Vapor-Liquid Equilibrium Prediction of Ammonia-Ionic Liquid Working Pairs of Absorption Cycle Using UNIFAC Model

On the basis of reported experimental vapor-liquid equilibrium （VLE） data of NH3-1-ethyl-3-methylimidazolium acetate （NH3-[Emim]Ac）, NH3-1-butyl-3-methylimidazolium tetrafluoroborate （NH3-[Bmim][BF4]）, NH3-1,3-dimethylimidazolium dimethyl phosphate （NH3-[Mmim]DMP） and NH3-1-ethyl-3-methylimidazolium ethylsulfate （NH3-[Emim]EtOSO3） binary systems, the interaction parameters of 14 new groups have been regressed by means of the UNIFAC model. To validate the reliability of the method, these parameters have been used to calculate the VLE data with the average relative deviation of pressures of less than 9.35%. The infinite dilution activity coefficient （ γ1∞ ） and the absorption potential （ φ1 ） are important evaluation criterions of the affinity between working pair species of the absorption cycle. The UNIFAC model is implemented to predict the values of and φ1 of t6 sets of NH3-ionic liquid （1L） systems. The work found that the φ1 gradually increases following the impact order： φ1（[Cnmim][BF4]）〈φ1（[Cnmim]EtOSO3）〈φ1（[Cnmim]DMP）〈φ1（[Cnmim]Ac） （n= 1, 2, 3, … ） at a given cation of IL species and constant temperature, and φ1（[Mmim]X）〈φ1（[Emim]X）〈φ1（[Pmim]X）〈 φ1（[Bmim]X）（X= Ac, [BF4], DMP or EtOSO3） at a given anion of IL species and constant temperature. Furthermore, the φ1 gradually increases with increasing temperature. Then, it could be concluded that the working pair NH3-[BmimlAc has the best potential research value relatively.

Thermodynamic analysis of simplified dual-pressure ammonia-water absorption power cycle

A simplified dual-pressure ammonia-water absorption power cycle(DPAPC-a) using low grade energy resources is presented and analyzed.This cycle uses turbine exhaust heat to distill the basic solution for desorption.The structure of the cycle is simple which comprises evaporator,turbine,regenerator(desorber),absorber,pump and throttle valves for both diluted solution and vapor.And it is of high efficiency,because the working medium has large temperature difference in evaporation and small temperature difference in absorptive condensation,which can match the sensible exothermal heat resource and the cooling water simultaneously.Orthogonal calculation was made to investigate the influence of the working concentration,the basic concentration and the circulation multiple on the cycle performance,with 85-110 ℃ heat resource and 20-32 ℃ cooling water.An optimum scheme was given in the condition of 110 ℃ sensitive heat resource and 20 ℃ cooling water,with the working concentration of 0.6,basic concentration of 0.385,and circulation multiple of 5.The thermal efficiency and the power recovery efficiency are 8.06 % and 6.66%,respectively.The power recovery efficiency of the DPAPC-a is 28.8% higher than that of the steam Rankine cycle(SRC) and 12.7% higher than that of ORC(R134a) under the optimized situation.

Simulation of Gas-Fired Triple-Effect LiBr/Water Absorption Cooling System with Exhaust Heat Recovery Generator

An exhaust heat recovery generator is proposed to be integrated with conventional gas-fired triple-effect LiBr/water absorption cooling cycles to improve system energy efficiency. As a case study, simulation of the novel cycle based on promising parallel flow with cooling capacity of 1 150 kW is carried out under various heat recovery generator vapor production ratios ranging from 0 to 3.5%. The life cycle saving economic analysis, for which the annual gas conservation is estimated with Bin method, is employed to prove the worthiness of extra expenditure. Results show that the optimum gas saving revenue is obtained at 2.8% heat recovery generator vapor production ratio with 42 kW exhaust heat recovered, and the system energy efficiency is improved from 1.78 to 1.83. The initial investment of exchanger can be paid back within 7 years and 9 000 CNY of gas saving revenue will be achieved over the 15-year life cycle of the machine. This technology can be easily implemented and present desirable economic effects, which is feasible to the development of triple-effect absorption cycles.

Vapor Pressure Measurement of Water+1,3-Dimethylimidazolium Tetrafluoroborate System

In absorption cycles,ionic liquid(IL)1,3-dimethylimidazolium tetrafluoroborate([Dmim]BF4)may be a promising absorbent of working pair using water as refrigerant.The vapor pressures of[Dmim]BF4 aqueous solution were measured with the boiling-point method in the temperature range from 312.25 to 403.60 K and in the mass concentration range of 65%to 90%of[Dmim]BF4.The experimental data were correlated with an Antoine-type equation and the Non-Random Two-Liquid(NRTL)model,and the average absolute deviations between the experimental and calculated values were 1.06%and 1.15%,respectively.For the[Dmim]BF4 aqueous solution,the experimental vapor pressures show negative deviations from the calculated data with Raoult's law.For higher mass concentration of the IL,the deviation is more negative.In addition,the vapor pressures,the hydrophilicity and the solubility of[Dmim]BF4 aqueous solutions were compared with those of[Dmim]Cl aqueous solutions and [Bmim]BF4 aqueous solutions at IL-mole fraction of 0.20.

