In order to establish methods for indentification and screening of rice genotypes with high nitrogen (N) efficiency, N absorption efficiency (NAE), N utilization efficiency (NUE) and N harvest index (NHI) in t...In order to establish methods for indentification and screening of rice genotypes with high nitrogen (N) efficiency, N absorption efficiency (NAE), N utilization efficiency (NUE) and N harvest index (NHI) in ten rice genotypes were investgated at the elongation, booting, heading and maturity stages under six N levels in a pot experiment with soil-sand mixtures at various ratios. NAE in various rice genotypes firstly increased, peaked under a medium nitrogen rate of 0.177 g/kg and then decreased, but NUE and NHI always decreased with increasing nitrogen levels. NAE in various rice genotypes ever increased with growing process and NUE indicated a descending tendency of elongation stage〉heading stage〉maturity stage〉booting stage. N level influenced rice NAE, NUE and NHI most, followed by genotype, and the both effects were significant at 0.01 level. In addition, the interaction effects of genotype and nitrogen level on rice NAE and NUE were significant at 0.01 level, but not significant on rice NHI. Because the maximum differences of NAE and NUE were found at the elongation stage, it was thought to be the most suitable stage for identification and screening these two paremeters. Therefore, the optimum conditions for identification and screening of rice NAE, NUE and NHI in a pot experiment were the nitrogen rate of 0.157 g/kg at the elongation stage, low nitrogen at the elongation stage, and the nitrogen rate of 0.277 g/kg at the maturity stage, respectively.展开更多
Photoelectrochemical(PEC)water splitting is one of the most promising approaches toward achieving the conversion of solar energy to hydrogen.Hematite is a widely applied photoanode material in PEC water splitting beca...Photoelectrochemical(PEC)water splitting is one of the most promising approaches toward achieving the conversion of solar energy to hydrogen.Hematite is a widely applied photoanode material in PEC water splitting because of its appropriate band structure,non-toxicity,high stability,and low cost.Nevertheless,its relatively low photochemical conversion efficiency limits its application,and enhancing its PEC water splitting efficiency remains a challenge.Consequently,increasing efforts have been rendered toward improving the performance of hematite photoanodes.The entire PEC water splitting efficiency typically includes three parts:the photon absorption efficiency,the separation efficiency of the semiconductor bulk,and the surface injection efficiency.This review briefly discusses the recent advances in studies on hematite photoanodes for water splitting,and through the enhancement of the three above-mentioned efficiencies,the corresponding strategies toward improving the PEC performance of hematite are comprehensively discussed and summarized.展开更多
In this study, four phosphorus-inefficient soybean genotypes (1903, 1305, D17 and D18) and four phosphorus-efficient soybean genotypes (D31, D34, D37 and D38 ) were selected as experimental materials for soil cult...In this study, four phosphorus-inefficient soybean genotypes (1903, 1305, D17 and D18) and four phosphorus-efficient soybean genotypes (D31, D34, D37 and D38 ) were selected as experimental materials for soil culture experiment under high and low phosphorus treatments, to investigate the grain yield, phosphorus content, phosphorus uptake and the relationship between phosphorus utilization efficiency and phosphorus efficiency of soybean genotypes with different phos- phorus efficiency in mature period. According to the experimental results, under low phosphorus treatment, four phosphorus-efficient soybean genotypes exhibited significantly high phosphorus uptake in mature period, especially for D31 and D37; however, three phosphorus-efficient genotypes showed no advantages in adapta- bility of phosphorus utilization efficiency, while only I)31 exhibited high phosphorus utilization and absorption capacity. Correlation analysis and path analysis showed that phosphorus deficiency of soybean was mainly detemained by phosphorus absorption capacity, and phosphorus deficiency under (-P) treatment was sig- nificandy higher than ( + P) treatment. Phosphorus uptake and phosphorus utilization efficiency posed great direct effects on phosphorus efficiency, and phosphorus uptake exhibited a greater contribution ; in addition, these two factors both posed small indirect effects. In mature period at reproductive growth stage, phosphorus absorption efficiency (phosphorus uptake) was the main variation source of phosphorus efficiency of various soybean genotypes in mature period. Therefore, strong phosphorus uptake and accumulation capacity of phosphorus-efficient soybean genotypes in mature period is an important nutrition foundation for the information of high grain yield.展开更多
