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Adsorption and Ozonation Kinetic Model for Phenolic Wastewater Treatment 被引量:13
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作者 Wongsarivej Pratarn TongpremPornsiri +2 位作者 Swasdisevi Thanit Charinpanitkul Tawatchai Tanthapanichakoon Wiwut 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2011年第1期76-82,共7页
A three phase fluidized bed reactor was used to investigate the combined effect of adsorption and oxidation for phenolic wastewater treatment.Aqueous solutions containing 10 mg·L 1of phenol and ozone were continu... A three phase fluidized bed reactor was used to investigate the combined effect of adsorption and oxidation for phenolic wastewater treatment.Aqueous solutions containing 10 mg·L 1of phenol and ozone were continuously fed co-currently as upward flow into the reactor at constant flow rate of 2 and 1 L·min 1,respectively.The phenolic treatment results in seven cases were compared:(a)O3 only,(b)fresh granular activated carbon(GAC),(c) 1st reused GAC,(d)2nd reused GAC,(e)fresh GAC enhanced with O3,(f)1st reused GAC enhanced with O3,and (g)2nd reused GAC enhanced with O3.The phenolic wastewater was re-circulated through the reactor and its concentration was measured with respect to time.The experimental results revealed that the phenolic degradation using GAC enhanced with O3 provided the best result.The effect of adsorption by activated carbon was stronger than the effect of oxidation by ozone.Fresh GAC could adsorb phenol better than reused GAC.All cases of adsorption on GAC followed the Langmuir isotherm and displayed pseudo second order adsorption kinetics.Finally,a differential equation for the fluidized bed reactor model was used to describe the phenol concentration with respect to time for GAC enhanced with O3.The calculated results agree reasonably well with the experimental results. 展开更多
关键词 adsorption OZONATION kinetic model PHENOL wastewater
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An overview of geological originated materials as a trend for adsorption in wastewater treatment
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作者 Yasmin Vieira Matias Schadeck Netto +3 位作者 Éder C.Lima Ioannis Anastopoulos Marcos L.S.Oliveira Guilherme L.Dotto 《Geoscience Frontiers》 SCIE CAS CSCD 2022年第1期457-477,共21页
Adsorption is a unit operation widely used for the tertiary treatment of the most diverse effluents,whose mechanism is based on removing recalcitrant compounds from the organic and inorganic origin.In this process,cho... Adsorption is a unit operation widely used for the tertiary treatment of the most diverse effluents,whose mechanism is based on removing recalcitrant compounds from the organic and inorganic origin.In this process,choosing a suitable adsorbent is a fundamental point.This review article focuses on the adsorbents with natural geological origin:minerals,clays,geopolymers,and even wastes resulted from mining activity.Therefore,over 450 articles and research papers were explored.These materials’main sources are described,and their characteristics,composition,and intrinsic properties are related to adsorption.Herein,we discuss the effects of several process parameters,such as p H,temperature,pollutant,and adsorbent concentration.Furthermore,equilibrium,kinetics,and thermodynamic aspects are also addressed,and relevant regeneration prospects and final disposal.Finally,some suggestions and perspectives on applying these adsorbents in wastewater treatment are presented as future trends. 展开更多
关键词 adsorption EQUILIBRIUM Geological-based adsorbents Process parameters wastewater treatment
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Urban Wastewater Treatment by Adsorption of Organic Matters on Modified Bentonite by(Iron-Aluminum)
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作者 Mecabih Zohra Jérome Rose Daniel Borschneck 《Journal of Encapsulation and Adsorption Sciences》 2014年第3期71-79,共9页
In this research, the natural bentonite clay (from Maghnia, western Algeria) was purified (Na+- montmorillonite, CEC = 91 meq/100 g), noted (puri.bent) and modified with mixed hydroxy-Fe-Al (FeAl-PILC). The purified b... In this research, the natural bentonite clay (from Maghnia, western Algeria) was purified (Na+- montmorillonite, CEC = 91 meq/100 g), noted (puri.bent) and modified with mixed hydroxy-Fe-Al (FeAl-PILC). The purified bentonite clay and FeAl-PILC were heated at 383 K for 2 hr and characte-rized by the chemical analyses data, XRD, and N2 adsorption to 77 K techniques. Puri.bent and FeAl-PILC were applied to fix the organic matter (OM) present in urban wastewater from the city of Sidi Bel-Abbes (western Algeria). The adsorption of organic matter was followed by spectro-photometry at 470 nm, and the adsorption data were a good fit with Freundlich isotherm for pu-ri.bent but for FeA-lPILC, were well fit by Elovitch isotherm model. The maximum adsorption ca-pacity (qm) was 571.6 mg/g for puri.bent and 1120.69 mg/g for FeAl-PLC. The degree of OM removal was 67% for puri.bent and 97% for FeAl-PILC. FeAl-PILC can be considered as a promising adsorbent for the removal of OM from wastewater. 展开更多
关键词 adsorption Urban wastewater Bentonite Clay Isotherm Models
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Scalable Ir‑Doped NiFe_(2)O_(4)/TiO_(2)Heterojunction Anode for Decentralized Saline Wastewater Treatment and H_(2)Production
