Employing carbonyl iron powder and Ethylene-Propylene-Diene Monomer (EPDM) as the absorbent and matrix, rubber radar absorbing materials (RAM) were prepared. Effects of the carbonyl iron volume fraction and the th...Employing carbonyl iron powder and Ethylene-Propylene-Diene Monomer (EPDM) as the absorbent and matrix, rubber radar absorbing materials (RAM) were prepared. Effects of the carbonyl iron volume fraction and the thickness of the RAM on the microwave absorption properties in the frequency range of 2.6-18GHz were studied, and a mathematical analysis was made using the electromagnetic theory. The experimental results indicate that the minimum reflectivity of the radar absorbing materials continuously decreases with the increase of the carbonyl iron volume fraction, and the absorption peak also moves towards the low frequency for the same thickness of the RAM. The minimum reflectivity of the 3.0 mm RAM is -21.7dB at 3.5 GHz when the volume fraction of carbonyl iron is 45%. The reflectivity of the RAM is not in direct proportional to the thickness of the RAM, when the RAM has the same volume fraction of the carbonyl iron. The reflectivity of the RAM presents a regular trend at a given carbonyl iron volume fraction in the frequency range of 2.6-18 GHz. With the increase of the thickness, the maximum absorption peak moves towards low frequency band, the minimum reflectivity firstly decreases and then increases, and the absorption bandwidth for reflectivity〈-10 dB firstly increases and then decreases. The microwave absorption properties of the RAM are determined by the thickness and the composition of the radar absorbing materials. Theoretical analysis indicates that the reflectivity of the RAM is determined by the matching degree of the air's characteristic impedance and the input impedance.展开更多
Magnesium-substituted Mn0.8Zn0.2Fe2O4 ferrite is synthesized by the sol–gel combustion method using citrate acid as the complex agent. The electromagnetic absorbing behaviors of ferrite/polymer coatings fabricated by...Magnesium-substituted Mn0.8Zn0.2Fe2O4 ferrite is synthesized by the sol–gel combustion method using citrate acid as the complex agent. The electromagnetic absorbing behaviors of ferrite/polymer coatings fabricated by dispersing Mn–Zn ferrite into epoxy resin (EP) are studied. The microstructure and morphology are characterized by X-ray diffraction and scanning electron microscope. Complex permittivity, complex permeability, and reflection loss of ferrite/EP composite coating are investigated in a low frequency range. It is found that the prepared ferrite particles are traditional cubic spinel ferrite particles with an average size of 200 nm. The results reveal that the electromagnetic microwave absorbing properties are significantly influenced by the weight ratio of ferrite to polymer. The composites with a weight ratio of ferrite/polymer being 3:20 have a maximum reflection loss of –16 dB and wide absorbing band. Thus, the Mn–Zn ferrite is the potential candidate in electromagnetic absorbing application in the low frequency range (10 MHz–1 GHz).展开更多
Microwave absorbing materials(MAMs)are playing an increasingly essential role in the development of wireless communications,high-power electronic devices,and advanced target detection technology.MAMs with a broad-band...Microwave absorbing materials(MAMs)are playing an increasingly essential role in the development of wireless communications,high-power electronic devices,and advanced target detection technology.MAMs with a broad-bandwidth response are particularly important in the area of communication security,radiation prevention,electronic reliability,and military stealth.Although considerable progress has been made in the design and preparation of MAMs with a broad-bandwidth response,a number of challenges still remain,and the structure–function relationship of MAMs is still far from being completely understood.Herein,the advances in the design and research of MAMs with a broad-bandwidth response are outlined.The main strategies for expanding the effective absorption bandwidth of MAMs are comprehensively summarized considering three perspectives:the chemical combination strategy,morphological control strategy,and macrostructure control strategy.Several important results as well as design principles and absorption mechanisms are highlighted.A coherent explanation detailing the influence of the chemical composition and structure of various materials on the microwave absorption properties of MAMs is provided.The main challenges,new opportunities,and future perspectives in this promising field are also presented.展开更多
(B4C+Al2O3)/Al composite designed for the dry storage of spent nuclear fuels was fabricated and then subjected to friction stir welding, at a welding speed of 100 mm/min and rotation rates of 400–800 r/min. Sound joi...(B4C+Al2O3)/Al composite designed for the dry storage of spent nuclear fuels was fabricated and then subjected to friction stir welding, at a welding speed of 100 mm/min and rotation rates of 400–800 r/min. Sound joints were obtained under all welding parameters;however, significant softening occurred in the nugget zone(NZ) for all the joints. Therefore, all the joints exhibited significantly decreased strength at both room temperature and high temperature compared with the base metal, with the joints fracturing in the NZs. Rotation rate exhibited no obvious effect on the tensile strength of the joints, but led to increased elongation as the result of the broadened NZs. The detailed microstructural examinations indicated that the welding thermomechanical effect broke up the near 3D amorphous Al2O3 netlike structure distributed at the Al grain boundaries, caused the coarsening of Al grains, and the agglomeration and crystallization of amorphous Al2O3, thereby resulting in the softening of the NZs and the reduction in the joint strength. Consequently, inhibiting the breakup and crystallization of 3D amorphous Al2O3 netlike structure is the key factor to improve the joint strength of the(B4C+Al2O3)/Al composite.展开更多