Performance Analysis and Evaluation of a Supercritical CO2 Rankine Cycle Coupled with an Absorption Refrigeration Cycle

The utilization of sensible waste heat such as flue gas and industrial surplus heat is essential for energy saving. Supercritical CO2 power generation cycle is a promising way to be used in this field. In this paper, a new supercritical CO2 Rankine cycle coupled with an absorption refrigeration cycle is proposed, which consists of a reheating supercritical CO2 cycle, a mixed-effect Li Br-H2O absorption refrigeration cycle and solar subsystem including evacuated-tube collector and a hot water storage tank. The system has four variants according to the presence or absence of solar subsystem and net cooling energy output. The thermodynamic model of the proposed system was established and its performance was evaluated. The proposed system is able to realize cascade utilization of flue gas waste heat and efficient conversion of solar energy. It has much higher thermodynamic efficiency than the reference system(i.e., the conventional supercritical CO2 Brayton cycle). Taking combined power and cooling system driven by flue gas waste heat and solar energy as an example, its thermal efficiency and exergy efficiency are 20.37% and 54.18% respectively, compared with the 14.74% and 35.96% of the reference system. Energy Utilization Diagrams(EUD) are implemented to investigate the irreversible losses and variation of the exergy destruction in the energy conversion process. Parametric analysis in two key parameters is conducted to provide guidance for the system optimal design.

Performance Analysis of an Integrated Supercritical CO_(2) Recompression/Absorption Refrigeration/Kalina Cycle Driven by Medium-Temperature Waste Heat

A novel power and cooling cogeneration system which combines a supercritical CO_(2) recompression cycle(SCRC), an ammonia-water absorption refrigeration cycle(AARC) and a Kalina cycle(KC) is proposed and investigated for the recovery of medium-temperature waste heat. The system is based on energy cascade utilization, and the waste heat can be fully converted through the simultaneous operation of the three sub-cycles. A steady-state mathematical model is built for further performance study of the proposed system. When the exhaust temperature is 505℃, it is shown that under designed conditions the thermal efficiency and exergy efficiency reach 30.74% and 61.55%, respectively. The exergy analysis results show that the main exergy destruction is concentrated in the heat recovery vapor generator(HRVG). Parametric study shows that the compressor inlet pressure, the SCRC pressure ratio, the main compressor and the turbine I inlet temperature, and the AARC generator pressure have significant effects on thermodynamic and economic performance of the combined system. The findings in this study could provide guidance for system design to achieve an efficient utilization of medium-temperature waste heat(e.g., exhaust heat from gas turbine, high-temperature fuel cells and internal combustion engine).

Comprehensive performance analysis and optimization of 1,3-dimethylimidazolylium dimethylphosphate-water binary mixture for a single effect absorption refrigeration system

The energy and exergy analyses of the absorption refrigeration system (ARS) using H2O-[mmim][DMP] mixture were investigated for a wide range of temperature. The equilibrium Dühring (P-T-XIL) and enthalpy (h-T-XIL) of mixture were assessed using the excess Gibbs free non-random two liquid (NRTL) model for a temperature range ??? of 20°C to 140°C and XIL from 0.1 to 0.9. The performance validation of the ARS cycle showed a better coefficient of performance (COP) of 0.834 for H2O-[mmim][DMP] in comparison to NH3-H2O, H2O-LiBr, H2O-[emim][DMP], and H2O-[emim][BF4]. Further, ARS performances with various operating temperatures of the absorber (Ta), condenser (Tc), generator (Tg), and evaporator (Te) were simulated and optimized for a maximum COP and exergetic COP (ECOP). The effects of Tg from 50°C to 150°C and Ta and Tc from 30°C to 50°C on COP and ECOP, the Xa, Xg, and circulation ratio (CR) of the ARS were evaluated and optimized for Te from 5°C to 15°C. The optimization revealed that Tg needed to achieve a maximum COP which was more than that for a maximum ECOP. Therefore, this investigation provides criteria to select low grade heat source temperature. Most of the series flow of the cases of cooling water from the condenser to the absorber was found to be better than the absorber to the condenser.

Low-temperature compression-assisted absorption thermal energy storage using ionic liquids

Thermal energy storage technologies play a significant role in building energy efficiency by balancing the mis-match between renewable energy supply and building energy demand.The absorption thermal energy storage(ATES)stands out due to its high energy storage density(ESD),high coefficient of performance(COP),low charg-ing temperature and wider application flexibility.A hybrid compression-assisted ATES(CATES)using ionic liquid(IL)-based working fluids is investigated to address the problems of the existing ATES cycle.Models for mixture property and cycle performance are established with verified accuracies.Four ILs([DMIM][DMP],[EMIM][Ac],[EMIM][DEP],and[EMIM][EtSO_(4)])are compared with H_(2)O/LiBr.Results show that the CATES effectively avoid the crystallization,decreases the circulation ratio,lowers the charging temperature,and improves the COP/ESD.H_(2)O/[DMIM][DMP]has the highest COP and performs better than H_(2)O/LiBr with generation temperatures above 86℃,while H_(2)O/[EMIM][EtSO_(4)]shows the highest COP with generation temperatures below 75℃.Among the H_(2)O/IL mixtures,H_(2)O/[EMIM][Ac]shows the highest ESD with generation temperatures above 86℃,otherwise H_(2)O/[EMIM][EtSO_(4)]shows the highest.The optimal compression ratio is 1.6-2.8 for H_(2)O/[DMIM][DMP]under the generation temperatures of 90-70℃with the maximum COP of 0.758-0.727.The ESD increases significantly with the compression ratio.