The ZrO2 ceranfic was successfully jointed to stainless steel by vacuum brazing with active filler metal. The AgCuTi active filler metal was used and the joining was performed at a temperature of 850 ℃ for 10 rain. T...The ZrO2 ceranfic was successfully jointed to stainless steel by vacuum brazing with active filler metal. The AgCuTi active filler metal was used and the joining was performed at a temperature of 850 ℃ for 10 rain. The microstructures of the joints were characterized by metallographic microscopy, scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS). Metallographic microscopy analysis shows that the morphology of the cross section was a sandwich structure and the TiO is observed in the surface of ZrO2/ stainless steel. The diffusion and enrichment of the elements are the key roles in the brazing of ZrO2 ceramic and stainless steel. The formation of TiCu compounds inhibited the further diffusion of titanium into stainless steel or the ZrO2 ceramic to form TiO compound. In the experimental conditions, the average tensile strength is 80MPa for the joint of ZrO2 ceramic / AgCuTi/ stainless steel systems. A complete joint is formed between the ZrO2 ceramic and stainless steel with the leakage rate at the degree of 10 ^-12 Pa · m^3/s.展开更多
The flexural strengths and oxidative resistant properties of the ceramics derived from polycarbosilane and active fillers (Ti, TiH 2, TiB 2, Cr, and CrSi 2) were measured and characterized. The introduction of acti...The flexural strengths and oxidative resistant properties of the ceramics derived from polycarbosilane and active fillers (Ti, TiH 2, TiB 2, Cr, and CrSi 2) were measured and characterized. The introduction of active fillers enhances slightly the flexural strengths, and further densification is required to obtain higher strengths. The oxidative resistant behaviors of the specimens with active fillers are, by means of weight gain in air, poorer compared with those without active fillers.展开更多
Estuaries have been described as one of the most difficult environments on Earth. It is difficult to know how to treat the combined wastewater in tidal rivers at the estuary, where the situation is very different from...Estuaries have been described as one of the most difficult environments on Earth. It is difficult to know how to treat the combined wastewater in tidal rivers at the estuary, where the situation is very different from ordinary fresh water rivers. Waste oyster shell was used as the active filler in this study in a bio-contact oxidation tank to treat the combined wastewater at the Fengtang Tidal River. With a middle-experimental scale of 360 ma/day, the average removal efficiency of COD, BOD, NH3-N, TP and TSS was 80.05%, 85.02%, 86.59%, 50.58% and 85.32%, respectively, in this bio-contact oxidation process. The living microbes in the biofilms on the waste oyster shell in this bio-contact oxidation tank, which were mainly composed of zoogloea, protozoa and micro-metazoa species, revealed that waste oyster shell as the filler was suitable material for combined wastewater degradation. This treatment method using waste oyster shell as active filler was then applied in a mangrove demonstration area for water quality improvement near the experiment area, with a treatment volume of 5 × 10^3 m^3/day. Another project was also successfully applied in a constructed wetland, with a wastewater treatment volume of 1 ×10^3 m^3/day. This technology is therefore feasible and can easily be applied on a larger scale,展开更多
Granite is well known as an acid aggregate. An active mineral filler produced in the laboratory is first used as an anti-stripping filler in the granite asphalt concrete. Four aggregate gradations were chosen in this ...Granite is well known as an acid aggregate. An active mineral filler produced in the laboratory is first used as an anti-stripping filler in the granite asphalt concrete. Four aggregate gradations were chosen in this study,and the effects of the active mineral filler and aggregates on the rutting resistance performance and fatigue properties of granite asphalt concrete were investigated by means of rutting test and four-point bending fatigue test. The results indicate that the dynamic stability of granite asphalt concrete increase significantly with the addition of active mineral filler and the fatigue properties can also be improved especially at lower strain level. Meanwhile,the results demonstrate that granite asphalt concrete has better rutting resistance performance and fatigue properties than limestone asphalt concrete.展开更多