B4C reinforced Al composites are widely used as neutron absorbing materials(NAMs)due to excellent neutron absorbing efficiency,however,such NAMs exhibit poor high-temperature properties.To meet the requirement for str...B4C reinforced Al composites are widely used as neutron absorbing materials(NAMs)due to excellent neutron absorbing efficiency,however,such NAMs exhibit poor high-temperature properties.To meet the requirement for structure-function integration,NAMs with enhanced high-temperature mechanical properties are desired.In this work,a novel(B4 C+Al_(2)O_(3))/Al NAM with netlike distribution of Al_(2)O_(3)was fabricated by powder metallurgy method and subjected to high-temperature tensile creep test.It was shown that the creep resistance was enhanced by several orders of magnitude via the addition of only2.1 vol.%netlike-distributed Al_(2)O_(3).(B_(4)C+Al_(2)O_(3))/Al exhibited high apparent stress exponents ranging from 16 to 25 and high apparent activation energy of 364 kJ/mol.The creep behaviour could be rationalized using the substructure-invariant model and its rupture behaviour could be described by the Dobes-Milicka equation.展开更多
Using the multi-physical field simulation software COMSOL,the acoustic characteristics of the multilayer sound absorbing material straight-through perforated pipe muffler are studied by the finite element method.The r...Using the multi-physical field simulation software COMSOL,the acoustic characteristics of the multilayer sound absorbing material straight-through perforated pipe muffler are studied by the finite element method.The results show that the finite element calculation of the multilayer sound absorbing material straight-through the perforated pipe muffler agrees well with the experimental measurement results.The reliability of the finite element method for studying the acoustic performance of the straight-through perforated pipe muffler with multilayer sound absorbing materials is shown.Furthermore,the influence of some structural parameters of porous sound absorbing material and micro-perforated plate on the acoustic performance of the multilayer sound absorbing material straight-through perforated pipe muffler is analyzed.The muffler based on multilayer sound absorbing material is different from the traditional muffler.After applying the multilayer sound absorbing material to the straight-through perforated pipe muffler,the transmission loss value greatly increases,which provides new ideas and directions for future research on the muffler.展开更多
The structure and electrochemical properties of nanocrystalline LaNi_5-type alloys were studied. These materials were prepared by mechanical alloying (MA) followed by annealing. The properties of hydrogen host materia...The structure and electrochemical properties of nanocrystalline LaNi_5-type alloys were studied. These materials were prepared by mechanical alloying (MA) followed by annealing. The properties of hydrogen host materials can be modified substantially by alloying to obtain the desired storage characteristics. It was found that the partial substitution of Ni by Al or Mn in LaNi_(5-x)M_x alloy leads to an increase in discharge capacity. The alloying elements such as Al, Mn and Co greatly improved the cycle life of LaNi_5 material. For example, in the nanocrystalline LaNi_(3.75)Mn_(0.75)Al_(0.25)Co_(0.25) powder, discharge capacity up to 258 mAh·g^(-1) was measured (at 40 mA·g^(-1) discharge current). Furthermore, the effect of the graphite coating on the structure of some nanocrystalline alloys and the electrodes characteristics were investigated. The mechanical coating with graphite effectively reduced the degradation rate of the studied electrode materials. The combination of a nanocrystalline LaNi_5-type hydride electrodes and a nickel positive electrode to form a Ni-MH battery, was successful.展开更多
The in-situ synthesized mullite bonded SiC ceramics for solar thermal tower plant were prepared from Silicon carbide (SIC), manufactured aluminum hydroxide (Al(OH)3) and Suzhou kaolin via semi-dry pressing and p...The in-situ synthesized mullite bonded SiC ceramics for solar thermal tower plant were prepared from Silicon carbide (SIC), manufactured aluminum hydroxide (Al(OH)3) and Suzhou kaolin via semi-dry pressing and pressureless firing. The results indicate that sample B3 (designed mullite content 15 wt%) fired at 1 400 ℃ exhibited optimal performance with a bending strength of 97.41 MPa. Sample B3 can withstand 30-cycles thermal shock without cracking (wind cooling from 1 100 ℃ to room temperature), and the bending strength after thermal shock decreased by 17.92%. When the service temperature is 600℃, the thermal diffusivity, specific heat capacity, thermal conductivity and heat capacity are 6.48× 10-2 cm:.s-1, 0.69 kJ·kg-1. K-1, 9.62 W·m-1·K-1 and 977.76 kJ·kg-1, respectively. The XRD and SEM results show that SiC, mullite, or-quartz, and tridymite are connected closely, which gives the material a good bending strength. After 30-time thermal shock cycles, the structure of samples becomes loose. SiC grains are intersectingly arranged with rodshape mullite, exhibiting a favorable thermal shock resistance. The addition of Al(OH)3 and Suzhou kaolin can accelerate the synthesis of mullite, thus to reduce the firing temperature effectively. The volume effect of tfidymite is relatively small, improving the thermal shock resistance of materials. A higher designed muUite content yields a lower loss rate of bending strength. The mullite content should not be more than 15 wt% or else the bending strength would be diminished.展开更多
Al2O3/TiOe/FeeO3/Yb2O3 composite powder was synthesized via the sol-gel method. The structure, morphology, and ra- dar-absorption properties of the composite powder were characterized by transmission electron microsco...Al2O3/TiOe/FeeO3/Yb2O3 composite powder was synthesized via the sol-gel method. The structure, morphology, and ra- dar-absorption properties of the composite powder were characterized by transmission electron microscopy, X-ray diffraction analysis and RF impedance analysis. The results show that two types of particles exist in the composite powder. One is irregular flakes (100-200 rim) and the other is spherical A1203 particles (smaller than 80 rim). Electromagnetic wave attenuation is mostly achieved by dielectric loss. The maximum value of the dissipation factor reaches 0.76 (at 15.68 GHz) in the frequency range of 2-18 GHz. The electromagnetic absorption of waves covers 2-18 GHz with the matching thicknesses of 1.5-4.5 mm. The absorption peak shifts to the lower-frequency area with increas- ing matching thickness. The effective absorption hand covers the frequency range of 2.16-9.76 GHz, and the maximum absorption peak reaches -20.18 dB with a matching thickness of 3.5 mm at a frequency of 3.52 GHz.展开更多