Electromagnetic wave(EMW)-absorbing materials have considerable capacity in the military field and the prevention of EMW radiation from harming human health.However,obtaining lightweight,high-performance,and broadband...Electromagnetic wave(EMW)-absorbing materials have considerable capacity in the military field and the prevention of EMW radiation from harming human health.However,obtaining lightweight,high-performance,and broadband EMW-absorbing material remains an overwhelming challenge.Creating dielectric/magnetic composites with customized structures is a strategy with great promise for the development of high-performance EMW-absorbing materials.Using layered double hydroxides as the precursors of bimetallic alloys and combining them with porous biomass-derived carbon materials is a potential way for constructing multi-interface heterostructures as efficient EMW-absorbing materials because they have synergistic losses,low costs,abundant resources,and light weights.Here,FeNi alloy nanosheet array/Lycopodium spore-derived carbon(FeNi/LSC)was prepared through a simple hydrothermal and carbonization method.FeNi/LSC presents ideal EMW-absorbing performance by benefiting from the FeNi alloy nanosheet array,sponge-like structure,capability for impedance matching,and improved dielectric/magnetic losses.As expected,FeNi/LSC exhibited the minimum reflection loss of-58.3 dB at 1.5 mm with 20wt%filler content and a widely effective absorption bandwidth of 4.92 GHz.FeNi/LSC composites with effective EMW-absorbing performance provide new insights into the customization of biomass-derived composites as high-performance and lightweight broadband EMW-absorbing materials.展开更多
Lots of studies have been conducted on the optical properties of gold nanoparticles in the first region of near infrared(650 nm–950 nm), however new findings show that the second region of near-infrared(1000 nm–1...Lots of studies have been conducted on the optical properties of gold nanoparticles in the first region of near infrared(650 nm–950 nm), however new findings show that the second region of near-infrared(1000 nm–1350 nm) penetrates to the deeper tissues of the human body. Therefore, using the above-mentioned region in photo-thermal therapy(PTT) of cancer will be more appropriate. In this paper, absorption efficiency is calculated for gold spherical and rod-shaped nanoshells by the finite element method(FEM). The results show that the surface plasmon frequency of these nanostructures is highly dependent on the dimension and thickness of shell and it can be adjusted to the second region of near-infrared. Thus, due to their optical tunability and their high absorption efficiency the hollow nanoshells are the most appropriate options for eradicating cancer tissues.展开更多
The useful life of wooden pallets is lower because of the defects in lumbers. The quality of lumber can be significantly enhanced by heat treatment. In this paper,the larch pallet decks samples were heat-treated under...The useful life of wooden pallets is lower because of the defects in lumbers. The quality of lumber can be significantly enhanced by heat treatment. In this paper,the larch pallet decks samples were heat-treated under the conditions of different time and temperatures. The quantity of water uptake has reduced 16. 8% under the condition of 250 ℃ for 150 min. The resistance of water absorption efficiency increases 165. 34% under the condition of 175 ℃ for 90 min. The anti-shrink efficiency increases 72. 08% under the condition of 250 ℃ for 90min. The results showed that the dimension stability of larch panels can be improved by heat treatment. The condition of 250 ℃ for 180 min is the best heat treating condition to improve the dimension stability.展开更多
Flexible net barriers are a new type of effective mitigation measure against debris flows in valleys and can affect the kinematic energy and mass of debris flows. Here, ten flume tests were performed to study the dyna...Flexible net barriers are a new type of effective mitigation measure against debris flows in valleys and can affect the kinematic energy and mass of debris flows. Here, ten flume tests were performed to study the dynamic behaviours of debris flows with differences in volumes, concentrations(solid volume fraction), and travel distances after interception by a uniform flexible net barrier. A high-speed camera was used to monitor the whole test process, and their dynamic behaviours were recorded. A preliminary computational framework on energy conversion is proposed according to the deposition mechanisms and outflow of debris flow under the effects of the flexible net barrier. The experimental results show that the dynamic interaction process between a debris flow and the flexible net barrier can be divided into two stages:(a) the two-phase impact of the leading edge of the debris flow with the net and(b) collision and friction between the body of the debris flow and intercepted debris material. The approach velocity of a debris flow decreases sharply(a maximum of 63%) after the interception by the net barrier, and the mass ratio of the debris material being intercepted and the kinetic energy ratio of the debris material being absorbed by the net barrier are close due to the limited interception efficiency of the flexible net barrier, which is believed to be related to the flexibility. The energy ratio of outflow is relative small despite the large permeability of the flexible net barrier.展开更多