An AlSi-Mg2Si self-fluxing brazing filler metal was obtained by activating AlSi brazing filler metal with the Mg2Si phase and applying a metamorphism treatment of Mg2Si and Si crystals with Sr and SmO. A good wetting ...An AlSi-Mg2Si self-fluxing brazing filler metal was obtained by activating AlSi brazing filler metal with the Mg2Si phase and applying a metamorphism treatment of Mg2Si and Si crystals with Sr and SmO. A good wetting performance between the modi-fied AlSi-Mg2Si and 3003 Al alloys was achieved in the vacuum brazing without Mg vapour as the activator. The melting point of the brazing filler was measured by STA409Pc differential scanning calorimetry. A scanning electron microscope was used to analyse the microstructure and the component distribution of the brazing filler. The results indicated that the change in morphology of the Mg2Si phase was remarkable after metamorphism. The analyses of the microstructure indicated that the Mg2Si and Si phases presented small needle-type and granular morphologies. The follows were found to occur: intergranular penetration of Mg and Si on the base metal, a large amount of granular eutectic structure, and a significant grain boundary effect. The shear fracture of the lap joint presented cleavage fracture; in addition, with the decrease of the Mg2Si phases, the fracture morphology transformed from a rock candy shape to a steam shape, and cleavage steps appeared. The rock candy-shaped fracture areas enlarged after metamorphism treatment.展开更多
Solid-state electrolytes(SSEs)can address the safety issue of organic electrolyte in rechargeable lithium batteries.Unfortunately,neither polymer nor ceramic SSEs used alone can meet the demand although great progress...Solid-state electrolytes(SSEs)can address the safety issue of organic electrolyte in rechargeable lithium batteries.Unfortunately,neither polymer nor ceramic SSEs used alone can meet the demand although great progress has been made in the past few years.Composite solid electrolytes(CSEs)composed of flexible polymers and brittle but more conducting ceramics can take advantage of the individual system for solid-state lithium metal batteries(SSLMBs).CSEs can be largely divided into two categories by the mass fraction of the components:“polymer rich”(PR)and“ceramic rich”(CR)systems with different internal structures and electrochemical properties.This review provides a comprehensive and in-depth understanding of recent advances and limitations of both PR and CR electrolytes,with a special focus on the ion conduction path based on polymer-ceramic interaction mechanisms and structural designs of ceramic fillers/frameworks.In addition,it highlights the PR and CR which bring the leverage between the electrochemical property and the mechanical property.Moreover,it further prospects the possible route for future development of CSEs according to their rational design,which is expected to accelerate the practical application of SSLMBs.展开更多
基金supported by the National Key R&D Program of China(Grant No.2017YFB0305700)
文摘The ZrO2 ceranfic was successfully jointed to stainless steel by vacuum brazing with active filler metal. The AgCuTi active filler metal was used and the joining was performed at a temperature of 850 ℃ for 10 rain. The microstructures of the joints were characterized by metallographic microscopy, scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS). Metallographic microscopy analysis shows that the morphology of the cross section was a sandwich structure and the TiO is observed in the surface of ZrO2/ stainless steel. The diffusion and enrichment of the elements are the key roles in the brazing of ZrO2 ceramic and stainless steel. The formation of TiCu compounds inhibited the further diffusion of titanium into stainless steel or the ZrO2 ceramic to form TiO compound. In the experimental conditions, the average tensile strength is 80MPa for the joint of ZrO2 ceramic / AgCuTi/ stainless steel systems. A complete joint is formed between the ZrO2 ceramic and stainless steel with the leakage rate at the degree of 10 ^-12 Pa · m^3/s.
文摘The flexural strengths and oxidative resistant properties of the ceramics derived from polycarbosilane and active fillers (Ti, TiH 2, TiB 2, Cr, and CrSi 2) were measured and characterized. The introduction of active fillers enhances slightly the flexural strengths, and further densification is required to obtain higher strengths. The oxidative resistant behaviors of the specimens with active fillers are, by means of weight gain in air, poorer compared with those without active fillers.
