Aerosols represent an important source of terrestrial organic carbon(OC)from the East Asian continent to the China marginal seas,thus their provenance and transport play important roles in the global carbon cycle.Fift...Aerosols represent an important source of terrestrial organic carbon(OC)from the East Asian continent to the China marginal seas,thus their provenance and transport play important roles in the global carbon cycle.Fifty samples of total suspended particle were collected seasonally from the nearshore Huaniao Island(HNI)in East China Sea(ECS)from April 2018 to January 2019;and they were analyzed for total organic carbon(TOC)content and stable carbon isotope(δ^(13)C),as well as terrestrial bio-markers including n-alkanes(C_(20)-C_(33)),n-alkanols(C_(20)-C32)and n-fatty acids(n-FAs,C_(20)-C30),to distinguish the seasonal variabili-ties of terrestrial OC sources and reveal the influence of the long-range air mass transport on these sources.The TOC-δ^(13)C values(range from−27.3‰to−24.3‰)and molecular distributions of terrestrial biomarkers both suggested that terrestrial OC contribu-tions to aerosols had significant seasonal variations.The source indices of terrestrial biomarkers(e.g.,Fossil%=82.8%for n-alkanes)revealed that the fossil fuel OC contributions,including coal burning and vehicular emission,were higher in winter,mainly because of the long-range air mass transport from the north of the East Asian continent.The terrestrial plant OC contributions were higher in summer(e.g.,Wax%=32.4%for n-alkanes),likely due to local vegetation sources from HNI and East Asian continental air masses.Cluster analysis of air mass backward-trajectories clearly showed that transport pathway plays an important role in determining the organic constituents of aerosols in China marginal seas.A comparison of these terrestrial OC contributions from different air mass origins suggested that fossil fuel OC showed less variations among various air mass origins from northern China in winter,while terrestrial plant OC sources from northern and southern China in summer contributed more than that from the air masses transported through the ECS.These results provided a basis for future quantification of terrestrial OC from different origins in marine aerosols,by combining biomarker index and carbon isotopes.展开更多
The Asian monsoon(AM) region is a well-known region with prevailing stratosphere–troposphere exchange(STE).However,how the STE across this region changes with the weakening AM remains unclear.Here,we particularly dia...The Asian monsoon(AM) region is a well-known region with prevailing stratosphere–troposphere exchange(STE).However,how the STE across this region changes with the weakening AM remains unclear.Here,we particularly diagnose the air mass transport between the planetary boundary layer(PBL) and the stratosphere over the AM region during 1992–2017 using the Lagrangian particle dispersion model FLEXPART based on the ERA-Interim reanalysis data.The results show that both the downward and upward deep STEs exhibit a detectable increasing trend,while the latter,namely,the deep troposphere-to-stratosphere transport(DTST),is relatively more significant.Further analysis reveals that the long-term trend of DTST over the AM region could be partly attributed to changes in the Pacific Walker circulation and the air temperature(especially at upper levels).Additionally,it is found that DTST increases markedly over the tropical oceanic regions,while the increasing DTST into the stratosphere can be attributed to the enhanced air masses originated from the PBL over the terrestrial regions,where large amounts of pollutant emissions occur.The results imply that the influence of the DTST on the chemical composition and the climate of the stratosphere over the AM region is expected to become increasingly important,and is thereby of relevance to climate projection in an evolving climate.展开更多
One hundred and ten samples of rainwater were collected for chemical analysis at the summit of Huangshan Mountain, a high-altitude site in East China, from July 2010 to June 2011. The volume-weighted-mean （VWM） pH f...One hundred and ten samples of rainwater were collected for chemical analysis at the summit of Huangshan Mountain, a high-altitude site in East China, from July 2010 to June 2011. The volume-weighted-mean （VWM） pH for the whole sampling period was 5.03. SO2- and Ca2＋ were the most abundant anion and cation, respectively. The ionic concentrations varied monthly with the highest concentrations in winter/spring and the lowest in summer. Evident inter-correlations were found among most ions, indicating the common sources for some species and fully mixing characteristics of the alpine precipitation chemistry. The VWM ratio of [SO]-]/[NO3] was 2.54, suggesting the acidity of rainwater comes from both nitric and sulfuric acids. Compared with contemporary observations at other alpine continental sites in China, the precipitation at Huangshan Mountain was the least polluted, with the lowest ionic concentrations. Trajectories to Huangshan Mountain on rainy days could be classified into six groups. The rainwater with influencing air masses originating in Mongolia was the most polluted with limited effect. The emissions of Jiangxi, Anhui, Zhejiang and Jiangsu provinces had a strong influence on the overall rain chemistry at Huangshan Mountain. The rainwater with influencing air masses from Inner Mongolia was heavily polluted by anthropogenic pollutants.展开更多