Methylammmonium lead iodide perovskites(CH3NH3PbI3) have received wide attention due to their superior optoelectronic properties. We performed first-principles calculations to investigate the structural, electronic,...Methylammmonium lead iodide perovskites(CH3NH3PbI3) have received wide attention due to their superior optoelectronic properties. We performed first-principles calculations to investigate the structural, electronic, and optical properties of mixed halide perovskites CH3NH3Pb(I(1-y)Xy)3(X = Cl, Br; y = 0, 0.33, 0.67). Our results reveal the reduction of the lattice constants and dielectric constants and enhancement of band gaps with increasing doping concentration of Cl-/Br-at I-. Electronic structure calculations indicate that the valance band maximum(VBM) is mainly governed by the halide p orbitals and Pb 6 s orbitals, Pb 6 p orbitals contribute the conduction band minimum(CBM) and doping does not change the direct semiconductor material. The organic cation [CH3NH3]~+does not take part in the formation of the band and only one electron donates to the considered materials. The increasing trends of the band gap with Cl content from y = 0(0.793 eV) to y = 0.33(0.953 eV) then to y = 0.67(1.126 eV). The optical absorption of the considered structures in the visible spectrum range is decreased but after doping the stability of the material is improving.展开更多
We present a theory to simulate a coherent GaN QD with an adjacent pure edge threading dislocation by using a finite element method. The piezoelectric effects and the strain modified band edges are investigated in the...We present a theory to simulate a coherent GaN QD with an adjacent pure edge threading dislocation by using a finite element method. The piezoelectric effects and the strain modified band edges are investigated in the framework of multi-band κ · p theory to calculate the electron and the heavy hole energy levels. The linear optical absorption coefficients corresponding to the interband ground state transition are obtained via the density matrix approach and perturbation expansion method. The results indicate that the strain distribution of the threading dislocation affects the electronic structure. Moreover, the ground state transition behaviour is also influenced by the position of the adjacent threading dislocation.展开更多
For active wave absorbers in force-control mode,the optimal feedback(control)force provided by the control system depends on the hydrodynamic forces.This work investigates a piston-type wave absorber with different dr...For active wave absorbers in force-control mode,the optimal feedback(control)force provided by the control system depends on the hydrodynamic forces.This work investigates a piston-type wave absorber with different draft-to-water depth ratios,focusing on the frequency-dependent hydrodynamic coefficients,wave absorption efficiency,wave absorber displacement and velocity,and control force.Analytical results were derived based on potential flow theory,confirming that regular incident waves can be fully absorbed by the piston-type active wave absorber at any draft ratio by optimizing the control force.The results for the wave tank with a typical water depth of 3 m were studied in detail.The draft ratio has a strong influence on the hydrodynamic coefficients.At the maximum wave absorption efficiency,the displacement and velocity amplitudes are sensitive to the draft ratio in the low-frequency region,increase with decreasing draft ratio,and are independent of the mass of the wave absorber.The control force required can be extremely large for a draft ratio greater than 1/3.The control force increases significantly as the draft ratio increases.The mass of the wave absorber has a weak influence on the control force.A time-domain numerical method based on the boundary element method was developed to verify the analytical solutions.Perfect agreements between the analytical solutions and the numerical results were obtained.展开更多
In order to realize mass transfer analysis for microwave hot in-place recycling of asphalt pavements, a volume element is established including asphalt mixtures, liquid water and vapor. A mass transfer control model i...In order to realize mass transfer analysis for microwave hot in-place recycling of asphalt pavements, a volume element is established including asphalt mixtures, liquid water and vapor. A mass transfer control model is built by the theory of multiphysics, phase transformation and diffusion. The model contains continuity equation, energy conservation equation, movement equation and vapor diffusion equation. To gain the solution of the mass transfer model, the formulas are simplified to one-dimensional differential equations. And then a mathematical model of boundary conditions is established. The mass transfer velocity and dissipative energy are obtained in different moisture contents through simulation of asphalt pavements recycling. The result indicates that when initial moisture content is certain, mass transfer velocity is almost uniform in depth direction at the same heating time and enertrv absorbed by water i,~ descendino with denletion of moisture.展开更多
Solar energy has always been a kind of energy with large reserves and wide application.It is well utilized through solar absorbers.In our study,the finite difference time domain method(FDTD)is used to simulate the abs...Solar energy has always been a kind of energy with large reserves and wide application.It is well utilized through solar absorbers.In our study,the finite difference time domain method(FDTD)is used to simulate the absorber composed of refractory metal materials,and its absorption performance and thermal emission performance are obtained.The ultra-wide band of 200 nm-3000 nm reaches 95.93%absorption efficiency,of which the bandwidth absorption efficiency of2533 nm(200 nm-2733 nm)is greater than 90%.The absorption efficiency in the whole spectrum range(200 nm-2733 nm)is 97.17%on average.The multilayer nanodisk structure of the absorber allows it to undergo strong surface plasmon resonance and near-field coupling when irradiated by incident light.The thermal emission performance of the absorber enables it to also be applied to the thermal emitter.The thermal emission efficiency of 95.37%can be achieved at a high temperature of up to 1500 K.Moreover,the changes of polarization and incident angle do not cause significant changes in absorption.Under the gradual change of polarization angle(0°-90°),the absorption spectrum maintains a high degree of consistency.As the incident angle increases from 0°to 60°,there is still 85%absorption efficiency.The high absorption efficiency and excellent thermal radiation intensity of ultra-wideband enable it to be deeply used in energy absorption and conversion applications.展开更多