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作者 Sukhwa Hong Jiseon Kim +3 位作者 Jaebeom Park Sunmi Im Michael R.Hoffmann Kangwoo Cho 《Nano-Micro Letters》 SCIE EI CAS 2025年第3期1-18,共18页
Wastewater electrolysis cells(WECs)for decentralized wastewater treatment/reuse coupled with H_(2)production can reduce the carbon footprint associated with transportation of water,waste,and energy carrier.This study ... Wastewater electrolysis cells(WECs)for decentralized wastewater treatment/reuse coupled with H_(2)production can reduce the carbon footprint associated with transportation of water,waste,and energy carrier.This study reports Ir-doped NiFe_(2)O_(4)(NFI,~5 at%Ir)spinel layer with TiO_(2)overlayer(NFI/TiO_(2)),as a scalable heterojunction anode for direct electrolysis of wastewater with circumneutral pH in a single-compartment cell.In dilute(0.1 M)NaCl solutions,the NFI/TiO_(2)marks superior activity and selectivity for chlorine evolution reaction,outperforming the benchmark IrO_(2).Robust operation in near-neutral pH was confirmed.Electroanalyses including operando X-ray absorption spectroscopy unveiled crucial roles of TiO_(2) which serves both as the primary site for Cl−chemisorption and a protective layer for NFI as an ohmic contact.Galvanostatic electrolysis of NH4+-laden synthetic wastewater demonstrated that NFI/TiO_(2)not only achieves quasi-stoichiometric NH_(4)^(+)-to-N_(2)conversion,but also enhances H_(2)generation efficiency with minimal competing reactions such as reduction of dissolved oxygen and reactive chlorine.The scaled-up WEC with NFI/TiO_(2)was demonstrated for electrolysis of toilet wastewater. 展开更多
关键词 wastewater electrolysis cell Ir-doped NiFe_(2)O_(4) Reactive chlorine species Decentralized H_(2)production On-site wastewater treatment
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Ordered mesoporous materials for water pollution treatment:Adsorption and catalysis 被引量:1
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作者 Peng Zhang Mingming He +4 位作者 Wei Teng Fukuan Li Xinyuan Qiu Kexun Li Hao Wang 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第8期1239-1256,共18页
To meet the growing emission of water contaminants,the development of new materials that enhance the efficiency of the water treatment system is urgent.Ordered mesoporous materials provide opportunities in environment... To meet the growing emission of water contaminants,the development of new materials that enhance the efficiency of the water treatment system is urgent.Ordered mesoporous materials provide opportunities in environmental processing applications due to their exceptionally high surface areas,large pore sizes,and enough pore volumes.These properties might enhance the performance of materials concerning adsorption/catalysis capability,durability,and stability.In this review,we enumerate the ordered mesoporous materials as adsorbents/catalysts and their modifications in water pollution treatment from the past decade,including heavy metals(Hg^(2+),Pb^(2+),Cd^(2+),Cr^(6+),etc.),toxic anions(nitrate,phosphate,fluoride,etc.),and organic contaminants(organic dyes,antibiotics,etc.).These contributions demonstrate a deep understanding of the synergistic effect between the incorporated framework and homogeneous active centers.Besides,the challenges and perspectives of the future developments of ordered mesoporous materials in wastewater treatment are proposed.This work provides a theoretical basis and complete summary for the application of ordered mesoporous materials in the removal of contaminants from aqueous solutions. 展开更多
关键词 Water pollution treatment Ordered mesoporous materials Toxic contaminants adsorption CATALYSIS
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Magnesium oxide(MgO)nanoadsorbents in wastewater treatment:A comprehensive review
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作者 H.C.S.Perera V.Gurunanthanan +3 位作者 Anoop Singh M.M.M.G.P.G.Mantilaka G.Das Sandeep Arya 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第5期1709-1773,共65页
Wastewater contamination by heavy metals and synthetic dyes presents a significant environmental challenge,necessitating effective and sustainable separation techniques.This review article provides a detailed examinat... Wastewater contamination by heavy metals and synthetic dyes presents a significant environmental challenge,necessitating effective and sustainable separation techniques.This review article provides a detailed examination of magnesium oxide(MgO)nanoparticles as an innovative nanoadsorbent for wastewater treatment,with a specific focus on heavy metal and dye removal.The review comprehensively explores various aspects of MgO nanoparticles,including their structural characteristics and synthesis techniques.The article delves into the morphology and crystallographic arrangement of MgO nanoparticles,offering insights into their structural attributes.Given the complexity of adsorption processes,the review identifies and analyzes parameters influencing the adsorption efficiency of MgO nanoparticles,such as temperature,pH,contact time,initial concentration,and co-existing ions.The interplay between these parameters and the adsorption capability of MgO nanoparticles emphasizes the importance of optimizing operational conditions.Furthermore,the