Research Progress of Additives to Improve Hydration Resistance of Magnesia-calcium Materials

Magnesia-calcium materials have stable hot performance,good resistance to the erosion and corrosion of liquid steel and steel slag,and a special role in purifying liquid steel,so they are widely used in iron and steel industry.However,hydration of magnesia-calcium materials seriously restricts their use,so researches have been done to improve their hydration resistance,obtaining a series of achievements.In this paper,the improvements on the hydration resistance of magnesia-calcium materials by additives in recent 20 years were presented,and their mechanisms were summarized.

An Abrasion Resistant TPU/SH-SiO_(2) Superhydrophobic Coating for Anti-Icing and Anti-Corrosion Applications

As a passive anti-icing strategy,properly designed superhydrophobic coatings can demonstrate outstanding performances.However,common preparation strategies for superhydrophobic coatings often lead to environmental pollution,high energy-consumption,high-cost and other undesirable issues.Besides,the durability of superhydrophobic coating also plagues its commercial application.In this paper,we introduced a facile and environment-friendly technique for fabricating abrasion-resistant superhydrophobic surfaces using thermoplastic polyurethane(TPU)and modified SiO_(2)particles(SH-SiO_(2)).Both materials are non-toxicity,low-cost,and commercial available.Our methodology has the following advantages:use of minimal amounts of formulation,take the most streamlined technical route,and no waste material.These advantages make it attractive for industrial applications,and its usage sustainability can be promised.In this study,the mechanical stability of the superhydrophobic surface was evaluated by linear wear test.It is found that the excellent wear resistance of the superhydrophobic coating benefits from the characteristics of raw materials,the preparation strategy,and the special structure.In anti-icing properties test,the TPU/SH-SiO_(2)coating exhibits the repellency to the cold droplets and the ability to extend the freezing time.The electrochemical corrosion measurement shows that the asprepared superhydrophobic surface has excellent corrosion resistance that can provide effective protection for the bare Q235 substrates.These results indicate that the TPU/SH-SiO_(2)coating possesses good abrasion resistance and has great potential in anti-corrosion and anti-icing applications.

Abrasion Resistant Refractory Materials

1 Scope This standard specifies the definition, classification, technical requirements, test methods, quality appraisal procedure, packing, marking, transportation, storage, and quality certificate of abrasion resistant refractory materials.

Wire arc additive manufacturing of a heat-resistant Al-Cu-Ag-Sc alloy:microstructures and high-temperature mechanical properties

With a high energy efficiency,low geometric limitation,and low cracking susceptivity to cracks,wire arc additive manufacturing(WAAM)has become an ideal substitute for casting in the manufacturing of load-bearing high strength aluminum components in aerospace industry.Recently,in scientific researches,the room temperature mechanical performance of additive manufactured high strength aluminum alloys has been continuously broken through,and proves these alloys can achieve comparable or even higher properties than the forged counterpart.Since the aluminum components for aerospace usage experience high-low temperature cycling due to the absence of atmosphere protection,the high temperature performances of additive manufactured high strength aluminum alloys are also important.However,few research focuses on that.A special 2319Ag Sc with 0.4 wt.%Ag and 0.2 wt.%Sc addition designed for high temperature application is deposited successfully via cold metal transfer(CMT)based on WAAM.The microstructures and high temperature tensile properties are investigated.The results show that the as-deposited 2319Ag Sc alloy presents an alternate distribution of columnar grains and equiaxed grains with no significant textures.Main second phases are Al_(2)Cu and Al3Sc,while co-growth of Al_(2)Cu and bulk Al_(3)Sc is found on the grain boundary.During manufacturing,nanoscale Al_(2)Cu can precipitate out from the matrix.Ag and Mg form nano-scaleΩphase on the Al_(2)Cu precipitates.At 260℃,average yield strengths in the horizontal direction and vertical direction are 87 MPa±2 MPa,87 MPa±4 MPa,while average ultimate tensile strengths are 140 MPa±7 MPa,141 MPa±11 MPa,and average elongations are 11.0%±2.5%,13.5%±3.0%.Anisotropy in different directions is weak.