The reasonable design of the composition of the composite materials is of great significance to optimized the electromagnetic(EM)wave absorption performance.Herein,the Ni/NiO@C hybrid composites with tunable Ni propor...The reasonable design of the composition of the composite materials is of great significance to optimized the electromagnetic(EM)wave absorption performance.Herein,the Ni/NiO@C hybrid composites with tunable Ni proportion were successfully synthesized through a two-step process.With the assistance of X-ray diffraction with refinement treatment,the specific proportion of Ni of as-obtained hybrid composites could be obtained.Employing controlling calcination time to adjust the Ni content of Ni/NiO@C hybrid composites,it has been found that the composite carbonized at 500℃exhibited remarkable EM wave absorption with the minimum reflection loss(RLmin)of-49.1 dB at 4.9 mm and the widest effective absorption bandwidth(EABmax)of 4.56 GHz at 2.1 mm.Moreover,by adjusting the Ni source,the optimal EM wave absorption performance could be achieved.Results illustrated that the N3PC with the Ni proportion of 13.17%showed the RLm inas low as-51.1 dB at 2.4 mm and the EABmax was 5.12 GHz at 2.7 mm.It is worth noting that this work demonstrates the relevance of the composition and EM wave absorption performance of hybrid composites,which offers a feasible reference for the absorption mechanism of absorber.展开更多
The dissolved oxygen (DO) concentration is an important index of water quality. This paper studies the dissolved oxygen recovery of the water and bubble mixture pipe flow through two sudden contractions and expansio...The dissolved oxygen (DO) concentration is an important index of water quality. This paper studies the dissolved oxygen recovery of the water and bubble mixture pipe flow through two sudden contractions and expansions. A 3-D computational fluid dy- namics model is established to simulate the water and bubble mixture flow with a DO transport model. An experiment is conducted to validate the mathematical model. The mathematical model is used to evaluate the effect of geometric parameters on the head loss coefficient, the relative saturation coefficient and the oxygen absorption efficiency. It is found that the contraction ratio is a signi- ficant influencing factor, other than the relative length and the relative distance. Given the same relative length and relative distance, the head loss coefficient, the relative saturation coefficient and the oxygen absorption efficiency increase with the decrease of the contraction ratio, respectively. Given the same relative length and contraction ratio, the head loss coefficient increases with the in- crease of the relative distance firstly, and then decreases gradually, in contrast, the relative saturation coefficient and the oxygen ab- sorption efficiency decrease with the increase of the relative distance firstly, and then increase gradually, the relative saturation coefficient and the oxygen absorption efficiency are inversely proportional to the head loss coefficient, respectively.展开更多
基金supported by the National High-Tech Research&Development program(Grant No.2003AA206030)the National Natural Science Foundation of China(Grant No.30030090)
文摘In order to establish methods for indentification and screening of rice genotypes with high nitrogen (N) efficiency, N absorption efficiency (NAE), N utilization efficiency (NUE) and N harvest index (NHI) in ten rice genotypes were investgated at the elongation, booting, heading and maturity stages under six N levels in a pot experiment with soil-sand mixtures at various ratios. NAE in various rice genotypes firstly increased, peaked under a medium nitrogen rate of 0.177 g/kg and then decreased, but NUE and NHI always decreased with increasing nitrogen levels. NAE in various rice genotypes ever increased with growing process and NUE indicated a descending tendency of elongation stage〉heading stage〉maturity stage〉booting stage. N level influenced rice NAE, NUE and NHI most, followed by genotype, and the both effects were significant at 0.01 level. In addition, the interaction effects of genotype and nitrogen level on rice NAE and NUE were significant at 0.01 level, but not significant on rice NHI. Because the maximum differences of NAE and NUE were found at the elongation stage, it was thought to be the most suitable stage for identification and screening these two paremeters. Therefore, the optimum conditions for identification and screening of rice NAE, NUE and NHI in a pot experiment were the nitrogen rate of 0.157 g/kg at the elongation stage, low nitrogen at the elongation stage, and the nitrogen rate of 0.277 g/kg at the maturity stage, respectively.
