Cement used in severe maritime environments must be attached with exceptional properties such as high sulfate resistance and abrasion strength.A sulfate resistant material typically used in marine engineering is high ...Cement used in severe maritime environments must be attached with exceptional properties such as high sulfate resistance and abrasion strength.A sulfate resistant material typically used in marine engineering is high ferrite cement,which has been utilized in sulfate-rich environments.This study aims at exploring the effect of C_(4)AF and heat-curing on the abrasion resistance of high ferrite cement(HFC,C_(4)AF:14%-22%)in order to have a comprehensive understanding of this mechanism and promote the application of HFC in marine engineering.A new invention was designed for the abrasion resistance device by considering the sea-wave abrasion and seawater erosion in laboratory.The compressive strength and abrasion resistance of HFC were measured.Additionally,advanced analytical methods were used to explore the abrasion resistance mechanism of HFC,including X-ray fluorescence(XRF),X-ray diffraction(XRD),and thermogravimetric(TG)analyses,as well as mercury intrusion porosimetry(MIP).The results showed that HFC had the best abrasion resistance under appropriate heat-curing system that the curing temperature was 50℃and the hosting time was 4 hours,compared with PI(Portland cement)and LHC(low heat cement),meanwhile the abrasion resistance of HFC had a 62.4%increase when C_(4)AF content is increased from 14%to 22%.It can be ascribed that the content of portlandite is decreased due to the increase of C_(4)AF,which can reduce the portlandite assembled in ITZ(interfacial transition zone).It can also be ascribed that the DEF(delayed ettringite formation)is successfully avoided in HFC and the hydration degree of HFC can continue to be boosted under appropriate heat-curing system.展开更多
Ultra fast cooling（UFC） processing after hot deformation was conducted on X70 and X80 linepipe steels. Tensile and charpy impact properties of both steels have been investigated in this work. The results have shown ...Ultra fast cooling（UFC） processing after hot deformation was conducted on X70 and X80 linepipe steels. Tensile and charpy impact properties of both steels have been investigated in this work. The results have shown that the mechanical properties satisfy all the standard requirements of the X70 and X80 steels. UFC results in a presence of microstructure containing quasi polygonal（QF）, acicular ferrite（AF） and granular bainite（GB）. The alloying elements and UFC enhance the strengthening contribution caused by solid solution, dispersion, dislocation and precipitation strengthening. The size and distribution of precipitates in the linepipe steels are fine and dispersed. MA is also homogeneously dispersed due to UFC. Average grain size in the X80 steel is finer than that in the X70 steel. The volume fractions of secondary phases in the X80 steel are greater than those in the X70 steel. The X80 steel remains finer and more dispersed precipitates compared to the X70 steel. As a result, the tensile properties of X80 steel are higher than those of X70 steel. The Charpy absorbed energies of X70 and X80 steels at-10 ℃ reached 436 and 460 J, respectively. They reached 433 and 461 J at-15 ℃, respectively. This is mainly attributed to the presence of larger amounts of AFs in the X80 steel. A microstructure of AF for the X80 steel results in combining high strength and high toughness.展开更多
基金National Key Research and Development Program of China(No.2016YFB0303501)National Natural Science Foundation of China(Nos.51709209,51872216)Natural Science Foundation of Hubei Province(No.2020CFB827)。
文摘Cement used in severe maritime environments must be attached with exceptional properties such as high sulfate resistance and abrasion strength.A sulfate resistant material typically used in marine engineering is high ferrite cement,which has been utilized in sulfate-rich environments.This study aims at exploring the effect of C_(4)AF and heat-curing on the abrasion resistance of high ferrite cement(HFC,C_(4)AF:14%-22%)in order to have a comprehensive understanding of this mechanism and promote the application of HFC in marine engineering.A new invention was designed for the abrasion resistance device by considering the sea-wave abrasion and seawater erosion in laboratory.The compressive strength and abrasion resistance of HFC were measured.Additionally,advanced analytical methods were used to explore the abrasion resistance mechanism of HFC,including X-ray fluorescence(XRF),X-ray diffraction(XRD),and thermogravimetric(TG)analyses,as well as mercury intrusion porosimetry(MIP).The results showed that HFC had the best abrasion resistance under appropriate heat-curing system that the curing temperature was 50℃and the hosting time was 4 hours,compared with PI(Portland cement)and LHC(low heat cement),meanwhile the abrasion resistance of HFC had a 62.4%increase when C_(4)AF content is increased from 14%to 22%.It can be ascribed that the content of portlandite is decreased due to the increase of C_(4)AF,which can reduce the portlandite assembled in ITZ(interfacial transition zone).It can also be ascribed that the DEF(delayed ettringite formation)is successfully avoided in HFC and the hydration degree of HFC can continue to be boosted under appropriate heat-curing system.
基金Funded by the National High-Tech Research and Development Program of of China(863 Program)(No.2015AA03A501)Shenyang City Application Basic Research Project(No.F13-316-1-15)the State Key Laboratory Opening Project of Northeastern University(No.12SYS05)
文摘Ultra fast cooling（UFC） processing after hot deformation was conducted on X70 and X80 linepipe steels. Tensile and charpy impact properties of both steels have been investigated in this work. The results have shown that the mechanical properties satisfy all the standard requirements of the X70 and X80 steels. UFC results in a presence of microstructure containing quasi polygonal（QF）, acicular ferrite（AF） and granular bainite（GB）. The alloying elements and UFC enhance the strengthening contribution caused by solid solution, dispersion, dislocation and precipitation strengthening. The size and distribution of precipitates in the linepipe steels are fine and dispersed. MA is also homogeneously dispersed due to UFC. Average grain size in the X80 steel is finer than that in the X70 steel. The volume fractions of secondary phases in the X80 steel are greater than those in the X70 steel. The X80 steel remains finer and more dispersed precipitates compared to the X70 steel. As a result, the tensile properties of X80 steel are higher than those of X70 steel. The Charpy absorbed energies of X70 and X80 steels at-10 ℃ reached 436 and 460 J, respectively. They reached 433 and 461 J at-15 ℃, respectively. This is mainly attributed to the presence of larger amounts of AFs in the X80 steel. A microstructure of AF for the X80 steel results in combining high strength and high toughness.