The experiment samples of La1-xSrxMn1-y FeyO3(x = 0. 15, 0.20, 0.23; y = 0. 10, 0. 12, 0.14, 0.16) were prepared by sol-gel process, and the loss tangent and absorption coefficient in the range of 2 - 18 GHz were me...The experiment samples of La1-xSrxMn1-y FeyO3(x = 0. 15, 0.20, 0.23; y = 0. 10, 0. 12, 0.14, 0.16) were prepared by sol-gel process, and the loss tangent and absorption coefficient in the range of 2 - 18 GHz were measured by HP8722 net analyzing apparatus. It is found that changing the content of Sr or Fe would effect the microwave absorbing. When the thickness of La1-x SrxMn1-y FeyO3 is 2 mm and x =0.20, y = 0.14, the capability of microwave absorbing is the best one. There are two absorption peaks; the maximum is 34 dB and effective band width with 10 dB and more reaches 6.2 GHz.展开更多
A two-dimensional metal model is established to investigate the stealth mechanisms of radar absorbing material (RAM) and plasma when they cover the model together. Using the finite-difference time-domain (FDTD) me...A two-dimensional metal model is established to investigate the stealth mechanisms of radar absorbing material (RAM) and plasma when they cover the model together. Using the finite-difference time-domain (FDTD) method, the interaction of electromagnetic (EM) waves with the model can be studied. In this paper, three covering cases are considered: a. RAM or plasma covering the metal solely; b. RAM and plasma covering the metal, while plasma is placed outside; e. RAM and plasma covering the metal, while RAM is placed outside. The calculated results show that the covering order has a great influence on the absorption of EM waves. Compared to case a, case b has an advantage in the absorption of relatively high-frequency EM waves (HFWs), whereas case c has an advantage in the absorption of relatively low-frequency EM waves (LFWs). Through the optimization of the parameters of both plasma and RAM, it is hopeful to obtain a broad absorption band by RAM and plasma covering. Near-field attenuation rate and far-field radar cross section (RCS) are employed to compare the different cases.展开更多
The multilayer impedance composite sound absorption structure of the new muffler is proposed by combining the microporous plate structure with the resonant sound absorption structure of the porous material.Firstly,the...The multilayer impedance composite sound absorption structure of the new muffler is proposed by combining the microporous plate structure with the resonant sound absorption structure of the porous material.Firstly,the acoustic impedance and acoustic absorption coefficient of the new muffler structure are calculated by acoustic electric analogy method,and then the noise attenuation is calculated.When the new muffler structure parameters change,the relationship among the noise frequency,the sound absorption coefficient and the noise attenuation is calculated by using MATLAB.Finally,the calculated results are compared with the experimental data to verify the correctness of the theoretical calculation.The variation of resonance peak,resonance frequency and attenuation band width of each structural parameter is analyzed by the relation curve.The conclusion shows that it is feasible to use multilayer sound absorbing materials as the body structure of the new muffler.And the influence relationship between the change of various parameters of the sound absorption structure with the sound absorption coefficient and noise attenuation is obtained.展开更多
Objective:To study the effects of absorbable materials in non-weight-bearing bone fractures of extremities.Methods:After 66 patients with nonweight-bearing bone fractures of extremities were selected,absorbable materi...Objective:To study the effects of absorbable materials in non-weight-bearing bone fractures of extremities.Methods:After 66 patients with nonweight-bearing bone fractures of extremities were selected,absorbable materials were used in the observation group and metal materials were used in the control group.Results:After treatment,the bone healing in the observation group was significantly improved(P<0.05).Conclusion:the application of absorbable materials in non-weight-bearing bone fractures of extremities is effective.展开更多
Anisotropic powder was prepared with precursor (NdDy)-(FeCoNbCu)-B sintered magnets by hydrogen decrepitation, desorption, and subsequent annealing treatment. The hydrogen desorption was performed in magnetic fiel...Anisotropic powder was prepared with precursor (NdDy)-(FeCoNbCu)-B sintered magnets by hydrogen decrepitation, desorption, and subsequent annealing treatment. The hydrogen desorption was performed in magnetic fields of 0, 1, 3, and 5 T. The orientation of tetragonal phase grains of the powder was evaluated from the hysteresis loops measured by extraction magnetometer. Residual hydrogen content of the powder was evaluated by thermal-magnetic analysis. The powder with Hcj, Br, and (BH)max of 1138 kA.m^-1, 1.029 T, and 172.5 kJ.m^-3, respectively, was achieved under the condition of the magnetic field of 3 T. Magnetic properties of the powder, especially, the remanence of the powder, are enhanced upon magnetic fields, which is due to better orientation of powder particles and less residual hydrogen in the powder resulted from the magnetic field during the hydrogen desorption process.展开更多
For enhancing the electromagnetic wave(EW)attenuation and adsorption,rational constructing and homogeneously distributing bimetallic electromagnetic coupling units in hollow structure is an effective way,but hard to a...For enhancing the electromagnetic wave(EW)attenuation and adsorption,rational constructing and homogeneously distributing bimetallic electromagnetic coupling units in hollow structure is an effective way,but hard to achieve.Herein,a CoNi-doped hybrid zeolite imidazole framework was synthesized as precursor,which was further converted into a hollow CoNi-bimetallic doped molyb-denum carbide sphere(H-CoNi@MoC/NC)through a two-step etching and calcination strategy.At the loading amount of 15 wt%,a strong absorption of minimum reflection loss(RL_(min))of-60.05 dB at 7.2 GHz with the thickness of 3.1 mm and a wide effective ad-sorption bandwidth(EAB)of 3.52 GHz at the thickness of 2.5 mm were achieved,which was far beyond the reported MoC-based metallic hybrids.The crucial synergistic Co-Ni electromagnetic coupling effect in the composite was characterized,not only enhanc-ing the dipolar/interfacial polarization,but also promoting the impedance matching,displaying the optimized EW absorbing perfor-mance.展开更多