文摘Photoelectrochemical(PEC)water splitting is one of the most promising approaches toward achieving the conversion of solar energy to hydrogen.Hematite is a widely applied photoanode material in PEC water splitting because of its appropriate band structure,non-toxicity,high stability,and low cost.Nevertheless,its relatively low photochemical conversion efficiency limits its application,and enhancing its PEC water splitting efficiency remains a challenge.Consequently,increasing efforts have been rendered toward improving the performance of hematite photoanodes.The entire PEC water splitting efficiency typically includes three parts:the photon absorption efficiency,the separation efficiency of the semiconductor bulk,and the surface injection efficiency.This review briefly discusses the recent advances in studies on hematite photoanodes for water splitting,and through the enhancement of the three above-mentioned efficiencies,the corresponding strategies toward improving the PEC performance of hematite are comprehensively discussed and summarized.
基金Supported by Doctoral Scientific Research Start-up Project of Mudanjiang Normal University(MSB200912)Provincial Key Pre-research Project of Mudanjiang Normal University(SY2014010)Teaching Reform Project of Mudanjiang Normal University(2013JGZX0074)
文摘In this study, four phosphorus-inefficient soybean genotypes (1903, 1305, D17 and D18) and four phosphorus-efficient soybean genotypes (D31, D34, D37 and D38 ) were selected as experimental materials for soil culture experiment under high and low phosphorus treatments, to investigate the grain yield, phosphorus content, phosphorus uptake and the relationship between phosphorus utilization efficiency and phosphorus efficiency of soybean genotypes with different phos- phorus efficiency in mature period. According to the experimental results, under low phosphorus treatment, four phosphorus-efficient soybean genotypes exhibited significantly high phosphorus uptake in mature period, especially for D31 and D37; however, three phosphorus-efficient genotypes showed no advantages in adapta- bility of phosphorus utilization efficiency, while only I)31 exhibited high phosphorus utilization and absorption capacity. Correlation analysis and path analysis showed that phosphorus deficiency of soybean was mainly detemained by phosphorus absorption capacity, and phosphorus deficiency under (-P) treatment was sig- nificandy higher than ( + P) treatment. Phosphorus uptake and phosphorus utilization efficiency posed great direct effects on phosphorus efficiency, and phosphorus uptake exhibited a greater contribution ; in addition, these two factors both posed small indirect effects. In mature period at reproductive growth stage, phosphorus absorption efficiency (phosphorus uptake) was the main variation source of phosphorus efficiency of various soybean genotypes in mature period. Therefore, strong phosphorus uptake and accumulation capacity of phosphorus-efficient soybean genotypes in mature period is an important nutrition foundation for the information of high grain yield.
