Aerosol deposition technology and its applications in batteries

Aerosol deposition(AD)method is a kind of additive manufacturing technology for fabricating dense films such as metals and ceramics at room temperature.It resolves the challenge of integrating ceramic films onto temperaturesensitive substrates,including metals,glasses,and polymers.It should be emphasized that the AD is a spray coating technology that uses powder without thermal assistance to generate films with high density.Compared to the traditional sputter-based approach,the AD shows several advantages in efficiency,convenience,better interfacial bonding and so on.Therefore,it opens some possibilities to the field of batteries,especially all-solidstate batteries(ASSBs)and draws much attention not only for research but also for large scale applications.The purpose of this work is to provide a critical review on the science and technology of AD as well as its applications in the field of batteries.The process,mechanism and effective parameters of AD,and recent developments in AD applications in the field of batteries will be systematically reviewed so that a trend for AD will be finally provided.

Efficient coating fabrication of onion-like carbon nanoparticles via aerosol deposition

In this work,an onion-like carbon(OLC)nanoparticle coating with a micron-sized thickness was fabricated via aerosol deposition(AD).During the room temperature impact consolidation(RTIC),the OLC nanoparticles(5-10 nm)experienced remarkable deformation along both the perpendicular and parallel directions to the coating-substiate interface.Particle deformation,mechanical interlocking,and van der Waals forces between the OLC particles were revealed as the major regimes for coating formation.The aerosol deposition technique might open new avenues for fabricating carbonaceous nanostructures for various functional applications.

Simulating Dry Deposition Fluxes of PM_(10) and Particulate Inorganic Nitrogen over the Eastern China Seas During a Severe Asian Dust Event Using WRF-Chem Model

A WRF-Chem model including a comprehensive gas-phase nitrogen chemistry module was used to simulate a severe dust event appearing in the eastern China on 19-25 March, 2002. The modeling result well reproduced PM10 concentrations in various distances from the dust sources and the transport pathway of the dust strom. The results showed that both the concentrations and the dry deposition fluxes of PM10 increased over the China seas during the dust event following the passage of a cold front system. The maximum fluxes of PM10 in the Yellow Sea and the East China Sea during the dust event were 5.5 and 8.4 times of those before the event, respectively. However, the temporal variations of the dry deposition fluxes of particulate inorganic nitrogen differed over the Yellow Sea from those over the East China Sea. Nitrate and ammonium in the whole northern China rapidly decreased because of the intrusion of dust-loaded air on 19 March. The dust plume arrived in the Yellow Sea on 20 March, decreasing the particulate inorganic nitrogen in mass concentration accordingly. The minimum dry deposition fluxes of nitrate and ammonium in the Yellow Sea were about 3/5 and 1/6 of those before the dust arrival, respectively. In contrast, when the dust plume crossed over the Yangtze Delta area, it became abundant in nitrate and ammonium and increased the concentrations and dry deposition fluxes of particulate inorganic nitrogen over the East China Sea, where the maximum dry deposition fluxes of nitrate and ammonium increased approximately by 4.1 and 2.6 times of those prior to the dust arrival.

Ecophysiological responses of winter wheat seedling to aerosol wet deposition of Xi'an area, China

Aerosol leads to 30% reduction in solar radiation reaching the earth’s surface, and a similar reduction in crops yield for both wheat and rice. To determine the effect of aerosol wet deposition on crops, aerosol samples were collected in September, 2006 at Xi’an urban suburb （34 44 N, 109 49 E）, and wheat seedlings were treated with aerosol of different concentrations in laboratory conditions. Changes in physiological and biochemical parameters of wheat seedlings were measured. In comparison with the control, the activities of superoxide dismudase （SOD） and catalase （CAT） and the concentration malondialdehyde （MDA） and oxidized glutathione （GSSG） of wheat seedlings increased progressively with increasing concentrations of added aerosol, while the opposite trend was seen for the activities of nitric oxide synthase （NOS）, the concentrations of glutathione （GSH） and nitric oxide （NO）, and the ratio of GSH/GSSG. When the seedlings were treated with the aerosol of 1 and 2 mg/L, the coleoptile elongation, shoot elongation and biomass accumulation were increased, the effect at treatment of 2 mg/L was most significant. However, aerosol treatments with rates of 3 and 4 mg/L resulted in a decrease in coleoptile elongation, shoot elongation and biomass accumulation in seedlings, and significant effect was for the treatment of 4 mg/L. Hence, lower concentrations of aerosol wet deposition were in favor of crops growth, but its higher concentrations could result in deleterious effects for crops and decreased crops growth.

