Zonal activation of molecular carbon dioxide and hydrogen over dual sites Ni-Co-MgO catalyst for CO_(2) methanation:Synergistic catalysis of Ni and Co species

An in-depth mechanism in zonal activation of CO_(2)and H2molecular over dual-active sites has not been revealed yet.Here,Ni-Co-MgO was rationally constructed to elucidate the CO_(2)methanation mechanism.The abundant surface nickel and cobalt components as active sites led to strong Ni-Co interaction with charge transfer from nickel to cobalt.Notably,electron-enriched Coδ-species participated in efficient chemisorption and activation of CO_(2)to generate monodentate carbonate.Simultaneously,plentiful available Ni0sites facilitated H2dissociation,thus CO_(2)and H2were smoothly activated at zones of Coδ-species and Ni0,respectively.Detailed in situ DRIFTS,quasi situ XPS,TPSR,and DFT calculations substantiated a new formate evolution mechanism via monodentate carbonate instead of traditional bidentate carbonate based on synergistic catalysis of Coδ-species and Ni0.The zonal activation of CO_(2)and H2by tuning electron behaviors of double-center catalysts can boost heterogeneous catalytic hydrogenation performance.

Uncertainties of ENSO-related Regional Hadley Circulation Anomalies within Eight Reanalysis Datasets

El Nino-Southern Oscillation(ENSO),the leading mode of global interannual variability,usually intensifies the Hadley Circulation(HC),and meanwhile constrains its meridional extension,leading to an equatorward movement of the jet system.Previous studies have investigated the response of HC to ENSO events using different reanalysis datasets and evaluated their capability in capturing the main features of ENSO-associated HC anomalies.However,these studies mainly focused on the global HC,represented by a zonal-mean mass stream function(MSF).Comparatively fewer studies have evaluated HC responses from a regional perspective,partly due to the prerequisite of the Stokes MSF,which prevents us from integrating a regional HC.In this study,we adopt a recently developed technique to construct the three-dimensional structure of HC and evaluate the capability of eight state-of-the-art reanalyses in reproducing the regional HC response to ENSO events.Results show that all eight reanalyses reproduce the spatial structure of HC responses well,with an intensified HC around the central-eastern Pacific but weakened circulations around the Indo-Pacific warm pool and tropical Atlantic.The spatial correlation coefficient of the three-dimensional HC anomalies among the different datasets is always larger than 0.93.However,these datasets may not capture the amplitudes of the HC responses well.This uncertainty is especially large for ENSO-associated equatorially asymmetric HC anomalies,with the maximum amplitude in Climate Forecast System Reanalysis(CFSR)being about 2.7 times the minimum value in the Twentieth Century Reanalysis(20CR).One should be careful when using reanalysis data to evaluate the intensity of ENSO-associated HC anomalies.

Fracture sealing performance of granular lost circulation materials at elevated temperature:A theoretical and coupled CFD-DEM simulation study

Lost circulation is a common downhole problem of drilling in geothermal and high-temperature,high-pressure(HTHP)formations.Lost circulation material(LCM)is a regular preventive and remedial measure for lost circulation.However,conventional LCMs seem ineffective in high-temperature formations.This may be due to the changes in the mechanical properties of LCMs and their sealing performance under high-temperature conditions.To understand how high temperature affects the fracture sealing performance of LCMs,we developed a coupled computational fluid dynamics-discrete element method(CFD-DEM)model to simulate the behavior of granular LCMs in fractures.We summarized the literature on the effects of high temperature on the mechanical properties of LCMs and the rheological properties of drilling fluid.We conducted sensitivity analyses to investigate how changing LCM slurry properties affected the fracture sealing efficiency at increasing temperatures.The results show that high temperature reduces the size,strength,and friction coefficient of LCMs as well as the drilling fluid viscosity.Smaller,softer,and less frictional LCM particles have lower bridging probability and slower bridging initiation.Smaller particles tend to form dual-particle bridges rather than single-particle bridges.These result in a deeper,tighter,but unstable sealing zone.Reduced drilling fluid viscosity leads to faster and shallower sealing zones.

