Impact of ethanol on the flotation efficiency of imidazolium ionic liquids as collectors:Insights from dynamic surface tension and solvation analysis

To conduct extensive research on the application of ionic liquids as collectors in mineral flotation,ethanol(EtOH)was used as a solvent to dissolve hydrophobic ionic liquids(ILs)to simplify the reagent regime.Interesting phenomena were observed in which EtOH exerted different effects on the flotation efficiency of two ILs with similar structures.When EtOH was used to dissolve 1-dodecyl-3-methylimidazolium chloride(C12[mim]Cl)and as a collector for pure quartz flotation tests at a concentration of 1×10^(−5)mol·L^(−1),quartz recovery increased from 23.77%to 77.91%compared with ILs dissolved in water.However,quartz recovery of 1-dodecyl-3-methylim-idazolium hexafluorophosphate(C12[mim]PF6)decreased from 60.45%to 24.52%under the same conditions.The conditional experi-ments under 1×10^(−5)mol·L^(−1)ILs for EtOH concentration and under 2vol%EtOH for ILs concentration confirmed this difference.After being affected by EtOH,the mixed ore flotation tests of quartz and hematite showed a decrease in the hematite concentrate grade and re-covery for the C12[mim]Cl collector,whereas the hematite concentrate grade and recovery for the C12[mim]PF6 collector increased.On the basis of these differences and observations of flotation foam,two-phase bubble observation tests were carried out.The EtOH promoted the foam height of two ILs during aeration.It accelerated static froth defoaming after aeration stopped,and the foam of C12[mim]PF6 de-foaming especially quickly.In the discussion of flotation tests and foam observation,an attempt was made to explain the reasons and mechanisms behind the diverse phenomena using the dynamic surface tension effect and solvation effect results from EtOH.The solva-tion effect was verified through Fourier transform infrared(FT-IR),X-ray photoelectron spectroscopy(XPS),and Zeta potential tests.Al-though EtOH affects the adsorption of ILs on the ore surface during flotation negatively,it holds an positive value of inhibiting foam mer-ging during flotation aeration and accelerating the defoaming of static foam.And induce more robust secondary enrichment in the mixed ore flotation of the C12[mim]PF6 collector,facilitating effective mixed ore separation even under inhibitor-free conditions.

Suitable region of dynamic optimal interpolation for efficiently altimetry sea surface height mapping

The dynamic optimal interpolation(DOI)method is a technique based on quasi-geostrophic dynamics for merging multi-satellite altimeter along-track observations to generate gridded absolute dynamic topography(ADT).Compared with the linear optimal interpolation(LOI)method,the DOI method can improve the accuracy of gridded ADT locally but with low computational efficiency.Consequently,considering both computational efficiency and accuracy,the DOI method is more suitable to be used only for regional applications.In this study,we propose to evaluate the suitable region for applying the DOI method based on the correlation between the absolute value of the Jacobian operator of the geostrophic stream function and the improvement achieved by the DOI method.After verifying the LOI and DOI methods,the suitable region was investigated in three typical areas:the Gulf Stream(25°N-50°N,55°W-80°W),the Japanese Kuroshio(25°N-45°N,135°E-155°E),and the South China Sea(5°N-25°N,100°E-125°E).We propose to use the DOI method only in regions outside the equatorial region and where the absolute value of the Jacobian operator of the geostrophic stream function is higher than1×10^(-11).

Mechanical properties and fracture surface roughness of thermally damaged granite under dynamic splitting

In order to understand the mechanical properties and the fracture surface roughness characteristics of thermally damaged granite under dynamic splitting,dynamic Brazilian splitting tests were conducted on granite samples after thermal treatment at 25,200,400,and 600℃.Results show that the dynamic peak splitting strength of thermally damaged granite samples increases with increasing strain rate,showing obvious strain‐rate sensitivity.With increasing temperature,thermally induced cracks in granite transform from intergranular cracks to intragranular cracks,and to a transgranular crack network.Thermally induced damages reduce the dynamic peak splitting strength and the maximum absorbed energy while increasing the peak radial strain.The fracture mode of the thermally damaged granite under dynamic loads is mode Ⅱ splitting failure.By using the axial roughness index Z2 a,the distribution ranges of the wedge‐shaped failure zones and the tensile failure zones in the fracture surfaces under dynamic Brazilian splitting can be effectively identified.The radial roughness index Z_(2)^(r)is sensitive to the strain rate and temperature.It shows a linear correlation with the peak splitting strength and the maximum absorbed energy and a linear negative correlation with the peak radial strain.Z_(2)^(r)can be used to quantitatively estimate the dynamic parameters based on the models proposed.

