The bimetallic Ru-M (M=Co,Fe,Ni,Mo, Rh,Cr, Mn) catalysts were prepared from SiO_2-supported bimetallic carbonyl clusters, and it was found that the Ru-Co, Ru-Fe and Ru-Mo bimetallic carbonyl cluster-derived catalysts ...The bimetallic Ru-M (M=Co,Fe,Ni,Mo, Rh,Cr, Mn) catalysts were prepared from SiO_2-supported bimetallic carbonyl clusters, and it was found that the Ru-Co, Ru-Fe and Ru-Mo bimetallic carbonyl cluster-derived catalysts showed higher activity and selectivity for oxygenates such as C_1-C_5 alcohols in CO hydrogenation,in contrast to catalysts prepared from SiO_2-supported homometallic Ru and Co carbonyl clusters. In situ FT-IR studies revealed that the bands at 1584 and 1555 cm^(-1) species were intermediates to produce methanol and higher oxygenates,and at higher temperatures the 1584 cm^(-1) species could react with alkyl to form 1555 cm^(-1) species. By the surface chemical reaction and the IR study of isotopic molecules,it was suggested that 1584 and 1555 cm^(-1) were assigned to surface formyl and acetyl species.展开更多
基金Project supported by the JSPS and NSF Japan-US Cooperative Science Program (1989-1990)the National Natural Science Foundation of China.
文摘The bimetallic Ru-M (M=Co,Fe,Ni,Mo, Rh,Cr, Mn) catalysts were prepared from SiO_2-supported bimetallic carbonyl clusters, and it was found that the Ru-Co, Ru-Fe and Ru-Mo bimetallic carbonyl cluster-derived catalysts showed higher activity and selectivity for oxygenates such as C_1-C_5 alcohols in CO hydrogenation,in contrast to catalysts prepared from SiO_2-supported homometallic Ru and Co carbonyl clusters. In situ FT-IR studies revealed that the bands at 1584 and 1555 cm^(-1) species were intermediates to produce methanol and higher oxygenates,and at higher temperatures the 1584 cm^(-1) species could react with alkyl to form 1555 cm^(-1) species. By the surface chemical reaction and the IR study of isotopic molecules,it was suggested that 1584 and 1555 cm^(-1) were assigned to surface formyl and acetyl species.