review assesses various synthesis methods for MgO nanoparticles,including sol-gel,hydrothermal,precipitation,green synthesis,solvothermal,and template-assisted techniques.It discusses the advantages,limitations,and resulting nanoparticle characteristics of each method,enabling readers to grasp the implications of synthesis processes on adsorption efficiency.This comprehensive review consolidates current insights into the effectiveness of MgO nanoparticles as a potent nanoadsorbent for removing heavy metals and dyes from wastewater covering a wide spectrum of aspects related to MgO nanoparticles.Moreover,there is a need to investigate the use of MgO in the treatment of actual wastewater or river water,in order to leverage its cost-effectiveness and high efficiency for practical water treatment applications in real-time. 展开更多
关键词 MgO nanoparticles Nanoadsorbent wastewater treatment Heavy metals Dye separation adsorption Synthesis methods
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Mechanism study of Cu(Ⅱ) adsorption from acidic wastewater by ultrasonic-modified municipal solid waste incineration fly ash
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作者 Shunda lin Yang Lu +3 位作者 Lin Zheng Ling Long Xuguang Jiang Jianhua Yan 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第3期157-165,共9页
High concentrations of copper ions(Cu(Ⅱ)) in water will pose health risks to humans and the ecological environment. Therefore, this study aims to utilize ultrasonic-cured modified municipal solid waste incineration(M... High concentrations of copper ions(Cu(Ⅱ)) in water will pose health risks to humans and the ecological environment. Therefore, this study aims to utilize ultrasonic-cured modified municipal solid waste incineration(MSWI) fly ash for Cu(Ⅱ) adsorption to achieve the purpose of “treating waste by waste.” The effects of p H, adsorption time, initial concentration, and temperature on the modified MSWI fly ash’s adsorption efficiency were systematically studied in this article. The adsorption performance of the modified MSWI fly ash can be enhanced by the ultrasonic modification. At pH = 2, 3 and 4, the adsorption capacity of the modified MSWI fly ash for Cu(Ⅱ) increased by 2.7, 1.9 and 1.2 times, respectively. Furthermore, it was suggested that the adsorption process of the modified MSWI fly ash can be better simulated by the pseudo-second-order kinetic model, with a maximum adsorption capacity calculated by the Langmuir model of 24.196 mg.g-1. Additionally, the adsorption process is spontaneous,endothermic, and chemisorption-dominated from the thermodynamic studies(ΔH and ΔS > 0, ΔG < 0).Finally, the enhanced adsorption performance of the modified MSWI fly ash for Cu(Ⅱ) may be attributed to electrostatic interaction and chelation effects. 展开更多
关键词 ULTRASOUND MSWI fly ash Cu(Ⅱ) wastewater adsorption
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Effective removal of chromium,copper,and nickel heavy metal ions from industrial electroplating wastewater by in situ oxidative adsorption using sodium hypochlorite as oxidant and sodium trititanate nanorod as adsorbent
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作者 Muhammad Tayyab Butt Hengbo Yin 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第10期312-330,共19页
Sodium hypochlorite and synthesized sodium trititanate nanorods(Na_(2)Ti_(3)O_(7),186 nm×1270 nm)were used as the oxidant and adsorbents for in situ oxidative adsorption treatment of actual electroplating wastewa... Sodium hypochlorite and synthesized sodium trititanate nanorods(Na_(2)Ti_(3)O_(7),186 nm×1270 nm)were used as the oxidant and adsorbents for in situ oxidative adsorption treatment of actual electroplating wastewater containing Cr(Ⅵ)(2.6-5.2 mg·L^(-1)),Cu^(2+)(2.7-5.4 mg·L^(-1)),and Ni^(2+)(0.2705-0.541 mg·L^(-1))ions at pH of 8.8-9.1 and 20-60℃.The as-synthesized sodium trititanate nanorods were characterized by XRD,HRTEM,N2 adsorption/desorption,SEM,EDX,and zeta potential techniques.The concentrations of heavy metal ions in wastewater were analyzed by ICP technique.After in situ oxidative adsorption treatment under the concentrations of 25 g·L^(-1) for sodium hypochlorite and 125 mg·L^(-1) for sodium trititanate nanorods at 60℃ for 5 h,the heavy metal ion concentrations could be reduced from initial value of 2.6 to final value of 1.92 mg·L^(-1) for Cr(Ⅵ),3.6 to 0.17 mg·L^(-1) for Cu^(2+),and from 0.2705 to 0.097 mg·L^(-1) for Ni^(2+),respectively.Cr(Ⅵ),Cu^(2+) and Ni^(2+) ions could be effectively removed by the in situ oxidative adsorption method.The in situ oxidative adsorption processes of Cr(Ⅵ),Cu^(2+) and Ni^(2+) ions are satisfactorily simulated by the pseudo-second order adsorption kinetics and Langmuir adsorption isotherm,respectively.Adsorption thermodynamics analyses reveal that the oxidative adsorption processes of Cr(Ⅵ),Cu^(2+) and Ni^(2+) ions are spontaneous and endothermic.The oxidation degree of metalcontained complexes influences the values of thermodynamics functions. 展开更多
关键词 Heavy metals Oxidative adsorption Electroplating wastewater Sodium trititanate nanorods Nanomaterials Oxidation
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Review of wastewater treatment technologies,soil and water conservation measures in nuclear power plants,and inspirations to Fukushima accident