Based on a first-order state-vector differential equation representation of Maxwell's equations, an analytical formulation is derived for the equivalent currents on an anisotropic material backed by a metal surfa...Based on a first-order state-vector differential equation representation of Maxwell's equations, an analytical formulation is derived for the equivalent currents on an anisotropic material backed by a metal surface, and the relation between two currents is also considered. These expressions are degenerated into the common forms for some simple cases. This effort will provide the theoretical preparation for the approximate calculation of electromagnetic scattering from a conducting object coated by an anisotropic material.展开更多
The article presents problems related to mechanical protection of vehicles with different add-on armours against chemical,biological and radiological contamination.This applies to vehicles with additional passive,reac...The article presents problems related to mechanical protection of vehicles with different add-on armours against chemical,biological and radiological contamination.This applies to vehicles with additional passive,reactive and hybrid protection in the form of cassettes against piercing with anti-tank projectiles,piercing with their kinetic energy of impact,and as a result of chemical energy of shaped charges as well as explosively formed projectiles.It has been shown how increased ballistic protection of these vehicles at the same time reduces their decontaminability in various places of the vehicle due to the increased additional surface of the vehicle with cassettes.Prevention of contamination of these cassettes has been presented as a way of reducing hard to reach surface for decontamination and a method of insulating construction elements(stands),fixing these cassettes to the vehicle,from the environment to prevent contact with contaminated liquids and dusts.The selection of appropriate materials is shown,which may affect the improvement of the decontamination efficiency of the vehicle with such cassettes.This applies to the use of materials with low absorption of chemical warfare agents,which prevent the accumulation of large amounts of these agents on contaminated surfaces and improve the effectiveness of decontamination.It also shows how to ensure better access of the disinfectant to as much of the vehicle surface as possible,covered with cassettes that have been contaminated.It shows how a vehicle,in particular with such cassettes,can provide protection against radar detection when Radar Absorbent Material is used on vehicle cassettes.展开更多
A novel bunched cerium oxide(CeO_(2))was prepared and its binary composite material with multi-walled carbon nanotubes presented an excellent microwave absorbing properties.The morphology,structure,and absorbing prope...A novel bunched cerium oxide(CeO_(2))was prepared and its binary composite material with multi-walled carbon nanotubes presented an excellent microwave absorbing properties.The morphology,structure,and absorbing properties of the composite material were investigated.It was found that the minimum reflection loss(RL)of the composite material at 15.79 GHz was−45.7 dB when the thickness was 5.5 mm.It was worth noting that when the composite material was in the thickness range of 5.0-7.5 mm and the frequency was 11.36-17.77 GHz,the electromagnetic wave RL was<−30 dB,which illustrated that the composite material had a good absorbing effect over a wide thickness range.The results of the study contributed to the design and preparation of efficient microwave absorbing materials(MAM)with rare earth oxide composites and their applications,which demonstrated the importance of new composites with special structures in the field of MAM.展开更多
To develop a new generation of absorbable fracture fixation devices with enhanced biocompatibility, the biodegradation mechanism and its influence on the cellular response at the tissue/implant interface of hydroxyapa...To develop a new generation of absorbable fracture fixation devices with enhanced biocompatibility, the biodegradation mechanism and its influence on the cellular response at the tissue/implant interface of hydroxyapatite/ poly DL lactide (HA/PDLLA) composites were investigated in vitro and in vivo.HA/PDLLA rods were immersed in phosphate buffered saline,or implanted in muscle and bony tissue for 52 weeks.Scanning electron microscopic and histological studies were done.The degradation rate was the slowest in vitro,slower in muscle tissue and fast in bone.In vitro, the composites degraded heterogeneously and a hollow structure was formed.In bone,the limited clearing capacity leads to the accumulation of oligomeric debris,which contribute totally to the autocatalytic effect.So,the fastest degradation and intense tissue response were seen.In muscle tissue,oligomeric debris migrated into vicinal fibers over a long distance from the original implant cavity and the tissue reactions were,however, quite moderate.For the same size organic/inorganic composite,the environment where it was placed is the major factor in determining its biodegradation process and cellular reaction.In living tissue,factors such as cells,enzymes and mechanical stress have an obvious influence on the biodegradation and biological process at the tissue/implant interface.The biocompatibility of the HA/PDLLA composites is enhanced with the incorporating of the resorbable HA microparticles.展开更多
