CO_2 exchange at air-sea interface in the Huanghai Sea

During the Huanghai Sea Circulation and Material Flux Expedition in Spring 1996, fco_2 in surface water and atmosphere was measured. The fco2 in surface water varied in a range from 220 to 360 uatm1) while atmospheric concentration was nearly constant at 360μatm, showing that the Huanghai Sea surface waters were undersaturated with respect to atmospheric Co during the time of investigation. A model was developed in this study in order to estimate the Co flux at the air-sea interface. The model incorporates the time-series variations of the distributions in SST (sea surface temperature), salinity, mixed-layer depth, atmospheric fco2, gas-transfer velocity, and CZCS chlorophyll concentration in the Huanghai Sea and was calibrated with the observed fco2 data. The primary parameter affecting fco2 in surface water is the variation of SST through time. The annual fluxes of Co are estimated as 0. 033 Gt C from the sea into the atmosphere and 0. 044 Gt C from the air into sea. The Huanghai Sea, thus behaves as a CO2 sink absorbing 0. 011 Gi C of CO2 a year. which.corresponds to about 0. 5 % of global oceanic absorption capacity.

Modeling the contribution of abiotic exchange to CO_2 flux in alkaline soils of arid areas

Recent studies on alkaline soils of arid areas suggest a possible contribution of abiotic exchange to soil CO2 flux(Fc).However,both the overall contribution of abiotic CO2 exchange and its drivers remain unknown.Here we analyzed the environmental variables suggested as possible drivers by previous studies and constructed a function of these variables to model the contribution of abiotic exchange to Fc in alkaline soils of arid areas.An automated flux system was employed to measure Fc in the Manas River Basin of Xinjiang Uygur autonomous region,China.Soil pH,soil temperature at 0–5 cm(Ts),soil volumetric water content at 0–5 cm(θs)and air temperature at10 cm above the soil surface(Tas)were simultaneously analyzed.Results highlight reduced sensitivity of Fc to Ts and good prediction of Fc by the model Fc=R10Q10(Tas–10)/10+r7q7(pH–7)+λTas+μθs+e which represents Fc as a sum of biotic and abiotic components.This presents an approximate method to quantify the contribution of soil abiotic CO2 exchange to Fc in alkaline soils of arid areas.

Preparation and characterization of Ag^+ ion-exchanged zeolite-Matrimid~5218 mixed matrix membrane for CO_2/CH_4 separation

In this work, the zeolite-Y was ion-exchanged by introducing silver cations into the framework of microsized nano-porous sodium zeolite-Y using a liquid-phase ion exchanged method. The Ag+ion-exchanged zeolite, was then embedded into the Matrimid5218 matrix to form novel mixed matrix membranes(MMMs). The particles and MMMs were characterized by ultraviolet-visible diffuse reflectance spectroscopy(UV–vis DRS), N2adsorption–desorption isotherm, X-ray diffraction(XRD), Fourier transform infrared(FTIR) and scanning electron microscopy(SEM). Furthermore, the effects of filler content(0–20wt%) on pure and mixed gas experiments, feed pressure(2–20 bar) and operating temperature(35–75 oC)on CO2/CH4transport properties of Matrimid/Ag Y MMMs were considered. Characterization results confirmed an appropriate ion-exchange treatment of the zeolites. The SEM results confirmed the superior interfacial adhesion between polymer and zeolites, particularly in the case of Matrimid/Ag Y membranes.This is due to the proper silverous zeolite/Matrimid functional groups’ interactions. The gas permeation results showed that the CO2permeability increased about 123%, from 8.34 Barrer for pure Matrimid to18.62 Barrer for Matrimid/Ag Y(15 wt%). The CO2/CH4selectivity was improved about 66%, from 36.3 for Matrimid to 60.1 for Matrimid/Ag Y(15 wt%). The privileged gas separation performance of Matrimid/Ag Y(15 wt%) was the result of a combined effect of facilitated transport mechanism of Ag+ions as well as the intrinsic surface diffusion mechanism of Y-type zeolite. In order to survey the possibility of using the developed MMMs in industry, the CO2-induced plasticization effect and mixed gas experiment were accomplished. It was deduced that the fabricated MMMs could maintain the superior performance in actual operating conditions.

