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Direct Synthesis of Zn_(1-x)Cd_xS (0≤x≤1) Quantum Dots in Aqueous Solution and Application in Biology
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作者 黄克阳 何声太 +6 位作者 LIU Yulan ZHANG Yongxiao LI Yanan HOU Xiaoqin XU Hu SUN Minglin WEN Lingang 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2013年第2期265-268,共4页
A simple procedure was presented to directly synthesize Zn1_xCdxS (0 ≤x≤1) quantum dots (QDs) in aqueous solution. QDs' structures and properties were characterized by TEM (transmission electron microscopy), ... A simple procedure was presented to directly synthesize Zn1_xCdxS (0 ≤x≤1) quantum dots (QDs) in aqueous solution. QDs' structures and properties were characterized by TEM (transmission electron microscopy), XRD (X-ray diffraction) and fluorescence microscopy. For those as-synthesized Zn1_xCdxS QDs, when the molar ratio between Zn and Cd changed from 1 to 0, its photoluminescence (PL) emission peak shifted from 430 nm to 675 nm. PL emission quantum efficiency was up to 15%. The experiment results demonstrated that those alloyed QDs showed a good biocompatibility and could be used as labelling materials in cell biology. 展开更多
关键词 zn1_xCdxS quantum dot luminescence synthesis
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共价固定CdTe/CdS/ZnS量子点构建1-羟基芘电化学发光传感器 被引量:1
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作者 郭露露 李皖豫 +2 位作者 沈晓芳 杨成 庞月红 《中国科学:化学》 CAS CSCD 北大核心 2019年第10期1299-1307,共9页
本文以乙二胺为连接分子,将水溶性CdTe/CdS/ZnS量子点通过共价作用键合在对氨基苯甲酸修饰的玻碳电极上,构建一种1-羟基芘的新型量子点电化学发光传感方法.通过循环伏安、电化学阻抗和电致化学发光等方法考察了该传感器对1-羟基芘的检... 本文以乙二胺为连接分子,将水溶性CdTe/CdS/ZnS量子点通过共价作用键合在对氨基苯甲酸修饰的玻碳电极上,构建一种1-羟基芘的新型量子点电化学发光传感方法.通过循环伏安、电化学阻抗和电致化学发光等方法考察了该传感器对1-羟基芘的检测性能.结果表明,在200~800 nmol/L范围内,发光相对强度I/I0与1-羟基芘浓度呈良好的线性关系,检出限为133.5 nmol/L(S/N=3),在尿液实际样品检测中,回收率为83.9%~104.7%,检测结果与高效液相色谱(HPLC)结果相符合,具有一定的实际应用价值. 展开更多
关键词 CdTe/CdS/znS量子点 1-羟基芘 电化学发光传感
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