In this paper, we present an efficient method to obtain absorbers with broadened operating frequency bands. They are accomplished by using conventional magnetic absorbing materials (MAMs) in the forms of array and m...In this paper, we present an efficient method to obtain absorbers with broadened operating frequency bands. They are accomplished by using conventional magnetic absorbing materials (MAMs) in the forms of array and mesh structures, which are similar to those in the case of a frequency selective surface. The proposed approach is verified not only by simulations but also by experimental results under the normal incidence at microwave frequencies. Moreover, the wideband absorber is lighter than the conventional magnetic absorber. These results indicate that our proposed absorbing structures can be used for designing good electromagnetic absorbers.展开更多
基金the Natural Science Foundation of the Jiangsu Higher Education Institutions of China(No.04KJB430040)
文摘Employing carbonyl iron powder and Ethylene-Propylene-Diene Monomer (EPDM) as the absorbent and matrix, rubber radar absorbing materials (RAM) were prepared. Effects of the carbonyl iron volume fraction and the thickness of the RAM on the microwave absorption properties in the frequency range of 2.6-18GHz were studied, and a mathematical analysis was made using the electromagnetic theory. The experimental results indicate that the minimum reflectivity of the radar absorbing materials continuously decreases with the increase of the carbonyl iron volume fraction, and the absorption peak also moves towards the low frequency for the same thickness of the RAM. The minimum reflectivity of the 3.0 mm RAM is -21.7dB at 3.5 GHz when the volume fraction of carbonyl iron is 45%. The reflectivity of the RAM is not in direct proportional to the thickness of the RAM, when the RAM has the same volume fraction of the carbonyl iron. The reflectivity of the RAM presents a regular trend at a given carbonyl iron volume fraction in the frequency range of 2.6-18 GHz. With the increase of the thickness, the maximum absorption peak moves towards low frequency band, the minimum reflectivity firstly decreases and then increases, and the absorption bandwidth for reflectivity〈-10 dB firstly increases and then decreases. The microwave absorption properties of the RAM are determined by the thickness and the composition of the radar absorbing materials. Theoretical analysis indicates that the reflectivity of the RAM is determined by the matching degree of the air's characteristic impedance and the input impedance.
基金Project supported by the Specialized Research Fund for the Doctoral Program of Higher Education of China(Grant No.20121101110014)
文摘Magnesium-substituted Mn0.8Zn0.2Fe2O4 ferrite is synthesized by the sol–gel combustion method using citrate acid as the complex agent. The electromagnetic absorbing behaviors of ferrite/polymer coatings fabricated by dispersing Mn–Zn ferrite into epoxy resin (EP) are studied. The microstructure and morphology are characterized by X-ray diffraction and scanning electron microscope. Complex permittivity, complex permeability, and reflection loss of ferrite/EP composite coating are investigated in a low frequency range. It is found that the prepared ferrite particles are traditional cubic spinel ferrite particles with an average size of 200 nm. The results reveal that the electromagnetic microwave absorbing properties are significantly influenced by the weight ratio of ferrite to polymer. The composites with a weight ratio of ferrite/polymer being 3:20 have a maximum reflection loss of –16 dB and wide absorbing band. Thus, the Mn–Zn ferrite is the potential candidate in electromagnetic absorbing application in the low frequency range (10 MHz–1 GHz).
基金supported by the National Natural Science Foundation of China(Nos.21771151 and 21931009).
文摘Microwave absorbing materials(MAMs)are playing an increasingly essential role in the development of wireless communications,high-power electronic devices,and advanced target detection technology.MAMs with a broad-bandwidth response are particularly important in the area of communication security,radiation prevention,electronic reliability,and military stealth.Although considerable progress has been made in the design and preparation of MAMs with a broad-bandwidth response,a number of challenges still remain,and the structure–function relationship of MAMs is still far from being completely understood.Herein,the advances in the design and research of MAMs with a broad-bandwidth response are outlined.The main strategies for expanding the effective absorption bandwidth of MAMs are comprehensively summarized considering three perspectives:the chemical combination strategy,morphological control strategy,and macrostructure control strategy.Several important results as well as design principles and absorption mechanisms are highlighted.A coherent explanation detailing the influence of the chemical composition and structure of various materials on the microwave absorption properties of MAMs is provided.The main challenges,new opportunities,and future perspectives in this promising field are also presented.
基金supported by the National Natural Science Foundation of China (Grant Nos. U1508216,51771194)the Youth Innovation Promotion Association,CAS (Grant No. 2016179)the National Key R&D Program of China (Grant No. 2017YFB0703104)。
文摘(B4C+Al2O3)/Al composite designed for the dry storage of spent nuclear fuels was fabricated and then subjected to friction stir welding, at a welding speed of 100 mm/min and rotation rates of 400–800 r/min. Sound joints were obtained under all welding parameters;however, significant softening occurred in the nugget zone(NZ) for all the joints. Therefore, all the joints exhibited significantly decreased strength at both room temperature and high temperature compared with the base metal, with the joints fracturing in the NZs. Rotation rate exhibited no obvious effect on the tensile strength of the joints, but led to increased elongation as the result of the broadened NZs. The detailed microstructural examinations indicated that the welding thermomechanical effect broke up the near 3D amorphous Al2O3 netlike structure distributed at the Al grain boundaries, caused the coarsening of Al grains, and the agglomeration and crystallization of amorphous Al2O3, thereby resulting in the softening of the NZs and the reduction in the joint strength. Consequently, inhibiting the breakup and crystallization of 3D amorphous Al2O3 netlike structure is the key factor to improve the joint strength of the(B4C+Al2O3)/Al composite.