Global air-sea CO_(2) exchange fl ux since 1980s: results from CMIP6 Earth System Models

The ocean could profoundly modulate the ever-increasing atmospheric CO_(2) by air-sea CO_(2) exchange process,which is also able to cause signifi cant changes of physical and biogeochemical properties in return.In this study,we assessed the long-term average and spatial-temporal variability of global air-sea CO_(2) exchange fl ux(F CO_(2))since 1980s basing on the results of 18 Coupled Model Intercomparison Project Phase 6(CMIP6)Earth System Models(ESMs).Our fi ndings indicate that the CMIP6 ESMs simulated global CO_(2) sink in recent three decades ranges from 1.80 to 2.24 Pg C/a,which is coincidence with the results of cotemporaneous observations.What’s more,the CMIP6 ESMs consistently show that the global oceanic CO_(2) sink has gradually intensifi ed since 1980s as well as the observations.This study confi rms the simulated F CO_(2) could reach agreements with the observations in the aspect of primary climatological characteristics,however,the simulation skills of CIMP6 ESMs in diverse open-sea biomes are unevenness.None of the 18 CMIP6 ESMs could reproduce the observed F CO_(2) increasement in the central-eastern tropical Pacifi c and the midlatitude Southern Ocean.Defi ciencies of some CMIP6 ESMs in reproducing the atmospheric pressure systems of the Southern Hemisphere and the El Niño-Southern Oscillation(ENSO)mode of the tropical Pacifi c are probably the major causes.

Experimental Study on Performance of Supercritical CO_2 Heat Exchanger with Four Different Inner Tubes

The experiment was conducted to investigate the heat transfer performance of supercritical CO_2 in a casing heat exchanger by comparing their heat transfer,entropy production unit number,non-dimensional entropy production rate and field synergy factor.The results show that both heat transfer and entropy production unit number in four tubes decrease with water temperature increasing.Heat transfer and entropy production unit number in multiple tubes( i. e.,triple straight tube and double helix tube) is higher than their single counterparts; the non-dimensional entropy production rate increases with water temperature. Non-dimensional entropy production rate of triple straight tube and double helix tube is far below the single tube. Field synergy factor of double helix tube is much higher than that of the triple straight tube under the same condition. Further experiment was carried out in double helix tube,under various CO_2 pressure and inlet water temperature,the results are analyzed and reported in this paper.

Roles of Na^+/Ca^(2+) exchanger 1 in digestive system physiology and pathophysiology

The Na^+/Ca^(2+) exchanger(NCX) protein family is a part of the cation/Ca^(2+) exchanger superfamily and participates in the regulation of cellular Ca^(2+) homeostasis. NCX1, the most important subtype in the NCX family, is expressed widely in various organs and tissues in mammals and plays an especially important role in the physiological and pathological processes of nerves and the cardiovascular system. In the past few years, the function of NCX1 in the digestive system has received increasing attention; NCX1 not only participates in the healing process of gastric ulcer and gastric mucosal injury but also mediates the development of digestive cancer, acute pancreatitis, and intestinal absorption.This review aims to explore the roles of NCX1 in digestive system physiology and pathophysiology in order to guide clinical treatments.

Study on the Separation of Co^(2+) from Zn^(2+) , Cd^(2+) by Anion-exchange Chromatography

The separation of Co 2+ from Zn 2+ , Cd 2+ by anion exchange chromatography was discussed. The chromatographic column containing anion resin 201×7 which was saturated with a solution of ammonium chloride. The effects of the eluant acidity and eluant composition on the separation were investigated. The results indicate that this anion exchange chromatography is suitable to the separation of Co 2+ from Zn 2+ , Cd 2+ , and the condition of separation is simple and convenient. When the column is saturated with NH 4Cl solution (2.0 mol/L, pH=4.0), the separation can be completed effectively. Zn 2+ and Cd 2+ can also be separa ted when different eluants are used and the pure solution with high concentration of Zn 2+ , Cd 2+ respectively can be obtained ea sily.