基金financial support from the National Natural Science Foundation of China(Nos.21776026,22075034,and 22178037)the Liaoning Revitalization Talents Program,China(Nos.XLYC1902037 and XLYC2002114)the Natural Science Foundation of Liaoning Province of China(No.2021-MS-303)。
文摘Electromagnetic wave(EMW)-absorbing materials have considerable capacity in the military field and the prevention of EMW radiation from harming human health.However,obtaining lightweight,high-performance,and broadband EMW-absorbing material remains an overwhelming challenge.Creating dielectric/magnetic composites with customized structures is a strategy with great promise for the development of high-performance EMW-absorbing materials.Using layered double hydroxides as the precursors of bimetallic alloys and combining them with porous biomass-derived carbon materials is a potential way for constructing multi-interface heterostructures as efficient EMW-absorbing materials because they have synergistic losses,low costs,abundant resources,and light weights.Here,FeNi alloy nanosheet array/Lycopodium spore-derived carbon(FeNi/LSC)was prepared through a simple hydrothermal and carbonization method.FeNi/LSC presents ideal EMW-absorbing performance by benefiting from the FeNi alloy nanosheet array,sponge-like structure,capability for impedance matching,and improved dielectric/magnetic losses.As expected,FeNi/LSC exhibited the minimum reflection loss of-58.3 dB at 1.5 mm with 20wt%filler content and a widely effective absorption bandwidth of 4.92 GHz.FeNi/LSC composites with effective EMW-absorbing performance provide new insights into the customization of biomass-derived composites as high-performance and lightweight broadband EMW-absorbing materials.
文摘Lots of studies have been conducted on the optical properties of gold nanoparticles in the first region of near infrared(650 nm–950 nm), however new findings show that the second region of near-infrared(1000 nm–1350 nm) penetrates to the deeper tissues of the human body. Therefore, using the above-mentioned region in photo-thermal therapy(PTT) of cancer will be more appropriate. In this paper, absorption efficiency is calculated for gold spherical and rod-shaped nanoshells by the finite element method(FEM). The results show that the surface plasmon frequency of these nanostructures is highly dependent on the dimension and thickness of shell and it can be adjusted to the second region of near-infrared. Thus, due to their optical tunability and their high absorption efficiency the hollow nanoshells are the most appropriate options for eradicating cancer tissues.
文摘The useful life of wooden pallets is lower because of the defects in lumbers. The quality of lumber can be significantly enhanced by heat treatment. In this paper,the larch pallet decks samples were heat-treated under the conditions of different time and temperatures. The quantity of water uptake has reduced 16. 8% under the condition of 250 ℃ for 150 min. The resistance of water absorption efficiency increases 165. 34% under the condition of 175 ℃ for 90 min. The anti-shrink efficiency increases 72. 08% under the condition of 250 ℃ for 90min. The results showed that the dimension stability of larch panels can be improved by heat treatment. The condition of 250 ℃ for 180 min is the best heat treating condition to improve the dimension stability.
基金supported by the National Natural Science Foundation of China (51639007)the Youth Science and Technology Fund of Sichuan Province (2016JQ0011)the Science and Technology Fund of Chengdu Water Authority (14H1055).
文摘Flexible net barriers are a new type of effective mitigation measure against debris flows in valleys and can affect the kinematic energy and mass of debris flows. Here, ten flume tests were performed to study the dynamic behaviours of debris flows with differences in volumes, concentrations(solid volume fraction), and travel distances after interception by a uniform flexible net barrier. A high-speed camera was used to monitor the whole test process, and their dynamic behaviours were recorded. A preliminary computational framework on energy conversion is proposed according to the deposition mechanisms and outflow of debris flow under the effects of the flexible net barrier. The experimental results show that the dynamic interaction process between a debris flow and the flexible net barrier can be divided into two stages:(a) the two-phase impact of the leading edge of the debris flow with the net and(b) collision and friction between the body of the debris flow and intercepted debris material. The approach velocity of a debris flow decreases sharply(a maximum of 63%) after the interception by the net barrier, and the mass ratio of the debris material being intercepted and the kinetic energy ratio of the debris material being absorbed by the net barrier are close due to the limited interception efficiency of the flexible net barrier, which is believed to be related to the flexibility. The energy ratio of outflow is relative small despite the large permeability of the flexible net barrier.