Effects of additives on corrosion and wear resistance of micro-arc oxidation coatings on TiAl alloy

Ceramic coating was deposited on TiAl alloy substrate by micro-arc oxidation(MAO)in a silicate-aluminate electrolyte solution with additives including sodium citrate,graphite and sodium tungstate.The microstructures and compositions were analyzed by SEM,EDX and XRD.The corrosion and wear properties of the coatings were investigated by potentiodynamic polarization and ball-on-disc wear test,respectively.The results show that the MAO coatings consist of WO3,Ti2O3,graphite and Al2O3 besides Al2TiO5 and Al2SiO5.With additives in the electrolyte,the working voltage at the micro-arc discharge stage decreases,and the ceramic coating gets smoother and more compact.The corrosion current density of MAO coating is much lower than that of TiAl substrate.It can be reduced from 9.81×10-8A/cm 2to 3.02×10-10A/cm 2 .The MAO coatings composed of hard Al2O3,WO3 and Ti2O3 obviously improve the wear resistance of TiAl alloy.The wear rate is-3.27×10-7g/(N·m).

Influence of secondary carbide precipitation and transformation on abrasion resistance of a 3Cr15Mo1V1.5 white iron

The relationship between the secondary carbide precipitation and transformation of the 3Cr15Mo1V1.5 white iron and abrasion resistance was investigated by using optical microscope （OM）, transmission electron microscopy （TEM） and X-ray diffrac- tion （XRD）. The results show that the properties of secondary carbides precipitated at holding stage play an important role in the abrasion resistance. After certain holding time at 833 K subcritical treatment, the grainy （Fe, Cr）23C6 carbide precipitated and the fresh martensite transformed at the holding stage for 3Cr15Mo1V1.5 white iron improve the bulk hardness and abrasion resistance of the alloy. Prolonging holding time, MoC and （Cr, V）2C precipitations cause the secondary hardening peak and the corresponding better abrasion resistance. Finally, granular （Fe, Cr）23C6 carbide in situ transforms into laminar M3C carbide and the matrix structure transforms into pearlitic matrix. These changes weaken hardness and abrasion resistance of the alloy sharply.

Influences of Polypropylene Fiber and SBR Polymer Latex on Abrasion Resistance of Cement Mortar

Influences of polypropylene （PP） fiber and styrene-butadiene rubber （SBR） polymer latex on the strength performance, abrasion resistance of cement mortar were studied. The experimental results show that the flexural strength, brittleness index （σF/σC） and abrasion resistance can be improved significantly by the addition of PP fiber and SBR polymer latex. The relationship between the flexural strength and abrasion resistance was analyzed, showing a good linear relationship between them. The reinforced mechanism of PP fiber and SBR polymer latex on cement mortar was analyzed by some microscopic tests. The test results show that the addition of SBR polymer latex has no significant influence on the cement hydration after 7 d curing. Adding SBR polymer latex into cement mortar can form a polymer transition layer in the interfaces of PP fiber and cement hydrates, which improves the bonding properties between the PP fiber and cement mortar matrix effectively.

The Abrasion-resistance Investigation of Rubberized Concrete

The abrasion resistance properties of rubberized concrete were comparatively studied by taking silica fume and crumb tire rubber as the additives. The abrasion tests were conducted in accordance with the Chinese standard test method DL/T 5150 - 2001, two recommended test methods： under water method and ring method, were used. The crumb tire rubbers with the sieve size of 8-mesh and 16-mesh were incorporated into the concrete by replacing same volume of sand and as an additive. The abrasion resistance of concrete was evaluated according to the abrasion resistance strength and the mass loss. Test results show that the addition of silica fume enhanced both compressive strength and abrasion resistance of concrete, and the addition of crumb rubber reduced the compressive strength but increased notably the abrasion resistance of the concrete. Silica fume concrete performed a better abrasion resistance than control concrete, and the rubberized concrete performed a much better abrasion resistance than silica fume concrete. The abrasion resistance of rubberized concrete increased with the increase of rubber content.