基金financially supported by the National Natural Science Foundation of China(No.51771194)the CNNC Science Fund for Talented Young Scholars,the LingChuang Research Project of China National Nuclear Corporation,the LiaoNing Revitalization Talents Program(No.XLYC1902058)the IMR Innovation Fund(Nos.2021-ZD02 and 2021-PY12)。
文摘B4C reinforced Al composites are widely used as neutron absorbing materials(NAMs)due to excellent neutron absorbing efficiency,however,such NAMs exhibit poor high-temperature properties.To meet the requirement for structure-function integration,NAMs with enhanced high-temperature mechanical properties are desired.In this work,a novel(B4 C+Al_(2)O_(3))/Al NAM with netlike distribution of Al_(2)O_(3)was fabricated by powder metallurgy method and subjected to high-temperature tensile creep test.It was shown that the creep resistance was enhanced by several orders of magnitude via the addition of only2.1 vol.%netlike-distributed Al_(2)O_(3).(B_(4)C+Al_(2)O_(3))/Al exhibited high apparent stress exponents ranging from 16 to 25 and high apparent activation energy of 364 kJ/mol.The creep behaviour could be rationalized using the substructure-invariant model and its rupture behaviour could be described by the Dobes-Milicka equation.
基金National Natural Science Foundation of China(Nos.51705545 and 15A460041)。
文摘Using the multi-physical field simulation software COMSOL,the acoustic characteristics of the multilayer sound absorbing material straight-through perforated pipe muffler are studied by the finite element method.The results show that the finite element calculation of the multilayer sound absorbing material straight-through the perforated pipe muffler agrees well with the experimental measurement results.The reliability of the finite element method for studying the acoustic performance of the straight-through perforated pipe muffler with multilayer sound absorbing materials is shown.Furthermore,the influence of some structural parameters of porous sound absorbing material and micro-perforated plate on the acoustic performance of the multilayer sound absorbing material straight-through perforated pipe muffler is analyzed.The muffler based on multilayer sound absorbing material is different from the traditional muffler.After applying the multilayer sound absorbing material to the straight-through perforated pipe muffler,the transmission loss value greatly increases,which provides new ideas and directions for future research on the muffler.
文摘The structure and electrochemical properties of nanocrystalline LaNi_5-type alloys were studied. These materials were prepared by mechanical alloying (MA) followed by annealing. The properties of hydrogen host materials can be modified substantially by alloying to obtain the desired storage characteristics. It was found that the partial substitution of Ni by Al or Mn in LaNi_(5-x)M_x alloy leads to an increase in discharge capacity. The alloying elements such as Al, Mn and Co greatly improved the cycle life of LaNi_5 material. For example, in the nanocrystalline LaNi_(3.75)Mn_(0.75)Al_(0.25)Co_(0.25) powder, discharge capacity up to 258 mAh·g^(-1) was measured (at 40 mA·g^(-1) discharge current). Furthermore, the effect of the graphite coating on the structure of some nanocrystalline alloys and the electrodes characteristics were investigated. The mechanical coating with graphite effectively reduced the degradation rate of the studied electrode materials. The combination of a nanocrystalline LaNi_5-type hydride electrodes and a nickel positive electrode to form a Ni-MH battery, was successful.
基金Funded by the National Basic Research Program(973 Program)(No.2010CB227105)
文摘The in-situ synthesized mullite bonded SiC ceramics for solar thermal tower plant were prepared from Silicon carbide (SIC), manufactured aluminum hydroxide (Al(OH)3) and Suzhou kaolin via semi-dry pressing and pressureless firing. The results indicate that sample B3 (designed mullite content 15 wt%) fired at 1 400 ℃ exhibited optimal performance with a bending strength of 97.41 MPa. Sample B3 can withstand 30-cycles thermal shock without cracking (wind cooling from 1 100 ℃ to room temperature), and the bending strength after thermal shock decreased by 17.92%. When the service temperature is 600℃, the thermal diffusivity, specific heat capacity, thermal conductivity and heat capacity are 6.48× 10-2 cm:.s-1, 0.69 kJ·kg-1. K-1, 9.62 W·m-1·K-1 and 977.76 kJ·kg-1, respectively. The XRD and SEM results show that SiC, mullite, or-quartz, and tridymite are connected closely, which gives the material a good bending strength. After 30-time thermal shock cycles, the structure of samples becomes loose. SiC grains are intersectingly arranged with rodshape mullite, exhibiting a favorable thermal shock resistance. The addition of Al(OH)3 and Suzhou kaolin can accelerate the synthesis of mullite, thus to reduce the firing temperature effectively. The volume effect of tfidymite is relatively small, improving the thermal shock resistance of materials. A higher designed muUite content yields a lower loss rate of bending strength. The mullite content should not be more than 15 wt% or else the bending strength would be diminished.