Arterial Duct Stenting Versus Modified Blalock-Taussig Shunt in Patient with Ductal-Dependent Pulmonary Circulation: Systematic Review & Meta-Analysis

Objective:Patients with ductal-dependent pulmonary circulation require alternative bloodflow to provide and maintain adequate oxygenation.Modified Blalock-Taussig Shunt(MBTS)has been the standard for providing such a result.Currently,less invasive methods such as Arterial Duct(AD)stenting have been performed as alter-natives.This study aims to compare the outcome of AD stenting and MBTS.Method:Systematic research was performed in online databases using the PRISMA protocol.The outcomes measured were 30-day mortality,com-plication,unplanned intervention,oxygen saturation,duration of hospital,and ICU length of stay.Any compara-tive study provided with full text is included.The outcome of each study was analyzed using a trandom effects model with relative risk and mean difference as the effect size.Bias risk assessment was conducted using the New-castle-Ottawa Scale.All analyses were performed using Review Manager 5.4.1.Result:A total of 11 studies with 3154 samples included in this study.There is no significant difference in 30-day mortality between the two groups(p-value=0.10).However,there is significantly less complication(RR 0.53[0.35,0.82];p-value=0.004)and unplanned intervention(RR 0.59[0.38,0.92];p-value=0.02)in the AD stent group.Comparison of the Nakata index showed no significant difference(p-value=0.88).Post-operative oxygen saturation was measured signifi-cantly higher in the AD stenting(MD 1.80[0.85,2.74];p-value=0.0002).However,AD stent group shows sig-nificantly lower long-term oxygen saturation(MD-8.43[-14.38,-2.48];p-value=0.005).Both hospital and ICU length of stay was significantly shorter in the AD stent group(MD-8.30[-11.13,-5.48];p-value<0.00001;MD-5.09[-7.79,-2.38];p-value=0.0002).Conclusion:AD stenting provides comparable outcomes relative to MBTS as it provides less complication and unplanned intervention and higher post-procedural O2 saturation.However,MBTS proved its superiority in maintaining higher long-term oxygen saturation and still became the preferred option to manage complex cases where stenting is either challenging or unsuccessful.

A novel predictor of unsustained return of spontaneous circulation in cardiac arrest patients through a combination of capnography and pulse oximetry: a multicenter observational study

BACKGROUND:Unsustained return of spontaneous circulation(ROSC)is a critical barrier to survival in cardiac arrest patients.This study examined whether end-tidal carbon dioxide(ETCO_(2))and pulse oximetry photoplethysmogram(POP)parameters can be used to identify unsustained ROSC.METHODS:We conducted a multicenter observational prospective cohort study of consecutive patients with cardiac arrest from 2013 to 2014.Patients’general information,ETCO_(2),and POP parameters were collected and statistically analyzed.RESULTS:The included 105 ROSC episodes(from 80 cardiac arrest patients)comprised 51 sustained ROSC episodes and 54 unsustained ROSC episodes.The 24-hour survival rate was significantly higher in the sustained ROSC group than in the unsustained ROSC group(29.2%vs.9.4%,P<0.05).The logistic regression analysis showed that the difference between after and before ROSC in ETCO_(2)(ΔETCO_(2))and the difference between after and before ROCS in area under the curve of POP(ΔAUCp)were independently associated with sustained ROSC(odds ratio[OR]=0.931,95%confi dence interval[95%CI]0.881-0.984,P=0.011 and OR=0.998,95%CI 0.997-0.999,P<0.001).The area under the receiver operating characteristic curve ofΔETCO_(2),ΔAUCp,and the combination of both to predict unsustained ROSC were 0.752(95%CI 0.660-0.844),0.883(95%CI 0.818-0.948),and 0.902(95%CI 0.842-0.962),respectively.CONCLUSION:Patients with unsustained ROSC have a poor prognosis.The combination ofΔETCO_(2) andΔAUCp showed signifi cant predictive value for unsustained ROSC.