Effects of Nano Chinese Herbal Medicine Feed Additive on Growth Performance,Meat Quality and Disease Resistance of Chickens

[Objectives]To explore the effects of nano compound Chinese herbal medicine feed additive on growth performance,meat quality and disease resistance of chickens.[Methods]Chickens were fed with nano compound Chinese herbal medicine feed additive developed by Hunan Polytechnic of Environment and Biology,including 120 chickens in the treatment group and 120 chickens in the control group(CK).The growth performance indices(body weight gain,feed to gain ratio and slaughter index),meat quality indices(pH value,color,drip loss,shear force)and disease resistance indices(morbidity and mortality)of the chickens in the treatment and CK groups were recorded and determined,respectively.[Results]The inclusion of 2%nano compound Chinese herbal medicine feed additive in the diet significantly increased the growth rate,reduced the feed-to-gain ratio and improved the meat quality of the chickens.Supplementing Chinese herbal medicine could increase the pH value and reduce the drip loss and shear force of chicken meat.At the same time,the body's immune function,antioxidant level and resistance against diseases of the chickens fed with nano compound Chinese herbal medicine feed additive were improved.[Conclusions]The inclusion of nano compound Chinese herbal medicine feed additive in the diet can improve the growth performance,meat quality and disease resistance of chickens.

Microstructure and Corrosion Resistance of Arc Additive Manufactured 316L Stainless Steel

The gas tungsten arc welding based additive manufacturing (GTAW-AM) was carried out by printing 316L austenitic stainless steel on carbon steel substrate with different arc currents (140,160,180 A).Microstructure and corrosion resistance of additive manufactured components were investigated.The results show that the microstructure of the GTAW-AM austenitic stainless steel is obviously changed by the arc current.With arc current increasing from 140 to 180 A,the austenite grains become coarse due to the effect of welding heat input.Meanwhile,the quantity of ferrites in the austenite matrix is decreased and the morphology transforms from lath to skeleton.Moreover,σ phases are finally formed under the arc currents of 180 A owing to high welding heat input.Therefore,as the microstructure transform into coarse-grained austenites,low-quantity ferrites and new-generated σ phases,the GTAW-AM austenitic stainless steel presents a significantly decrease in corrosion resistance.And the reduction of corrosion resistance is mainly due to the formation of σ phase as a result from consuming the large amounts of Cr element from the matrix.

Relations of abrasion resistance and hardness of 16Cr-3C white irons with retained austenite content

The relationship between the retained austenite content of the matrix in16Cr-3C white irons and the abrasion resistance was investigated. The results show that: (1) theabrasion resistance can be improved by sub-critical heat treatment, which could be attributed to thedecrease of the retained austenite content; (2) both the abrasion resistance and hardness can beimproved by controlling the retained austenite content below 20 percent-30 percent and arrive at themaximum when the retained austenite content is reduced to about 10 percent; (3) the abrasionresistance decreases abruptly once the retained austenite content is lower than 10 percent, whichstems from both the in situ transformation of (Fe, Cr)_(23)C_6 to M_3C carbides and the formation ofpearlitic matrix.

Effect of additive on corrosion resistance of NiFe_2O_4 ceramics as inert anodes

In order to improve the corrosion resistance of NiFe2O4 ceramics as inert anode,additive V2O5 was added to raw materials NiO and Fe2O3.The inert anodes of nickel-ferrite ceramics were prepared by powder metallurgic method and the static corrosion rate in Na3AlF6-Al2O3 was determined by mass loss measurement.The effect of V2O5 on sintering property and corrosion resistance was studied.The results show that V2O5 can promote the grain to develop completely and improve sintering property.EDS results show the reaction product Ni2FeVO6 distributes along the grain boundary.The corrosion tests show that V2O5 is beneficial to improving corrosion resistance remarkably.The reasons that V2O5 can improve the corrosion resistance must be V2O5 promoting the gains to develop completely and Ni2FeVO6 distributes along the grain boundary.The stable structure can control the chemical dissolution of ceramics anode and the reinforced grain boundary can control the grain-boundary corrosion rate.

