Tianshan and the Baogutu porphyry Cu deposits in West Junggar. Collectively, the large-scale Late Carboniferous porphyry Cu-Mo metallogenesis in the Central Asian metallogenic domain is related to Hercynian tectono-magmatic activities. 展开更多
关键词 Re-Os geochronology Metallogenic age Porphyry cu-mo deposit Greisen W--Mo deposits Balkhash metallogenicbelt Kazakhstan
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Geology,Geochemistry and Zircon U-Pb Geochronology of Porphyries in the Dabate Mo-Cu Deposit,Western Tianshan,China:Petrogenesis and Tectonic Implications 被引量:7
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作者 DUAN Shigang ZHANG Zuoheng +1 位作者 WANG Dachuan LI Fengming 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2017年第2期530-544,共15页
The Dabate Mo-Cu deposit is a medium-sized porphyry-type deposit in the Sailimu Lake region, western Tianshan, China. We present the geology, geochemistry and zircon U-Pb geochronology of granite porphyries from the D... The Dabate Mo-Cu deposit is a medium-sized porphyry-type deposit in the Sailimu Lake region, western Tianshan, China. We present the geology, geochemistry and zircon U-Pb geochronology of granite porphyries from the Dabate district with the intent to constrain their tectonic setting and petrogenesis. Porphyries in the Dabate district include granite porphyry I(gray white color with large phenocrysts), granite porphyry II(pink color with small phenocrysts) and quartz porphyry. Granite porphyry II is the Cu and Mo ore-bearing granitoid in the Dabate deposit. LA-ICPMS zircon U-Pb analyses indicate that granite porphyry II was emplaced at 284.2±1.8 Ma. Granite porphyry I and II have similar geochemical features and are both highly fractionated granites:(1) They have high SiO2 content(70.93–80.18 wt% and 72.14–72.64 wt%, respectively), total alkali(7.58–8.95 wt% and 9.35–9.68 wt%, respectively), mafic index(0.95–0.98 and 0.93–0.94, respectively) and felsic index(0.79–0.94 and 0.89–0.91, respectively);(2) They are characterized by pronounced negative Eu anomaly, "seagullstyle" chondrite-normalized REE patterns and "tetrad effect" of REE;(3) They are rich in Rb, K, Th, Ta, Zr, Hf, Y and REE, but depleted in Sr, P, Ti and Nb. The magma of granite porphyries in Dabate can be interpreted to have been generated by partial melting of the upper crust due to mantle-derived magma underplating in a post-collisional extensional setting. 展开更多
关键词 porphyry cu-mo deposit post-collisional extension zircon U-Pb age PETROGENESIS Dabate TIANSHAN Proto-Tethys