Application Effect of External Diaphragm Pacemaker Combined with Active Respiratory Circulation Technology in Pulmonary Rehabilitation of Perioperative Lung Cancer Patients

Aim: To explore the application effect of external diaphragm pacemaker combined with active respiratory circulation technology in pulmonary rehabilitation of perioperative lung cancer patients. Methods: A total of 98 lung cancer patients admitted to our hospital from April 2020 to November 2021 were selected as the observation objects, and then divided into a control group and an observation group using the random number table method, with 49 cases in each group. The control group received routine admission guidance and active respiratory circulation training, while the observation group was supplemented with external diaphragm pacemaker on the basis of the control group. The intervention effect was evaluated by blood gas indicators, pulmonary function indicators, diaphragm function indicators, sputum comfort degree, and activity tolerance indicators before and after intervention. Results: Before intervention, there were no significant differences in blood gas analysis indicators, pulmonary function indicators, diaphragm function indicators, sputum comfort degree, and activity tolerance indicators between the two groups (P > 0.05). After intervention, the improvement degree of the above indicators in the observation group was higher than that in the control group (P < 0.05). Conclusions: The application of external diaphragm pacemaker combined with active respiratory circulation technology in pulmonary rehabilitation of perioperative lung cancer patients is significant, which can effectively improve the pulmonary function, blood gas function, and diaphragm function of lung cancer patients after surgery, and improve the activities of daily living and quality of life of patients.

Numerical simulations of Atlantic meridional overturning circulation(AMOC)from OMIP experiments and its sensitivity to surface forcing

Atlantic meridional overturning circulation(AMOC)plays an important role in transporting heat meridionally in the Earth’s climate system and is also a key metrical tool to verify oceanic general circulation models.Two OMIP(Ocean Model Intercomparison Project phase 1 and 2)simulations with LICOM3(version 3 of the LASG/IAP Climate System Ocean Model)developed at the State Key Laboratory of Numerical Modeling for Atmospheric Sciences and Geophysical Fluid Dynamics(LASG),Institute of Atmospheric Physics(IAP),are compared in this study.Both simulations well reproduce the fundamental characteristics of the AMOC,but the OMIP1 simulation shows a significantly stronger AMOC than the OMIP2 simulation.Because the LICOM3 configurations are identical between these two experiments,any differences between them must be attributed to the surface forcing data.Further analysis suggests that sea surface salinity(SSS)differences should be mainly responsible for the enhanced AMOC in the OMIP1 simulation,but sea surface temperature(SST)also play an unignorable role in modulating AMOC.In the North Atlantic,where deep convection occurs,the SSS in OMIP1 is more saline than that in OMIP1.We find that in the major region of deep convection,the change of SSS has more significant effect on density than the change of SST.As a result,the SSS was more saline than that in OMIP2,leading to stronger deep convection and subsequently intensify the AMOC.We conduct a series of numerical experiments with LICOM3,and the results confirmed that the changes in SSS have more significant effect on the strength of AMOC than the changes in SST.

Correction:Establishment of a prediction model for prehospital return of spontaneous circulation in out-of-hospital patients with cardiac arrest

This is an erratum to an already published paper named“Establishment of a prediction model for prehospital return of spontaneous circulation in out-ofhospital patients with cardiac arrest”.We found errors in the affiliated institution of the authors.We apologize for our unintentional mistake.Please note,these changes do not affect our results.