基金financially supported by the National Natural Science Foundation of China (No.51471023)the Major State Basic Research Development Program of China (No.2014GB120000)
文摘Al2O3/TiOe/FeeO3/Yb2O3 composite powder was synthesized via the sol-gel method. The structure, morphology, and ra- dar-absorption properties of the composite powder were characterized by transmission electron microscopy, X-ray diffraction analysis and RF impedance analysis. The results show that two types of particles exist in the composite powder. One is irregular flakes (100-200 rim) and the other is spherical A1203 particles (smaller than 80 rim). Electromagnetic wave attenuation is mostly achieved by dielectric loss. The maximum value of the dissipation factor reaches 0.76 (at 15.68 GHz) in the frequency range of 2-18 GHz. The electromagnetic absorption of waves covers 2-18 GHz with the matching thicknesses of 1.5-4.5 mm. The absorption peak shifts to the lower-frequency area with increas- ing matching thickness. The effective absorption hand covers the frequency range of 2.16-9.76 GHz, and the maximum absorption peak reaches -20.18 dB with a matching thickness of 3.5 mm at a frequency of 3.52 GHz.
文摘The experiment samples of La1-xSrxMn1-y FeyO3(x = 0. 15, 0.20, 0.23; y = 0. 10, 0. 12, 0.14, 0.16) were prepared by sol-gel process, and the loss tangent and absorption coefficient in the range of 2 - 18 GHz were measured by HP8722 net analyzing apparatus. It is found that changing the content of Sr or Fe would effect the microwave absorbing. When the thickness of La1-x SrxMn1-y FeyO3 is 2 mm and x =0.20, y = 0.14, the capability of microwave absorbing is the best one. There are two absorption peaks; the maximum is 34 dB and effective band width with 10 dB and more reaches 6.2 GHz.
基金National Nature Science Foundation of China(No.90405004)
文摘A two-dimensional metal model is established to investigate the stealth mechanisms of radar absorbing material (RAM) and plasma when they cover the model together. Using the finite-difference time-domain (FDTD) method, the interaction of electromagnetic (EM) waves with the model can be studied. In this paper, three covering cases are considered: a. RAM or plasma covering the metal solely; b. RAM and plasma covering the metal, while plasma is placed outside; e. RAM and plasma covering the metal, while RAM is placed outside. The calculated results show that the covering order has a great influence on the absorption of EM waves. Compared to case a, case b has an advantage in the absorption of relatively high-frequency EM waves (HFWs), whereas case c has an advantage in the absorption of relatively low-frequency EM waves (LFWs). Through the optimization of the parameters of both plasma and RAM, it is hopeful to obtain a broad absorption band by RAM and plasma covering. Near-field attenuation rate and far-field radar cross section (RCS) are employed to compare the different cases.
基金National Natural Science Foundation of China(Nos.51705545 and 15A460041)。
文摘The multilayer impedance composite sound absorption structure of the new muffler is proposed by combining the microporous plate structure with the resonant sound absorption structure of the porous material.Firstly,the acoustic impedance and acoustic absorption coefficient of the new muffler structure are calculated by acoustic electric analogy method,and then the noise attenuation is calculated.When the new muffler structure parameters change,the relationship among the noise frequency,the sound absorption coefficient and the noise attenuation is calculated by using MATLAB.Finally,the calculated results are compared with the experimental data to verify the correctness of the theoretical calculation.The variation of resonance peak,resonance frequency and attenuation band width of each structural parameter is analyzed by the relation curve.The conclusion shows that it is feasible to use multilayer sound absorbing materials as the body structure of the new muffler.And the influence relationship between the change of various parameters of the sound absorption structure with the sound absorption coefficient and noise attenuation is obtained.
文摘Objective:To study the effects of absorbable materials in non-weight-bearing bone fractures of extremities.Methods:After 66 patients with nonweight-bearing bone fractures of extremities were selected,absorbable materials were used in the observation group and metal materials were used in the control group.Results:After treatment,the bone healing in the observation group was significantly improved(P<0.05).Conclusion:the application of absorbable materials in non-weight-bearing bone fractures of extremities is effective.
基金the French Embassy in Beijing for provision of a collaborative research grant as part of a co-research program under the frame of LIA-LAS2M between Northwestern Polytechnic University-Xi'an,China and CNRS-Grenoble,France
文摘Anisotropic powder was prepared with precursor (NdDy)-(FeCoNbCu)-B sintered magnets by hydrogen decrepitation, desorption, and subsequent annealing treatment. The hydrogen desorption was performed in magnetic fields of 0, 1, 3, and 5 T. The orientation of tetragonal phase grains of the powder was evaluated from the hysteresis loops measured by extraction magnetometer. Residual hydrogen content of the powder was evaluated by thermal-magnetic analysis. The powder with Hcj, Br, and (BH)max of 1138 kA.m^-1, 1.029 T, and 172.5 kJ.m^-3, respectively, was achieved under the condition of the magnetic field of 3 T. Magnetic properties of the powder, especially, the remanence of the powder, are enhanced upon magnetic fields, which is due to better orientation of powder particles and less residual hydrogen in the powder resulted from the magnetic field during the hydrogen desorption process.
基金financially supported by the National Natural Science Foundation of China(22001156,22271178)the Youth Talent Fund of University Association for Science and Technology in Shaanxi,China(20210602)International Cooperation Key Project of Science and Technology Department of Shaanxi,China(2022KWZ-06).