In-situ transformation of Bi_2WO_6 to highly photoreactive Bi_2WO_6@Bi_2S_3 nanoplate via ion exchange

As a two dimensional(2D)visible‐light‐responsive semiconductor photocatalyst,the photoreactivity of Bi2WO6 is not high enough for practical application owing to its limited response to visible light and rapid recombination of photogenerated electron‐hole pairs.In this paper,2D core‐shell structured Bi2WO6@Bi2S3 nanoplates were prepared by calcination of a mixture of Bi2WO6(1.3 g)and a certain amount of Na2S·9H2O(0–3.0 g)at 350°C for 2 h.The reactivity of the resulting photocatalyst materials was evaluated by photocatalytic degradation of Brilliant Red X‐3B(X3B),an anionic dye,under visible light irradiation(?>420 nm).As the amount of Na2S·9H2O was increased from 0 to 1.5 g,the degradation rate constant of X3B sharply increased from 0.40×10?3 to 6.6×10?3 min?1.The enhanced photocatalytic activity of Bi2WO6@Bi2S3 was attributed to the photosensitization of Bi2S3,which greatly extended the light‐responsive range from the visible to the NIR,and the formation of a heterojunction,which retarded the recombination rate of photogenerated electron‐hole pairs.However,further increases in the amount of Na2S·9H2O(from 1.5 to 3.0 g)resulted in a decrease of the photocatalytic activity of the Bi2WO6@Bi2S3 nanoplates owing to the formation of a photo‐inactive NaBiS2 layer covering the Bi2WO6 surface.

Distributions and air-sea fluxes of CO_2 in the summer Bering Sea

The 3rd Chinese National Arctic Research Expedition （CHINARE-Arctic III） was carried out from July to September in 2008. The partial pressure of CO2 （pCO2） in the atmosphere and in surface seawater were determined in the Bering Sea during luly 11-27, 2008, and a large number of seawater samples were taken for total alkalinity （TA） and total dissolved inorganic carbon （DIC） analysis. The distributions of CO2 parameters in the Bering Sea and their controlling factors were discussed. The pCO2 values in surface seawater presented a drastic variation from 148 to 563 laatm （1 μatm = 1.013 25× 10-1Pa）. The lowest pCOz values were observed near the Bering Sea shelf break while the highest pCO2 existed at the western Bering Strait. The Bering Sea generally acts as a net sink for atmospheric CO2 in summer. The air-sea CO2 fluxes in the Bering Sea shelf, slope, and basin were estimated at -9.4, -16.3, and -5.1 mmol/（m2.d）, respectively. The annual uptake of CO2 was about 34 Tg C in the Bering Sea.

Interannual variations of the air-sea carbon dioxide exchange in the different regions of the Pacific Ocean

Interannual variations of the air-sea CO2 exchange from 1965 to 2000 in the Pacific Ocean are studied with a Pacific Ocean model. Two numerical experiments are performed, including the control run that is forced by climatological monthly mean physical data and the climate-change run that is forced by interannually varying monthly mean physical data. Climatological monthly winds are used in both runs to calculate the coefficient of air-sea CO2 exchange. The analysis through the differences between the two runs shows that in the tropical Pacific the variation of export production induced by interannual variations of the physical fields is negatively correlated with that of the air-sea CO2 flux, while there is no correlation or a weak positive correlation in the subtropical North and South Pacific. It indicates that the variation of the physical fields can modulate the variation of the air-sea CO2 flux in converse ways in the tropical Pacific by changing the direct transport and biochemical process. Under the interannually varying monthly mean forcing, the simulated EOF 1 of the air-sea CO2 flux is basically consistent with that of sea surface temperature （SST） in the tropical Pacific, but contrary in the two subtropical Pacific Ocean. The correlation coefficient between the regionally integrated air-sea CO2 flux and area-mean SST shows that when the air-sea CO2 flux lags SST by about 5 months, the positive coefficient in the three regions is largest, indicating that in the tropical Pacific or on the longer time scale in the three regions, physical processes control the fiux-SST relationship.