Comparative Analysis of Energy Characteristics of Two Southwest Vortices in Sichuan Under Similar Circulation Backgrounds

Based on ERA5 reanalysis data,the present study analyzed the thermal energy development mechanism and kinetic energy conversion characteristics of two extreme rainstorm processes in relation to the shallow southwest vortex in the warm-sector during a“rain-generated vortex”process and the deep southwest vortex in a“vortex-generated rain”process.The findings were as follows:(1)During the extreme rainstorm on August 11,2020(hereinafter referred to as the“8·11”process),intense surface heating and a high-energy unstable environment were observed.The mesoscale convergence system triggered convection to produce heavy rainfall,and the release of latent condensation heat generated by the rainfall promoted the formation of a southwest vortex.The significant increase(decrease)in atmospheric diabatic heating and kinetic energy preceded the increase(decrease)in vorticity.By contrast,the extreme rainstorm on August 16,2020(hereinafter referred to as the“8·16”process)involved the generation of southwest vortex in a low-energy and highhumidity environment.The dynamic uplift of the southwest vortex triggered rainfall,and the release of condensation latent heat from rainfall further strengthened the development of the southwest vortex.The significant increase(decrease)in atmospheric diabatic heating and kinetic energy exhibited a delayed progression compared to the increase(decrease)in vorticity.(2)The heating effect around the southwest vortex region was non-uniform,and the heating intensity varied in different stages.In the“8·11”process,the heating effect was the strongest in the initial stage,but weakened during the vortex's development.On the contrary,the heating effect was initially weak in the“8·16”process,and intensified during the development stage.(3)The available potential energy of the“8·11”process significantly increased in kinetic energy converted from rotational and divergent winds through baroclinic action,and the divergent wind energy continued to convert into rotational wind energy.By contrast,the“8·16”process involved the conversion of rotational wind energy into divergent wind energy,which in turn converted kinetic energy back into available potential energy,thereby impeding the further development and maintenance of the southwest vortex.

Circulation Pattern Controls of Summer Temperature Anomalies in Southern Africa

This study investigates the relationship between circulation patterns and austral summer temperature anomalies in southern Africa. The results show that the formation of continental lows tends to increase the thickness of the lower atmosphere. Further, the distinct variabilities of high and low pressure under the circulation types, influence air mass advection from the adjacent oceans, as well as atmospheric stability over land. Stronger anticyclonic circulation at the western branch of the Mascarene high-pressure system enhances the low-level cold air advection by southeast winds,decreases the thickness, and lowers the temperature over a majority of the land in southern Africa. Conversely, a weaker Mascarene High, coupled with enhanced cyclonic activity in the southwest Indian Ocean increases low-level warm air advection and increases temperature anomalies over vast regions in southern Africa. The ridging of a closed South Atlantic anticyclone at the southern coast of southern Africa results in colder temperatures near the tip of southern Africa due to enhanced low-level cold air advection by southeast winds. However, when the ridge is weak and westerly winds dominate the southern coast of southern Africa, these areas experience temperature increases. The northward track of the Southern Hemisphere mid-latitude cyclone, which can be linked to the negative Southern Annular Mode, reduces the temperature in the southwestern part of southern Africa. Also, during the analysis period, El Ni?o was associated with temperature increases over the central parts of southern Africa;while the positive Indian Ocean dipole was linked to a temperature increase over the northeastern, northwestern, and southwestern parts of southern Africa.

Spatio-temporal Variation Characteristics of Extreme Climate Events and Their Teleconnections to Large-scale Ocean-atmospheric Circulation Patterns in Huaihe River Basin,China During 1959–2019