基金supported by the Financial Support from the"12th Five-Year"Science and Technology Research Project of the Education Department of Jilin Province(Grant No.[2016]494)the National Natural Science Foundation of China(Grant No.21173035)
文摘Methylammmonium lead iodide perovskites(CH3NH3PbI3) have received wide attention due to their superior optoelectronic properties. We performed first-principles calculations to investigate the structural, electronic, and optical properties of mixed halide perovskites CH3NH3Pb(I(1-y)Xy)3(X = Cl, Br; y = 0, 0.33, 0.67). Our results reveal the reduction of the lattice constants and dielectric constants and enhancement of band gaps with increasing doping concentration of Cl-/Br-at I-. Electronic structure calculations indicate that the valance band maximum(VBM) is mainly governed by the halide p orbitals and Pb 6 s orbitals, Pb 6 p orbitals contribute the conduction band minimum(CBM) and doping does not change the direct semiconductor material. The organic cation [CH3NH3]~+does not take part in the formation of the band and only one electron donates to the considered materials. The increasing trends of the band gap with Cl content from y = 0(0.793 eV) to y = 0.33(0.953 eV) then to y = 0.67(1.126 eV). The optical absorption of the considered structures in the visible spectrum range is decreased but after doping the stability of the material is improving.
基金Project supported by the National High Technology Research and Development Program of China(Grant No.2009AA03Z405)the National Natural Science Foundation of China(Grant Nos.60908028 and 60971068)+1 种基金the High School Innovation and Introducing Talent Project of China(Grant No.B07005)the Chinese Universities Scientific Fund(Grant No.BUPT2009RC0412)
文摘We present a theory to simulate a coherent GaN QD with an adjacent pure edge threading dislocation by using a finite element method. The piezoelectric effects and the strain modified band edges are investigated in the framework of multi-band κ · p theory to calculate the electron and the heavy hole energy levels. The linear optical absorption coefficients corresponding to the interband ground state transition are obtained via the density matrix approach and perturbation expansion method. The results indicate that the strain distribution of the threading dislocation affects the electronic structure. Moreover, the ground state transition behaviour is also influenced by the position of the adjacent threading dislocation.
文摘For active wave absorbers in force-control mode,the optimal feedback(control)force provided by the control system depends on the hydrodynamic forces.This work investigates a piston-type wave absorber with different draft-to-water depth ratios,focusing on the frequency-dependent hydrodynamic coefficients,wave absorption efficiency,wave absorber displacement and velocity,and control force.Analytical results were derived based on potential flow theory,confirming that regular incident waves can be fully absorbed by the piston-type active wave absorber at any draft ratio by optimizing the control force.The results for the wave tank with a typical water depth of 3 m were studied in detail.The draft ratio has a strong influence on the hydrodynamic coefficients.At the maximum wave absorption efficiency,the displacement and velocity amplitudes are sensitive to the draft ratio in the low-frequency region,increase with decreasing draft ratio,and are independent of the mass of the wave absorber.The control force required can be extremely large for a draft ratio greater than 1/3.The control force increases significantly as the draft ratio increases.The mass of the wave absorber has a weak influence on the control force.A time-domain numerical method based on the boundary element method was developed to verify the analytical solutions.Perfect agreements between the analytical solutions and the numerical results were obtained.
基金Supported by the National Natural Science Foundation of China (51106001) Anhui College Provincial Natural Science Research Project (No. KJ2011B018)
文摘In order to realize mass transfer analysis for microwave hot in-place recycling of asphalt pavements, a volume element is established including asphalt mixtures, liquid water and vapor. A mass transfer control model is built by the theory of multiphysics, phase transformation and diffusion. The model contains continuity equation, energy conservation equation, movement equation and vapor diffusion equation. To gain the solution of the mass transfer model, the formulas are simplified to one-dimensional differential equations. And then a mathematical model of boundary conditions is established. The mass transfer velocity and dissipative energy are obtained in different moisture contents through simulation of asphalt pavements recycling. The result indicates that when initial moisture content is certain, mass transfer velocity is almost uniform in depth direction at the same heating time and enertrv absorbed by water i,~ descendino with denletion of moisture.
