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Role of activation energies of individual phases in two-phase range on constitutive equation of Zr-2.5Nb-0.5Cu alloy 被引量:2
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作者 K.K.SAXENA S.K.JHA +4 位作者 V.PANCHOLI G.P.CHAUDHARI D.SRIVASTAVA G.K.DEY N.SAIBABA 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2017年第1期172-183,共12页
Dominant phase during hot deformation in the two-phase region of Zr-2.5Nb-0.5Cu (ZNC) alloy was studied using activation energy calculation of individual phases. Thermo-mechanical compression tests were performed on... Dominant phase during hot deformation in the two-phase region of Zr-2.5Nb-0.5Cu (ZNC) alloy was studied using activation energy calculation of individual phases. Thermo-mechanical compression tests were performed on a two-phase ZNC alloy in the temperature range of 700-925 ℃ and strain rate range of 10-2-10 s-l, Flow stress data of the single phase were extrapolated in the two-phase range to calculate flow stress data of individual phases. Activation energies of individual phases were then calculated using calculated flow stress data in the two-phase range, Comparison of activation energies revealed that a phase is the dominant phase (deformation controlling phase) in the two-phase range. Constitutive equations were also developed on the basis of the deformation temperature range (or according to phases present) using a sine-hyperbolic type constitutive equation. The statistical analysis revealed that the constitutive equation developed for a particular phase showed good agreement with the experimental results in terms of correlation coefficient (R) and average absolute relative error (AARE). 展开更多
关键词 zr-2.5nb-0.5cu alloy hot deformation activation energy constitutive equation two-phase material
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预退火对Sm_5Fe_(74.3)Nb_(1.5)Si_(11.7)B_(4.5)C_(2.5)Cu_(0.5)非晶合金晶化动力学的影响
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作者 刘建华 张朋越 +5 位作者 谌岩 杨丽 关颍 张克勤 张静武 张湘义 《功能材料》 EI CAS CSCD 北大核心 2002年第4期374-375,378,共3页
研究了预退火对Sm5Fe74.3 Nb1.5Si11.7B4.5C2 .5Cu0 .5非晶合金晶化动力学的影响。结果表明 ,预退火处理使非晶合金晶化相α Fe和Sm2 Fe17Cx 的晶化温度 (Tp)和晶化表观激活能(Ec)值降低 ,且改变晶化相α Fe在晶化过程中晶化激活能的变... 研究了预退火对Sm5Fe74.3 Nb1.5Si11.7B4.5C2 .5Cu0 .5非晶合金晶化动力学的影响。结果表明 ,预退火处理使非晶合金晶化相α Fe和Sm2 Fe17Cx 的晶化温度 (Tp)和晶化表观激活能(Ec)值降低 ,且改变晶化相α Fe在晶化过程中晶化激活能的变化趋势 ,有助于该合金在晶化退火中形成晶粒尺寸较小的α Fe相。 展开更多
关键词 预退火 非晶合金 晶化动力学 晶化激活能
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Cu在Zr-2.5Nb-0.5Cu合金及其腐蚀生成氧化膜中的存在形式 被引量:5
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作者 李强 梁雪 +2 位作者 周邦新 姚美意 彭剑超 《稀有金属材料与工程》 SCIE EI CAS CSCD 北大核心 2012年第1期92-95,共4页
用电子显微镜研究了合金元素Cu在Zr-2.5Nb-0.5Cu合金及其腐蚀生成氧化膜中的存在形式。合金基体中的元素Cu主要以四方结构的CuZr2第二相形式存在,CuZr2相中会富集杂质元素Fe。合金经过550℃,25MPa超临界水条件深度腐蚀后,伴随着合金基... 用电子显微镜研究了合金元素Cu在Zr-2.5Nb-0.5Cu合金及其腐蚀生成氧化膜中的存在形式。合金基体中的元素Cu主要以四方结构的CuZr2第二相形式存在,CuZr2相中会富集杂质元素Fe。合金经过550℃,25MPa超临界水条件深度腐蚀后,伴随着合金基体发生的H致β相变,CuZr2第二相也发生了相消溶、扩散及凝聚长大过程。在腐蚀生成的氧化膜中,合金元素Cu以非晶氧化物的形式存在于氧化锆的晶界。 展开更多
关键词 cu zr-2.5nb-0.5cu合金 显微组织 腐蚀
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