By using the ECMWF reanalysis daily data and daily precipitation data of 80 stations in Northeast China from 1961 to 2002, the impacts of moisture transport of East Asian summer monsoon on the summer precipitation ano...By using the ECMWF reanalysis daily data and daily precipitation data of 80 stations in Northeast China from 1961 to 2002, the impacts of moisture transport of East Asian summer monsoon on the summer precipitation anomaly in Northeast China, and the relationship between the variation of moisture budget and the establishment of East Asian summer monsoon in this region are studied. The results demonstrate that the moisture of summer precipitation in Northeast China mainly originates from subtropical, South China Sea, and South Asia monsoon areas. East China and its near coastal area are the convergent region of the monsoonal moisture currents and the transfer station for the currents continually moving northward. The monsoonal moisture transport, as an important link or bridge, connects the interaction between middle and low latitude systems. In summer half year, there is a moisture sink in Northeast China where the moisture influx is greater than outflux. The advance transport and accumulation of moisture are of special importance to pentad time scale summer precipitation. The onset, retreat, and intensity change of the monsoonal rainy season over Northeast China are mainly signified by the moisture input condition along the southern border of this area. The establishment of East Asian summer monsoon in this area ranges from about 10 July to 20 August and the onset in the west is earlier than that in the east. The latitude that the monsoon can reach is gradually northward from west to east, reaching 50°N within longitude 120°-135°E. In summer, the difference of air mass transport between summers with high and low rainfall mainly lies in whether more air masses originating from lower latitudes move northward through East China and its coastal areas, consequently transporting large amounts of hot and humid air into Northeast China.展开更多
基金This study was supported by the National Natural Science Foundation of China(No.U1706219).This is MCTL(Key Laboratory of Marine Chemistry Theory and Technology)contribution#237.
文摘Aerosols represent an important source of terrestrial organic carbon(OC)from the East Asian continent to the China marginal seas,thus their provenance and transport play important roles in the global carbon cycle.Fifty samples of total suspended particle were collected seasonally from the nearshore Huaniao Island(HNI)in East China Sea(ECS)from April 2018 to January 2019;and they were analyzed for total organic carbon(TOC)content and stable carbon isotope(δ^(13)C),as well as terrestrial bio-markers including n-alkanes(C_(20)-C_(33)),n-alkanols(C_(20)-C32)and n-fatty acids(n-FAs,C_(20)-C30),to distinguish the seasonal variabili-ties of terrestrial OC sources and reveal the influence of the long-range air mass transport on these sources.The TOC-δ^(13)C values(range from−27.3‰to−24.3‰)and molecular distributions of terrestrial biomarkers both suggested that terrestrial OC contribu-tions to aerosols had significant seasonal variations.The source indices of terrestrial biomarkers(e.g.,Fossil%=82.8%for n-alkanes)revealed that the fossil fuel OC contributions,including coal burning and vehicular emission,were higher in winter,mainly because of the long-range air mass transport from the north of the East Asian continent.The terrestrial plant OC contributions were higher in summer(e.g.,Wax%=32.4%for n-alkanes),likely due to local vegetation sources from HNI and East Asian continental air masses.Cluster analysis of air mass backward-trajectories clearly showed that transport pathway plays an important role in determining the organic constituents of aerosols in China marginal seas.A comparison of these terrestrial OC contributions from different air mass origins suggested that fossil fuel OC showed less variations among various air mass origins from northern China in winter,while terrestrial plant OC sources from northern and southern China in summer contributed more than that from the air masses transported through the ECS.These results provided a basis for future quantification of terrestrial OC from different origins in marine aerosols,by combining biomarker index and carbon isotopes.