Temperature-dependent dielectric anomalies in powder aerosol deposited ferroelectric ceramic films

Room-temperature fabrication of functional ceramic films using powder aerosol deposition(AD)is important for practical applications.However,the as-processed ferroelectric films show unusual temperature-dependent dielectric response,including enhanced conductivity in the as-processed state and subsequent significant increase in the permittivity following heat treatment.In this work,we investigate the influence of the residual internal stresses developed during the high-impact consolidation process on the dielectric response.Moreover,the recombination of charged defects generated during deposition is driven by the temperature and the atmospheric condition during the heat treatment as well as the carrier gas type used during deposition.Thermal treatment up to 500℃ in different atmospheres was used to tune the dielectric and ferroelectric response,highlighting that irrespective of the type of carrier gas,AD deposition process induces charged defects in polar oxide ceramics that can be reduced through heat-treatment far-below their bulk sintering temperature.Macroscopic electromechanical properties are contrasted to in-situ heating scanning transmission electron microscopy to observe possible local effects,such as crystallization,grain growth,crystal defect structure,or grain reorientation.In addition X-ray diffraction and X-ray photoelectron spectroscopy studies were conducted to gain insight into the effect of annealing on the crystal structure and local moisture adsorption.

Experimental-computational study of fibrous particle transport and deposition in a bifurcating lung model

Experiments carried out using a lung model with a single horizontal bifurcation under different steady inhalation conditions explored the orientation of depositing carbon fibers, and particle deposition frac- tions. The orientations of deposited fibers were obtained from micrographs. Specifically, the effects of the sedimentation parameter （γ）, fiber length, and flow rate on orientations were analyzed. Our results indicate that gravitational effect on deposition cannot be neglected for 0.0228 〈 γ 〈 0.247. The absolute orientation angle of depositing fibers decreased linearly with increasing y for values 0.0228 〈 γ 〈 0.15. Correspondence between Stokes numbers and y suggests these characteristics can be used to estimate fiber deposition in the lower airways. Computer simulations with sphere-equivalent diameter models for the fibers explored deposition efficiency vs. Stokes number. Using the volume-equivalent diameter model, our experimental data for the horizontal bifurcation were replicated. Results for particle deposition using a lung model with a vertical bifurcation indicate that body position also affects deposition.

Characteristics of dry deposited mineral particles associated with weather conditions in the adjacent sea areas of East China during a cruise in spring 2011

Dry deposited particles, larger than 1.3 μm, were collected under clear, cloudy, and foggy conditions during a cruise, traversing the Yellow Sea and the East China Sea from 23 March to 8 April 2011. In these areas, air masses are influenced by pollution outflows from the Asian continent. The size and elemental composition of dry deposited particles were investigated using a scanning electron microscope. Number-size distributions of these particles were approximately lognormal. Under clear conditions, the mode size was about 5.0 μm, with a mean diameter of 6.9 μm. Under cloudy and foggy conditions, the mean diameters were 5.7 and 6.0 μm, respectively, but the mode sizes were vague. Non-mixed mineral particles, sea salt, and mixed mineral-sea salt particles were the major particle types. Correspondingly, Al and Si were the most frequently detected elements. Frequencies of K-, Ca-, and S-containing particles were highest under foggy conditions, while the frequency of Na-containing particles was lowest. These results indicate that fog favored sulfate production on the particles and led to the deposited mineral particles more abundant in secondary salt, suggesting the importance to consider the dependence of the comoosition of deoosited mineral narticles on weather as well as narticle size.