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作者 WANG Chu NIU Jianzhi +2 位作者 LUN Xiaoxiu ZHANG Linus BERNDTSSON Ronny 《中国水土保持科学》 CSCD 北大核心 2024年第6期10-28,193-200,共27页
[Background]The previous studies suggest that radioactive elements like Cs and Sr may adversely affect marine ecosystems and the fishing industry.Traditional treatment systems for radioactive wastewater like the Advan... [Background]The previous studies suggest that radioactive elements like Cs and Sr may adversely affect marine ecosystems and the fishing industry.Traditional treatment systems for radioactive wastewater like the Advanced Liquid Processing System(ALPS)and Kurion have faced challenges in limiting concentration and achieving safety criteria.Studies suggest potential long-term impacts on benthic organisms and seafood networks due to radioactive elements like Cs and Sr from the discharged radioactive wastewater,which may hinder post-disaster recovery and provoke economic losses in the fishing industry both domestically and internationally.A series of studies indicate that there are issues of Cs and Sr pollution migration in soil and water conservation in Fukushima.[Methods]To provide feasible solutions,the main article includes five nuclear wastewater treatment technologies,and soil and water conservation measures for different media(water and soil)were evaluated through reviewing the previous fifteen years'articles.To provide feasible solutions,the main articles,the phytoextraction technologies in Cs and Sr treatment within different land use areas were wildly analyzed(Camellia japonica,Arabidopsis halleri and other local species).[Results]1)A 99.9%removal rate for Cs^(+)and 99.5%for Sr^(2+)was achieved by the KFe[Fe(CN)_(6)]and BaSO_(4)co-precipitation method.2)For membrane filtration,Sr^(2+)and Cs^(+)were removed using metal-organic framework(MOF/graphene oxide)and ion exchange techniques using inorganic materials like titanosilicates.The absorption efficiency of membrane filtration for Sr^(2+)and Cs^(+)was at least 92%and 94%,respectively.The study analyzed soil and water conservation technologies in different land uses,river basins and catchments.3)The underground water treatment mainly were completed via the membrance technologies like reverse osmosis and Permeable Reactive Barriers(PRB)technologies.The ^(90) Sr concentration decreased 77%-91%compared to the initial concentration by PRB technology.These diverse methods offered effective strategies for radioactive wastewater treatment,especially the co-precipitation method may be feasible remediation measures to ensure ecological safety surrounding nuclear power utilizing areas.Soil and water conservation measures for soil pollution treatment mainly focused on the use of stabilizers to hinder the migration of Cs and Sr in the soil and the effects of wind erosion such as interpolyelectrolyte complexes.[Conclusions]We evaluated the pollution of Cs and Sr in the Fukushima nuclear radiation soil and water to provide solutions for the treatment of nuclear wastewater and to prevent radionuclide pollutants from migrating into the soil and water. 展开更多
关键词 Fukushima nuclear power accident nuclear wastewater treatment environmental strategy soil and water conservation technologies
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Feasibility Study on the Treatment of Wastewater Containing High-concentration Hg by Coagulation Sedimentation-Adsorption
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作者 Zhao Lijun Fu Wei Li Kuixiao 《Meteorological and Environmental Research》 CAS 2016年第5期59-61,共3页
For the wastewater containing high-concentration Hg,the feasibility of high-concentration Hg in wastewater treated by coagulation sedimentation,adsorption and the combined process was studied. Research results showed ... For the wastewater containing high-concentration Hg,the feasibility of high-concentration Hg in wastewater treated by coagulation sedimentation,adsorption and the combined process was studied. Research results showed that if using the single coagulation sedimentation process,when FeSO_4·7H_2O dosage was 1. 39 g / L,and NaOH dosage was 0. 40 g / L,it could meet discharge requirement,but the reagent cost was 13. 1yuan / t,which was high. Because that there was subsequent adsorption process,it was selected 0. 28 g / L of FeSO_4·7H_2O and 0. 36 g / L of NaOH,and the estimated reagent cost was 2. 62 yuan / t. In selection process of adsorption materials,powdered activated carbon,granular activated carbon and diatomite all could effectively adsorb Hg,and the technology was feasible. When using the combined process of coagulation sedimentation + adsorption to treat the wastewater containing high-concentration Hg( 800 μg / L),removal rate could reach 99%,and operation cost was 2. 71 yuan. It could meet the requirement of sewage discharged into sewer( 20 μg / L) at the technology,and was acceptable at the economy.Therefore,treatment of wastewater containing high-concentration Hg by the combined process was feasible at the aspects of technology and economy. 展开更多
关键词 COAGULATION SEDIMENTATION adsorption wastewater CONTAINING HG FLOCCULANT Activated carbon China
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The Treatment of Polymer-bearing Wastewater from Refinery by Fenton Oxidation - Activated Carbon Adsorption