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Rare Earth Element Behaviour in theWunugetushan Copper - Molybdenum Deposit,Inner Mongolia, and Its Implications 被引量:3
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作者 Qin Kezhang and Wang ZhitianBeijing Institute of Geology for M ineral Resources, CNNC, Beijing 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 1994年第2期153-167,共15页
Considering porphyry and wall rocks as a whole system, the behaviour of rare earth elements (REE) in hydrothermal alteration and mineralization of the exceedingly large Wunugetushan porphyry Cu-Mo deposit of Inner Mon... Considering porphyry and wall rocks as a whole system, the behaviour of rare earth elements (REE) in hydrothermal alteration and mineralization of the exceedingly large Wunugetushan porphyry Cu-Mo deposit of Inner Mongolia has been studied. It has been found for the first time that there exists complementary REE variation in hydrothermal alteration between porphyry and wall rocks, and Eu depletion has certain significance in indicating mineralization. Based on an analysis of the variation in REE contents of relevant minerals during the hydrothermal alteration, the ore-forming fluids are inferred to be depleted in ∑REE, comparatively enriched in ∑Y and strongly depleted in Eu. In the intermediate-strong alteration zones, porphyry and wall rock took part in hydrothermal metasomatism and alteration almost in equal ratio mass. Furthermore, studies of REE and hydrogen and oxygen isotopes and fluid inclusions confirm the existence of hydrothermal convection and the possibility of supplying part of ore materials by the wall rock and indicate that the application of REE geochemistry in mineral prospecting is promising. 展开更多
关键词 REE complementary nature Eu depletion hydrothermal convection Wunugetushan cu-mo deposit Inner Mongolia
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Late Jurassic Cu-Mo Mineralization at the Zhashui-Shanyang District,South Qinling,China:Constraints from Re-Os Molybdenite and Laser Ablation-Inductively Coupled Plasma Mass Spectrometry U-Pb Zircon Dating 被引量:2
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作者 LI Qiugen LIU Shuwen +4 位作者 WANG Zongqi WANG Dongsheng YAN Zhen YANG Kai WU Fenghui 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2011年第3期661-672,共12页