Huaihe River Basin(HRB) is located in China’s north-south climatic transition zone,which is very sensitive to global climate change.Based on the daily maximum temperature,minimum temperature,and precipitation data of 40 meteorological stations and nine monthly large-scale ocean-atmospheric circulation indices data during 1959–2019,we present an assessment of the spatial and temporal variations of extreme temperature and precipitation events in the HRB using nine extreme climate indices,and analyze the teleconnection relationship between extreme climate indices and large-scale ocean-atmospheric circulation indices.The results show that warm extreme indices show a significant(P < 0.05) increasing trend,while cold extreme indices(except for cold spell duration) and diurnal temperature range(DTR) show a significant decreasing trend.Furthermore,all extreme temperature indices show significant mutations during 1959-2019.Spatially,a stronger warming trend occurs in eastern HRB than western HRB,while maximum 5-d precipitation(Rx5day) and rainstorm days(R25) show an increasing trend in the southern,central,and northwestern regions of HRB.Arctic oscillation(AO),Atlantic multidecadal oscillation(AMO),and East Atlantic/Western Russia(EA/WR) have a stronger correlation with extreme climate indices compared to other circulation indices.AO and AMO(EA/WR) exhibit a significant(P < 0.05) negative(positive)correlation with frost days and diurnal temperature range.Extreme warm events are strongly correlated with the variability of AMO and EA/WR in most parts of HRB,while extreme cold events are closely related to the variability of AO and AMO in eastern HRB.In contrast,AMO,AO,and EA/WR show limited impacts on extreme precipitation events in most parts of HRB.

Evaluation of the Mechanisms Acting on the Atlantic Meridional Overturning Circulation in CESM2 for the 1pctCO_(2) Experiment

The Atlantic Meridional Overturning Circulation(AMOC)is a crucial component of the Earth’s climate system due to its fundamental role in heat distribution,carbon and oxygen transport,and the weather.Other climate components,such as the atmosphere and sea ice,influence the AMOC.Evaluating the physical mechanisms of those interactions is paramount to increasing knowledge about AMOC’s functioning.In this study,the authors used outputs from the Community Earth System Model version 2 and observational data to investigate changes in theAMOC and the associated physical processes.Two DECK experiments were evaluated:piControl and 1pctCO_(2),with an annual increase of 1%of atmospheric CO_(2).The analysis revealed a significant decrease in the AMOC,associated with changes in mixed layer depth and buoyancy in high latitudes of the North Atlantic,resulting in the shutdown of deep convection and potentially affecting the formation of North Atlantic Deep Water and Antarctic Bottom Water.A vital aspect observed in this study is the association between increased runoff and reduced water evaporation,giving rise to a positive feedback process.Consequently,the rates of freshwater spreading have intensified during this period,which could lead to an accelerated disruption of the AMOC beyond the projections of existing models.

Westward extension of summer atmospheric circulation over the North Pacific after the 1990s

本文研究了20世纪90年代前后夏季北太平洋大气环流(NPcirculation)向西扩展,并探讨了其可能的原因.结果表明,在1961-1983年期间NP中心主要位于东北太平洋,而在1994-2016年期间NP中心发生西移,至北太平洋中部进一步分析指出,90年代以后NP活动中心的西移和春季中纬度北太平洋海温(SST_NP)与NP关系的加强有关.春季SST_NP异常通过引起后期夏季北太平洋中部地表热通量(即感热通量和潜热通量)和垂直运动异常,有利于NP活动中心向西移动,此外,20世纪90年代以后,北太平洋中部海平面气压的年际变率增加,这可能是NP向西扩展的另一原因。

Linkage Between the Northeast Mongolian Precipitation and the Northern Hemisphere Zonal Circulation

The long-term relationship between the tree-ring-reconstructed annual precipitation in northeastern Mongolia （PRM） and the Northern Hemisphere Zonal Circulation （NHZC）, defined as the normalized zonal mean sea-level pressure at 60°N in May-June-July, is examined in this study. A significant correlation coefficient （0.31） was found between the NHZC indices and PRM based on the dataset for the period of 1872-1995. The mechanisms responsible for the relationship are discussed through analyses of the atmospheric general circulation variability associated with NHZC. It follows that NHZC-related atmospheric circulation variability provides an anomalous southeast flow from the ocean to Northeast Mongolia （northwest flow from Northeast Mongolia to the ocean） in the middle and low troposphere in positive （negative） phase of NHZC, resulting in more （less） water vapor transport to the target region and more （less） precipitation in Northeast Mongolia.