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作者 Su Changchun 《Meteorological and Environmental Research》 CAS 2017年第1期33-35,共3页
To solve the problem of polymer-bearing effluent of crude oil not reaching the standard,deep treatment system of Fenton oxidation-activated carbon adsorption is established in one refinery,and the most suitable condit... To solve the problem of polymer-bearing effluent of crude oil not reaching the standard,deep treatment system of Fenton oxidation-activated carbon adsorption is established in one refinery,and the most suitable condition of Fenton oxidation reaction is determined.Operation results show that CODCrconcentration of effluent treated by the system could be lower than 50 mg/L,and ammonia nitrogen content is less than 3 mg/L,which meets design requirement. 展开更多
关键词 Polymer-bearing wastewater FENTON oxidation Activated carbon adsorption SEDIMENTATION TANK China
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Comparative study of the adsorption performance of NH_(2)-functionalized metal organic frameworks with activated carbon composites for the treatment of phenolic wastewaters
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作者 Bolong Jiang Shunjie Shi +3 位作者 Yanyan Cui Jiayou Li Nan Jiang Yanguang Chen 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第11期130-139,共10页
To better understand the role of the-NH_(2)group in adsorption process of phenolic wastewaters,NH_(2)-functionalized MIL-53(Al)composites with activated carbon(NH_(2)-M(Al)@(B)AC)were prepared.The results showed that ... To better understand the role of the-NH_(2)group in adsorption process of phenolic wastewaters,NH_(2)-functionalized MIL-53(Al)composites with activated carbon(NH_(2)-M(Al)@(B)AC)were prepared.The results showed that the-NH_(2)group could increase the mesopore volume for composites,which promotes mass transfer and full utilization of active sites,because hierarchical mesopore structure makes the adsorbent easier to enter the internal adsorption sites.Furthermore,the introduction of the-NH_(2)group can improve the adsorption capacity,decrease the activation energy,and enhance the interaction between the adsorbent and p-nitrophenol,demonstrating that the-NH_(2)group plays a crucial role in the adsorption of p-nitrophenol.The density functional theory calculation results show that the H-bond interaction between the-NH_(2)group in the adsorbent and the-NO_(2)in the p-nitrophenol(adsorption energy of -35.5 kJ·mol^(-1)),and base-acid interaction between the primary-NH_(2)group in the adsorbent and the acidic-OH group in the p-nitrophenol(adsorption energy of -27.3 kJ·mol^(-1))are predominant mechanisms for adsorption in terms of the NH_(2)-functionalized adsorbent.Both NH_(2)-functionalized M(Al)@AC and M(Al)@BAC composites exhibited higher p-nitrophenol adsorption capacity than corresponding nonfunctionalized composites.Among the composites,the NH_(2)-M(Al)@BAC had the highest p-nitrophenol adsorption capacity of 474 mg·g^(-1). 展开更多
关键词 NH_(2)-functionalized adsorbent Phenolic wastewaters adsorption Mechanism Density functional theory
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Advancements in adsorption and photodegradation technologies for Rhodamine B dye wastewater treatment:fundamentals,applications,and future directions
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作者 Peter Olusakin Oladoye Mohammed Kadhom +2 位作者 Idrees Khan Kosar Hikmat Hama Aziz Yakubu Adekunle Alli 《Green Chemical Engineering》 EI CSCD 2024年第4期440-460,共21页
Organic dye pollutants present in wastewater pose a significant global challenge.Among pollutants,the synthetic dye Rhodamine B(RB)stands out due to its non-biodegradable nature and associated neurotoxic,carcinogenic,... Organic dye pollutants present in wastewater pose a significant global challenge.Among pollutants,the synthetic dye Rhodamine B(RB)stands out due to its non-biodegradable nature and associated neurotoxic,carcinogenic,and respiratory irritant properties.Extensive research has been conducted on the efficacy of adsorption and photodegradation techniques for the removal of RB from wastewater.While adsorption and advanced oxidation processes(AOPs)have gained considerable attention for their effectiveness in recent years,the underlying behaviors and mechanisms of these technologies remain incompletely understood.Therefore,a comprehensive of recent research progress in this domain is imperative to clarify the basics and present the up-to-date achievements.This review provides an in-depth exploration of the fundamentals,advancements,and future trajectories of RB wastewater treatment technologies,mainly encompassing adsorption and photodegradation.This work starts with a general introduction of outlining the sources,toxicity,and diverse applicable removal strategies.Subsequently,it thoroughly examines crucial techniques within non-photochemical,photochemical,and adsorption technologies,such as UV light assisted AOP,catalyst assisted AOP,ozonation,Fenton system,electrochemical AOP,and adsorption technology.The primary objective is to furnish a broad overview of these techniques,elucidating their effectiveness,limitations,and applicability.Following this,the review encapsulates state-of-theart computational simulations pertaining to RB adsorption and interactions with clays and other adsorbents.Lastly,it delves into column adsorption of RB dye,and elucidates various influencing factors,including bed height,feed concentration,pollutant(RB)feeding or flow rate,and column regeneration.This panoramic review aims to provide valuable insights into suitable techniques,research gaps,and the applicability of nonphotochemical,photochemical,and adsorption technologies in the treatment of wastewater containing RB dye. 展开更多