Study on Abrasion Resistance of Modified Polypropylene Fiber Reinforced Cement

Modified polypropylene fiber reinforced cement compos-ites were investigated in their abrasion resistance andsurface morphology. The test results showed the addingof fiber could noticeably improve the abrasion resistanceof composite. The bonding and friction of fibers/cementwere the main contribution to abrasion resistance im-provement, which resulted from the surface morphologyobservation.

Research of Test Method on Abrasion Resistance at Elevated Temperatures of Refractories

In this work,the factors and parameters of a test method on abrasion resistance at elevated temperatures were discussed and researched.First of all,the precision tests of the test method on abrasion resistance at elevated temperatures were conducted in 8 laboratories.The results such as the standard deviation and reproducibility show good repeatability and reliability.The relationship between the stability of refractory performance and the standard deviation of their wear value was analyzed.Then the impact of the heat treatment condition of unshaped refractories and oxidation of SiC sand as abrasive on the lost volume of the tested specimens was researched.

A New Test Method for Hot Abrasion Resistance on Refractories

Test methods for hot abrasion resistance of refractories in China and overseas were briefly introduced. A new test method for hot abrasion resistance was researched. The new method inherits test principle of cold abrasion resistance in Chinese standard totally, adopts compressed air pre-heating and electricity heating sam- ples, and is featured with complete structure, good con- trollability, simple operation, and small size. The characteristics and operating procedure of HAT-14A tester were introduced. The hot abrasion resistance of various refractories at different temperatures was tested.

Abrasion Resistance of Cement Paste with Granulated Blast Furnace Slag and Its Relations to Microhardness and Microstructure

The abrasion resistance of cement pastes with 30 wt%,40 wt%and 50 wt%granulated blast furnace slag(GBFS),and its relations to microhardness and microstructure like hydration products and pore structure were studied.Results indicated that GBFS decreased the abrasion resistance of paste,and among the pastes with GBFS,the paste with 40 wt%GBFS showed the highest abrasion resistance.The microhardness of GBFS was lower than that of the cement,and the microhardness of the hydration products in paste with GBFS was also lower than that of the hydration products in paste without GBFS,so that the abrasion resistance of paste decreased when GBFS was incorporated.The reason for the decrease of microhardness of pastes with GBFS was that the contents of Ca(OH)_(2)in pastes with GBFS was significantly lower than that in the paste without GBFS,while large amounts of calcium aluminate hydrates and hydrotalcite-like phases(HT)in pastes with GBFS were generated.Furthermore,among the pastes with GBFS,the paste with 40 wt%GBFS showed the lowest porosity which was the main reason for its highest abrasion resistance.

Performance comparison of training algorithms for the estimation of B?hme abrasion resistance using neural networks

Natural stones used as floor and wall coverings are exposed to many different abrasive forces,so it is essential to choose suitable materials for wear resistance in terms of the life of the structure.The abrasion resistance of natural stones can be determined in the laboratory by applying the B?hme abrasion resistance(BAR)test.However,the direct analysis of BAR in the laboratory has disadvantages such as wasting time and energy,experimental errors,and health impacts.To eliminate these disadvantages,the estimation of BAR using artificial neural networks(ANN)was proposed.Different natural stone samples were collected from Türkiye,and uniaxial compressive strength(UCS),flexural strength(FS),water absorption rate(WA),unit volume weight(UW),effective porosity(n),and BAR tests were carried out.The outputs of these tests were gathered and a data set,consisting of a total of 105 data,was randomly divided into two groups:testing and training.In the current study,the success of three different training algorithms of Levenberg-Marquardt(LM),Bayesian regularization(BR),and scaled conjugate gradient(SCG)were compared for BAR prediction of natural stones.Statistical criteria such as coefficient of determination(R~2),mean square error(MSE),mean square error(RMSE),and mean absolute percentage error(MAPE),which are widely used and adopted in the literature,were used to determine predictive validity.The findings of the study indicated that ANN is a valid method for estimating the BAR value.Also,the LM algorithm(R~2=0.9999,MSE=0.0001,RMSE=0.0110,and MAPE=0.0487)in training and the BR algorithm(R~2=0.9896,MSE=0.0589,RMSE=0.2427,and MAPE=1.2327)in testing showed the best prediction performance.It has been observed that the proposed method is quite practical to implement.Using the artificial neural networks method will provide an advantage in similar laborintensive experimental studies.