Zonal overturning circulation and heat flux induced by heaving modes in the world oceans

Zonal overturning circulation （ZOC） and its associated zonal heat flux （ZHF） are important components of the oceanic circulation and climate system, although these conceptions have not received adequate attentions. Heaving induced by inter-annual and decadal wind stress perturbations can give rise to anomalous ZOC and ZHF. Based on a simple reduced gravity model, the anomalous ZOC and ZHF induced by idealized heaving modes in the world oceans are studied. For example, in a Pacific-like model basin intensified equatorial easterly on decadal time scales can lead to a negative ZOC with a non-negligible magnitude （-0.3×10^6 m^3/s） and a considerable westward ZHF with an amplitude of -11.2 TW. Thus, anomalous ZOC and ZHF may consist of a major part of climate signals on decadal time scales and thus play an important role in the oceanic circulation and climate change.

A Two-way Stratosphere–Troposphere Coupling of Submonthly Zonal-Mean Circulations in the Arctic

This paper examines the dominant submonthly variability of zonally symmetrical atmospheric circula- tion in the Northern Hemisphere （NH） winter within the context of the Northern Annular Mode （NAM）, with particular emphasis on interactive stratosphere-troposphere processes. The submonthly variability is identified and measured using a daily NAM index, which concentrates primarily on zonally symmetrical circulation. A schematic lifecycle of submonthly variability is developed that reveals a two-way coupling pro- cess between the stratosphere and troposphere in the NH polar region. Specifically, anomalous tropospheric zonal winds in the Atlantic and Pacific sectors of the Arctic propagate upwards to the low stratosphere, disturbing the polar vortex, and resulting in an anomalous stratospheric geopotential height （HGT） that subsequently propagates down into the troposphere and changes the sign of the surface circulations. From the standpoint of planetary-scale wave activities, a feedback loop is also evident when the anoma- lous planetary-scale waves （with wavenumbers 2 and 3） propagate upwards, which disturbs the anomalous zonally symmetrical flow in the low stratosphere, and induces the anomalous HGT to move poleward in the low stratosphere, and then propagates down into the troposphere. This increases the energy of waves at wavenumbers 2 and 3 in the low troposphere in middle latitudes by enhancing the land-sea contrast of the anomalous HGT field. Thus, this study supports the viewpoint that the downward propagation of stratospheric NAM signals may not originate in the stratosphere.

The Zonal Structure of the Hadley Circulation

A discussion of the mass transport of the Hadley circulation is presented, with regard to its longitudinal structure. Data from the NCEP/NCAR reanalysis data set for the period 1948-2005 is examined, focusing on the solsticial seasons of June-August and December-February. Quantitative estimates have been extracted from the data to observe connections between the zonal mean of the upper tropospheric north/south mass transports and their relationship to the driving factor of tropical precipitation （implying latent heat release） and subsidence in the subtropical high pressure belts. The longitudinal structure of this flow is then examined with regard to these three main variables. The poleward upper tropospheric transport has four （JJA） or three （DJF） main branches, which link regions of major precipitation with corresponding regions of large subsidence, and one （June, July, August） or two （December, January, February） reverse branches. This structure has remained stable over the past sixty years. Although the total upper tropospheric transport in each season is less than the total sinking transport in the target subtropical high pressure belt, this does not apply to the individual branches, the balance being made up by the upper tropospheric reverse transports. An analysis of correlations between all of these various components shows, however, that the complete picture is more complex, with some precipitation regions being linked to subsidence regions outside their own branch.