关键词 Rhodamine B wastewater treatment PHOTODEGRADATION Column adsorption Dye removal Advanced oxidation processes
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Treatment of Enzymolysis Wastewater by Centrifugation- Coagulation- Fenton Reagent Oxidation- Adsorption Process 被引量:4
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作者 Jian Zhai Chunhua Jiang +1 位作者 Guoqing Cao Xiuguo Lu 《Meteorological and Environmental Research》 CAS 2013年第9期43-46,共4页
[ Objective ] The study aimed to discuss the optimal conditions for the treatment of enzymolysis wastewater by centrifugation - coagu- lation - Fenton reagent oxidation - adsorption process. [ Metbod] According to the... [ Objective ] The study aimed to discuss the optimal conditions for the treatment of enzymolysis wastewater by centrifugation - coagu- lation - Fenton reagent oxidation - adsorption process. [ Metbod] According to the water-quality characteristics of wastewater from a heparin so- dium production factory of Jiangsu Province, enzymolysis wastewater was segregated from intestinal lavage wastewater and treated through cen- trifugation- coagulation- Fenton reagent oxidation-adsorption process, and the optimal technical parameters were determined. E Resultl After enzymolysis wastewater was centrifuged at a speed of 4 000 rpm, 0.6 g/L CTS as the coagulant was added to the supematant. Hereafter, pH of the coagulated effluent was adjusted to 3, and then 1.5% (V/V) H2O2 was added to the coagulated effluent; a certain amount of ferrous sul- fate (n H2O2-.n FeSO4 . 7H2O =8:1 ) was added to the mixture; the reaction conducted for 30 min, and then solution pH was adjusted to about 9. Finally, the oxidized effluent flowed through a resin red until the adsorptive capacity reached 240 BV, and COD of the effluent water was lower than 100 mg/L, meeting the Grade-I standard of Comprehensive Discharge Standard of Sewage (GB8978-1996). [Condusio] The research could provide a new process for the treatment of enzymolysis wastewater. 展开更多
关键词 Segregation treatment Enzymolysis wastewater High salt content Fenton regent China
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Digital Twins for Wastewater Treatment:A Technical Review
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作者 Ai-Jie Wang Hewen Li +6 位作者 Zhejun He Yu Tao Hongcheng Wang Min Yang Dragan Savic Glen TDaigger Nanqi Ren 《Engineering》 SCIE EI CAS CSCD 2024年第5期21-35,共15页
The digital twins concept enhances modeling and simulation through the integration of real-time data and feedback.This review elucidates the foundational elements of digital twins,covering their concept,entities,domai... The digital twins concept enhances modeling and simulation through the integration of real-time data and feedback.This review elucidates the foundational elements of digital twins,covering their concept,entities,domains,and key technologies.More specifically,we investigate the transformative potential of digital twins for the wastewater treatment engineering sector.Our discussion highlights the application of digital twins to wastewater treatment plants(WWTPs)and sewage networks,hardware(i.e.,facilities and pipes,sensors for water quality and activated sludge,hydrodynamics,and power consumption),and software(i.e.,knowledge-based and data-driven models,mechanistic models,hybrid twins,control methods,and the Internet of Things).Furthermore,two cases are provided,followed by an assessment of current challenges in and perspectives on the application of digital twins in WWTPs.This review serves as an essential primer for wastewater engineers navigating the digital paradigm shift. 展开更多
关键词 Digital twins Urban water systems wastewater treatment
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Multimodal Machine Learning Guides Low Carbon Aeration Strategies in Urban Wastewater Treatment
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作者 Hong-Cheng Wang Yu-Qi Wang +4 位作者 Xu Wang Wan-Xin Yin Ting-Chao Yu Chen-Hao Xue Ai-Jie Wang 《Engineering》 SCIE EI CAS CSCD 2024年第5期51-62,共12页
The potential for reducing greenhouse gas(GHG)emissions and energy consumption in wastewater treatment can be realized through intelligent control,with machine learning(ML)and multimodality emerging as a promising sol... The potential for reducing greenhouse gas(GHG)emissions and energy consumption in wastewater treatment can be realized through intelligent control,with machine learning(ML)and multimodality emerging as a promising solution.Here,we introduce an ML technique based on multimodal strategies,focusing specifically on intelligent aeration control in wastewater treatment plants(WWTPs).The generalization of the multimodal strategy is demonstrated on eight ML models.The results demonstrate that this multimodal strategy significantly enhances model indicators for ML in environmental science and the efficiency of aeration control,exhibiting exceptional performance and interpretability.Integrating random forest with visual models achieves the highest accuracy in forecasting aeration quantity in multimodal models,with a mean absolute percentage error of 4.4%and a coefficient of determination of 0.948.Practical testing in a full-scale plant reveals that the multimodal model can reduce operation costs by 19.8%compared to traditional fuzzy control methods.The potential application of these strategies in critical water science domains is discussed.To foster accessibility and promote widespread adoption,the multimodal ML models are freely available on GitHub,thereby eliminating technical barriers and encouraging the application of artificial intelligence in urban wastewater treatment. 展开更多