Droplet Condensation and Transport Properties on Multiple Composite Surface:A Molecular Dynamics Study

To investigate the microscopicmechanism underlying the influence of surface-chemical gradient on heat andmass recovery,a molecular dynamicsmodel including droplet condensation and transport process has been developed to examine heat and mass recovery performance.This work aimed at identify optimal conditions for enhancing heat and mass recovery through the combination of wettability gradient and nanopore transport.For comprehensive analysis,the structure in the simulation was categorized into three distinct groups:a homogeneous structure,a small wettability gradient,and a large wettability gradient.The homogeneous surface demonstrated low efficiency in heat and mass transfer,as evidenced by filmwise condensation.In contrast,the surface with a small wettability gradient experienced a transition from dropwise condensation to filmwise condensation,resulting in a gradual decrease in the efficiency of vapor heat and mass transfer.Only a large wettability gradient could achieve periodic and efficient dropwise condensation heat and mass transfer which was attributed to the rapid droplet coalescence and transport to the nanopore after condensing on the cold surface.

Robust adaptive dynamic surface control for nonlinear uncertain systems

We propose a new method for robust adaptive backstepping control of nonlinear systems with parametric uncertainties and disturbances in the strict feedback form. The method is called dynamic surface control. Traditional backstepping algorithms require repeated differentiations of the modelled nonlinearities. The addition of n first order low pass filters allows the algorithm to be implemented without differentiating any model nonlinearities, thus ending the complexity arising due to the 'explosion of terms' that makes other methods difficult to implement in practice. The combined robust adaptive backstepping/first order filter system is proved to be semiglobally asymptotically stable for sufficiently fast filters by a singular perturbation approach. The simulation results demonstrate the feasibility and effectiveness of the controller designed by the method.

Numerical simulation of dynamic surface deformation based on DInSAR monitoring

Differential interferometric synthetic aperture radar （DInSAR） technology is a new method to monitor the dynamic surface subsidence. It can monitor the large scope of dynamic deformation process of surface subsidence basin and better reflect the surface subsidence form in different stages. But under the influence of factors such as noise and other factors, the tilt and horizontal deformation curves regularity calculated by DInSAR data are poorer and the actual deviation is larger. The tilt and horizontal deformations are the important indices for the safety of surface objects protection. Numerical simulation method was used to study the dynamic deformation of LW32 of West Cliff colliery in Australia based on the DInSAR monitoring data. The result indicates that the subsidence curves of two methods fit well and the correlation coefficient is more than 95%. The other deformations calculated by numerical simulation results are close to the theory form. Therefore, considering the influence, the surface and its subsidiary structures and buildings due to mining, the numerical simulation method based on the DInSAR data can reveal the distribution rules of the surface dynamic deformation values and supply the shortcomings of DInSAR technology. The research shows that the method has good applicability and can provide reference for similar situation.

Adaptive Dynamic Surface Control for Integrated Missile Guidance and Autopilot

Integrated guidance and control for homing missiles utilizing adaptive dynamic surface control approach is considered based on the three channels independence design idea. A time-varying integrated guidance and control model with unmatched uncertainties is first formulated for the pitch channel, and an adaptive dynamic surface control algorithm is further developed to deal with these unmatched uncertainties. It is proved that the proposed feedback controller can ensure not only the accuracy of target interception, but also the stability of the missile dynamics. Then, the same control approach is further applied to the control design of the yaw and roll channels. The 6-degree-of-freedom （6-DOF） nonlinear missile simulation results demonstrate the feasibility and advantage of the proposed integrated guidance and control design scheme.