Enabling low-cost decentralized power reserves adopting carbon dioxide for green methane exchange in stabilized clathrate adsorbent

1.Challenges circular methane energy systems In recent decades,methane-based energy systems have rapidly gained traction across the globe because of the increasing availability of low-cost methane production capacity.However,fossil methane production and combustion lead to large greenhouse gas emissions,contributing to climate change[1].

A Brief Study on pH, Exchangeable Ca²⁺and Mg²⁺in Farmlands under Tobacco-Rice Rotation in Xuancheng City of South Anhui

pH, exchangeable Ca2+ and Mg2+ of soil can influence the yield and quality of flue-cured tobacco. Xuancheng city is the dominant tobacco-planting region in Anhui province since 2008. A general soil survey was conducted in Xuancheng city to understand the current situations of pH, exchangeable Ca2+ and Mg2+ of farmlands under tobacco-rice rotation and to decide whether continuous applying dolomite powders to abate soil acidification. In total 124 topsoil samples (0-20 cm) were collected from the typical farmlands and soil pH, exchangeable Ca2+ and Mg2+ were measured. The results showed that soil pH and Ca2+ and Mg2+ in Xuancheng city were generally in the suitable grades, pH ranged from 4.56 to 8.42 with an average of 5.87, exchangeable Ca2+ ranged from 1.01 cmol(1/2Ca2+) kg-1 to 100.55 cmol(1/2Ca2+) kg-1 with an average of 11.07 cmol(1/2Ca2+) kg-1, and exchangeable Mg2+ ranged from 0.14 cmol(1/2Mg2+) kg-1 to 2.86 cmol(1/2Mg2+) kg-1 with an average of 0.81 cmol(1/2Mg2+) kg-1, all spanned from the low grades to the high grades. To the whole Xuancheng city, 37.10%, 62.10% and 72.58% of the surveyed farmlands were in the low grades of pH, exchangeable Ca2+ and Mg2+, respectively, while 52.42%, 25.00% and 20.97% of the farmlands were in the suitable grades, respectively. pH had an extremely significantly positive Napierian logarithm correlation with exchangeable Ca2+ and an extremely significantly positive power correlation with exchangeable Mg2+. In total about 338.2 kg·hm-2 of Ca2+ and 202.4 kg·hm-2 of Mg2+ are annually input into the farmlands, while about 110.4 kg·hm-2 of Ca2+ and 7.4 kg·hm-2 of Mg2+ are annually moved out from the farmlands, exchangeable Ca2+ and Mg2+ were annually increased by 225.2 kg·hm-2 and 187.6 kg·hm-2 in the farmlands, respectively. It is necessary to monitor the farmlands dynamically in order to decide whether continuous applying dolomite powders which should be dependent upon the specific conditions of individual farmlands.

Low-cost and efficient visible-light-driven CaMg(CO_3)_2@Ag_2CO_3 microspheres fabricated via an ion exchange route

CaMg(CO3)2microspheres were prepared and used as hard templates to fabricate a series of CaMg(CO3)2@Ag2CO3composite microspheres via a fast and low‐cost ion exchange process.The effects of ion exchange time and temperature on the physicochemical properties and photocatalytic activities of the composite microspheres were studied through photocatalytic degradation of Acid Orange II under xenon lamp irradiation.The obtained samples were analyzed by X‐ray diffraction,scanning electron microscopy,Fourier transform infrared spectroscopy,UV‐vis diffuse reflectance spectroscopy,N2physical adsorption,and photocurrent tests.The CaMg(CO3)2@Ag2CO3sample with the highest activity was obtained with an ion exchange time of4h and temperature of40°C.The degradation rate of Acid Orange II by this sample reached83.3%after15min of light irradiation,and the sample also performed well in phenol degradation.The CaMg(CO3)2@Ag2CO3produced under these ion exchange conditions showed a well‐ordered hierarchical morphology with small particle sizes,which was beneficial to light absorption and the transfer of photoelectrons(e-)and holes(h+)to the catalyst surface.Moreover,the separation of photogenerated carriers over the composites was greatly improved relative to bare CaMg(CO3)2.Despite the very low content of Ag2CO3(2.56%),excellent photocatalytic performance was obtained over the CaMg(CO3)2@Ag2CO3microspheres.