关键词 wastewater treatment Multimodal machine learning Deep learning Aeration control Interpretable machine learning
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Cloud-Model-Based Feature Engineering to Analyze the Energy-Water Nexus of a Full-Scale Wastewater Treatment Plant
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作者 Shan-Shan Yang Xin-Lei Yu +8 位作者 Chen-Hao Cui Jie Ding Lei He Wei Dai Han-Jun Sun Shun-Wen Bai Yu Tao Ji-Wei Pang Nan-Qi Ren 《Engineering》 SCIE EI CAS CSCD 2024年第5期63-75,共13页
Wastewater treatment plants(WWTPs)are important and energy-intensive municipal infrastructures.High energy consumption and relatively low operating performance are major challenges from the perspective of carbon neutr... Wastewater treatment plants(WWTPs)are important and energy-intensive municipal infrastructures.High energy consumption and relatively low operating performance are major challenges from the perspective of carbon neutrality.However,water-energy nexus analysis and models for WWTPs have rarely been reported to date.In this study,a cloud-model-based energy consumption analysis(CMECA)of a WWTP was conducted to explore the relationship between influent and energy consumption by clustering its influent’s parameters.The principal component analysis(PCA)and K-means clustering were applied to classify the influent condition using water quality and volume data.The energy consumption of the WWTP is divided into five standard evaluation levels,and its cloud digital characteristics(CDCs)were extracted according to bilateral constraints and golden ratio methods.Our results showed that the energy consumption distribution gradually dispersed and deviated from the Gaussian distribution with decreased water concentration and quantity.The days with high energy efficiency were extracted via the clustering method from the influent category of excessive energy consumption,represented by a compact-type energy consumption distribution curve to identify the influent conditions that affect the steady distribution of energy consumption.The local WWTP has high energy consumption with 0.3613 kW·h·m^(-3)despite low influent concentration and volumes,across four consumption levels from low(I)to relatively high(IV),showing an unsatisfactory operation and management level.The average oxygenation capacity,internal reflux ratio,and external reflux ratio during high energy efficiency days recognized by further clustering were obtained(0.2924-0.3703 kg O_(2)·m^(-3),1.9576-2.4787,and 0.6603-0.8361,respectively),which could be used as a guide for the days with low energy efficiency.Consequently,this study offers a water-energy nexus analysis method to identify influent conditions with operational management anomalies and can be used as an empirical reference for the optimized operation of WWTPs. 展开更多
关键词 wastewater treatment plants Cloud-model theory Data mining Principal component analysis K-means clustering Cloud-model-based energy consumption analysis
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Ecological Wastewater Treatment System in a School Environment Using a Horizontal Flow Biological Reactor: The Case of Typha
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作者 Falilou Coundoul Abdou Khafor Ndiaye Abdoulaye Deme 《Journal of Environmental Protection》 2024年第1期1-12,共12页
The overarching goal of this study is to offer an effective and sustainable solution to the challenges of sanitation in rural and school settings in the northern region of Senegal. The study explores a wastewater trea... The overarching goal of this study is to offer an effective and sustainable solution to the challenges of sanitation in rural and school settings in the northern region of Senegal. The study explores a wastewater treatment approach based on phytoremediation, with a particular focus on the use of horizontally-flowing reed bed filters. Furthermore, it aims to adapt and optimize these systems for the specific needs of Senegal, focusing on wastewater in school environments. Thus, we constructed a horizontally-flowing reed bed filter, planted with Typha, at the Ndiébène Gandiol school in Senegal. We will investigate the efficiency of wastewater treatment by this horizontally-flowing reed bed filter, emphasizing the role of the plant used: Typha. The filter is described in detail, specifying its dimensions, its composition of flint gravel, and the choice of plants, namely Typha. The experimental protocol is detailed, describing the sampling at the entrance and exit of the filter to evaluate water quality. The parameters analyzed include Chemical Oxygen Demand (COD), Biochemical Oxygen Demand over 5 days (BOD5), suspended solids, ammonium, nitrates, phosphates, pH, conductivity, and