Reactions of NaAcebiim （NaAcebiim = 1-acetic acid-2, 2＇-biimidazote monoso- dium salt） and cadmium or zinc nitrate produce two supramolecular architectures, namely, 1D [Cd（Acebiim）（NO3）（H20）]n （1） and 0D [Z...Reactions of NaAcebiim （NaAcebiim = 1-acetic acid-2, 2＇-biimidazote monoso- dium salt） and cadmium or zinc nitrate produce two supramolecular architectures, namely, 1D [Cd（Acebiim）（NO3）（H20）]n （1） and 0D [Zn（Acebiim）2（H20）2]＇2H20 （2） in acidic aqueous solutions. Single-crystal X-ray diffraction analysis reveals that complex 1 crystallizes in the triclinic system, space group Pi, and 2 is of monoclinic system, space group P2 1/n. In 1, two nitrate groups link two Cd（Ⅱ） ions forming [Cd2（NO3）2（H20）2] as secondary building units that are interconnected by the Acebiim ligand into an infinite ladder. In2, the hydrogen-bonded synthon R22（16） between the N-H moieties and carboxylic acid link [Zn（Acebiim）2（H20）2], generating a 1D-extended ribbon. Moreover, hydrogen bonds and π-π interactions further stabilize the 3D supramolecular architecture.展开更多
Thermal effect in crystals is the main obstacle blocking diode-pumped solid state laser to get high and stable output power. Diffusion bonding crystal has been demonstrated to be an effective method to relieve the the...Thermal effect in crystals is the main obstacle blocking diode-pumped solid state laser to get high and stable output power. Diffusion bonding crystal has been demonstrated to be an effective method to relieve the thermal lensing theoretically based on the numerical heat analysis to the end-pumped anisotropic laser crystal. The temperature distributions in Nd：YVO4/YVO4 composite crystal and conventional crystal were analyzed and compared. The end-pumped Nd：YVO4/YVO4 composite crystal laser was designed and set up with z-cavity. The maximum output powers of 9.87 W at 1064 nm and 6.14 W at 532 nm were obtained at the incident pump power of 16.5 W. The highest optical-optical conversion efficiencies were up to 59.8% at 1064 nm and 37.2% at 532 nm respectively.展开更多
In this work,competition between different supramolecular interactions is investigated based on a fibrous crystal composed of hydrogen-bonded cyanuric acid(CA)and amidinothiourea(ADT).Melamine(M)is found to prevail ov...In this work,competition between different supramolecular interactions is investigated based on a fibrous crystal composed of hydrogen-bonded cyanuric acid(CA)and amidinothiourea(ADT).Melamine(M)is found to prevail over ADT and bond to CA due to its stronger triple H-bonding affiliation,forming hollow microtubes assembled by oriented CAM crystalline arrays,as guided by the directionality of peripheral hydrogen bonds.Furthermore,competitive interaction between hydrogen bonding and ionic/covalent bonding is demonstrated by mixing Ag+ions with the CA-ADT fibers,where sulfur atoms are abstracted from ADT molecules to produce Ag_(2)S ligaments.The in situ-formed Ag_(2)S serves as a binding glue to generate CA-ADT/Ag_(2)S composites with significantly enhanced mechanical strength compared to the pristine CA-ADT fiber pellet.展开更多
报道了相同实验条件下激光二极管端面抽运生长型复合Nd:YVO4晶体声光调Q和RTP电光调Q激光器。应用声光调Q和RTP电光调Q分别实现了最高重复频率200 k Hz和500 k Hz的TEM00模1 064 nm激光输出,输出平均功率分别达到12.13 W和13.56 W,脉冲...报道了相同实验条件下激光二极管端面抽运生长型复合Nd:YVO4晶体声光调Q和RTP电光调Q激光器。应用声光调Q和RTP电光调Q分别实现了最高重复频率200 k Hz和500 k Hz的TEM00模1 064 nm激光输出,输出平均功率分别达到12.13 W和13.56 W,脉冲宽度分别为16.65 ns和27.27 ns,并首次对比了两种调Q体制下的高重频激光输出特性。实验结果表明,RTP电光调Q具有更好的高重频关断能力,但由于受到高压驱动的限制,RTP电光调Q无法在更高重复频率下实现窄脉宽高峰值功率激光输出,而在更高重频下仍有较好输出性能的声光调Q将取代电光调Q成为几百千甚至上兆Hz高重频激光器的首选调Q机制。展开更多
基金supported by the National Natural Science Foundation of China(No.#21003125,21073190)the Natural Science Foundation of Fujian Province(2010 J01057)
文摘Reactions of NaAcebiim （NaAcebiim = 1-acetic acid-2, 2＇-biimidazote monoso- dium salt） and cadmium or zinc nitrate produce two supramolecular architectures, namely, 1D [Cd（Acebiim）（NO3）（H20）]n （1） and 0D [Zn（Acebiim）2（H20）2]＇2H20 （2） in acidic aqueous solutions. Single-crystal X-ray diffraction analysis reveals that complex 1 crystallizes in the triclinic system, space group Pi, and 2 is of monoclinic system, space group P2 1/n. In 1, two nitrate groups link two Cd（Ⅱ） ions forming [Cd2（NO3）2（H20）2] as secondary building units that are interconnected by the Acebiim ligand into an infinite ladder. In2, the hydrogen-bonded synthon R22（16） between the N-H moieties and carboxylic acid link [Zn（Acebiim）2（H20）2], generating a 1D-extended ribbon. Moreover, hydrogen bonds and π-π interactions further stabilize the 3D supramolecular architecture.
基金This work was supported by the Science & Technology Research Fund of Shandong Province under Grant No. 031080125The authors would like to appreciate for the support from Science & Technology Board of Shandong Province.
文摘Thermal effect in crystals is the main obstacle blocking diode-pumped solid state laser to get high and stable output power. Diffusion bonding crystal has been demonstrated to be an effective method to relieve the thermal lensing theoretically based on the numerical heat analysis to the end-pumped anisotropic laser crystal. The temperature distributions in Nd：YVO4/YVO4 composite crystal and conventional crystal were analyzed and compared. The end-pumped Nd：YVO4/YVO4 composite crystal laser was designed and set up with z-cavity. The maximum output powers of 9.87 W at 1064 nm and 6.14 W at 532 nm were obtained at the incident pump power of 16.5 W. The highest optical-optical conversion efficiencies were up to 59.8% at 1064 nm and 37.2% at 532 nm respectively.
基金the financial support by the Australian Research Council.
文摘In this work,competition between different supramolecular interactions is investigated based on a fibrous crystal composed of hydrogen-bonded cyanuric acid(CA)and amidinothiourea(ADT).Melamine(M)is found to prevail over ADT and bond to CA due to its stronger triple H-bonding affiliation,forming hollow microtubes assembled by oriented CAM crystalline arrays,as guided by the directionality of peripheral hydrogen bonds.Furthermore,competitive interaction between hydrogen bonding and ionic/covalent bonding is demonstrated by mixing Ag+ions with the CA-ADT fibers,where sulfur atoms are abstracted from ADT molecules to produce Ag_(2)S ligaments.The in situ-formed Ag_(2)S serves as a binding glue to generate CA-ADT/Ag_(2)S composites with significantly enhanced mechanical strength compared to the pristine CA-ADT fiber pellet.