The Zhashui-Shanyang district is one of the most important sulfide deposits in the Qinling Orogen where the formation of porphyry-skarn Cu-Mo deposits has a close genetic link with the Yanshannian magmatism.Laser Abla... The Zhashui-Shanyang district is one of the most important sulfide deposits in the Qinling Orogen where the formation of porphyry-skarn Cu-Mo deposits has a close genetic link with the Yanshannian magmatism.Laser Ablation-Inductively Coupled Plasma Mass Spectrometry(LA-ICP-MS) U-Pb zircon dating of two granodiorite intrusions(Xiaohekou and Lengshuigou deposits)was investigated in the Zhashui-Shanyang district and the rock-forming ages obtained from 148.3±2.8 to 152.6±1.2 Ma,averaging 150.5 Ma,accompanied by a younger disturbance age of 144.3±1.7 Ma in the Lengshuigou intrusion,which is in excellent agreement with published sensitive high resolution ion micro-probe(SHRIMP)zircon date on the later monzodiorite porphyry phase in the Lenshuigou deposit.Two samples were selected for molybdenite ICP-MS Re-Os isotopic analyses from the Lengshuigou granodiorite porphyry,yielding Re-Os model ages from 149.2±2.7 Ma to 150.6±3.4 Ma, with a weighted mean age of 149.7±2.1 Ma.These mineralization ages overlap rock-forming ages of the host intrusions within the error range.This implies that the mineralization occurred in the Late Jurassic,which belongs to the tectonic phase B event of the Yanshan Movement,not Cretaceous as previously thought.Therefore,the Late Jurassic mineralization of the Zhashui-Shanyang district could be connected to the large-scale Yanshan molybdenum metallogenic period,the geodynamic regime of which is attributable to the far field response of convergence of surrounding plates,perhaps the approximately westward subduction of the Izanagi plate beneath the Eurasian continent. 展开更多
关键词 Re-Os isotope MOLYBDENITE zircon porphyry-skarn cu-mo deposit QINLING
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粤西圆珠顶斑岩型铜钼矿床成矿地质特征及成岩成矿作用年代学研究 被引量:33
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作者 陈富文 李华芹 +5 位作者 王登红 肖光铭 杨晓君 高亦文 梅玉萍 林秀广 《地质学报》 CAS CSCD 北大核心 2012年第8期1298-1305,共8页
园珠顶大型铜钼矿床位于大瑶山隆起北缘、粤桂交界的广东省封开县境内。铜钼矿化普遍发育于斑岩体及其外接触带中,岩体内部见星点状黄铁矿、黄铜矿、辉钼矿分布,但铜钼工业矿体主要产于岩体外接触带中,并围绕着岩体具椭圆形环状矿化分... 园珠顶大型铜钼矿床位于大瑶山隆起北缘、粤桂交界的广东省封开县境内。铜钼矿化普遍发育于斑岩体及其外接触带中,岩体内部见星点状黄铁矿、黄铜矿、辉钼矿分布,但铜钼工业矿体主要产于岩体外接触带中,并围绕着岩体具椭圆形环状矿化分带特征,由内向外依次为钼矿化带→铜钼矿化带→铜矿化带,成矿作用与二长花岗斑岩有关。运用高分辨率和高灵敏度离子探针和Re-Os分析技术,作者分别对矿区二长花岗斑岩和矿体进行了年代学研究,获得二长花岗斑岩的锆石U-Pb SHRIMP年龄为154±2Ma(95%可信度,MSWD=0.75,N=11),铜钼矿体辉钼矿Re-Os等时线年龄为155±5Ma(95%可信度,MSWD=0.31,N=8),表明圆珠顶斑岩型铜钼区的成岩成矿作用都发生于中侏罗世晚期,成矿作用发生于华南拉张大地构造背景下。 展开更多
关键词 圆珠顶 斑岩型铜钼矿床 二长花岗斑岩 锆石SHRIMP U-PB定年 辉钼矿RE-OS定年