基金Supported by the National Key Research and Development Program of China (2023YFC3010700)Second Tibetan Plateau Comprehensive Scientific Expedition and Research Program (2019QZKK0105)Science and Technology Development Fund of Chinese Academy of Meteorological Sciences (2023KJ027 and 2024KJ012)。
文摘The Asian monsoon(AM) region is a well-known region with prevailing stratosphere–troposphere exchange(STE).However,how the STE across this region changes with the weakening AM remains unclear.Here,we particularly diagnose the air mass transport between the planetary boundary layer(PBL) and the stratosphere over the AM region during 1992–2017 using the Lagrangian particle dispersion model FLEXPART based on the ERA-Interim reanalysis data.The results show that both the downward and upward deep STEs exhibit a detectable increasing trend,while the latter,namely,the deep troposphere-to-stratosphere transport(DTST),is relatively more significant.Further analysis reveals that the long-term trend of DTST over the AM region could be partly attributed to changes in the Pacific Walker circulation and the air temperature(especially at upper levels).Additionally,it is found that DTST increases markedly over the tropical oceanic regions,while the increasing DTST into the stratosphere can be attributed to the enhanced air masses originated from the PBL over the terrestrial regions,where large amounts of pollutant emissions occur.The results imply that the influence of the DTST on the chemical composition and the climate of the stratosphere over the AM region is expected to become increasingly important,and is thereby of relevance to climate projection in an evolving climate.
基金supported by funds from the Scientific Research Projects of High-level Talents of the Department of Human Resources and Social Security of Anhui Province (Grant No.2009Z019)the State Key Laboratory of Atmospheric Boundary Physics and Atmospheric Chemistry (Grant No.LAPC-KF-201105)
文摘One hundred and ten samples of rainwater were collected for chemical analysis at the summit of Huangshan Mountain, a high-altitude site in East China, from July 2010 to June 2011. The volume-weighted-mean （VWM） pH for the whole sampling period was 5.03. SO2- and Ca2＋ were the most abundant anion and cation, respectively. The ionic concentrations varied monthly with the highest concentrations in winter/spring and the lowest in summer. Evident inter-correlations were found among most ions, indicating the common sources for some species and fully mixing characteristics of the alpine precipitation chemistry. The VWM ratio of [SO]-]/[NO3] was 2.54, suggesting the acidity of rainwater comes from both nitric and sulfuric acids. Compared with contemporary observations at other alpine continental sites in China, the precipitation at Huangshan Mountain was the least polluted, with the lowest ionic concentrations. Trajectories to Huangshan Mountain on rainy days could be classified into six groups. The rainwater with influencing air masses originating in Mongolia was the most polluted with limited effect. The emissions of Jiangxi, Anhui, Zhejiang and Jiangsu provinces had a strong influence on the overall rain chemistry at Huangshan Mountain. The rainwater with influencing air masses from Inner Mongolia was heavily polluted by anthropogenic pollutants.
基金the National Natural Science Foundation of China under Grant Nos. 40633016 , 40575047 the Special Social Public Welfare Foundation of the Ministry of Science and Technology of China+1 种基金 the Open Foundation of Wuhan Institute of Heavy Rain under Grant No. IHR2006K05 the Special Foundation of Climate Change of China Meteorological Administration under Grant CCSF2006-18.
文摘By using the ECMWF reanalysis daily data and daily precipitation data of 80 stations in Northeast China from 1961 to 2002, the impacts of moisture transport of East Asian summer monsoon on the summer precipitation anomaly in Northeast China, and the relationship between the variation of moisture budget and the establishment of East Asian summer monsoon in this region are studied. The results demonstrate that the moisture of summer precipitation in Northeast China mainly originates from subtropical, South China Sea, and South Asia monsoon areas. East China and its near coastal area are the convergent region of the monsoonal moisture currents and the transfer station for the currents continually moving northward. The monsoonal moisture transport, as an important link or bridge, connects the interaction between middle and low latitude systems. In summer half year, there is a moisture sink in Northeast China where the moisture influx is greater than outflux. The advance transport and accumulation of moisture are of special importance to pentad time scale summer precipitation. The onset, retreat, and intensity change of the monsoonal rainy season over Northeast China are mainly signified by the moisture input condition along the southern border of this area. The establishment of East Asian summer monsoon in this area ranges from about 10 July to 20 August and the onset in the west is earlier than that in the east. The latitude that the monsoon can reach is gradually northward from west to east, reaching 50°N within longitude 120°-135°E. In summer, the difference of air mass transport between summers with high and low rainfall mainly lies in whether more air masses originating from lower latitudes move northward through East China and its coastal areas, consequently transporting large amounts of hot and humid air into Northeast China.