基金support from the National Natural Science Foundation of China (Grant No.51606158,11604311,12074151)the Guangxi Science and Technology Base and Talent Special Project (Grant No.AD21075009)+6 种基金the Sichuan Science and Technology Program (Grant No.2021JDRC0022)the Natural Science Foundation of Fujian Province (Grant No.2021J05202)the Research Project of Fashu Foundation (Grant No.MFK23006)the Open Fund of the Key Laboratory for Metallurgical Equipment and Control Technology of Ministry of Education in Wuhan University of Science and Technology,China (Grant No.MECOF2022B01MECOF2023B04)the Project supported by Guangxi Key Laboratory of Precision Navigation Technology and Application,Guilin University of Electronic Technology (Grant No.DH202321)the Scientific Research Project of Huzhou College (Grant No.2022HXKM07)。
文摘Solar energy has always been a kind of energy with large reserves and wide application.It is well utilized through solar absorbers.In our study,the finite difference time domain method(FDTD)is used to simulate the absorber composed of refractory metal materials,and its absorption performance and thermal emission performance are obtained.The ultra-wide band of 200 nm-3000 nm reaches 95.93%absorption efficiency,of which the bandwidth absorption efficiency of2533 nm(200 nm-2733 nm)is greater than 90%.The absorption efficiency in the whole spectrum range(200 nm-2733 nm)is 97.17%on average.The multilayer nanodisk structure of the absorber allows it to undergo strong surface plasmon resonance and near-field coupling when irradiated by incident light.The thermal emission performance of the absorber enables it to also be applied to the thermal emitter.The thermal emission efficiency of 95.37%can be achieved at a high temperature of up to 1500 K.Moreover,the changes of polarization and incident angle do not cause significant changes in absorption.Under the gradual change of polarization angle(0°-90°),the absorption spectrum maintains a high degree of consistency.As the incident angle increases from 0°to 60°,there is still 85%absorption efficiency.The high absorption efficiency and excellent thermal radiation intensity of ultra-wideband enable it to be deeply used in energy absorption and conversion applications.
基金financially supported by the National Natural Science Foundation of China(Nos.51407134,51801001 and 51801108)Natural Science Foundation of Shandong Province(No.ZR2019YQ24)+5 种基金China Postdoctoral Science Foundation(No.2016M590619,No.2016M601878)Provincial Key Research and Development Program of Shaanxi(No.2019GY-197)the Qingchuang Talents Induction Program of Shandong Higher Education Institution(Research and Innovation Team of Structural-Functional Polymer Composites)the support from The Thousand Talents PlanThe World-Class University and DisciplineThe Taishan Scholar’s Advantageous and Distinctive Discipline Program of Shandong ProvinceThe World-Class Discipline Program of Shandong Province。
文摘The reasonable design of the composition of the composite materials is of great significance to optimized the electromagnetic(EM)wave absorption performance.Herein,the Ni/NiO@C hybrid composites with tunable Ni proportion were successfully synthesized through a two-step process.With the assistance of X-ray diffraction with refinement treatment,the specific proportion of Ni of as-obtained hybrid composites could be obtained.Employing controlling calcination time to adjust the Ni content of Ni/NiO@C hybrid composites,it has been found that the composite carbonized at 500℃exhibited remarkable EM wave absorption with the minimum reflection loss(RLmin)of-49.1 dB at 4.9 mm and the widest effective absorption bandwidth(EABmax)of 4.56 GHz at 2.1 mm.Moreover,by adjusting the Ni source,the optimal EM wave absorption performance could be achieved.Results illustrated that the N3PC with the Ni proportion of 13.17%showed the RLm inas low as-51.1 dB at 2.4 mm and the EABmax was 5.12 GHz at 2.7 mm.It is worth noting that this work demonstrates the relevance of the composition and EM wave absorption performance of hybrid composites,which offers a feasible reference for the absorption mechanism of absorber.
基金supported by the National Natural Science Foundation of China(Grant No.51009123)the Qingdao Science and Technology Development Plan(Grant No.11-2-4-1-(7)-jch)
文摘The dissolved oxygen (DO) concentration is an important index of water quality. This paper studies the dissolved oxygen recovery of the water and bubble mixture pipe flow through two sudden contractions and expansions. A 3-D computational fluid dy- namics model is established to simulate the water and bubble mixture flow with a DO transport model. An experiment is conducted to validate the mathematical model. The mathematical model is used to evaluate the effect of geometric parameters on the head loss coefficient, the relative saturation coefficient and the oxygen absorption efficiency. It is found that the contraction ratio is a signi- ficant influencing factor, other than the relative length and the relative distance. Given the same relative length and relative distance, the head loss coefficient, the relative saturation coefficient and the oxygen absorption efficiency increase with the decrease of the contraction ratio, respectively. Given the same relative length and contraction ratio, the head loss coefficient increases with the in- crease of the relative distance firstly, and then decreases gradually, in contrast, the relative saturation coefficient and the oxygen ab- sorption efficiency decrease with the increase of the relative distance firstly, and then increase gradually, the relative saturation coefficient and the oxygen absorption efficiency are inversely proportional to the head loss coefficient, respectively.