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粤西-桂东成矿带园珠顶铜钼矿床成矿年代学及其地质意义 被引量:50
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作者 钟立峰 夏斌 +4 位作者 刘立文 李杰 林秀广 徐力峰 林良庄 《矿床地质》 CAS CSCD 北大核心 2010年第3期395-404,共10页
最近在粤西-桂东成矿带园珠顶地区发现了大型斑岩Cu-Mo矿床。为研究其成矿时代,笔者选取了该矿床钼矿体中的2个钻孔岩芯样品中的辉钼矿进行了Re-Os法同位素定年,2个岩芯共11个辉钼矿样品获得的Re-Os模式年龄为149.8~155.9 Ma;对ZK12-11... 最近在粤西-桂东成矿带园珠顶地区发现了大型斑岩Cu-Mo矿床。为研究其成矿时代,笔者选取了该矿床钼矿体中的2个钻孔岩芯样品中的辉钼矿进行了Re-Os法同位素定年,2个岩芯共11个辉钼矿样品获得的Re-Os模式年龄为149.8~155.9 Ma;对ZK12-112岩芯8个辉钼矿分析数据进行Re-Os等时线拟合,获得等时线年龄为(157.3±4.3)Ma,初始^187Os为(-0.15±0.18)ng/g,MSWD=0.92;对2个钻孔样品测得的11个数据进行Re-Os等时线拟合,获得等时线年龄为(155.6±3.4)Ma,初始187Os为(-0.08±0.15)ng/g,MSWD=0.85。这些年龄数据表明该矿床形成于中侏罗世晚期。选自钻孔ZK16-104岩芯的辉钼矿样品的Re含量非常高,可能指示园珠顶Cu-Mo矿床成矿物质来源于地幔,这也被区域内出露的许多同时代的基性侵入体所佐证。园珠顶斑岩Cu-Mo矿床辉钼矿Re、Os同位素数据可能指示早侏罗世具高浮力块体的Izanagi板块俯冲到粤西-桂东地区而改变了俯冲角度,导致俯冲板片撕裂而开天窗或岩石圈加厚而发生拆沉,在该地区出现一系列NE向壳幔相互作用强烈的伸展带,引发了软流圈物质在中晚侏罗世沿着NE向深断裂与EW向古断裂的交汇部位上涌,形成了粤西-桂东地区许多同时代的花岗岩类岩体、基性侵入体(或包体)和与此相关的Cu、Pb、Zn、Au、Ag矿床、W-Sn多金属矿床以及园珠顶斑岩型Cu-Mo矿床。 展开更多
关键词 地质学 RE-OS同位素定年 辉钼矿 园珠顶矿床 粤西-桂东成矿带 华南
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广东圆珠顶斑岩型铜钼矿床成矿物质、成矿流体来源和成矿机理研究 被引量:19
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作者 楚克磊 毛景文 +4 位作者 陈懋弘 赵军 余长发 林良庄 林秀广 《地学前缘》 EI CAS CSCD 北大核心 2013年第5期115-125,共11页
圆珠顶斑岩型铜钼矿床位于钦杭成矿带西南端,是该成矿带近年来发现的又一大型铜钼矿床。文中通过对圆珠顶矿床地质特征的详细剖析并结合H、O、S、Pb等同住素地球化学的研究,对圆珠顶斑岩型铜钼矿床的成矿流体和成矿物质来源进行了初... 圆珠顶斑岩型铜钼矿床位于钦杭成矿带西南端,是该成矿带近年来发现的又一大型铜钼矿床。文中通过对圆珠顶矿床地质特征的详细剖析并结合H、O、S、Pb等同住素地球化学的研究,对圆珠顶斑岩型铜钼矿床的成矿流体和成矿物质来源进行了初步的讨论。研究结果表明:矿石金属硫化物δ34 S值分布于4.3‰~3.9‰,硫主要来源于岩浆岩;矿石铅同位素组成稳定,为正常普通铅;不同成矿阶段H、O同位素组成变化及流体包裹体研究指示大气降水与含矿岩浆热液混合是金属矿物从成矿流体中沉淀的重要因素。结合成矿动力学背景研究,认为圆珠顶矿床成矿作用与岩浆活动密切相关,矿床成因是由于板块俯冲作用引起的地壳与地幔物质混合。 展开更多
关键词 圆珠顶 斑岩铜钼矿床 同位素组成 成矿物质来源 金属沉淀机制
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广东园珠顶铜钼矿床花岗斑岩年代学、地球化学特征及锆石Hf同位素 被引量:19
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作者 胡升奇 朱强 +5 位作者 张先进 易顺华 彭松柏 周国发 吴林波 陈海红 《矿床地质》 CAS CSCD 北大核心 2013年第6期1139-1158,共20页
园珠顶铜钼矿床位于钦杭成矿带南段的大瑶山隆起北缘,为大型斑岩型铜钼矿床。通过LA-ICP-MS锆石U-Pb同位素测年,获得了花岗斑岩的高精度成岩年龄,为(154.3±1.7) Ma (n=12,MSWD=3.1),为晚侏罗世岩浆活动的产物,与辉钼矿的... 园珠顶铜钼矿床位于钦杭成矿带南段的大瑶山隆起北缘,为大型斑岩型铜钼矿床。通过LA-ICP-MS锆石U-Pb同位素测年,获得了花岗斑岩的高精度成岩年龄,为(154.3±1.7) Ma (n=12,MSWD=3.1),为晚侏罗世岩浆活动的产物,与辉钼矿的Re-Os同位素年龄155 Ma相吻合。岩石地球化学分析表明,园珠顶花岗斑岩高硅〔w(SiO2)为68.81%~70.21%〕、富碱〔w(Na2O)+w(K2O)为6.78%~8.01%〕、准铝质-弱过铝质(A/CNK为0.96~1.04);稀土元素总量中等(ΣREE 为142.15×10-6~170.83×10-6),富集轻稀土元素(ΣLREE 为135.05×10-6~162.34×10-6),轻重稀土元素分馏明显〔(La/Yb)N=30.97~32.10〕,弱的Eu负异常(δEu=0.86~0.89),稀土元素配分模式总体右倾;岩石相对富集Rb、K等大离子亲石元素(LILE)及高场强元素Th、U,亏损Nb、Ta、P、Ti等高场强元素(HFSE)及部分大离子亲石元素Ba、Sr。LA-MC-ICP-MS锆石Hf 的原位分析表明,176Hf/177Hf值变化于0.282 500~0.282 801之间,εHf(t)值介于-6.27~4.19。综合分析表明,园珠顶花岗斑岩为准铝质-弱过铝质的I型花岗岩,具有壳幔混合源成因,锆石εHf(t)值反映了园珠顶花岗斑岩的成岩源区较为复杂,总体具亏损岩浆源区的特征,以幔源物质为主,但在岩浆侵位过程中遭受了古老地壳物质的混染。结合区域构造背景和前人研究成果,认为园珠顶斑岩体及铜钼矿,与钦杭成矿带北段的永平铜矿具有一致的成岩成矿构造背景,形成于板块俯冲环境。 展开更多