Distributed Collaborative Response Surface Method for Mechanical Dynamic Assembly Reliability Design

Because of the randomness of many impact factors influencing the dynamic assembly relationship of complex machinery, the reliability analysis of dynamic assembly relationship needs to be accomplished considering the randomness from a probabilistic perspective. To improve the accuracy and efficiency of dynamic assembly relationship reliability analysis, the mechanical dynamic assembly reliability（MDAR） theory and a distributed collaborative response surface method（DCRSM） are proposed. The mathematic model of DCRSM is established based on the quadratic response surface function, and verified by the assembly relationship reliability analysis of aeroengine high pressure turbine（HPT） blade-tip radial running clearance（BTRRC）. Through the comparison of the DCRSM, traditional response surface method（RSM） and Monte Carlo Method（MCM）, the results show that the DCRSM is not able to accomplish the computational task which is impossible for the other methods when the number of simulation is more than 100 000 times, but also the computational precision for the DCRSM is basically consistent with the MCM and improved by 0.40-4.63% to the RSM, furthermore, the computational efficiency of DCRSM is up to about 188 times of the MCM and 55 times of the RSM under 10000 times simulations. The DCRSM is demonstrated to be a feasible and effective approach for markedly improving the computational efficiency and accuracy of MDAR analysis. Thus, the proposed research provides the promising theory and method for the MDAR design and optimization, and opens a novel research direction of probabilistic analysis for developing the high-performance and high-reliability of aeroengine.

Dynamic shear modulus of undisturbed soil under different consolidation ratios and its effects on surface ground motion

The dynamic shear modulus for three types of undisturbed soil under different consolidation ratios is presented by using the resonant column test method. Its effects on surface ground motion is illustrated by calculation. The test results indicate that the power function is a suitable form for describing the relationship between the ratio of the maximum dynamic shear modulus due to anisotropic and isotropic consolidations and the increment of the consolidation ratio. When compared to sand, the increment of the maximum dynamic shear modulus for undisturbed soil due to anisotropic consolidation is much larger. Using a one-dimensional equivalent linearization method, the earthquake influence factor and the characteristic period of the surface acceleration are calculated for two soil layers subjected to several typical earthquake waves. The calculated results show that the difference in nonlinear properties due to different consolidation ratios is generally not very notable, but the degree of its influence on the surface acceleration spectrum is remarkable for the occurrence of strong earthquakes. When compared to isotropic consolidation, the consideration of actual anisotropic consolidation causes the characteristic period to decrease and the earthquake influence factor to increase.

Adaptive dynamic surface control for air-breathing hypersonic vehicle

This paper describes an adaptive control approach for an air-breathing hypersonic vehicle. The control objective is to provide robust altitudes and velocity tracking in the presence of model uncertainties and varying disturbances. A fuzzy-neural disturbance observer is developed to estimate uncertainties and disturbances, and the adaptive controller is synthesized by the dynamic surface approach combing with the observer. The tracking error at the steady state can be guaranteed to converge to inside of a small residue set which the size of the set can be an arbitrary small value. Simulation results demonstrate the effectiveness of the presented approach.

Output-feedback Dynamic Surface Control for a Class of Nonlinear Non-minimum Phase Systems

In this paper, an output-feedback tracking controller is proposed for a class of nonlinear non-minimum phase systems.To keep the unstable internal dynamics bounded, the method of output redefinition is applied to let the stability of the internal dynamics depend on that of redefined output, thus we only need to consider the new external dynamics rather than internal dynamics in the process of designing control law. To overcome the explosion of complexity problem in traditional backstepping design, the dynamic surface control(DSC) method is firstly used to deal with the problem of tracking control for the nonlinear non-minimum phase systems. The proposed outputfeedback DSC controller not only forces the system output to asymptotically track the desired trajectory, but also drives the unstable internal dynamics to follow its corresponding bounded and causal ideal internal dynamics, which is solved via stable system center method. Simulation results illustrate the validity of the proposed output-feedback DSC controller.