The Impact of an Abnormal Zonal Vertical Circulation in Autumn of Super El Ni?o Years on Non-tropical-cyclone Heavy Rainfall over Hainan Island

This study reveals a significant positive connection between autumn non-tropical-cyclone heavy rainfall on Hainan Island and the intensity of Eastern Pacific(EP)El Ni?o events.That is,the amount of rainfall in super EP El Ni?o years is more than that in normal EP El Ni?o years.Comparing EP El Ni?o years of different intensities,the cooler sea surface temperature in the northwestern Pacific during super EP El Ni?o years stimulates a negative surface latent heat flux(LHF)anomaly and abnormal anticyclonic circulation at 850 hPa.Under these conditions,an abnormal zonal vertical circulation develops in the northern South China Sea once a positive LHF anomaly and abnormal cyclonic circulation(ACC)at 850hPa occur in the Beibu Gulf.The abnormal zonal vertical circulation further strengthens the ascending motion over Hainan Island,as the critical factor that leads to excessive rainfall.Further analysis shows that the positive LHF anomaly,which can be attributed to the increased latent heat transfer which resulted from the increased surface wind speed,is an important trigger for the ACC.However,the ACC is also the supplier of favorable moisture conditions because it intensifies vapor convergence over Hainan Island and meridionally transports moisture from the South China Sea to northeastern Hainan Island,thereby generating heavy rainfall.This paper emphasizes that the impact of El Ni?o events,especially super El Ni?o events,on rainfall over Hainan Island cannot be ignored,even if the traditional view is that frequent rainfall occurs mainly in La Ni?a years.

ABRUPT SEASONAL CHANGE OF ZONAL CIRCULATION OVER THE TIBETAN PLATEAU

The abrupt changes of zonal circulation in the Tibetan Plateau(TP) region and their likely causes are derived from National Centers for Environmental Prediction and the National Center for Atmospheric Research reanalysis data.The zonal circulation over the TP abruptly changed in summer(31st pentad) and winter(59th pentad).The switch from summer to winter circulation is characterized by a sudden northward shift of the westerlies and the zero-velocity curve and disappearance of the westerly jet.The winter-summer switch is characterized by the reverse pattern.Therefore,the circulation conversion between summer and winter can be judged from the position of the zero-velocity curve.Curves located north of 20 °N indicate summer circulation over the TP and vice versa.The abrupt change of zonal circulation is mainly caused by the thermodynamic effect of the TP.In June,this effect causes a huge monsoon circulation cell extending from the TP to low latitudes.Consequently,the westerlies jump to the north as easterlies develop.This process,which is enhanced by the strong northerly in Coriolis,establishes the summer circulation.In October,the Hadley cell recurs as the thermal effects of the TP diminish,the westerlies rush southward,and the winter circulation is established.

Lower-order zonal gravitational coefficients caused by zonal circulations inside gaseous planets: Convective flows and numerical comparison between modeling approaches

To infer the internal equilibrium structure of a gaseous planet, especially the equation of state(EOS) and size of its inner core,requires accurate determination of lower-order zonal gravitational coefficients. Modeling of the gravitational signature associated with deep zonal circulation depends critically upon reliable subtraction of the dynamical components from totally derived gravitational coefficients. In the era of the Juno mission and the Grand Finale phase of the Cassini mission, it is timely and necessary to revisit and examine the so-called ‘Thermal Wind Equation(TWE)’, which has been extensively utilized to diagnose the dynamical parts of the gravitational fields measured by the two spacecrafts. TWE treats as negligible a few terms in the full equation of balance. However, the self-gravitational anomaly of the distorted fluid, unlike oblateness effects of solid-body rotation, is not a priori minor and thus should not be neglected in the name of approximation. Another equation, the ‘Thermal Gravitational Wind Equation(TGWE)’, includes this important additional term;we compare it with the TWE and show that physically the TGWE models a fundamentally different balance from the TWE and delivers numerical results considerably different from models based on the TWE. We conclude that the TWE balance cannot be relied upon to produce realistic convection models. Only after the TGWE balance is obtained can the relative importance of terms be assessed.The calculations we report here are based on two types of zonal circulations that are produced by realistically possible convections inside planets, instead of being constructed or assumed.