fecal coliforms. The results indicate a significant improvement in water quality after treatment. COD, BOD5, suspended solids, and fecal coliforms are greatly reduced, thus demonstrating the efficacy of the Typha filter. However, nitrate concentrations remain relatively stable, suggesting room for improvement in their elimination. A perspective of reuse of the treated water is considered, showing that the effluents from the planted filter meet Senegalese and international standards for irrigation. The findings suggest that these waters could be used for a variety of crops, thereby reducing the pressure on freshwater resources. In conclusion, the Typha-based filtration system shows promising results for improving water quality in this region of Senegal. However, adjustments are necessary for more effective nitrate removal. This study paves the way for sustainable use of treated wastewater for irrigation, thus contributing to food security and the preservation of water resources. 展开更多
关键词 Hydraulic Engineering wastewater Quality wastewater treatment Agricultural Irrigation SANITATION ENGINEERING Environment
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Ecological Wastewater Treatment System Using a Horizontal Flow Biological Reactor: The Case of Vetiver
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作者 Falilou Coundoul Abdou Khafor Ndiaye Abdoulaye Deme 《Journal of Environmental Protection》 2024年第1期26-38,共13页
Confronted with the challenge of wastewater management, particularly in the school environment of Senegal, our study set out to achieve multiple objectives. Following field surveys, laboratory analyses of wastewater s... Confronted with the challenge of wastewater management, particularly in the school environment of Senegal, our study set out to achieve multiple objectives. Following field surveys, laboratory analyses of wastewater samples were carried out, revealing a significant pollutant load. In the community of Gandiol, near Saint-Louis (Senegal), the school of Ndiebene Gandiol 1 faces significant sanitation challenges. Our study aimed to address this issue by using a constructed filter composed of two filtering bed cells measuring 12 × 8.5 m, preceded by a septic tank. We particularly focused on the influence of Vetiver;a plant chosen for its purification potential. Our analyses showed remarkable efficiency of the filter. Elimination rates reached 95% for 5-Day Biochemical Oxygen Demand (BOD5), 91% for Chemical Oxygen Demand (COD), and 92% for SS, far exceeding the Senegalese standards set at 50 mg/L, 200 mg/L, and 40 mg/L, respectively. Furthermore, the concentration of fecal coliforms was reduced to 176 FCU/100mL, well below the Senegalese threshold of 2000 FCU/100mL and close to the World Health Organization’s (WHO) recommendation of 1000 FCU/100mL. However, despite these promising results, some parameters, particularly the concentration of certain pollutants, approached the thresholds defined by European legislation. For example, for Suspended Solids (SS), the post-treatment level of 3 mg/L was well below the Senegalese standard but edged close to the European minimum of 10 mg/L. In conclusion, the Vetiver filter demonstrated a remarkable ability to treat school wastewater, offering high pollutant elimination percentages. These results suggest significant opportunities for the reuse of treated water, potentially in areas such as irrigation, though some adjustments may be necessary to meet the strictest standards such as those of the European union (EU). 展开更多
关键词 Hydraulic Engineering wastewater Quality wastewater treatment Agricultural Irrigation SANITATION ENGINEERING ENVIRONMENT
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Advanced Oxidation Wastewater Treatment of 3 LPS of an Avocado Sauce Company,at Morelia,Michoacan,Mexico
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作者 Alfonso Espitia-Cabrera Francisco Javier Barrón-Santos +2 位作者 JoséL.Méndez-Antonio Héctor M.Alemán-Vásquez Omar G.Color-Vázquez 《Journal of Environmental Science and Engineering(A)》 CAS 2024年第5期151-155,共5页
This paper describes the wastewater treatment of 3 liters per second of capacity of discharges of capacity,from the avocado washed,as well as the production of avocado sauce.Effluents were pretreated with a grease and... This paper describes the wastewater treatment of 3 liters per second of capacity of discharges of capacity,from the avocado washed,as well as the production of avocado sauce.Effluents were pretreated with a grease and oil trap and contained small amounts of oil and grease,dissolved and total solids,organic matter and trace of organic and inorganic compounds from the vitamins and minerals of avocado.The treatment train is located in an small surface and the train is integrated with coagulation in line with alumina in a static mixer,rapid filtration in two steps,double advanced oxidation with ozone and heterocyclic photocatalysis with a nanofilm of zinc oxide as,photocatalyzer and final adsorption of refractory compounds with activated charcoal.The treated wastewater meets the environmental regulation to urban sewerage discharges of the city,according to the results of a Mexican Certified Laboratory. 展开更多
关键词 wastewater primary treatment rapid filter performance static mixer
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