Dynamic modeling of wave driven unmanned surface vehicle in longitudinal profile based on D-H approach

Wave driven unmanned surface vehicle(WUSV) is a new concept ocean robot drived by wave energy and solar energy,and it is very suitable for the vast ocean observations with incomparable endurance.Its dynamic modeling is very important because it is the theoretical foundation for further study in the WUSV motion control and efficiency analysis.In this work,the multibody system of WUSV was described based on D-H approach.Then,the driving principle was analyzed and the dynamic model of WUSV in longitudinal profile is established by Lagrangian mechanics.Finally,the motion simulation of WUSV and comparative analysis are completed by setting different inputs of sea state.Simulation results show that the WUSV dynamic model can correctly reflect the WUSV longitudinal motion process,and the results are consistent with the wave theory.

A Surface Femtosecond Two-Photon Photoemission Spectrometer for Excited Electron Dynamics and Time-Dependent Photochemical Kinetics

A surface femtosecond two-photon photoemission （2PPE） spectrometer devoted to the study of ultrafast excited electron dynamics and photochemical kinetics on metal and metal oxide surfaces has been constructed. Low energy photoelectrons are measured using a hemispherical electron energy analyzer with an imaging detector that allows us to detect the energy and the angular distributions of the photoelectrons simultaneously. A Mach-Zehnder interferom- eter was built for the time-resolved 2PPE （TR-2PPE） measurement to study ultrafast surface excited electron dynamics, which was demonstrated on the Cu（111） surface. A scheme for measuring time-dependent 2PPE （TD-2PPE） spectra has also been developed for studies of surface photochemistry. This technique has been applied to a preliminary study on the photochemical kinetics on ethanol/TiO2（110）. We have also shown that the ultrafast dynamics of photoinduced surface excited resonances can be investigated in a reliable way by combining the TR-2PPE and TD-2PPE techniques.

Dynamic Responses of Top Tensioned Riser Under Combined Excitation of Internal Solitary Wave, Surface Wave and Vessel Motion

An investigation on the dynamic response of a top tensioned riser （TTR） under combined excitation of internal solitary wave, surface wave and vessel motion is presented in this paper. The riser is idealized as a tensioned slender beam with dynamic boundary conditions. The KdV-mKdV equation is chosen to simulate the internal solitary wave, and the vessel motion is analysed by using the method proposed by Sexton. Using finite element method, the governing equation is solved in time domain with Newmark-13 method. The computation programs for solving the differential equations in time domain are compiled and numerical results are obtained, including dimensionless displacement and stress. The action of internal solitary wave on the riser is like a slow powerful impact, and is much larger than those of surface wave and vessel motion. When the riser is under combined excitation, it vibrates at frequencies of both surface wave and vessel motion, and the vibration is dominated by internal solitary wave. As the internal solitary wave crest passes by the centre of the riser, the maximum displacement and stress along the riser occur. Compared to the lower part, the displacement and stress of the riser in the upper part are much larger.

Impact of Spin-up Forcing on Vegetation States Simulated by a Dynamic Global Vegetation Model Coupled with a Land Surface Model

A dynamic global vegetation model （DGVM） coupled with a land surface model （LSM） is generally initialized using a spin-up process to derive a physically-consistent initial condition. Spin-up forcing, which is the atmospheric forcing used to drive the coupled model to equilibrium solutions in the spin-up process, varies across earlier studies. In the present study, the impact of the spin-up forcing in the initialization stage on the fractional coverages （FCs） of plant functional type （PFT） in the subsequent simulation stage are assessed in seven classic climate regions by a modified Community Land Model’s Dynamic Global Vegetation Model （CLM-DGVM）. Results show that the impact of spin-up forcing is considerable in all regions except the tropical rainforest climate region （TR） and the wet temperate climate region （WM）. In the tropical monsoon climate region （TM）, the TR and TM transition region （TR-TM）, the dry temperate climate region （DM）, the highland climate region （H）, and the boreal forest climate region （BF）, where FCs are affected by climate non-negligibly, the discrepancies in initial FCs, which represent long-term cumulative response of vegetation to different climate anomalies, are large. Moreover, the large discrepancies in initial FCs usually decay slowly because there are trees or shrubs in the five regions. The intrinsic growth timescales of FCs for tree PFTs and shrub PFTs are long, and the variation of FCs of tree PFTs or shrub PFTs can affect that of grass PFTs.