基金supported by the National Natural Science Foundation of China(No.51278318)the Key Scientific and Technological Projects of Sichuan Provincial Environmental Protection Bureau(No.2011HB001,2012HB002)+2 种基金the Science-Technology Support Plan Program from the Science and Technology Department of Sichuan Province(No.2013SZ0103)the State Key Laboratory of Hydraulics and Mountain River Engineering in China(No.1111)the Youth Foundation of the Sichuan Education Bureau(No.10ZB046)
文摘Estuaries have been described as one of the most difficult environments on Earth. It is difficult to know how to treat the combined wastewater in tidal rivers at the estuary, where the situation is very different from ordinary fresh water rivers. Waste oyster shell was used as the active filler in this study in a bio-contact oxidation tank to treat the combined wastewater at the Fengtang Tidal River. With a middle-experimental scale of 360 ma/day, the average removal efficiency of COD, BOD, NH3-N, TP and TSS was 80.05%, 85.02%, 86.59%, 50.58% and 85.32%, respectively, in this bio-contact oxidation process. The living microbes in the biofilms on the waste oyster shell in this bio-contact oxidation tank, which were mainly composed of zoogloea, protozoa and micro-metazoa species, revealed that waste oyster shell as the filler was suitable material for combined wastewater degradation. This treatment method using waste oyster shell as active filler was then applied in a mangrove demonstration area for water quality improvement near the experiment area, with a treatment volume of 5 × 10^3 m^3/day. Another project was also successfully applied in a constructed wetland, with a wastewater treatment volume of 1 ×10^3 m^3/day. This technology is therefore feasible and can easily be applied on a larger scale,
基金Department of Transportation in Hubei Province,China and Headguarters of Ma-Wu Expressway in Hubei Province for its financial support of this work.
文摘Granite is well known as an acid aggregate. An active mineral filler produced in the laboratory is first used as an anti-stripping filler in the granite asphalt concrete. Four aggregate gradations were chosen in this study,and the effects of the active mineral filler and aggregates on the rutting resistance performance and fatigue properties of granite asphalt concrete were investigated by means of rutting test and four-point bending fatigue test. The results indicate that the dynamic stability of granite asphalt concrete increase significantly with the addition of active mineral filler and the fatigue properties can also be improved especially at lower strain level. Meanwhile,the results demonstrate that granite asphalt concrete has better rutting resistance performance and fatigue properties than limestone asphalt concrete.
基金supported by Natural Scientific Research Projects of Education Department of Anhui Province(KJ2013Z046)Innovation Training Project of Department of Education of Anhui Province(AH201310879077)+1 种基金Jiangsu Province Natural Science Foundation of China(BK20131261)General Project of Anhui Science and Technology University(ZRC2013377)
文摘An AlSi-Mg2Si self-fluxing brazing filler metal was obtained by activating AlSi brazing filler metal with the Mg2Si phase and applying a metamorphism treatment of Mg2Si and Si crystals with Sr and SmO. A good wetting performance between the modi-fied AlSi-Mg2Si and 3003 Al alloys was achieved in the vacuum brazing without Mg vapour as the activator. The melting point of the brazing filler was measured by STA409Pc differential scanning calorimetry. A scanning electron microscope was used to analyse the microstructure and the component distribution of the brazing filler. The results indicated that the change in morphology of the Mg2Si phase was remarkable after metamorphism. The analyses of the microstructure indicated that the Mg2Si and Si phases presented small needle-type and granular morphologies. The follows were found to occur: intergranular penetration of Mg and Si on the base metal, a large amount of granular eutectic structure, and a significant grain boundary effect. The shear fracture of the lap joint presented cleavage fracture; in addition, with the decrease of the Mg2Si phases, the fracture morphology transformed from a rock candy shape to a steam shape, and cleavage steps appeared. The rock candy-shaped fracture areas enlarged after metamorphism treatment.
基金supported by the National Key R&D Program of China(Grant No.2021YFB2500100)the National Natural Science Foundation of China(Grant Nos.51872196 and 22109114).
文摘Solid-state electrolytes(SSEs)can address the safety issue of organic electrolyte in rechargeable lithium batteries.Unfortunately,neither polymer nor ceramic SSEs used alone can meet the demand although great progress has been made in the past few years.Composite solid electrolytes(CSEs)composed of flexible polymers and brittle but more conducting ceramics can take advantage of the individual system for solid-state lithium metal batteries(SSLMBs).CSEs can be largely divided into two categories by the mass fraction of the components:“polymer rich”(PR)and“ceramic rich”(CR)systems with different internal structures and electrochemical properties.This review provides a comprehensive and in-depth understanding of recent advances and limitations of both PR and CR electrolytes,with a special focus on the ion conduction path based on polymer-ceramic interaction mechanisms and structural designs of ceramic fillers/frameworks.In addition,it highlights the PR and CR which bring the leverage between the electrochemical property and the mechanical property.Moreover,it further prospects the possible route for future development of CSEs according to their rational design,which is expected to accelerate the practical application of SSLMBs.