关键词 地球化学 斑岩型铜钼矿 花岗斑岩 LA-ICP-MS锆石U-PB年龄 锆石HF同位素 园珠顶铜钼矿 广东 大瑶山
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粤西-桂东四套成矿系统地质特征、成因类型及构造启示 被引量:10
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作者 郑义 余盼 +1 位作者 王岳军 林振文 《岩石学报》 SCIE EI CAS CSCD 北大核心 2017年第3期682-694,共13页
粤西-桂东地区是我国重要的矿产资源基地,是研究区域成矿作用和大地构造演化耦合关系的理想地区。本文基于粤西-桂东地区四套主要成矿系统的地质特征的研究,结合区域内矿床精确定年和构造演化的研究成果,探讨四套主要成矿系统的成因类... 粤西-桂东地区是我国重要的矿产资源基地,是研究区域成矿作用和大地构造演化耦合关系的理想地区。本文基于粤西-桂东地区四套主要成矿系统的地质特征的研究,结合区域内矿床精确定年和构造演化的研究成果,探讨四套主要成矿系统的成因类型、成矿构造背景及其对钦杭结合带构造演化的启示。其中,广东云浮硫铁矿产于震旦系大绀山组,块状和条带状矿石呈层状产于火山沉积岩系中,是一套与海底热液活动密切相关的VMS成矿系统,形成于新元古代俯冲相关的弧后(间)拉张盆地;盘龙铅锌矿产于泥盆系上伦组,角砾状和胶状矿石产于浅海相白云质碎屑岩中,是一套加里东期被动大陆边缘的SEDEX型铅锌成矿系统;河台金矿田赋存于震旦系乐昌组,脉状矿体严格受断裂和蚀变带控制,是一套变质热液主导的造山型金矿成矿系统,形成于印支-燕山期陆内走滑或陆陆碰撞背景;圆珠顶铜钼矿床形成与燕山期(155Ma)二长花岗斑岩密切相关,细脉浸染状矿石赋存于岩体的内外接触带,是一套陆内伸展背景的斑岩铜钼成矿系统。总体而言,粤西-桂东地区经历了新元古代俯冲、加里东期被动大陆边缘、印支期陆内走滑(或陆陆碰撞)和燕山期陆内伸展四个重要的构造事件,这与钦杭结合带总体构造演化过程一致。 展开更多
关键词 成矿系统 大地构造演化 粤西-桂东 大降坪硫铁矿 盘龙铅锌矿 河台金矿田 圆珠顶钼矿 钦杭结合带
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广东省封开县园珠顶铜钼矿床地质特征及成矿规律 被引量:3
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作者 高亦文 《地质找矿论丛》 CAS CSCD 2013年第2期189-196,共8页
广东省封开县圆珠顶铜钼矿产于粤西—桂东成矿带上,受郴州—怀集断裂和六堡复式背斜联合控制,铜钼矿体围绕燕山早期圆珠顶花岗斑岩体呈环状展布:内环为钼矿体,外环为铜矿体。围岩为寒武系水口群上亚群中组,热液蚀变从内向外为硅化→辉... 广东省封开县圆珠顶铜钼矿产于粤西—桂东成矿带上,受郴州—怀集断裂和六堡复式背斜联合控制,铜钼矿体围绕燕山早期圆珠顶花岗斑岩体呈环状展布:内环为钼矿体,外环为铜矿体。围岩为寒武系水口群上亚群中组,热液蚀变从内向外为硅化→辉钼矿、绿泥石、绢云母化→黄铁矿化→黄铁矿、黄铜矿化。矿床类型为与斑岩有关的细脉浸染型铜钼矿。 展开更多
关键词 圆珠顶铜钼矿 斑岩型矿床 成矿规律 找矿标志 广东省
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广东圆珠顶斑岩型铜钼矿床蚀变及元素迁移特征分析 被引量:1
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作者 林振文 梁志鹏 +3 位作者 庄文明 周永章 牛佳 李出安 《矿物岩石地球化学通报》 CAS CSCD 北大核心 2023年第2期325-339,共15页
圆珠顶铜钼矿床是近年来在钦杭结合带南段发现的大型斑岩型铜钼矿床。为查明成矿过程中的围岩蚀变作用及元素迁移特征和研究成矿物质的沉淀机制,对圆珠顶铜钼矿床蚀变与矿化进行了岩相学研究,采用X射线荧光光谱(XRF)和电感耦合等离子质... 圆珠顶铜钼矿床是近年来在钦杭结合带南段发现的大型斑岩型铜钼矿床。为查明成矿过程中的围岩蚀变作用及元素迁移特征和研究成矿物质的沉淀机制,对圆珠顶铜钼矿床蚀变与矿化进行了岩相学研究,采用X射线荧光光谱(XRF)和电感耦合等离子质谱法(ICP-MS)对围岩进行全岩主、微量元素分析。结果表明,圆珠顶矿床围岩蚀变以花岗斑岩为中心,向外依次划分为钾硅酸盐化带、绢英岩化带和黄铁绢英岩化带三个蚀变带,蚀变矿物组合分别为黑云母+钾长石+石英+辉钼矿+黄铜矿+黄铁矿+斑铜矿、石英+绢云母+黄铜矿+黄铁矿+辉钼矿和绢云母+石英+黄铁矿+磁铁矿+黄铜矿±辉钼矿±方解石。热液蚀变过程中,Al_(2)O_(3)、MgO、CaO、Na_(2)O、Th、U、Ta、Sr、Zr、Ni、Co等组分发生不同程度的迁出,K_(2)O、Cu、Mo等组分发生迁入,以黄铁绢英岩化带最为显著。热液蚀变作用与流体混合作用是Cu、Mo沉淀的主要机制,钼矿化与钾硅酸盐化蚀变关系密切,铜矿化与绢英岩化蚀变关系密切。 展开更多
关键词 斑岩型铜钼矿 围岩蚀变 元素迁移 圆珠顶 钦杭结合带
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