Improving the Vegetation Dynamic Simulation in a Land Surface Model by Using a Statistical-dynamic Canopy Interception Scheme

Canopy interception of incident precipitation, as a critical component of a forest＇s water budget, can affect the amount of water available to the soil, and ultimately vegetation distribution and function. In this paper, a statistical-dynamic approach based on leaf area index and statistical canopy interception is used to parameterize the canopy interception process. The statistical-dynamic canopy interception scheme is implemented into the Community Land Model with dynamic global vegetation model （CLM-DGVM） to improve its dynamic vegetation simulation. The simulation for continental China by the land surface model with the new canopy interception scheme shows that the new one reasonably represents the precipitation intercepted by the canopy. Moreover, the new scheme enhances the water availability in the root zone for vegetation growth, especially in the densely vegetated and semi-arid areas, and improves the model＇s performance of potential vegetation simulation.

Adaptive Fuzzy Dynamic Surface Control for Uncertain Nonlinear Systems

In this paper, a robust adaptive fuzzy dynamic surface control for a class of uncertain nonlinear systems is proposed. A novel adaptive fuzzy dynamic surface model is built to approximate the uncertain nonlinear functions by only one fuzzy logic system. The approximation capability of this model is proved and the model is implemented to solve the problem that too many approximators are used in the controller design of uncertain nonlinear systems. The shortage of ＂explosion of complexity＂ in backstepping design procedure is overcome by using the proposed dynamic surface control method. It is proved by constructing appropriate Lyapunov candidates that all signals of closed-loop systems are semi-globally uniformly ultimate bounded. Also, this novel controller stabilizes the states of uncertain nonlinear systems faster than the adaptive sliding mode controller （SMC）. Two simulation examples are provided to illustrate the effectiveness of the control approach proposed in this paper.

Adaptive Neural Network Dynamic Surface Control for Perturbed Nonlinear Time-delay Systems

This paper proposes an adaptive neural network control method for a class of perturbed strict-feedback nonlinear systems with unknown time delays. Radial basis function neural networks are used to approximate unknown intermediate control signals. By constructing appropriate Lyapunov-Krasovskii functionals, the unknown time delay terms have been compensated. Dynamic surface control technique is used to overcome the problem of ＂explosion of complexity＂ in backstepping design procedure. In addition, the semiglobal uniform ultimate boundedness of all the signals in the closed-loop system is proved. A main advantage of the proposed controller is that both problems of ＂curse of dimensionality＂ and ＂explosion of complexity＂ are avoided simultaneously. Finally, simulation results are presented to demonstrate the effectiveness of the approach.

Trajectory tracking control for underactuated unmanned surface vehicles with dynamic uncertainties

The trajectory tracking control problem for underactuated unmanned surface vehicles(USV) was addressed, and the control system took account of the uncertain influences induced by model perturbation, external disturbance, etc. By introducing the reference, trajectory was generated by a virtual USV, and the error equation of trajectory tracking for USV was obtained, which transformed the tracking problem of underactuated USV into the stabilization problem of the trajectory tracking error equation. A backstepping adaptive sliding mode controller was proposed based on backstepping technology and method of dynamic slide model control. By means of theoretical analysis, it is proved that the proposed controller ensures that the solutions of closed loop system have the ultimate boundedness property. Simulation results are presented to illustrate the effectiveness of the proposed controller.

Global Robust and Adaptive Output Feedback Dynamic Positioning of Surface Ships

A constructive method was presented to design a global robust and adaptive output feedback controller for dynamic positioning of surface ships under environmental disturbances induced by waves, wind, and ocean currents. The ship's parameters were not required to be known. An adaptive observer was first designed to estimate the ship's velocities and parameters. The ship position measurements were also passed through the adaptive observer to reduce high frequency measurement noise from entering the control system. Using these estimate signals, the control was then designed based on Lyapunov's direct method to force the ship's position and orientation to globally asymptotically converge to desired values. Simulation results illustrate the effectiveness of the proposed control system. In conclusion, the paper presented a new method to design an effective control system for dynamic positioning of surface ships.