文摘For enhancing the electromagnetic wave(EW)attenuation and adsorption,rational constructing and homogeneously distributing bimetallic electromagnetic coupling units in hollow structure is an effective way,but hard to achieve.Herein,a CoNi-doped hybrid zeolite imidazole framework was synthesized as precursor,which was further converted into a hollow CoNi-bimetallic doped molyb-denum carbide sphere(H-CoNi@MoC/NC)through a two-step etching and calcination strategy.At the loading amount of 15 wt%,a strong absorption of minimum reflection loss(RL_(min))of-60.05 dB at 7.2 GHz with the thickness of 3.1 mm and a wide effective ad-sorption bandwidth(EAB)of 3.52 GHz at the thickness of 2.5 mm were achieved,which was far beyond the reported MoC-based metallic hybrids.The crucial synergistic Co-Ni electromagnetic coupling effect in the composite was characterized,not only enhanc-ing the dipolar/interfacial polarization,but also promoting the impedance matching,displaying the optimized EW absorbing perfor-mance.
文摘Based on a first-order state-vector differential equation representation of Maxwell's equations, an analytical formulation is derived for the equivalent currents on an anisotropic material backed by a metal surface, and the relation between two currents is also considered. These expressions are degenerated into the common forms for some simple cases. This effort will provide the theoretical preparation for the approximate calculation of electromagnetic scattering from a conducting object coated by an anisotropic material.
文摘The article presents problems related to mechanical protection of vehicles with different add-on armours against chemical,biological and radiological contamination.This applies to vehicles with additional passive,reactive and hybrid protection in the form of cassettes against piercing with anti-tank projectiles,piercing with their kinetic energy of impact,and as a result of chemical energy of shaped charges as well as explosively formed projectiles.It has been shown how increased ballistic protection of these vehicles at the same time reduces their decontaminability in various places of the vehicle due to the increased additional surface of the vehicle with cassettes.Prevention of contamination of these cassettes has been presented as a way of reducing hard to reach surface for decontamination and a method of insulating construction elements(stands),fixing these cassettes to the vehicle,from the environment to prevent contact with contaminated liquids and dusts.The selection of appropriate materials is shown,which may affect the improvement of the decontamination efficiency of the vehicle with such cassettes.This applies to the use of materials with low absorption of chemical warfare agents,which prevent the accumulation of large amounts of these agents on contaminated surfaces and improve the effectiveness of decontamination.It also shows how to ensure better access of the disinfectant to as much of the vehicle surface as possible,covered with cassettes that have been contaminated.It shows how a vehicle,in particular with such cassettes,can provide protection against radar detection when Radar Absorbent Material is used on vehicle cassettes.
文摘A novel bunched cerium oxide(CeO_(2))was prepared and its binary composite material with multi-walled carbon nanotubes presented an excellent microwave absorbing properties.The morphology,structure,and absorbing properties of the composite material were investigated.It was found that the minimum reflection loss(RL)of the composite material at 15.79 GHz was−45.7 dB when the thickness was 5.5 mm.It was worth noting that when the composite material was in the thickness range of 5.0-7.5 mm and the frequency was 11.36-17.77 GHz,the electromagnetic wave RL was<−30 dB,which illustrated that the composite material had a good absorbing effect over a wide thickness range.The results of the study contributed to the design and preparation of efficient microwave absorbing materials(MAM)with rare earth oxide composites and their applications,which demonstrated the importance of new composites with special structures in the field of MAM.
文摘To develop a new generation of absorbable fracture fixation devices with enhanced biocompatibility, the biodegradation mechanism and its influence on the cellular response at the tissue/implant interface of hydroxyapatite/ poly DL lactide (HA/PDLLA) composites were investigated in vitro and in vivo.HA/PDLLA rods were immersed in phosphate buffered saline,or implanted in muscle and bony tissue for 52 weeks.Scanning electron microscopic and histological studies were done.The degradation rate was the slowest in vitro,slower in muscle tissue and fast in bone.In vitro, the composites degraded heterogeneously and a hollow structure was formed.In bone,the limited clearing capacity leads to the accumulation of oligomeric debris,which contribute totally to the autocatalytic effect.So,the fastest degradation and intense tissue response were seen.In muscle tissue,oligomeric debris migrated into vicinal fibers over a long distance from the original implant cavity and the tissue reactions were,however, quite moderate.For the same size organic/inorganic composite,the environment where it was placed is the major factor in determining its biodegradation process and cellular reaction.In living tissue,factors such as cells,enzymes and mechanical stress have an obvious influence on the biodegradation and biological process at the tissue/implant interface.The biocompatibility of the HA/PDLLA composites is enhanced with the incorporating of the resorbable HA microparticles.
基金Project supported by the Aeronautical Science Foundation of China (Grant No. 2011ZF88013)
文摘In this paper, we present an efficient method to obtain absorbers with broadened operating frequency bands. They are accomplished by using conventional magnetic absorbing materials (MAMs) in the forms of array and mesh structures, which are similar to those in the case of a frequency selective surface. The proposed approach is verified not only by simulations but also by experimental results under the normal incidence at microwave frequencies. Moreover, the wideband absorber is lighter than the conventional magnetic absorber. These results indicate that our proposed absorbing structures can be used for designing good electromagnetic absorbers.