The rotational anisotropies in the ferromagnetism/antiferromagnetism 1/ antiferromagnetism 2 exchange bias structures

The rotational anisotropies in the exchange bias structures of ferromagnetism/antiferromagnetism 1/antiferro- magnetism 2 are studied in this paper. Based on the model, in which the antiferromagnetism is treated with an Ising mean field theory and the rotational anisotropy is assumed to be related to the field created by the moment induced on the antiferromagnetic layer next to the ferromagnetic layer, we can explain why in experiments for ferromag- netism （FM）/antiferromagntism 1 （AFM1）/antiferromagnetism 2 （AFM2） systems the thickness-dependent rotational anisotropy value is non-monotonic, i.e. it reaches a minimum for this system at a specific thickness of the first anti- ferromagnetic layer and exhibits oscillatory behaviour. In addition, we find that the temperature-dependent rotational anisotropy value is in good agreement with the experimental result.

A New and Original Method to Produce Ca(OH)<SUB>2</SUB>Nanoparticles by Using an Anion Exchange Resin

Ca(OH)2 nanoparticles in hydro-alcoholic dispersion (nanolime) were successfully employed in Cultural Heritage conservation, thanks to the ability to overcome the limiting aspects of traditional lime treatments. Nanolime were currently produced by chemical precipitation process, at high temperature, with long times of synthesis, and after several purification steps to remove undesired secondary phases. In this paper, an innovative, simple and original method for nanolime production was described. The method was based on an ion exchange process between an anionic resin and a calcium chloride aqueous solution, operating at room temperature. A pure Ca(OH)2 nanoparticles suspension can be rapidly obtained after separating the resin from suspension, and any purification step was necessary. The exhausted resins can be regenerated and reused for a cyclic nanolime production. Structural and morphological features of the produced nanolime were preliminarily characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). Moreover, XRD measurements allowed estimating nanoparticles reactivity by following their carbonatation process in air, in relation to different water/alcohol ratios and medium or high relative humidity conditions. The produced Ca(OH)2 nanoparticles appeared hexagonally plated, with dimension less than 100 nm and, compared with those obtained by typical wet precipitation method, they proved to be more reactive.

Heat transfer enhancement of finned shell and tube heat exchanger using Fe_(2)O_(3)/water nanofluid

Heat transfer mechanisms and their thermal performances need to be comprehensively studied in order to optimize efficiency and minimize energy losses.Different nanoparticles in the base fluid are investigated to upgrade the thermal performance of heat exchangers.In this numerical study,a finned shell and tube heat exchanger has been designed and different volume concentrations of nanofluid were tested to determine the effect of utilizing nanofluid on heat transfer.Fe_(2)O_(3)/water nanofluids with volume concentration of 1%,1.5% and 2% were utilized as heat transfer fluid in the heat exchanger and the obtained results were compared with pure water.ANSYS Fluent software as a CFD method was employed in order to simulate the mentioned problem.Numerical simulation results indicated the successful utilization of nanofluid in the heat exchanger.Also,increasing the ratio of Fe_(2)O_(3) nanoparticles caused more increment in thermal energy without important pressure drop.Moreover,it was revealed that the highest heat transfer rate enhancement of 19.1% can be obtained by using nanofluid Fe_(2)O_(3)/water with volume fraction of 2%.

Analysis of Air Exchange System Influence on Thermal and Concentration Modes in the Local Working Area under Radiant Heating Conditions

One of the effective options for energy saving in terms of heat costs for the formation of routine thermal conditions of working areas of large-sized industrial premises is the replacement of traditional convective(water)heating systems with systems,the main part of which are gas infrared emitters.But the mass introduction of such systems based on emitters was held back until recently by the lack of scientific and technical foundations for ensuring not only the routine thermal conditions of local working areas,but also ensuring acceptable concentrations of carbon dioxide,which is formed during the operation of a gas emitter.Solving the latter problem by the method of experimental selection of heating and air exchange modes is practically impossible due to the multivariate nature of possible solutions to this problem.Therefore,the purpose of the work is to analyze the results of theoretical studies of the possibility of ensuring an acceptable level of carbon dioxide concentrations in local working areas during the operation of gas infrared emitters and an air exchange system.Numerical modeling of heat and mass transfer processes under such conditions was performed in a fairly wide range of the main significant factors:air flow rate in the air exchange system from 0.01 to 0.04 kg/s,the position of the air inlet and outlet channels relative to the radiator and the local workplace(height from 0.3 to 4.1 m).It was found that by varying the numerical values of these factors,it is possible to ensure carbon dioxide concentrations in the local working area within the permissible limits of up to 1400 ppm.