Effect of the CaF_2-fraction in the glass-ceramic with abrasion resistance on crystallization

Investigated the effect of an addition of CaF2 on the crystallization of a glass-ceramic with abrasion resistance. X-ray diffraction, differential thermal analysis and scanning electron microscopy were used to determine the effect. The results showed that a suitable addition of CaF2 promoted crystallization by forming an interme- diate crystalline phase. CaF2 can decrease the temperature and active energy of the base-glass for crystallization. When 4 mass-% of CaF2-fraction is added in the glass, the crystallization temperature and active energy is 936 ℃and 172.75 kJ/mol respectively. When CaF2 is increased to 6 mass-%, the temperature and active energy decrease to 890 ℃ and 88.81 kJ/mol. CaF2 is an efficient nucleating agent for the glass-ceramics with abrasion resistant, the optimal content of CaF2 is about 6 mass-%.

Mechanism of C_(4)AF Content and Heat-curing Process on the Abrasion Resistance of High Ferrite Cement

Cement used in severe maritime environments must be attached with exceptional properties such as high sulfate resistance and abrasion strength.A sulfate resistant material typically used in marine engineering is high ferrite cement,which has been utilized in sulfate-rich environments.This study aims at exploring the effect of C_(4)AF and heat-curing on the abrasion resistance of high ferrite cement(HFC,C_(4)AF:14%-22%)in order to have a comprehensive understanding of this mechanism and promote the application of HFC in marine engineering.A new invention was designed for the abrasion resistance device by considering the sea-wave abrasion and seawater erosion in laboratory.The compressive strength and abrasion resistance of HFC were measured.Additionally,advanced analytical methods were used to explore the abrasion resistance mechanism of HFC,including X-ray fluorescence(XRF),X-ray diffraction(XRD),and thermogravimetric(TG)analyses,as well as mercury intrusion porosimetry(MIP).The results showed that HFC had the best abrasion resistance under appropriate heat-curing system that the curing temperature was 50℃and the hosting time was 4 hours,compared with PI(Portland cement)and LHC(low heat cement),meanwhile the abrasion resistance of HFC had a 62.4%increase when C_(4)AF content is increased from 14%to 22%.It can be ascribed that the content of portlandite is decreased due to the increase of C_(4)AF,which can reduce the portlandite assembled in ITZ(interfacial transition zone).It can also be ascribed that the DEF(delayed ettringite formation)is successfully avoided in HFC and the hydration degree of HFC can continue to be boosted under appropriate heat-curing system.

Compressive Strength and Abrasion Resistance of Concretes under Varying Exposure Conditions

The purpose of this study is to comparatively evaluate the wear resistance of concretes under abrasion rates. Five concrete mix proportions of a fixed water-cement ratio of 0.45 were considered in the study, but the constituent materials, age of concrete and exposure contact conditions were varied. The coarse aggregate type employed in the study was crushed granite. The compressive strength and abrasion resistance of concretes were tested between at ages 7 to 70 days and 100 - 500 revolutions of abrasion wheels respectively. The study revealed that the compressive strength and abrasion resistance had the optimal performance when the coarse aggregate content was 45% and the worst performance when the fine aggregate content was 28.7% of the total weight of concrete constituents. There was a remarkable loss of concrete particles to wear between 200 revs and 300 revs of abrasion wheel contact. Concrete grade in excess of 60 N/mm2 is required to resist abrasion beyond 200 revolutions of abrasion wheel contact on concrete specimens. Concretes investigated also showed weak resistance to deep abrasion at and above 300 revolutions of abrasion wheel contact.