The obstacles of inferior microstructure and poor magnetic properties of(La,Ce)-Fe-B type magnets stand in the way of expanding their applications.In this work,(La,Ce)-Fe-B melt-spun ribbons were prepared with differe...The obstacles of inferior microstructure and poor magnetic properties of(La,Ce)-Fe-B type magnets stand in the way of expanding their applications.In this work,(La,Ce)-Fe-B melt-spun ribbons were prepared with different La/Ce ratios and rare earth contents.The microstructure and magnetic properties of these ribbons were investigated.With the La/Ce ratio increased,the fraction of the CeFe_(2)phase decreased and the β-La phase segregated among matrix grains,which deteriorated the coercivity of the ribbons.Reducing the rare earth content effectively suppressed the β-La phase and improved the proportion of the matrix phase in the ribbons.Here,the optimal alloy composite(La_(15)Ce_(85))_(14)Fe_(80)B_(6) has been obtained with modified microstructure and inhibited secondary phases.Good ribbon performance was tested,with H_(cj)=4.51 kOe,B_(r)=6.29 kG and(BH)_(max)=6.81 MGOe.展开更多
基金Project supported by the fifth batch of major scientific and technological research projects in the Panxi Experimental Zone of Sichuan Province,the new functional materials and applications of rare earth vanadium titanium(Grant No.2020SCUNG201).
文摘The obstacles of inferior microstructure and poor magnetic properties of(La,Ce)-Fe-B type magnets stand in the way of expanding their applications.In this work,(La,Ce)-Fe-B melt-spun ribbons were prepared with different La/Ce ratios and rare earth contents.The microstructure and magnetic properties of these ribbons were investigated.With the La/Ce ratio increased,the fraction of the CeFe_(2)phase decreased and the β-La phase segregated among matrix grains,which deteriorated the coercivity of the ribbons.Reducing the rare earth content effectively suppressed the β-La phase and improved the proportion of the matrix phase in the ribbons.Here,the optimal alloy composite(La_(15)Ce_(85))_(14)Fe_(80)B_(6) has been obtained with modified microstructure and inhibited secondary phases.Good ribbon performance was tested,with H_(cj)=4.51 kOe,B_(r)=6.29 kG and(BH)_(max)=6.81 MGOe.