Recovery of V_2O_5 from Bayer liquor by ion exchange

A new technology was developed to recover V2O5 from Bayer spent liquor by ion exchange.The experimental results show that in the conditions of 105℃ and 0.20-0.25 mass ratios between CaO in lime and Al2O3 in spent liquor, the precipitation rate of vanadium in Bayer liquor is more than 85%.The vanadium-bearing precipitation is leached by NaHCO3 solution.The leaching rate of vanadium can reach 85% in the conditions of 95℃, 40 g·L-1 of NaHCO3 concentration, and ventilating of CO2.The 201 × 7 type of resin has good adsorption effect on vanadium in the leaching solution.The adsorption rate is more than 94% with the flow rate of 0.09 mL·min-1·g-1 of leaching solution and the temperature of 40-50℃.By using 3 mol·L-1 of NaOH to desorb the saturated resin after adsorption at 40-50℃, a solution with more than 5 g·L-1 of V2O5 can be obtained.After roasting ammonium metavanadate that precipitates from the desorption solution when NH4Cl is added at the temperature of 500-550℃ for 2 h, V2O5 with more than 99% of purity is obtained.

Using SiO₂Nanopowders in Anode Catalyst Layer to Improve the Performance of a Proton Exchange Membrane Fuel Cell at Low Humidity

In this study, the transfer method is employed to add hydrophilic SiO2 nanopowders to a Pt/C catalyst ink to form an anode catalyst layer on a proton exchange membrane (PEM). The SiO2-layered membrane electrode assembly improves the performance of the PEM under low- or zero-humidification conditions. When the PEM fuel cell (PEMFC) undergoes electrochemical reaction, the moisture content of the PEM exhibits a substantial influence on the transmission of protons. To ensure the moisture content remains high, an external humidifier is typically employed to humidify the majority of PEMFCs. However, self-humidifying PEMFCs could utilize the water produced by the fuel cell reaction, thereby eliminating the need for an external humidifier. In this study, various SiO2 loadings were added to an anode catalyst layer, and the cell temperature and gas humidification conditions were adjusted to determine the influence of the SiO2 loadings on the fuel cell performance. The results show that adding SiO2 is preferable to not adding SiO2 when the fuel cell temperature is 50&deg;C.

Involvement of mitochondrial Na+-Ca2+ exchange in intestinal pacemaking activity

AIM： Interstitial cells of Cajal （ICCs） are the pacemaker cells that generate slow waves in the gastrointestinal （GI） tract. We have aimed to investigate the involvement of mitochondrial Na^＋-Ca^2＋ exchange in intestinal pacemaking activity in cultured interstitial cells of Cajal. METHODS： Enzymatic digestions were used to dissociate ICCs from the small intestine of a mouse. The whole-cell patch-clamp configuration was used to record membrane currents （voltage clamp） and potentials （current clamp） from cultured ICCs. RESULTS： Clonazepam and CGP37157 inhibited the pacemaking activity of ICCs in a dose-dependent manner. Clonazepam from 20 to 60 μmol/L and CGP37157 from 10 to 30 μmol/L effectively inhibited Ca^2＋ efflux from mitochondria in pacemaking activity of ICCs. The ICsos of clonazepam and CGP37157 were 37.1 and 18.2 μmol/ L, respectively. The addition of 20 μmol/L NiCl2 to the internal solution caused a ＂wax and wane＂ phenomenon of pacemaking activity of ICCs. CONCLUSION： These results suggest that mitochondria Na^＋-Ca^2＋ exchange has an important role in intestina pacemaking activity.